कासगंज कोचिंग सेंटर

Practice paper By Anees sir

Chemistry
Class : XII

Roll No. : Time -

Date : MM - 295  

1. Write IUPAC name of the following compound: 1

2. Write IUPAC name of the following compound: 1

3. Write the structure of 3-hydroxybutanal. 1

4. Write the structure of 3-methylbutanal. 1

5. Write the structure of 4-chloropentan-2-one. 1

6. Write the structure of p-Methylbenzaldehyde molecule. 1

7. Write the structure of 4-methylpent-3-en-2-one. 1

8. Write the structural formula of 2-phenylethanoic acid. 1

9. Write the IUPAC name of compound. 1

10. Write the IUPAC name of the compound 1

11. Ethanal is soluble in water. Why? 1

12. Compare the strength of following acids:

1
(i) Formic acid, (ii) Acetic acid, (iii) Benzoic acid.
13. Arrange the following in increasing order of acidic character: 1

HCOOH, ClCH2COOH, CF3COOH, CCl3COOH

14. Write the chemical equations for the following chemical reactions: Benzonitrile is converted to 1
acetophenone.
15. Write the IUPAC name of the compound 1

16. Write the structure of 2-hydroxy benzoic acid. 1

17. Write the IUPAC name of the following compound: 1

18. Write the IUPAC name of the following: 1

19. 1
Write IUPAC name of

20. Write the structure of the following compound:

1
3-oxopentanal.

21. Write the IUPAC name of 1

22. Write the IUPAC name of the following: 1

23. 1

Write the IUPAC name of

24. Write the IUPAC name of 1

25. Write IUPAC name of CH3CH2CHO. 1

26. Draw the structural formula of 1-phenylpropan-1-one molecule. 1

27. Write the IUPAC name of the following: 1

28. Write the IUPAC name of the following: 1

29. Write the IUPAC name of the following: 1

30. Write the IUPAC name of the following compound: 1

31. Write the structural formula of 1-phenylpentan-1-one. 1

32. Write the structure of pent-2-enal. 1

33. What IUPAC name would you give to the following compound? 1

34. Write IUPAC name of 1

35. Write IUPAC names of the following: 2

36. Give IUPAC names of compounds: 2

37. Why is acetic acid stronger than phenol whereas formic acid is stronger than acetic acid? 2

38. Arrange the following in increasing order of boiling points:

2
(i) C2H5OC2H5, C4H9COOH, C4H9OH

(ii) C3H7CHO, CH3COC2H5, C2H5COOCH3, (CH3CO)2O.

39. Name the reagents used in the folllowing reactions: 2

40. Name the reagents used in the following reactions: 2

41. Write the reagents required in the following reactions: 2

42. Name the reagents used in the following reactions: 2

43. Complete the following reactions and give the names of major products: 2

44. Write the structural formulae of compounds A, B and C and name the reagent D in the following 2
reaction:
45. Write chemical equations to illustrate each of the following reactions:
2
(i) Acylation reaction (ii) Rosenmund reduction

46. Give chemical tests to distinguish between the following pairs of compounds:
2
(i) Propanal and propanone

(ii) Benzaldehyde and benzoic acid.

47. Give chemical tests to distinguish between the following pairs of compounds:
2
(i) Propanoyl chloride and Propanoic acid

(ii) Benzaldehyde and Acetophenone

48. How will you bring about the following conversions in not more than two steps?
2
(i) Propanal to Butanone

(ii) Propanoyl chloride to Dipropylamine

(iii) Propanoic acid to Propenoic acid

(iv) Benzoyl chloride to Benzonitrile

49. (a) Write the steps and conditions involved in the following conversions:
2
(i) Acetophenone to 2-phenyl-2-butanol

(ii) Propene to acetone

50. Write the reagent used in the following reaction: 2

51. Arrange the following in increasing order of their property indicated:

2
(i) CH3CHO, C6H5CHO, HCHO

(reactivity towards nucleophilic addition reaction)

(ii) 2,4-Dinitro benzoic acid, 4-methoxy benzoic acid, 4-Nitro benzoic acid (acidic character)

52. Write the reagents used in the following reactions: 2

(i) C6H5COCl C6H5CHO

(ii) CH3COONa CH4

53. Arrange the following compounds in increasing order of their property as indicated:
2
(i) CH3COCH3, C6H5—CO—C6H5, CH3CHO (reactivity towards nucleophilic addition reaction)

(ii)

54. How will you carry out the following conversions:

2
(i) Acetone to chloroform?

(ii) Acetylene to Acetic acid?

55. Give reasons for the following:
3
(a) Carboxylic acids do not give characteristic reactions of carbonyl group.

(b) T reatment of benzaldehyde with HCN gives a mixture of two isomers which cannot be
separated even by careful fractional distillation.

(c) Sodium bisulphite is used for the purification of aldehydes and ketones.

56. Why is carboxyl group in benzoic acid meta directing? Support your answer with two examples. 3

57. Write balanced chemical equations for the following reactions:

3
(i) T hionyl chloride reacts with benzoic acid

(ii) Acetic acid is reacted with red phosphorus and HI

(iii) Acetic acid is treated with Zn metal.

58. What happens when:

3
(i) An aqueous solution of sodium acetate is electrolysed?

(ii) Calcium acetate is dry distilled?

(iii) S odium benzoate is heated with soda lime?

59. Predict the products: 3

60. Predict the products of the following reactions: 3

61. Predict the products of the following reactions: 3

62. Predict the products of the following reactions: 3

63. Write one chemical equation for each, to illustrate the following reactions:
3
(i) R osenmund reduction

(ii) Cannizzaro reaction

(iii) Fischer esterification

64. How are the following conversions carried out ?
3
(i) E thylcyanide to ethanoic acid

(ii) Butan-1-ol to butanoic acid

(iii) Benzoic acid to m-bromobenzoic acid.

65. Convert:
3
(i) Acetophenone to ethylbenzene

(ii) Ethanal to 2-aminoethanoic acid

(iii) Methyl chloride to ethanoic acid.

66. How will you convert ethanal into the following compounds?
3
(a) Butan-2-one (b) Butan-1-ol (c) Butanoic acid

67. Write the major products: 3

68. Predict the products of the following reactions. 3

69. Write the equations involved in the following reactions:

3
(i) Stephen reaction

(ii) Wolff-Kishner reduction

(iii) Etard reaction

70. An aliphatic compound ‘A’ with a molecular formula of C3H6O reacts with phenylhydrazine to 3
give compound ‘B’. Reaction of ‘A’ with I2 in alkaline medium on warming, gives a yellow precipitate
‘C’. Identify the compounds A, B and C.

71. Two moles of organic compound ‘A’ on treatment with a strong base gives two compounds B 3
and C. Compound ‘B’ on dehydrogenation with Cu gives ‘A’ while acidification of ‘C’ yields carboxylic
acid ‘D’ having molecular formula of CH2O2. Identify the compounds A, B, C and D.

72. (a) Describe (i) Aldol condensation (ii) Cannizaro's reaction. 5

(b) Describe a chemical test to distinguish between

(i) Ethanal and Propanal (ii) Benzaldehyde and Acetophenone

(iii) Pentan-2-one and pentan-3-one

73. (a) Write structures of following compounds:

5
(i) 4-chloro pentan-2-one (ii) But-2-en-1-al

(b) Predict the products of following reactions:

74. (a) Write IUPAC name of the following compounds: 5

(b) H ow will you carry out following conversions:

(i) E thanol to 3-hydroxy butanal

(ii) Benzoic acid to m-nitro benzyl alcohol.

(iii) Propanone to propene.

75. (a) Write the structures of following compounds:

5
(i) 4-chloro pentan-2-one (ii) p-nitro phenyl propanone

(b) How will you distinguish between the following by suitable chemical tests.

(i) Ethanal and propanal (ii) Phenol and Benzoic acid

(iii) Benzaldehyde and Acetophenone.

76. (a) How will you convert the following:

5
(i) Propanone to Propan-2-ol (ii) Ethanal to 2-Hydroxypropanoic acid

(iii) Toluene to Benzoic acid

(b) Give simple chemical test to distinguish between:

(i) Pentan-2-one and Pentan-3-one (ii) Ethanal and Propanal

77. (a) Write the products of the following reactions: 5

(b) Which acid of each pair shown here would you expect to be stronger?

78. (a) Although phenoxide ion has more number of resonating structures than Carboxylate ion, 5
Carboxylic acid is a stronger acid than phenol. Give two reasons.

(b) How will you bring about the following conversions?

(i) Propanone to propane

 (ii) Benzoyl chloride to benzaldehyde

(iii) Ethanal to but-2-enal

79. (a) Complete the following reactions: 5

(b) Give simple chemical tests to distinguish between the following pairs of compounds:

(i) Ethanal and Propanal

(ii) Benzoic acid and Phenol

80. (a) Give reasons for the following:

5
(i) Ethanal is more reactive than acetone towards nucleophilic addition reaction.

(ii) (CH3)3C—CHO does not undergo aldol condensation.

(iii) Carboxylic acids are higher boiling liquids than alcohols.

(b) Give a simple chemical test to distinguish between:

(i) Acetophenone and Benzophenone

(ii) Benzaldehyde and Ethanal

81. Write the structures of products of the following reactions: 5

82. (a) Write the products of the following reactions: 5

(b) Give simple chemical tests to distinguish between the following pairs of compounds:

(i) Benzaldehyde and Benzoic acid

(ii) Propanal and Propanone

83. (a) Account for the following:

5
(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.

 (ii) Carboxylic acid is a stronger acid than phenol.

(b) Write the chemical equations to illustrate the following name reactions:
(i) Wolff-Kishner reduction

(ii) Aldol condensation

(iii) Cannizzaro reaction

84. (a) Write the products formed when CH3CHO reacts with the following reagents:
5
(i) HCN            (ii) H2N—OH

(iii) CH3CHO in the presence of dilute NaOH

(b) Give simple chemical tests to distinguish between the following pairs of compounds:

(i) Benzoic acid and Phenol (ii) Propanal and Propanone

85. (a) Account for the following:

5
(i) Cl—CH2COOH is a stronger acid than CH3COOH.

(ii) Carboxylic acids do not give reactions of carbonyl group.

(b) Write the chemical equations to illustrate the following name reactions:
(i) Rosenmund reduction

(ii) Cannizzaro’s reaction

(c) Out of CH3CH2—CO—CH2—CH3 and CH3CH2—CH2—CO—CH3, which gives iodoform test?

86. (a) Write the products formed when ethanal reacts with the following reagents:
5
(i) CH3MgBr and then H3O+ (ii) Zn-Hg/conc. HCl

(iii) C6H5CHO in the presence of dilute NaOH

(b) Give simple chemical tests to distinguish between the following pairs of compounds:

(i) Benzoic acid and Ethyl benzoate

(ii) Propanal and Butan-2-one

87. (a) Account for the following:

5
(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.

(ii) There are two –NH2 groups in semicarbazide (H2NNHCONH2). However, only one is involved in
the formation of semicarbazone.

(b) Write the chemical equations to illustrate each of the following name reactions:
(i) Rosenmund reduction

(ii) Hell-Volhard-Zelinsky reaction

(iii) Cannizzaro reaction

88. (a) An organic compound A, having the formula, C3H8O, on treatment with copper at 573 K, gives 5
B. B does not reduce Fehling’s solution but gives a yellow precipitate of the compound C with I2/
NaOH. Deduce the structures of A, B and C.

(b) Predict the products of the following reactions:

89. (a) A compound A (C2H6O) on oxidation by PCC gave B, which on treatment with aqueous alkali 5
and subsequent heating furnished C. B on oxidation by KMnO4, forms a monobasic carboxylic acid
with molar mass 60 g mol–1. Deduce the sturctures of A, B and C.

(b) Predict the products of the following reactions:

90. An organic compound (A) on treatment with acetic acid in the presence of sulphuric acid 5
produces an ester (B). (A) on mild oxidation gives (C). (C) with 50% KOH followed by acidification
with dilute HCl generates (A) and (D). (D) with PCl5 followed by reaction with ammonia gives (E). (E)
on dehydratio produces hydrocyanic acid. Identify the compounds A, B, C, D and E.

91. Identify A, B, C, D and E in the following sequence of reactions: 5

92. (a) Draw the structure of the following derivatives:

5
(i) Propanoxime

(ii) Semicarbazone of acetaldehyde

(b) How will you convert ethanal into the following compounds? Give the chemical equation
involved.

93. (a) Identify A to D. 5

(b) Distinguish between the following by suitable chemical test.

(i) CH3COCH2CH3 and CH3CH2CH2CHO

(ii) Ethanal and ethanoic acid.

(c) Write the structure of 4-chloro pentan-2-one.

94. (a) Explain the mechanism of a nucleophilic attack on the carbonyl group of an aldehyde or a 5
ketone.

(b) An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric
acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid also
produced (B). On dehydration (c) gives but-1-ene. Write the equations for the reactions involved.

95. An organic compound (A) on treatment with ethyl alcohol gives a carboxylic acid (B) and 5
compound (C). Hydrolysis of (C) under acidified conditions gives (B) and (D). Oxidation of (D) with
KMnO4 also gives (B). (B) on heating with Ca(OH)2 gives (E) having molecular formula C3H6O. (E)
does not give Tollens’ test and does not reduce Fehling’s solution but forms a 2, 4-dinitro phenyl
hydrazone. Identify (A), (B), (C), (D) and (E).
96. 1

97. Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is 1
called:

(a) Cope reduction (b) Dow reduction

(c) Wolff Kishner reduction (d) Clemensen reduction

98. Acetophenone when reacted with base C2H5—ONa, yields a stable product: 1

99. 1

100.Propanoic acid with Br2/P4 yields a dibromo product. The structure will be 1

101. 1
102.CH3CHO and C6H5 CH2CHO can be distinguished chemically by
1
(a) Benedict’s test (b) Iodoform test (c) Tollen’s reagent test (d) Fehling’s solution test

103. 1

104.Which is most reactive towards Nucleophilic substitution reaction? 1

(a) Benzaldehyde (b) Acetophenone

105.Which of the following is not soluble in NaHCO3?

1
(a) 2, 4, 6-Trinitrophenol (b) Benzoic acid (c) o-Nitrophenol (d) Benzene sulphonic acid

106. 1

107.Which among the given molecules can exhibit tautomerism? 1

(a) III only (b) Both I and III (c) Both I and II (d) Both II and III

108.The product formed by the reaction of an aldehyde with a primary amine is

1
(a) Carboxylic acid (b) Aromatic acid (c) Schiff’s base (d) Ketone

109. 1

110.The correct order of increasing acidic strength is _____________. [NCERT Exemplar Problem]
1
(a) Phenol < Ethanol < Chloroacetic acid < Acetic acid (b) Ethanol < Phenol < Chloroacetic acid <
Acetic acid

(c) Ethanol < Phenol < Acetic acid < Chloroacetic acid (d) Chloroacetic acid < Acetic acid < Phenol <
Ethanol

111. 1
 (a) Phenol and benzoic acid in the presence of NaOH

(b) Phenol and benzoyl chloride in the presence of pyridine

(c) Phenol and benzoyl chloride in the presence of ZnCl2

(d) Phenol and benzaldehyde in the presence of palladium

112.Cannizaro’s reaction is not given by _____________. 1

(c) HCHO (d) CH3CHO

113.Which of the following compounds do not undergo aldol condensation? 1

114. 1

(a) Phenol (b) Sodium phenoxide (c) Sodium benzoate (d) Benzophenone

115.Benzophenone can be obtained by ____________. [NCERT Exemplar Problem]

1
(a) Benzoyl chloride + Benzene + AlCl3

(b) Benzoyl chloride + Diphenyl cadmium

(c) Benzoyl chloride + Phenyl magnesium chloride

(d) Benzene + Carbon monoxide + ZnCl2

116.Which of the following is the correct representation for intermediate of nucleophilic addition 1
reaction to the given carbonyl compound (A):

117.Match the common names given in Column I with the IUPAC names given in Column II. 1

Column I (Common names) Column II (IUPAC names)

(a) Cinnamaldehyde (i) Pentanal
(b) Acetophenone (ii) Prop-2-enal
(c) Valeraldehyde (iii) 4-Methylpent-3-en-2-one
(d) Acrolein (iv) 3-Phenylprop-2-enal
(e) Mesityl oxide (v) 1-Phenylethanone

118.Match the acids given in Column I with their correct IUPAC names given in Column II. 1

Column I (Acids) Column II (IUPAC names)

 (a) Phthalic acid (i) Hexane-1,6-dioic acid
(b) Oxalic acid (ii) Benzene-1,2-dicarboxylic acid
(c) Succinic acid (iii) Pentane-1,5-dioic acid
(d) Adipic acid (iv) Butane-1,4-dioic acid
(e) Glutaric acid (v) Ethane-1,2-dioic acid

119.Match the reactions given in Column I with the suitable reagents given in Column II. 1

Column II
Column I (Reactions)
(Reagents)
(a) Benzophenone → (i) LiAlH4
Diphenylmethane
(b) Benzaldehyde → 1-Phenylethanol (ii) DIBAL—H
(iii) Zn(Hg)/Conc.
(c) Cyclohexanone → Cyclohexanol
HCl
(d) Phenyl benzoate → Benzaldehyde (iv) CH3MgBr
   

120.In the following questions a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices. (Q.25 to Q.28)

(a) Assertion and reason both are correct and reason is correct explanation of assertion.

(b) Assertion and reason both are wrong statements.

(c) Assertion is correct but reason is wrong statement.

(d) Assertion is wrong but reason is correct statement.

(e) Assertion and reason both are correct statements but reason is not correct explanation of
assertion.

Assertion: Formaldehyde is a planar molecule.

Reason: It contains sp2 hybridised carbon atom.

121.In the following questions a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices. (Q.25 to Q.28)

(a) Assertion and reason both are correct and reason is correct explanation of assertion.

(b) Assertion and reason both are wrong statements.

(c) Assertion is correct but reason is wrong statement.

(d) Assertion is wrong but reason is correct statement.

(e) Assertion and reason both are correct statements but reason is not correct explanation of
assertion.

Assertion: Compounds containing —CHO group are easily oxidised to corresponding carboxylic
acids.

Reason: Carboxylic acids can be reduced to alcohols by treatment with LiAlH4.

122.In the following questions a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices. (Q.25 to Q.28)

(a) Assertion and reason both are correct and reason is correct explanation of assertion.

(b) Assertion and reason both are wrong statements.

(c) Assertion is correct but reason is wrong statement.

(d) Assertion is wrong but reason is correct statement.

 (e) Assertion and reason both are correct statements but reason is not correct explanation of
assertion.

Assertion: The α-hydrogen atom in carbonyl compounds is less acidic.

Reason: The anion formed after the loss of a-hydrogen atom is resonance stabilised.

123.In the following questions a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices. (Q.25 to Q.28)

(a) Assertion and reason both are correct and reason is correct explanation of assertion.

(b) Assertion and reason both are wrong statements.

(c) Assertion is correct but reason is wrong statement.

(d) Assertion is wrong but reason is correct statement.

(e) Assertion and reason both are correct statements but reason is not correct explanation of
assertion.

Assertion: Aromatic aldehydes and formaldehyde undergo Cannizaro reaction.

Reason: Aromatic aldehydes are almost as reactive as formaldehyde.

124.Pentan-2-one can be distinguished from pentan-3-one by _______________ test. 1

125.The pKa of acetic acid is _______________ than that of phenol. 1

126.Benzoate ion is more _______________ than acetate ion. 1

127.Formic acid does not undergo HVZ reaction because it does not have _______________. 1

128.Phenol does not liberate CO2 with NaHCO3. 1

129.All aldehydes turn Schiff’s reagent pink. 1

130. [True/False] 1

131. 1
[True/False]

132. 1
The IUPAC name of the compound 

(a) 2-Formyl hex-2-en-3-one

(b) 5-methyl-4-oxo hex-2-en-5al

(c) 3-keto-2-methyl hex-5en-al

(d) 3-keto-2-methyl hex-4-en-1-al

133.Predict the correct intermediate and the product in the following reaction: 1

134.Of the following which is the product formed when cyclohexanone undergoes aldol 1
condensation followed by heating?

135.Arrange the following in order of increasing acidity.

1
A. o-nitrobenzoic acid

B. p-nitrobenzoic acid

C. p-hydroxybenzoic acid

D. benzoic acid

 (a) A < B < C < D (b) B < C < A < D

(c) C < B < D < A (d) C < D < B < A

136.Which of the following carboxylic acid can undergo decarboxylation easily? 1

137.The increasing order of the rate of HCN addition to compound A to D is 1

A. HCHO B. CH3COCH3

D. PhCOPh

C. PhCOCH3 (where Ph is phenyl

group)
(a) D < B < C <
(b) D < C < B < A
A
(c) C < D < B <
(d) A < B < C < D
A

138.Compounds A and C in the following reaction are __________. 1

(a) identical (b) positional isomers

(c) functional isomers (d) optical isomers

139.Which is the most suitable reagent for the following conversion? 1

(a) Tollen’s reagent

(b) Benzoyl peroxide

(c) I2 and NaOH solution

(d) Sn and NaOH solution

140.In the following questions two or more options may be correct.

1
Which of the following conversions can be carried out by Clemmensen Reduction? [NCERT
Exemplar Problem]

(a) Benzaldehyde into benzyl alcohol

(b) Cyclohexanone into cyclohexane

(c) Benzoyl chloride into benzaldehyde

(d) Benzophenone into diphenyl methane

141.Match the example given in Column I with the name of the reaction in Column II. 1
142.In the following question a statement of assertion followed by a statement of reason is given. 1
Choose the correct answer out of the following choices.

(a) Assertion and reason both are correct and reason is correct explanation of assertion.

(b) Assertion and reason both are wrong statements.

(c) Assertion is correct statement but reason is wrong statement.

(d) Assertion is wrong statement but reason is correct statement.

(e) Assertion and reason both are correct statements but reasson is not correct explanation of
assertion.

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.

143.Acetaldehyde and Benzaldehyde can be distinguished by _______________ test. 1

144._______________ acid obtained from red ants gives silver mirror with Tollen’s reagent test. 1

145. 1
   [True/False]