BJ SERVICES COMPANY Region:

MATERIAL SAFETY DATA SHEET Asia Pacific

SECTION I - PRODUCT INFORMATION

Product Name: CI-27

Product Use: Corrosion inhibitor.
Chemical Family: Mixture.
Contact Address:
BJ Services Company (S) Pte Ltd
No 4 Tuas Avenue 18
Singapore 638890
Phone: (65) 6877 8700 Fax: (65) 6877 8707 / 8708

IN CASE OF EMERGENCY CALL: (65) 9757 4605 / (65) 6286 3128 (24 HRS)

HAZARD INDEX:
HEALTH: 2
FLAMMABILITY: 3
REACTIVITY: 0
PERSONAL PROTECTION: j

SECTION II - HAZARDOUS INGREDIENTS

Ingredient % Risk Phrases Safety Phrases Hazard

CAS # Symbol
Methanol 30-60 11 23/24/25 7 16 36/37 45 F;T
000067-56-1 39/23/24/25
Propargyl alcohol 5-10 10 23/24/25 34 26 28 36 45 61 T;N
000107-19-7 51/53
Oxyalkylated 10-30 36/38 36/37/39 Xi
alcohol

SECTION III - HAZARDS IDENTIFICATION

Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of very serious
irreversible effects through inhalation, in contact with skin and if swallowed. Irritating to eyes and skin.

SECTION IV - FIRST AID MEASURES

INHALATION:
If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Only trained personnel should administer oxygen. Get medical attention.
INGESTION:
Rinse mouth with water several times. Give victim plenty of water. DO NOT induce vomiting. Obtain
medical assistance immediately. If vomiting occurs naturally, keep head lower than hips to prevent
aspiration.

EYES:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention.

SKIN:
Wash with soap and water. Remove contaminated clothing and launder before reuse. Get medical
attention if irritation persists.

SECTION V - FIRE AND EXPLOSION DATA

NFPA-FLAMMABILITY CODE: 3
FLASHPOINT (METHOD): 9-15°C (PMCC)
LOWER EXPLOSION LIMIT (% v/v): Not available
UPPER EXPLOSION LIMIT (% v/v): Not available
AUTO-IGNITION TEMPERATURE: Not available

SPECIAL HAZARDS:
May form flammable vapour-air mixture. This product or a component there of can flow along surfaces to
reach a distant ignition source and flash back.

EXTINGUISHING MEDIA:
Water fog, carbon dioxide, alcohol foam, dry chemical.

SPECIAL FIREFIGHTING PROCEDURES:

Fire-fighters should wear self-contained breathing apparatus and full protective clothing when fighting
chemical fires. Cool exposed containers with water spray.

HAZARDOUS COMBUSTION PRODUCTS:

Oxides of carbon.

SECTION VI - ACCIDENTAL RELEASE MEASURES

Wear specified protective equipment. Remove sources of ignition. Small spills - Cover spill with absorbent
material. Scoop absorbed material into a suitable container for disposal. Large spills - Dike to contain.
Prevent from entering sewers or waterways. Recover product to suitable containers or vessel for reuse, if
possible, or for disposal. Use only explosion proof transfer equipment.

SECTION VII - HANDLING AND STORAGE

HANDLING:
Wear specified protective equipment. Use only in a well ventilated area. Use only spark-proof and
explosion-proof tools and equipment.

STORAGE REQUIREMENTS:
Keep in a cool, well ventilated place. Keep away from ignition sources. Keep away from heat. Keep away
from incompatible materials. Emptied containers may retain hazardous properties.
SECTION VIII - EXPOSURE CONTROLS AND PERSONAL PROTECTION

SPECIFIC ENGINEERING CONTROLS:

Use only in well-ventilated area. Local exhaust. Adequate ventilation should be provided to keep
concentrations below acceptable exposure limits.

PERSONAL PROTECTIVE EQUIPMENT:

Cartridge respirator. Chemical resistant goggles. Rubber gloves. Rubber apron. Rubber boots. Coveralls.

EXPOSURE GUIDELINES:
Methanol
000067-56-1 30-60% UK OES, TWA-ppm=200, STEL-ppm=250, skin
Propargyl alcohol
000107-19-7 5-10% UK OES, TWA-ppm=1, STEL-ppm=3, skin

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Liquid

COLOR: Amber
ODOR: Alcohol
ODOR THRESHOLD: Not available
SPECIFIC GRAVITY: 0.9 @ 20°C
VAPOR PRESSURE: 5.5 kPa @ 21°C
VAPOR DENSITY (air=1): >1
EVAPORATION RATE: Not available
BOILING POINT: Not available
FREEZING POINT: <-30°C (pour pt.)
pH: 3.1 (5% sol.)
SOLUBILITY IN WATER: Dispersible.

SECTION X - STABILITY AND REACTIVITY

STABILITY: Stable under normal conditions of use.

INCOMPATIBILITY/CONDITIONS OF REACTIVITY:
Strong oxidisers.

HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:

Carbon monoxide. Carbon dioxide.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION XI - TOXICOLOGICAL PROPERTIES

PRIMARY ROUTES OF EXPOSURE: Inhalation. Ingestion. Eye contact. Skin contact. Skin
absorption.

ACUTE OVEREXPOSURE EFFECTS:

INHALATION: Inhalation of solution vapour or mist may cause respiratory tract irritation. May cause
headache, dizziness, nausea and inco-ordination. May cause visual disturbances.

INGESTION: Harmful if swallowed. May cause nausea, dizziness or loss of co-ordination. May cause
visual impairments, ocular damage and possibly blindness if not treated medically.

EYE CONTACT: Vapour and/or liquid causes irritation.

SKIN CONTACT: May cause skin irritation. May be absorbed through the skin and contribute to the
symptoms listed under ingestion.

ACUTE TOXICITY:

Ingredient % LC50 (inhalation) LD50 (oral)

CAS #
Methanol 30-60 64000 ppm/4 (rat) 5628 mg/kg (rat)
000067-56-1
Propargyl alcohol 5-10 873 ppm/2 (rat) 20 mg/kg (rat)

000107-19-7

CHRONIC EFFECTS:
Dermatitis. Visual impairments.

SENSITIZATION: Not known.

CARCINOGENICITY: This product is not classified as a carcinogen in accordance with COSHH
Regulations.- Control of Substances Hazardous to Health
MUTAGENICITY: Not known.
REPRODUCTIVE TOXICITY: Not known.

SECTION XII - ECOLOGICAL INFORMATION

AQUATIC TOXICITY:

This product is present on the "OCNS (Offshore Chemical Notification Scheme) List of Notified
Chemicals" and has been included in Group C.

SECTION XIII - DISPOSAL CONSIDERATIONS

WASTE DISPOSAL:
Disposal should be made in accordance with EC, national and local regulations.

SECTION XIV - SHIPPING INFORMATION

SHIPPING NAME:
FLAMMABLE LIQUID, TOXIC, N.O.S.
(contains methanol, propargyl alcohol)

UN NUMBER: UN 1992

AIR-ICAO/IATA
Class: 3; Sub Risk 6.1
Packing Group: II
Labels: Flammable liquid & Toxic

SEA-IMO/IMDG
Class: 3.2; Sub Risk 6.1
Packing Group: II
IMDG Page No.: 3232
Labels: Class 3 and Subsidiary Risk 6.1
ADR/RID-ADNR
ADR/RID/ADNR Class: 3
ADR/RID/ADNR Item: 19(b)
Label No.: 3+6.1
Hazard ID No.: 336
CEFIC TEC(R) No.: 30G32

SECTION XV - REGULATORY INFORMATION

NAME(S) ON LABEL:
METHANOL
PROPARGYL ALCOHOL
OXYALKYLATED ALCOHOL
CLASSIFICATION/SYMBOL: Highly flammable and toxic/F;T
RISK PHRASES:
R11 Highly flammable.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin
and if swallowed.
R36/38 Irritating to eyes and skin.

SAFETY PHRASES:
S16 Keep away from sources of ignition - No Smoking.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S38 In case of insufficient ventilation wear suitable respiratory equipment.
S45 In case of accident or if you feel unwell, seek medical advice immediately.

SECTION XVI - OTHER INFORMATION

ISSUE DATE: 14/08/2000

SUPERSEDES: 01/09/1999
UPDATED : 01/01/2007
REVISIONS:
Sections II, III and XV.