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INSTRUCTIONS
Planck’s constant,
Mass of an electron,
Charge of an electron,
Avogadro’s number,
Boltzmann constant,
Atomic weight of copper = 63.54
1 nm = 10-9 m
1
SECTION A
QUESTION ONE
QUESTION TWO
b) Lead is fcc. If r and a are the radius of the lead atom and lattice parameter
QUESTION THREE
a) Draw the (112) and (120) planes of an fcc structure. (03 Marks)
b) Show that the atomic packing factor for fcc and hcp metals is the same. (03 Marks)
QUESTION FOUR
a) Magnesium has hcp structure. The radius of magnesium atom is 0.1605 nm. Calculate
b) Show that the maximum radius of the sphere that can just fit into the void at the body
centre of the fcc structure coordinated by the facial atoms is 0.414r, where r is the
2
SECTION B
QUESTION FIVE
Obtain Bragg’s equation for x-rays. Then apply the necessary correction for the x-rays
An electron initially at rest is accelerated through a p.d. of 5000 V. Calculate (i) the
momentum (ii) de Broglie wavelength and (iii) wave number. Also calculate the Bragg’s
angle for first order reflection from (111) planes which are 0.2 nm apart. (08 Marks)
QUESTION SIX
Copper has a density of 8.95 x 103 kg/m3 and an electrical conductivity 6.4 x 107 ohm-1m-1 at
room temperature. Calculate (a) the mean free time (b) Fermi energy (b) the Fermi velocity
(d) the mean free path at the Fermi level. (12 Marks)
QUESTION SEVEN
a) What would be the effect on the specific heat of solids at room temperature if
specific heat per kmol for diamond at 20 K. Also compute the highest lattice
QUESTION EIGHT
Give the assumptions of classical theory of lattice specific heat. (04 Marks)
Get the expression for the frequency of a classical oscillator. (04 Marks)
Obtain an expression for the specific heat of a solid on the basis of:
c) How far do the results from these theories agree with experimental data? (02 Marks)