CLS - ENG 22 23 XI - Che - Target 6 - Level 1 - Chapter 12

Step-1
Chapter 12
Hydrogen
Solutions
SECTION - A
1. Answer (2)
Fact
2. Answer (4)
Due to its small size.
3. Answer (2)
Use Fajan’s rules
4. Answer (4)
CH4
5. Answer (3)
Tritium is radioactive.
6. Answer (2)
Oxidising and reducing agent respectively.
7. Answer (2)
BaO2 is peroxide.
8. Answer (3)
No oxygen should evolve from H2O2.
9. Answer (1)
Oxygen should evolve from H2O2.
10. Answer (1)
Both
SECTION - B
11. Answer (1)
Mg + H2O
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2 Hydrogen Solutions of Assignment (Step-1)
12. Answer (1)

Proton spin
13. Answer (2)
Boiling
14. Answer (3)
O2
15. Answer (4)
Open book (non-planar)
16. Answer (3)
Na2O2
17. Answer (2)
Fact.
18. Answer (3)
D2O
19. Answer (1)
Na2CO3 + Ca2+/Mg2+ o CaCO3/MgCO3 (Insoluble)
20. Answer (1)
Fact.
SECTION - C
21. Answer (1)
Perhydrol is 30% H2O2.
SECTION - D
22. TiH1.5 – Metallic hydride
B2H6 – Covalent hydride (electron-deficient)
CH4 – Covalent hydride (electron-precise)
23. Interstitial hydrides are the metallic hydrides which are formed by transition metals (d-block elements) of group
3, 4, 5 and f-block elements. Interstitial hydrides are the hydrides in which hydrogen is thought to occupy the
interstices in the metal lattice. All these hydrides are non-stoichiometric i.e., their composition is not fixed.
For example :
LaH2.87, YbH2.55, TiH1.5 – 1.8
24. Water is an electron rich hydride with two lone pair of electrons ( OH2) and that is why it can act as a Lewis
base.
25. Autoprotolysis is a reaction in which two same molecules react to give ions with proton transfer. In water, a
proton from one H2O molecule is transferred to another water molecule leaving behind OH– ion and forming a
H3O+ ion.
H2O(l) + H2O(l) H3O+(aq) + OH–(aq)
Solutions of Assignment (Step-1) Hydrogen 3
26. The two disadvantages of hard water are
(i) It is unsuitable for the laundry purpose as insoluble precipitates are formed called scum and no lather
is produced until all the calcium and magnesium ions are precipitated.
(ii) Hard water reduces the efficiency of the boilers as lot of deposition of salts in the form of scales take
place.
27. In winters, ice which is the crystalline form of water being less denser forms on the surface of lakes, which
in turn provides thermal insulation so as to ensure the survival of the aquatic life. In this way it is of great
ecological significance.
28. (a) P4O10(s) + 6H2O(l) o 4H3PO4(aq)
(b) SiCl4(l) + 2H2O(l) o SiO2(s) + 4HCl(aq)
(c) N3–(s) + 3H2O(l) o NH3(g) + 3OH–(aq)
29. Hard water contains soluble calcium and magnesium ions (Ca2+, Mg2+). So, when these ions react with soap
(e.g., sodium stearate), they form corresponding calcium and magnesium salt which precipitate out (scum).
So, until whole of the Ca2+ and Mg2+ ions are precipitated, lather is not formed. Therefore, lot of soap is first
wasted to precipitate out the ions.
2C17H35 COONa  Ca2 

 (C17H35 COO)2 Ca  2Na
Sodium stearate Calcium stearate
2C17H35 COONa  Mg2 

 (C17H35 COO)2 Mg  2Na
Sodium stearate Magnesium stearate
30. Ion-exchange method of softening the hard water works on the principle of exchanging the ions responsible
for the hardness of water with the less damaging ions present in some compounds.
31. 20 ml of 30 volume H2O2 liberate = 20 × 30 = 600 ml of O2 at STP
2H2O2 
 2H2O  O2
68 g 22700 mL at STP
Amount of H2O2 required to liberate 22700 mL of O2 = 68 g
68
Amount of H2O2 required to liberate 1 mL of O2 = g
22700
68  600
Amount of H2O2 required to liberate 600 mL of O2 = g = 1.79 g
22700
32. Lead oxide (PbO) contained in old oil paintings gets converted into lead sulphide (PbS) which is black in colour
in the presence of H2S gas present in the atmosphere. So, H2O2 is used to restore the original whiteness by
keeping the tarnished oil paintings in hydrogen peroxide solution for sometime which results in the oxidation
of lead sulphide to lead sulphate.
PbS  4H2O2 
 PbSO4  4H2 O
(Black) (White)

Step-2
Chapter 12
Hydrogen
Solutions
Hydrogen
1. Answer (2)
As the mass of isotope increases bond strength increases.
2. Answer (2)
1
Bond strength 
bond length
3. Answer (2)
Deuterium or heavy hydrogen exists mostly in the form of HD.
4. Answer (1)
Zn and Sn react with NaOH and produce hydrogen.
Zn 2NaOH o Na2ZnO2 + H2
5. Answer (4)
Water gas is 1 : 1 mixture of CO and H2. As this mixture is used for the synthesis of methanol and a number of
hydrocarbons, it is also known as synthesis gas.
6. Answer (4)
Nascent hydrogen is more reactive than molecular hydrogen and can be produced in situ.
7. Answer (2)
Ortho and Para hydrogen have different nuclear spins.
8. Answer (2)
–H
H H H (Conjugate base of H2)
Hydride ion
9. Answer (2)
Na H + H — OH NaOH + H2
So, the solution would be basic.
10. Answer (2)
AlH3 is a Lewis acid.
H– is a Lewis base in I.
In II — H– accept H+ so Bronsted base.
11. Answer (2)
The elements of 7, 8 and 9 group do not form hydrides. This is actually known as HYDRIDE GAP.
12. Answer (4)
Metallic hydrides are interstitial and non-stoichiometric and poor conductor of electricity.
13. Answer (4)
LiH is ionic hydride, while MgH2 and CuH are intermediate hydrides.
14. Answer (4)
Transition elements form interstitial hydride.
 Water 
15. Answer (3)
Boiling point of water is exceptionally high due to hydrogen bonding.
16. Answer (4)
At atmospheric pressure ice crystallises in the hexagonal form, but at very low temperatures it condenses to
cubic form.
17. Answer (4)
O O
H H H H
O
H H
O
O
H H H
H
18. Answer (4)
19. Answer (3)
This is the condition of neutrality.
20. Answer (3)

 
(1) H2O
H  OH
(2) 6CO2  6H2O  C6H12O6  6O2
Hydrogen peroxide and Heavy water 

21. Answer (2)
2-ethyl anthraquinol produces H2O2 on oxidation.
22. Answer (1)
PbO2 is not a peroxide. So, it does not produce H2O2.
23. Answer (2)
Volume strength
M
11.2
Volume strength = 3.57 × 11.2 = 40 volume
24. Answer (1)
10 volumes of H2O2 means, 10 ml of oxygen is produced by the decomposition of 1 ml of H2O2 at STP.
25. Answer (4)
As both ‘O’ atoms are in sp3.
26. Answer (4)
H2O2 has open book like structure (Non-planar) and it is stored in wax lined glass vessel in dark.
27. Answer (4)
10  0.2 1
Normality of diluted solution = = N
20 10
1
? Normality of original solution =  10 = 1 N
10
? Volume strength = Normality × 5.6
= 5.6 V
28. Answer (3)

H
Cr2O7–2  H2O2  CrO5
29. Answer (3)
PbS + 4H2O2 o PbSO4 + 4H2O
30. Answer (3)
H2O2 acting as oxidizing agent.
In acidic medium
2K4[Fe(CN)6] + H2O2 + H2SO4 o 2K3[Fe(CN)6] + K2SO4 + H2O
H2O2 acting as reducing agent when it reacts with K3[Fe(CN)6].
In Basic medium
2K3[Fe(CN)6] + 2KOH + H2O2 o 2K4[Fe(CN)6] + 2H2O + O2
31. Answer (1)
oxidising
2H2O18 18
2  2H2 O  O2
agent
32. Answer (2)

It is deuterium oxide.
33. Answer (3)
N2  3D2  2ND3

34. Answer (4)
As it slows-down the neutron.
35. Answer (4)
Al, Zn, Pb, Sn liberate H2 on reaction with alkali.
36. Answer (5)
6 mg of MgSO4 present in 103 g of water.
106 g water will contain = 6000 mg of MgSO4 = 6 g of MgSO4
120 g of MgSO4 { 100 g of CaCO3
100
So, 6 g of MgSO4 =  6  5 g of CaCO3
120
i.e., Hardness = 5 ppm
37. Answer (1)
According to the law of equivalence,
X 2X
 2  NKMnO 
100  34 4 1000
1
NKMnO  N
4 3.4
38. Answer (11.2)
1 molar solution consists 34 g H2O2 per litre.
39. Answer (18.2)
10
Molarity = = 0.892
11.2
0.892  600  34
Mass in g = = 18.2 g
1000
40. Answer (2)
2KMnO4  3H2SO4  5H2O2  K 2SO4  2MnSO4  8H2O  5O2

2 mole 5 mole
Previous Years Questions

41. Answer (4)
Hydrogen has three isotopes :
Protium 1
1H
Deuterium 2
1H
Tritium 3
1H
Their natural abundance is in order H > D > T.

42. Answer (2)
Prescribed level of Mn is 0.5 ppm. So water sample containing Mn = 5ppm is water unsuitable for drinking.
43. Answer (4)
Bicarbonates cause temporary hardness. Chlorides and sulphates cause permanent hardness.
44. Answer (4)

There are three isotopes of H out of which only tritium is radioactive.
45. Answer (1)
SiH4 – Electron precise hydride
GaH3 – Electron deficient hydride
B2H6 – Electron deficient hydride
AlH3 – Electron deficient hydride
46. Answer (2)
10–3 M CaSO4 # 10–3 M CaCO3
10–3 M CaCO3 means 10–3 moles of CaCO3 are present in 1 L, i.e., 100 mg of CaCO3 is present in 1 L
solution.
Hardness of water = Number of milligram of CaCO3 per litre of water.
? Hardness of water = 100 ppm
47. Answer (1)
Volume strength | 11.2 × M | 11.2
48. Answer (3)
Moles of Ca(HCO3)2 = 0.005
Moles of Mg(HCO3)2 = 0.005
(0.005  0.005)  100

Hardness in terms of CaCO3 pm =  106 = 104 ppm
100
49. Answer (3)
11.2 V of H2O2
1
H2O2  H2O  O2
2
11.2 L of O2 at STP = 0.5 mol
It means 1 L of given H2O2 solution consist 1 mole of H2O2 (i.e., 34 g)
34
strength = × 100 = 3.4%
1000
50. Answer (2)
When steam is passed over red hot coke, an equimolar mixture of CO and H2 is obtained
H2O(g) + C o CO + H2
Steam Red hot
The gaseous mixture thus obtained is called water gas or syn gas.
51. Answer (2)
Temporary hardness is caused by bicarbonates of calcium and magnesium
Boiling
Mg(HCO3 )2 (aq)   Mg(OH)2   2CO2 
( X) (Y)
52. Answer (3)
Nowadays hard water is softened by using synthetic resins method. This method is more efficient than zeolite
process as it can exchange both cations as well as anions.
53. Answer (3)
 1
H 2O 2   H 2O  O2
2
KClO3, Pb(NO3)2, NaNO3 on heating will release O2 gas.
2NaBO 2  2H 2O 2  6H 2O  Na 2  OH 2 B  O  O  2 B  OH 2  .6H 2O

Sodium Sodium
metaborate Peroxoborate
54. Answer (3)

Isotopes of hydrogen and the number of neutrons present in them are
1 2 3
Number of neutrons 1H 1H (D) 1H (T)
0 1 2
(x) (y) (z)
Total number of neutrons in three isotopes of hydrogen = 0 + 1 + 2 = 3

55. Answer (1)
Distilled water is supposed to have no impurity and no ions, that’s why it is least conducting.
56. Answer (1)
Volume strength = 5.6
V.S = 11.2 × Molarity
V.S 5.6
Molarity (M)    0.5
11.2 11.2
0.5 M o 0.5 mole in 1 L
0.5  34 17  100
Mass percentage   100   1.7
1000  d 1000  1
57. Answer (4)
H
O Open book like structure
|
O  Non-planar
H
 Almost colourless
58. Answer (3)

Clark’s method is used to remove temporary hardness from water
59. Answer (2)
To obtain H2 of high purity (> 99.95 %) electrolysis of Ba(OH)2 solution is done using Ni electrodes
60. Answer (1)

Synthetic resin method is most suitable for preparing deionize water.
Synthetic resins method: Nowadays hard water is softened by using synthetic cation exchangers. This method
is more efficient than zeolite process. Cation exchange resins contain large organic molecule with - SO3H group
and are water insoluble. Ion exchange resin (RSO3H) is changed to RNa by treating it with NaCl. The resin
exchanges Na+ ions with Ca2+ and Mg2+ ions present in hard water to make the water soft. Here R is resin anion.
2RNa(s) + M2+(aq)  R2M(s) + 2Na+(aq)
The resin can be regenerated by adding aqueous NaCl solution.
Pure de-mineralised (de-ionized) water free from all soluble mineral salts is obtained by passing water successively
through a cation exchange (in the H+ form) and an anion - exchange (in the OH– form) resins:

2RH(s)  M2 (aq) 
MR 2 (s)  2H (aq)
In this cation exchange process, H+ exchanges for Na+, Ca2+, Mg2+ and other cations present in water. This
process results in proton release and thus makes the water acidic.
61. Answer (2)
Deuterium resembles hydrogen in properties but reacts slower than hydrogen due to its higher bond dissociation
energy.
62. Answer (4)
Na2O2 gives H2O2 readily. (This is Merck’s method of preparation of H2O2)
SnO2, PbO2 are oxides and can’t give peroxide on hydrolysis.
63. Answer (1)
x Heavy water (D2O) is used for the study of reaction mechanism.
x The rate of reaction for the cleavage of O-H bond should be faster than that of O–D bond because O–H bond
is weaker than O–D bond.
64. Answer (1)
x The process of producing syn - gas is called ‘coal gasification’ — statement 1 is true.
x Composition of syn - gas is CO : H2 as 1 : 1.
65. Answer (3)
The H–H bond dissociation enthalpy is the highest for a single bond between two atoms of any element.
It is because of this factor that the dissociation of dihydrogen into its atoms is only ~0.081% around 2000 K.
The atomic hydrogen is produced at a high temperature in an electric arc or under ultraviolet radiations.
Zn + 2HCl  ZnCl2 + H2
Zn + 2NaOH  Na2 ZnO2  H2
66. Answer (3)
I2  H 2 O 2  2O H   2I  2H 2 O  O 2
67. Answer (3)
Heavy water (D2O) is obtained as a by-product in fertilizer industry. It is used as a moderator in nuclear reactor
and for the study of reaction mechanism. Its dielectric constant is lower than that of H2O.
68. Answer (1)
Cation exchange resins contain large organic molecule with –SO3H group.
In cation exchange process H+ exchanges for Na+, Ca2+, Mg2+ and other cations present in water.
While anion exchange resins contain –NH2 in form of –NH3+ OH– where OH– exchanges for anions like Cl–,
HCO3–, SO42–, etc.
69. Answer (2)
x H2O2 is an important chemical used in pollution control treatment of domestic and industrial effluents.
x It has both oxidising and reducing properties.
x It has open-book like structure and both hydroxyl groups lie in different planes.
x It is miscible in water.
70. Answer (3)
Oxidising action in basic medium
2Fe2+ + H2O2 o 2Fe3+ + 2OH–
Reducing action in basic medium
I2 + H2O2 + 2OH– o 2I– + 2H2O + O2
Advantage of hydrogen economy is that energy is transmitted in the form of dihydrogen and not as electric
power.
71. Answer (2)
Possible reactions in basic medium are
Mn2+ o Mn4+
I2 o I–
PbS o PbSO4 is possible in acidic medium
72. Answer (4)
A : During the boiling of water having temporary hardness Mg(OH)2 is formed.
Given Assertion is false.
R : Mg(OH)2 has greater solubility product than that of MgCO3.
73. Answer (1)
H H
95.0 pm 98.8 pm
147.5 pm 111.5° 145.8 pm 90.2°
94.8° 101.9°
H H
(a) Gas phase (b) Solid phase
(a) H2O2 structure in gas phase, dihedral angle is 111.5°.

(b) H2O2 structure in solid phase at 110 K, dihedral angle is 90.2°.
Assertion is wrong.
Reason is true.
74. Answer (3)
The single largest industrial application of dihydrogen is in the synthesis of ammonia which is mainly used in
the manufacture of fertiliser.
75. Answer (2)
Cr has tendency to form hydride easily.
Elements of group – 7 and 8 do not form hydrides.
76. Answer (2)

Radioactive isotope of hydrogen is Tritium
Tritium o 1 proton
1 electron
2 neutron
77. Answer (1)
Enthalpy of bond dissociation (kJ mol–1) of hydrogen = 435.88
Enthalpy of bond dissociation (kJ mol–1) of deuterium = 443.35
EH = ED – 7.47
78. Answer (3)
Only Tritium is the radioactive isotope of Hydrogen which emits low energy E– particle with t1/2 12.33 years.
79. Answer (3)
Both A and R are true and R is the correct explanation of A.
Hydrogen is the lightest element. Because it is lighter than air, and so it can easily escape the earth’s gravity.
80. Answer (3)
–1 + –
HOCl + H2O2 H3O + CI + O°2
oxidation
–1 –
2I + 2H2O + O°2
–
I 2 + H2O 2 + 2OH
oxidation
So, H2O2 is acting as reducing agent in both reactions.
81. Answer (1)
1 1 0 2
2I–  H2O2  2H  I2  2H2O
I is oxidised from –1 to 0 oxidation state.

82. Answer (3)
H2O + CO2 o H2CO3
All other will produce CO on reaction with water.
1270 K
CnH2n 2  nH2O 
Ni
 nCO  (2n  1)H2
1270 K
CH4 (g)  H2O(g) 
Ni
 CO(g)  3H2 (g)
1270 K
C(s)  H2O(g)   CO(g)  H2 (g)
83. Answer (2)

Calgon is sodium hexametaphosphate, a polymeric compound also called as Graham’s salt.
Silicon is the 2nd most abundant element which is absent in calgon.
84. Answer (2)
Out of isotopes of hydrogen, only tritium is radioactive and emits low energy E– particles.
85. Answer (4)
x Viscosity of D2O is greater than H2O.
x B.P. of D2O is greater than H2O.
86. Answer (1)
Anode :
2H2SO4 
 H2S2O8 + 2H+ + 2e–
2H2O 
 O2 + 4H+ + 4e–
Cathode :
1
e– + H+ 
 H2
2
Main product of electrolysis of conc. H2SO4 is HO3SOOSO3H (H2S2O8)
87. Answer (100.00)
10 3 M MgSO 4  10 3 M CaCO 3
10 3 M CaCO 3  10 3  100 g CaCO 3 in 1 L water

? 10–1 × 103 g CaCO3 in 103 L or 106 g (using density 1 g/mL) water.
? Degree of Hardness = 100 ppm
88. Answer (10)
wt. of O 2
ppm of O 2   10 6
wt. of H 2O
10.3 mg
=  10 6
1.03  10 6 mg
= 10 ppm
89. Answer (100)
Molarity of H2O2 solution = 8.9 M
Volume strength of H2O2 solution = 8.9 × 11.2
100 V
90. Answer (1)
The number of hydrogen bonded water molecule associated with stoichiometry in CuSO45H2O is 1.

Step-3
Chapter 12
Hydrogen
Solutions
SECTION - A
Objective Type Questions (One option is correct)
1. Answer (3)
Order of B.P. – T2 > D2 > H2
2. Answer (2)
Syn gas or water gas is a mixture of CO and H2 which is formed by
1270 K
CH4 (g)  H2O(g) 
Ni
 CO(g)  3H2 (g)
3. Answer (4)
CO + H2 is called as syn gas or water gas.
4. Answer (4)
The reaction of H2 with F2 occurs even in the dark whereas its reaction with I2 requires a catalyst.
5. Answer (4)
Density of alkali metal hydride is greater than the parent atom.
6. Answer (1)
Metallic hydrides are not as efficient as their parent metals in conduction of heat and electricity.
7. Answer (4)
Bicarbonates of calcium, magnesium are responsible for temporary hardness.
8. Answer (1)
Mg HCO3 2 

 Mg  OH2  CO2
Mg HCO3 2  2Ca  OH2 


 2CaCO3  Mg  OH2  2H2O
9. Answer (3)
Sodium hexametaphosphate is called calgon.
10. Answer (3)
Cationic exchange replaces cations with H+ so pH decreases while anionic exchange replaces anions with
OH– so pH increases.
11. Answer (1)
CH4 + 2O2 o CO2 + 2H2O
7
C2H6 + O o 2CO2 + 3H2O
2 2
Mole of O2 required = 2 moles for methane + 7 moles of ethane = 9 moles

2H2O2 o 2H2O + O2
Moles of H2O2 required = 18 moles
n 18
M= 0.5 =
v V
V = 36 litre
12. Answer (4)
100% Pure H2O2 cannot be prepared.
13. Answer (3)
Volume strength of H2O2 solution = 28 V
5.6 × N = 28
N=5
14. Answer (4)
Viscosity of D2O is higher than that of H2O
D2O – 1.107 centipoise
H2O – 1.000 centipoise
15. Answer (3)
D2O is less acidic than H2O.
16. Answer (4)
Cylinder of compressed dihydrogen weighs about 30 times as much as a tank of petrol containing the same
amount of energy.
SECTION - B
Objective Type Questions (One or more than one option(s) is/are correct)
1. Answer (3)
n
 1.5
p
2. Answer (1, 2, 3, 4)
All the four mentioned option give the hydrogen gas a product.
3. Answer (1, 2, 3, 4)
Fact.
4. Answer (2, 3)
On increasing ortho concentration equilibrium will shift towards right. Decreasing temp. will also increase the
concentration of parahydrogen and hence equilibrium will shift in forward direction.
5. Answer (1, 4)
Saline hydride or ionic hydrides are CaH2 and SrH2.
6. Answer (1, 3)
CH4 and HCl are covalent hydride.
7. Answer (1, 2)
BH3 and BeH2 exist in polymeric form.
H H H
Be Be Be Be
H H H
(BeH2)n
H H H
B B
H H H
(BH3)2
8. Answer (2, 4)
VH and TiH3 are metallic hydride.
9. Answer (1, 2, 3)
7, 8, 9 group do not form hydride.
10. Answer (2, 3, 4)
Hardness of water is due to CaSO4, MgCl2 and MgSO4.
11. Answer (3, 4)
Ca(OH)2 form carbonate of Ca & Mg.
12. Answer (1, 2, 3)
Na2[Na4(PO3)6] o in Calgon method
Ca(OH)2 o Clark’s method
Na2CO3 also used to convert soluble salt of Ca & Mg to insoluble bicarbonate.
13. Answer (2, 3)
Density and viscosity of H2O2 is higher than water.
14. Answer (3)
H2O2 act as oxidising agent for PbS.
15. Answer (1, 2, 3, 4)
H2O2 acts as oxidising agent, reducing agent, bleaching agent and acid.
SECTION - C
Linked Comprehension Type Questions
Comprehension-I
1. Answer (1)
At. no. is same for all.
2. Answer (3)
Bond-strength and area overlapping.
3. Answer (1)
Comprehension-II
1. Answer (2)
Bleaching action of H2O2 is due to its ability to oxidize.
2. Answer (4)
Oxygen evolved = 30 × 1000 = 3 × 104 mol = 30 litre
3. Answer (3)
Pure H2O2 is a weak acid.
Comprehension-III
1. Answer (4)
Al4C3 + D2O o CD4 + Al(OD)3
2. Answer (1)
N2O5 + D2O o DNO3
3. Answer (4)
Heavy water is weaker acid than normal water.
Kw of D2O < Kw of H2O.
SECTION - D
Matrix-Match Type Questions
1. Answer A(t); B(q, r); C(p); D(s)
Self explanatory.
2. Answer A(r, s, t); B(p, s, t); C(p, s, t); D(q, s)
Ca(HCO3)2 + Na2CO3 o CaCO3 p + 2NaHCO3-
CaSO4 + Na2CO3 o CaCO3 p + Na2SO4
(NaPO3)6 is calgon.
3. Answer A(p, r, s); B(p, r, s); C(p); D(p, r, s)

(A) sp3 hybridisation is present in H2O, H2O2, B2H6 and NH3. H2O, H2O2 and NH3 can form hydrogen bonding.
H2O, H2O2 and NH3 also have lone pair in their structure.
4. Answer A(p, q, s, t); B(p, s, t); C(p, r, s, t); D(p, s, t)
Structures of H2O2 are same but with different bond lengths and bond angles. All are like half open book structure.
H2O is bent molecule.
SECTION - E
Assertion-Reason Type Questions
1. Answer (4)
Zn + 2NaOH o Na2ZnO2 + H2
Zn(OH)2 is amphoteric in nature.
2. Answer (3)
2Al + 2NaOH o 2NaAlO2 + H2n
NaAlO2 is water soluble.
3. Answer (1)
Statement-2 explains statement-1.
4. Answer (3)
Hydrolysis
HO3 S— O — O — SO3H   H2O2  2HSO4  2H
1mole 1mole
5. Answer (2)
O—O bond in O2F2 is shorter than that of H2O2. H2O2 is a polar covalent molecule.
6. Answer (1)
H SO
KMnO4  H2O2 
2 4
 MnSO4  H2O  O2
SECTION - F
Integer Answer Type Questions
1. Answer (3)
Solubility of NaCl is more in H2O due to high dielectric constant. pH value of H2O decreases by increasing
temperature.
2. Answer (4)
Each molecules is surrounded by 4 water.
3. Answer (2)
x
x=4 =2
2
4. Answer (4)
Be2C + 4H2O o 2Be(OH)2 + CH4

CLS - ENG 22 23 XI - Che - Target 6 - Level 1 - Chapter 12

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CLS - ENG 22 23 XI - Che - Target 6 - Level 1 - Chapter 12

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Step-1

12. Answer (1)

H2O(l) + H2O(l) H3O+(aq) + OH–(aq)

2C17H35 COONa  Ca2 

2C17H35 COONa  Mg2 

Amount of H2O2 required to liberate 22700 mL of O2 = 68 g

As the mass of isotope increases bond strength increases.

(2) 6CO2  6H2O  C6H12O6  6O2

Hydrogen peroxide and Heavy water 

23. Answer (2)

32. Answer (2)

N2  3D2  2ND3

As it slows-down the neutron.

2KMnO4  3H2SO4  5H2O2  K 2SO4  2MnSO4  8H2O  5O2

Previous Years Questions

Their natural abundance is in order H > D > T.

44. Answer (4)

(0.005  0.005)  100

KClO3, Pb(NO3)2, NaNO3 on heating will release O2 gas.

2NaBO 2  2H 2O 2  6H 2O  Na 2  OH 2 B  O  O  2 B  OH 2  .6H 2O

54. Answer (3)

Total number of neutrons in three isotopes of hydrogen = 0 + 1 + 2 = 3

0.5 M o 0.5 mole in 1 L

57. Answer (4)

58. Answer (3)

60. Answer (1)

(a) Gas phase (b) Solid phase

(a) H2O2 structure in gas phase, dihedral angle is 111.5°.

76. Answer (2)

I is oxidised from –1 to 0 oxidation state.

83. Answer (2)

10 3 M CaCO 3  10 3  100 g CaCO 3 in 1 L water

Order of B.P. – T2 > D2 > H2

Syn gas or water gas is a mixture of CO and H2 which is formed by

CO + H2 is called as syn gas or water gas.

Density of alkali metal hydride is greater than the parent atom.

Bicarbonates of calcium, magnesium are responsible for temporary hardness.

Mg HCO3 2  2Ca  OH2 

Sodium hexametaphosphate is called calgon.

Mole of O2 required = 2 moles for methane + 7 moles of ethane = 9 moles

At. no. is same for all.

Bond-strength and area overlapping.

Bleaching action of H2O2 is due to its ability to oxidize.

Oxygen evolved = 30 × 1000 = 3 × 104 mol = 30 litre

Pure H2O2 is a weak acid.

Al4C3 + D2O o CD4 + Al(OD)3

N2O5 + D2O o DNO3

Heavy water is weaker acid than normal water.

Kw of D2O < Kw of H2O.

1. Answer A(t); B(q, r); C(p); D(s)

2. Answer A(r, s, t); B(p, s, t); C(p, s, t); D(q, s)

Ca(HCO3)2 + Na2CO3 o CaCO3 p + 2NaHCO3-

CaSO4 + Na2CO3 o CaCO3 p + Na2SO4

3. Answer A(p, r, s); B(p, r, s); C(p); D(p, r, s)

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