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Hydrogen
Solutions
SECTION - A
Objective Type Questions (One option is correct)
1. Water gas is a mixture of
(1) CO and H2O (2) O2 and CO (3) CO and N2 (4) CO and H2
Sol. Answer (4)
Water gas is 1 : 1 mixture of CO and H2. As this mixture is used for the synthesis of methanol and a number of
hydrocarbons, it is also known as synthesis gas.
2. An orange coloured solution of K2Cr2O7 acidified with H2SO4 and treated with a substance X gives a blue
coloured solution of CrO5. The substance X is
(1) H2O (2) dil. HCl (3) H2O2 (4) conc. HCl
Sol. Answer (3)
H
Cr2O7–2 H2O2 CrO5
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2 Hydrogen Solution of Assignment (Set-2)
The elements of 7, 8 and 9 group do not form hydrides. This is actually known as HYDRIDE GAP.
Nascent hydrogen is more reactive than molecular hydrogen and can be produced in situ.
8. Which are the compounds, which can be oxidised and reduced by H2O2 in acidic and basic medium respectively?
In acidic medium
In Basic medium
Zn 2NaOH Na2ZnO2 + H2
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Solution of Assignment (Set-2) Hydrogen 3
10. Select the incorrect statement
(1) Ortho and para hydrogen are different due to difference in their nuclear spins
(2) Ortho and para hydrogen are different due to difference in their electron spins
(3) Para hydrogen has a lower internal energy than that of ortho hydrogen
Na H + H — OH NaOH + H2
(1) Are also called interstitial hydrides (2) Are non-stoichiometric, being deficient in hydrogen
(3) Pt and Pd hydrides are the example of it (4) Have all properties given above
Metallic hydrides are interstitial and non-stoichiometric and poor conductor of electricity.
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4 Hydrogen Solution of Assignment (Set-2)
Volume strength
M
11.2
2 2H2 O O2
oxidising
2H2O18 18
agent
17. H2O2 can be obtained when following reacts with H2SO4 except with
(1) PbO2 (2) BaO2 (3) Na2O2 (4) SrO2
Sol. Answer (1)
PbO2 is not a peroxide so, it does not produce H2O2.
H– is a Lewis base in I.
(3) D2O with heavy metal impurities (4) H2O with CaCO3
It is deuterium oxide.
(1) Two dipole moments are opposite but unequal (2) Two dipole moments are opposite and equal
(3) Two dipole moments are equal but not at 180° (4) Two dipole moments are equal but non-planar
(1) pH = 7 (2) Presence of salts (3) [H+] = [OH–] (4) Amphoteric nature
SECTION - B
Objective Type Questions (More than one options are correct)
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6 Hydrogen Solution of Assignment (Set-2)
H H H
Be Be Be Be
H H H
(BeH2)n
H H H
B B
H H Hs
(BH3)2
7. H2O2 is
(1) Lighter than water (2) Denser than water
(3) More viscous than water (4) Less viscous than water
Sol. Answer (2, 3)
Density and viscosity of H2O2 is higher than water.
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Solution of Assignment (Set-2) Hydrogen 7
(1) Stearic acid (2) Oxalic acid (3) Palmitic acid (4) Oleic acid
Stearic acid, palmitic acid and oleic acids are long chain fatty acid and hence their sodiumsalts can participate
in colloidal formation.
(1) The two nuclei have same spin (2) The two nuclei have opposite spin
(3) The two electrons have same spin (4) The two electrons have opposite spin
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8 Hydrogen Solution of Assignment (Set-2)
On increasing ortho concentration equilibrium will shift towards right. Decreasing temp. will also increase the
concentration of parahydrogen and hence equilibrium will shift in forward direction.
Hydrogen gas can be prepared by Lane’s process, Bosch’s process, electrolysis of acidulated water and Kolbes
electrolysis.
(1) Oxidising agent (2) Reducing agent (3) Bleaching agent (4) Acid
H2O2 acts as oxidising agent, reducing agent, bleaching agent and acid.
1 2 3
(1) 1H (2) 1H (3) 1H (4) He
n
1.5
p
SECTION - C
Linked Comprehension Type Questions
Comprehension-I
Hydrogen peroxide is a hydride of oxygen. It can be obtained by sodium peroxide or barium peroxide in laboratory.
Pure hydrogen peroxide is a colourless, syrupy liquid with bitter taste and odour like that of nitric acid. It is highly
soluble in water, alcohol and ether. It is an unstable liquid and readily decomposes to water and oxygen. It has
ability of both oxidising and reducing nature. It is used for restoring colour of oil painting. H2O2 on treatment with
acidified solution of titanium salt, orange colour is produced due to formation of pertitanic acid. Its strength is
measured as volume strength or percentage weight/volume strength.
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Solution of Assignment (Set-2) Hydrogen 9
2. A 30 volume solution of hydrogen peroxide means that 1 litre of the solution gives
= 3 × 104 mol
= 30 litre
(1) Weak base (2) Strong base (3) Weak acid (4) Strong acid
Comprehension-II
Heavy water is the oxide of heavy hydrogen (deuterium) and is also called deuterium oxide. It is represented as
D2O. Heavy water is chemically similar to ordinary water. Heavy water is used for the neutron moderator, as a tracer
compound and for the preparation of deuterium. Reaction of heavy water with alkali metals liberates heavy hydrogen.
Heavy water can also be used for exchanging labile hydrogen with deuterium completely or partially. Heavy water
reacts slower than ordinary water but forms stronger bonds with other elements as compared to hydrogen.
(1) DC CD (2) CD4 (3) Al(OD)3 (4) Both (2) & (3)
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10 Hydrogen Solution of Assignment (Set-2)
3. Which property of heavy water is lesser in magnitude as that compared with normal water?
(1) Molecular mass (2) Density (3) Boiling point (4) Ionisation constant
Comprehension-III
Size of nucleus increases from protium to tritium so in H2 D2 & T2 area of overlapping also increases in the same order.
(1) H2 = D2 = T2 (2) H2 > D2 > T2 (3) H2 < D2 < T2 (4) D2 < H2 < T2
(1) D2
(2) H2
(3) HD
SECTION - D
and
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Solution of Assignment (Set-2) Hydrogen 11
2. STATEMENT-1 : The O — O bond length in H2O2 is longer than that of O2F2.
and
STATEMENT-2 : H2O2 is a polar covalent molecule.
Sol. Answer (2)
O—O bond in O2F2 is shorter than that of H2O2. H2O2 is a polar covalent molecule.
3. STATEMENT-1 : Complete hydrolysis of one mole of peroxydisulphuric acid gives one mole of H2O2 and two
moles of H2SO4.
and
STATEMENT-2 : Peroxydisulphuric acid molecule has one peroxy linkage and four hydroxyl group.
Sol. Answer (3)
4. STATEMENT-1 : Zinc hydroxide dissolves in excess of NaOH solution to evolve dihydrogen gas.
and
STATEMENT-2 : Zinc hydroxide is amphoteric in nature.
Sol. Answer (4)
Zn + 2NaOH Na2ZnO2 + H2
Zn(OH)2 is amphoteric in nature.
5. STATEMENT-1 : Hydrogen gas is liberated by the action of aluminium with a concentrated solution of NaOH.
and
STATEMENT-2 : Aluminium with concentrated NaOH forms white ppt of Al(OH)3 and liberating H2(g).
Sol. Answer (3)
2NaAlO2 + H2
2Al + 2NaOH
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12 Hydrogen Solution of Assignment (Set-2)
SECTION - E
Matrix-Match Type Questions
Column-I Column-II
(A) H2O2 act as oxidizing agent, reducing agent, bleaching agent and acidic in nature.
(B) HNO2 act as both oxidising agent, reducing agent and acidic in nature.
(A) sp3 hybridisation is present in H2O, H2O2, B2H6 and NH3. H2O, H2O2 and NH3 can form hydrogen bonding.
H2O, H2O2 and NH3 also have lone pair in their structure.
Column I Column II
Structures of H2O2 are same but with different bond lengths and bond angles. All are like half open book structure.
H2O is bent molecule.
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Solution of Assignment (Set-2) Hydrogen 13
Column I Column II
(NaPO3)6 is calgon.
Column I Column II
(t) Proton
Self explanatory.
SECTION - F
Integer Answer Type Questions
1. In liquid water, the number of H2O molecules surrounded to one H2O molecule are ____.
Sol. Answer (4)
Each molecules is surrounded by 4 water.
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14 Hydrogen Solution of Assignment (Set-2)
SECTION - G
Multiple True-False Type Questions
1. STATEMENT-1 : H2O2 is more polar than H2O.
STATEMENT-2 : D2O has higher boiling point than H2O.
STATEMENT-3 : H2 bond energy is less than D2.
(1) T T T (2) TTF (3) TFF (4) FFT
Sol. Answer (1)
Dielectric constant of H2O2 is greater than H2O. Boiling point and freezing point of D2O are greater & H2 requires
less energy.
SECTION - H
Aakash Challengers Questions
1. The correct order of bond dissociation energy is
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Solution of Assignment (Set-2) Hydrogen 15
3. Not incorrect among the following.
(1) N2 & H2 do not react at room temperature
(2) Cl2 & H2 react in presence of sunlight
(3) N2 & D2 react at room temperature
(4) D2 on combustion forms heavy water
Sol. Answer (3)
(1) H (2) H–
(3) H+ (4) H+(aq)
Sol. Answer (4)
Factual
1
Bond strength bond length
7. How many grams of barium hydride must be treated with water to obtain 4.36 L of hydrogen at 20°C and
0.975 atm pressure (Ba = 137)?
Sol. BaH2 + 2H2O Ba(OH)2 + 2H2
4.36 0.975
Moles of hydrogen produced = = 0.1768 mole
293 1 0.0821
1
0.176 mole of hydrogen is produced = 0.176 = 0.088 moles of BaH2
2
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16 Hydrogen Solution of Assignment (Set-2)
8. When a substance A reacts with water, it produces a combustible gas B and a solution of substance C in
water. When another substance D reacts with this solution of C, it produces the same gas B on warming
but D can produce gas B on reaction with dilute sulphuric acid at room temperature. A imparts a deep
golden yellow colour to a smokeless flame of Bunsen burner. A, B, C and D respectively are _____?
Zn 2NaOH Na2ZnO 2 H2
D C B
Zn + H2SO4 ZnSO4 + H2
9. An element X reacts with H2 gas at 200°C to form compound Y. When Y is heated to a higher temperature, it
decomposes to element X and H2 gas in the ratio of 559 ml of H2 (measured at STP) for 1.00 g of X reacted. X also
combines with Cl2 to form a compound Z which contains 63.89 percent by mass of chlorine. Identify X, Y and Z.
Sol. X + H2 XH2
200 º C
XH2 X + H2
X + Cl2 XCl2
1
One equivalent of hydrogen is produced by = 11200 = 20 gm
559
36 .11
1 gm combine with metal =
63 .89
36 .11
35.5 gm combine with 35.5 = 20 g
63 .89
n factor: 2
So atomic wt. = 40
So metal is Ca.
X = Ca
Y = CaH2
Z = CaCl2
10. Hydrogen peroxide acts both as an oxidising agent and as a reducing agent in alkaline solution towards
certain first row transition metal ions. Illustrate both these properties of H2O2 using chemical equations.
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Solution of Assignment (Set-2) Hydrogen 17
11. A mixture of hydrazine and H2O2 with Cu (II) catalyst is used as a rocket propellant, why?
Sol. The reaction between hydrazine and H2O2 is highly exothermic and is accompanied by large increase in the
volume of the products and hence, this mixture is used as a rocket propellant.
Cu(II)
NH2 – NH2(l) + 2H2O2(l) N2(g) + 4H2O(g)
12. To a 25 ml H2O2 solution, excess of acidified solution of potassium iodide was added. The iodine liberated
required 20 ml of 0.3 N sodium thiosulphate solution. Calculate the volume strength of H2O2 solution.
20 25
So, 0 .3 N(H2O 2 )
1000 1000
20 0.3
N(H2O2) =
1000 25
4
= 2.4 10 1000
= 0.24 N
= 1.34 volume
13. Ionic metal hydrides react with water to give hydrogen gas and an aqueous solution of the metal hydroxide.
(i) On reaction of equal masses of LiH and CaH2 with water, which compound gives more H2?
(ii) How many kilograms of CaH2 is needed to fill a 100 L tank with compressed H2 gas at 150 atm pres-
sure and at 25°C? (Li = 9, H = 1, Ca = 40)
1
LiH H2O LiOH H2
2
Due to low molecular weight, in equal amount it has high no. of moles.
150 100
Moles of H2 produced : = 6.13×102
298 1.0821
2 mole of H2 is produced by = 42 g
42 6.13 102
6.13 × 102 mole of H2 will be produced by = kg
1000 2
= 12.873 kg
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18 Hydrogen Solution of Assignment (Set-2)
H2O2 H+ + HO2–
If pH of H2O2 at 20°C is found to be 5.91, calculate ionic product (auto-protolysis constant) of H2O2.
Sol. H2O2 ionise as
H2O2 H+ + HO2–
pH = –log(H+) = 5.9
H+ = 10–5.9
Xionic = 10–5.9 × 10–5.9 = 10–11.8 = 1.58 × 10–12
15. 1 mega litre water (density 1 g/cc) needs 106 Kg of Na2CO3 for removal of its permanent hardness. Determine
its hardness in the multiples of 20 ppm.
Sol. Answer (5)
1 mega litre = 106 L = 106 kg
106
(nmol )Na2CO3 kmol 1 kmol
106
nCaCO3 1 kmol
mCaCO3 100 kg
100
Hardness = 106 100 ppm 5 20 ppm
106
Answer is 5
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