1st Research/Review paper for the fulfillment of

the PhD Coursework Batch 2022

Removal of Organics in Wastewater by Adsolubilization

Anyone A. Author1a, Someone S. Author2b, Someone S. Author3bandSomeone S. Author4b*
a
Affiliation1, Address, City, Country, E-mail
b
Affiliation1, Address, City, Country, E-mail
c
Affiliation1, Address, City, Country, E-mail
d
Affiliation1, Address, City, Country, E-mail

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Abstract—Write brief abstract in 150 words. Write brief abstract
in 150 words.Write brief abstract in 150 words.Write brief
abstract in 150 words.Write brief abstract in 150 words.Write
brief abstract in 150 words.Write brief abstract in 150
words.Write brief abstract in 150 words.Write brief abstract in
150 words.Write brief abstract in 150 words.Write brief abstract
in 150 words.Write brief abstract in 150 words.Write brief
abstract in 150 words.Write brief abstract in 150 words.Write
brief abstract in 150 words.Write brief abstract in 150
words.Write brief abstract in 150 words.Write brief abstract in
150 words.Write brief abstract in 150 words.Write brief abstract
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abstract in 150 words.Write brief abstract in 150 words. Write
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Keywords— Adsolubilization, Dye, Surfactant modified silica
gel, Wastewater
I.Introduction
XXX is a well-known hazardous dye being used for various
purposes: a biological stain, a dermatological agent, a
veterinary medicine, an additive to poultry feed to inhibit
propagation of mold, intestinal parasites and fungus etc. It is
also extensively used in textile, dying and paper printing
industries. It is a mutagen and mitotic poison. It may cause
irritation in eye, skin and digestive track. Therefore, it is
necessary to remove this dye from contaminated water before
its discharge to environment. Various treatment technologies
that are available for the removal of it from wastewater include
adsorption [1], photodegradation [2], electrocoagulation [3],
advanced oxidation [4], biological process [5] etc.

* Corresponding author
Many of the above mentioned processes are not cost-
effective and hence are not suitable for being applied in
developing countries. Further dye recovery is not possible from
application of most of the above techniques. Very recently
removal of organic contaminants using surfactant modified
solid surface (e.g. metal oxide) has drawn much attention. The
surface of the metal oxides can be modified by surfactant to
form micelle like structures having potential to solubilize
organic molecules within the structures formed. These micelles
are called hemimicelles or admicelles and the phenomenon is
called Adsolubilization. For the last two decades this new
separation technology has been used for the removal of
different organic compounds [6-8]. Most of the studies
mentioned above have been conducted in only batch mode.
Reports regarding the engineering application of
adsolubilization for wastewater treatment in both batch and
continuous mode are only a few. Thus, the present study aims
towards the removal and recovery of XXX from wastewater by
quaternary ammonium based cationic surfactant (CS) (e.g.
YYYY) treated ZZZin both batch and continuous mode. The
effect of adsorbent dose, contact time, interfering substances,
operating conditions have been studied in details for the
treatment of highly concentrated dye bearing wastewater.
Fixed bed column study has been conducted and the results
were analysed using logit model and the field design
parameters have been calculated.
II. Materials and Methods
A. Reagents
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reagents used in the study.Write about the reagents used in the
study.Write about the reagents used in the study.Write about

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the reagents used in the study.Write about the reagents used in
the study.Write about the reagents used in the study.Write
about the reagents used in the study.Write about the reagents
used in the study.
B. Preparation of Sorbent
Write about the details of sorbent preparation method. Write
about the details of sorbent preparation method.
Write about the details of sorbent preparation method. Write
about the details of sorbent preparation method. Write about
the details of sorbent preparation method. Write about the
details of sorbent preparation method. Write about the details
of sorbent preparation method.
C. Analytical Method
Write about the analytical method. Write about the
analytical method. Write about the analytical method. Write
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.
Write about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.

about the analytical method.
method.
Write about the analytical
analytical method. Write about
about the analytical method.
method.
P e rc e nt re m ov a l of X X
Write about the analytical
method. Write about the
the analytical method. Write
Write about the analytical 120
Distilled water
100
Wastewater
80

D. Experimental Studies 60
40
Write about the experimental protocols in this section. Write
20
about the experimental protocols in this section.Write about the
0
experimental protocols in this section.Write about the 0 1 2 4 8 15 20 30 45 60 75
experimental protocols in this section.Write about the Contact time (min)

experimental protocols in this section.Write about the Fig. 1: Example of Figure1

experimental protocols in this section.Write about the
experimental protocols in this section.Write about the Table 1: Example of Table 1
experimental protocols in this section.Write about the Model Sample Equation of linear fit line R2
experimental protocols in this section.Write about the
First order Distilled water ln Ct =4.5144 - 0.0448 t 0.9644
experimental protocols in this section.
Write about the experimental protocols in this section.Write kinetic
model Wastewater ln Ct =4.6107 - 0.0658 t 0.9596
about the experimental protocols in this section.Write about the
experimental protocols in this section.Write about the Pseudo-first Distilled water ln (q1-qt) = 2.398 - 0.0522 t 0.9858
experimental protocols in this section.Write about the order kinetic
experimental protocols in this section.Write about the Wastewater ln (q1-qt) = 2.4005 - 0.0515 t 0.9834
model
experimental protocols in this section.Write about the
Second Distilled water 1/Ct + 0.006 = 0.0029 t 0.9324
experimental protocols in this section.Write about the
order kinetic
experimental protocols in this section.Write about the Wastewater 1/Ct + 0.0785 = 0.01169 t 0.8868
experimental protocols in this section.Write about the model
experimental protocols in this section.Write about the Pseudo-
Distilled water t/qt = 1.0735 + 0.0628 t 0.9901
experimental protocols in this section.Write about the second order
experimental protocols in this section.Write about the kinetic
experimental protocols in this section. model
Wastewater t/qt = 0.9226 + 0.0674 t 0.9900

III. Results and Discussion
A. Batch Study
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experimental results of batch study.Write about experimental
Write about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
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experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.
100
Percent removal of XX
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.

Distilled Water
80
Wastewater Table 2: Example of Table 2
60 Model Parameters Values

40 1/qe = 0.4369/Ce +
Equation
20 0.0426

Langmuir Maximum adsorption

0 23.47
0 1 2 4 6 8 10 12 isotherm capacity, qmax (mg/g)
SMSGW dose (g/L) model Constant related to energy
Fig. 2: Example of Figure 2 0.097
of sorption system, b

R2 0.9737
25 ln qe = 0.347 ln Ce
qe (mg/g)

Equation
20 +1.5956
Freundlich Freundlich constant related
15
isotherm to adsorption capacity, kf 4.931
10 Experimental
results model [(mg/g)(L/mg) ] 1/n

5
0 R
0 20 40 60
Ce (mg/l)
Fig. 3:Example of Figure 3
Write about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.
Write about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
about experimental results of batch study.Write about
experimental results of batch study.Write about experimental
results of batch study.Write about experimental results of batch
study.Write about experimental results of batch study.Write
Adsorption intensity, 1/n 0.347
2
0.9485
80 100
B. Batch Regeneration Study
Write about the observed results. Write about the observed
results. Write about the observed results. Write about the
observed results. Write about the observed results. Write about
the observed results. Write about the observed results. Write
about the observed results. Write about the observed results.
Write about the observed results. Write about the observed
results. Write about the observed results.
Write about the observed results. Write about the observed
results. Write about the observed results. Write about the
observed results. Write about the observed results. Write about
the observed results.
Write about the observed results. Write about the observed
results. Write about the observed results. Write about the
observed results. Write about the observed results. Write about
the observed results.
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results. Write about the observed results. Write about the
observed results. Write about the observed results. Write about
the observed results.
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observed results. Write about the observed results. Write about
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about the observed results. Write about the observed results. conclusion of your novel work in this section. Write the
Write about the observed results. Write about the observed conclusion of your novel work in this section. Write the
results. Write about the observed results. Write about the conclusion of your novel work in this section. Write the
observed results. Write about the observed results. conclusion of your novel work in this section. Write the
conclusion of your novel work in this section. Write the
C. Column Study conclusion of your novel work in this section. Write the
C.1. Behavior of adsorption column conclusion of your novel work in this section. Write the
Write your results. Write your results. Write your results. conclusion of your novel work in this section. Write the
Write your results. Write your results. Write your results. conclusion of your novel work in this section. Write the
Write your results. Write your results. Write your results. conclusion of your novel work in this section.
Write your results. Write your results. Write your results.
Write your results. Write your results. Write your results. References
Write your results. Write your results. Write your results. [1] A. Eisenberg, Guide to Technical Editing, Oxford University, New
Write your results. Write your results. York, 1992.
[2] H. Sun, S. Liu, S. Liu and S. Wang, “A comparative study of reduced
C.2. Evaluation of column design parameters graphene oxide modified TiO2, ZnO and Ta2O5 in visible light
photocatalytic/photochemical oxidation of methylene blue,” Applied
The fixed bed column was designed by LLL Model [6]. The Catalysis B: Environmental, vol. 146, pp. 162–168, March 2014.
linearized form of LLL equation can be written as: [3] M.S. Mahmoud, J.Y. Farah and T.E. Farrag, “Enhanced removal of

[ ]
Methylene Blue by electrocoagulation using iron electrodes,” Egyptian
C KN o x Journal of Petroleum, vol. 22, pp. 211-216, 2013.
ln =− + KC o t [4] C.-H. Weng and V. Huang, Application of Feo aggregate in ultrasound
C o−C V enhanced advanced Fenton process for decolorization of methylene
(1)
blue,” Journal of Industrial and Engineering Chemistry, vol. 28, pp.
153-160, August 2015.
Write your results. Write your results. Write your results. [5] S. Ledakowicz, M. Solecka and R.Zylla, “Biodegradation,
Write your results. Write your results. Write your results. decolourization and detoxification of textile wastewater enhanced by
advanced oxidation processes,” J. Biotech., vol. 89, pp. 175-184, 2001.
Write your results. Write your results. Write your results. [6] K. Esumi and S.Yamamoto, “Adsorption of Sodium dodecyl sulfate on
Write your results. Write your results. hydrotalcite and adsolubilization of 2-naphthol,” Col. And Sur. A:
Physicochem.l & Engg. Asp., vol. 137, pp. 385-388, 1998.

1.0
0.8
Exhaust point
C/Co

0.6
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Breakthrough
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template by substituting
0 2 4 6 8 10 12 14 16 18 20 his/her own text in each field
Time (h)
Fig. 4: Example of Figure 4
or by deleting all the text.
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IV. Conclusion
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the conclusion of your novel work in this section. Write the
conclusion of your novel work in this section. Write the