Cationes

Logged on User: Lenovo Page 1 of 216
Instrument: ICS1100 22/6/2016 6:37 p.m.

Sequence: 062116-CATIONES
Peak Integration Report
Sample Name: CAL1 Inj. Vol.: 500.00

Injection Type: Calibration Standard Dilution Factor: 1.0000
Program: SODIO Operator: Lenovo
Inj. Date / Time: 31-may-2016 / 15:34 Run Time: 13.00
No. Time Peak Name Peak Type Area Height Amount

min µS*min µS mg/L
1 3.59 Lithium Ru* 1.119 8.066 0.9405
3 4.25 Sodium Rd* 1.908 12.947 3.9867
4 4.83 Ammonium Rd* 0.313 1.764 4.7950
5 5.96 Potassium Rd* 2.300 11.835 4.4648
6 7.65 Magnesium Rd* 3.449 9.925 4.3569
7 9.03 Calcium Rd* 5.252 13.087 8.8328
TOTAL: 14.34 57.62 27.38
062116-CATIONES #1 [manually integrated] CAL1 ECD_1

16.0
3 - Sodium - 4.247
7 - Calcium - 9.027
5 - Potassium - 5.964
6 - Magnesium - 7.654
µS
14.0
1 - Lithium - 3.591
12.0
10.0
8.0
4 - Ammonium - 4.834
6.0
4.0
2 - 3.951
2.0
0.0
-2.0
-4.0
-6.0
min
-8.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
Chromeleon (c) Dionex 1996-2009

Anion/Integration Version 7.2.3.7553
Peak Analysis Report
Sample Name: CAL1 Injection Volume: 500.00

Instrument Method: SODIO Operator: Lenovo

16.0
3 - Sodium - 4.247
7 - Calcium - 9.027
µS
1 - Lithium - 3.591
10.0 4 - Ammonium - 4.834
5.0
2 - 3.951
0.0
-5.0
min
-8.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
No. Time Peak Name Width Height Resol. Resol. Plates Plates Asymmetry
min min µS (USP) (EP) (USP) (EP)
1 3.591 Lithium n.a. 8.066 n.a. n.a. n.a. n.a. n.a.
2 3.951 9.392 0.085 n.a. n.a. 3 1 8.578
3 4.247 Sodium n.a. 12.947 n.a. n.a. n.a. n.a. n.a.
4 4.834 Ammonium n.a. 1.764 n.a. n.a. n.a. n.a. n.a.
5 5.964 Potassium n.a. 11.835 n.a. n.a. n.a. n.a. n.a.
6 7.654 Magnesium n.a. 9.925 n.a. n.a. n.a. n.a. n.a.
7 9.027 Calcium n.a. 13.087 n.a. n.a. n.a. n.a. n.a.
AVERAGE: 9.392 8.244 #DIV/0! #DIV/0! 3. 1. 8.578

Anion/Peak Analysis Version 7.2.3.7553
1 CAL1 Audit Trail

Vial Position: 2 Channel: ECD_1
Injection Type: Calibration Standard Wavelength: n.a.
Instrument Method: SODIO Bandwidth: n.a.
Processing Method: sodio Dilution Factor: 1.0000
Recording Time: 31-may-16 15:34 Sample Weight: 1.0000
Run Time (min): 13.00 Int STD Amount: 1.0000
Day Time Ret. Time Command/Message

(UTC-06:00) min
15:34:47 Audit trail of injection "chrom://lenovo-pc/ChromeleonLocal/cationes/053116-CATIONES.seq/528.smp". Executed 31/
15:34:47 Start of injection 2 "CAL1", using instrument method "SODIO".
15:34:47 0.000 Entered stage "Instrument Setup"
15:34:47 0.000 Sampler.FlushFactor = 10
15:34:47 0.000 Sampler.DelayVolume = 125 µl
15:34:47 0.000 Sampler.DeliverSpeed = 4.0 ml/min
15:34:47 0.000 Pump_ECD.Pressure.UpperLimit = 5000 psi
15:34:47 0.000 Pump_ECD.%A.Equate = "sulf"
15:34:47 0.000 Pump_ECD.Pressure.LowerLimit = 200 psi
15:34:47 0.000 Pump_ECD.CellTemperature.Nominal = 35.0 °C
15:34:47 0.000 Pump_ECD.Flow = 1.00 ml/min
15:34:47 0.000 Sampler.LoadPosition
15:34:47 0.000 Sampler.DeliverSample Volume = 500
15:34:47 0.000 Current Deliver Position = 2, Deliver Volume = 500 µL.
15:36:11 0.000 Sampler.EndSamplePrep
15:36:11 0.000 Entered stage "Inject"
15:36:11 0.000 Wait Sampler.CycleTimeState
15:36:11 0.000 Wait finished
15:36:11 0.000 Sampler.Inject
15:36:11 0.001 Entered stage "Start Run"
15:36:11 0.001 Pump_ECD.Channel_Pressure.AcqOn
15:36:11 0.001 Pump_ECD.ECD_1.AcqOn
15:36:11 0.001 Pump_ECD.ECD_Total.AcqOn
15:36:11 0.001 Pump_ECD.Autozero
15:36:11 0.001 Entered stage "Run"
15:36:41 0.500 Log Pressure: 1086.08 [psi]
15:36:41 0.500 Log Background: 25.74 [µS]
15:36:41 0.500 Sampler.BeginOverlap
15:49:11 13.000 Entered stage "Stop Run"
15:49:11 13.000 Pump_ECD.Channel_Pressure.AcqOff
15:49:11 13.000 Pump_ECD.ECD_1.AcqOff
15:49:11 13.000 Pump_ECD.ECD_Total.AcqOff
15:49:13 End of injection "CAL1".

Anion/Audit Trail Version 7.2.3.7553
ES.seq/528.smp". Executed 31/05/2016 on instrument ICS1100 (server Lenovo-PC).



1 3.59 Lithium Ru* 2.323 16.784 2.3681
3 4.24 Sodium Rd* 3.221 21.992 9.1534
4 4.83 Ammonium Rd* 0.581 3.403 12.0148
6 7.64 Magnesium Rd* 7.006 20.345 11.6751
7 8.99 Calcium Rd*^ 9.879 24.497 24.3999
TOTAL: 23.01 87.02 59.61
062116-CATIONES #2 [manually integrated, 2 peak(s) manually assigned] ECD_1

30.0
3 - Sodium - 4.241
7 - Calcium - 8.994
µS 5 - 5.934
25.0
1 - Lithium - 3.591
20.0
15.0
10.0
5.0
2 - 3.991
0.0
-5.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



30.0
5 - 5.934
3 - Sodium - 4.241
7 - Calcium - 8.994
µS
25.0 1 - Lithium - 3.591
20.0
15.0
10.0
2 - 3.991
5.0
0.0
-5.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
2 3.991 7.985 0.098 n.a. n.a. 4 25 6.565
5 5.934 n.a. 24.562 n.a. n.a. n.a. n.a. n.a.
n.a. n.a. Potassium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
AVERAGE: 7.985 15.955 #DIV/0! #DIV/0! 4. 25. 6.565

2 CAL2 Audit Trail


(UTC-06:00) min
15:51:08 0.500 Log Pressure: 1079.54 [psi]




1 3.59 Lithium Ru* 4.651 33.372 5.1289
2 4.24 Sodium Rd* 6.106 41.512 20.5054
3 4.83 Ammonium Rd* 1.105 6.316 26.1647
5 5.91 Potassium Rd* 9.410 48.905 25.4205
6 7.60 Magnesium Ru* 13.919 40.398 25.8963
8 8.92 Calcium Rd* 17.937 43.560 51.5128
TOTAL: 53.13 214.06 154.63

60.0 5 - Potassium - 5.911
µS
8 - Calcium - 8.924
2 - Sodium - 4.244
50.0
1 - Lithium - 3.591
40.0
30.0
20.0
10.0
7 - 8.491
4 - 4.007
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



60.0
2 - Sodium - 4.244
8 - Calcium - 8.924
µS
1 - Lithium - 3.591
50.0
40.0
30.0
20.0
10.0 7 - 8.491
4 - 4.007
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
4 4.007 3.545 0.179 1.234 1.375 20 26 2.951
7 8.491 3.721 0.455 n.a. n.a. 83 101 1.475
AVERAGE: 3.633 26.837 1.234 1.375 52. 64. 2.213

3 CAL3 Audit Trail


(UTC-06:00) min
16:05:36 0.500 Log Pressure: 1078.19 [psi]




1 3.60 Lithium Ru* 9.280 65.068 10.6178
2 4.25 Sodium Ru* 11.729 78.530 42.6233
4 4.84 Ammonium Rd* 2.055 11.121 51.8303
5 5.89 Potassium Rd* 18.672 97.305 52.7165
6 7.53 Magnesium Ru* 27.409 78.665 53.6487
8 8.81 Calcium Rd*^ 34.030 79.571 105.6568
TOTAL: 103.17 410.26 317.09

120.0 5 - Potassium - 5.891
µS
112.5
8 - Calcium - 8.814
2 - Sodium - 4.251
100.0
1 - Lithium - 3.597
87.5
75.0
62.5
50.0
37.5
25.0
7 - 8.364
3 - 4.604
12.5
0.0
-12.5
min
-20.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



120
8 - Calcium - 8.814
2 - Sodium - 4.251
µS
1 - Lithium - 3.597
100
80
60
40
20
7 - 8.364
3 - 4.604
min
-20
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
3 4.604 3.102 0.606 1.485 1.140 35 48 1.454
7 8.364 1.963 0.829 n.a. n.a. 291 71 1.601
AVERAGE: 2.532 51.462 1.485 1.140 163. 60. 1.528

4 CAL4 Audit Trail


(UTC-06:00) min
16:20:03 0.500 Log Pressure: 1077.92 [psi]




1 3.60 Lithium Ru* 16.935 108.769 19.6947
2 4.26 Sodium Ru* 20.907 132.956 78.7311
4 4.86 Ammonium Rd* 3.801 17.444 98.9453
5 5.87 Potassium Rd* 34.257 176.399 98.6482
6 7.45 Magnesium Ru* 49.051 136.019 98.1730
8 8.68 Calcium Rd* 61.208 131.475 197.0976
TOTAL: 186.16 703.06 591.29

200
µS
180
2 - Sodium - 4.257
8 - Calcium - 8.681
160
1 - Lithium - 3.597
140
120
100
80
60
40
7 - 8.371
3 - 4.597
20
min
-20
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



200
µS
8 - Calcium - 8.681
2 - Sodium - 4.257
175 1 - Lithium - 3.597
150
125
100
75
50 7 - 8.371
3 - 4.597
25
0
min
-20
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
3 4.597 3.101 1.083 1.485 1.359 35 59 1.354
7 8.371 1.980 1.431 n.a. n.a. 286 111 1.529
AVERAGE: 2.540 88.197 1.485 1.359 161. 85. 1.441

5 CAL5 Audit Trail


(UTC-06:00) min
16:34:31 0.500 Log Pressure: 1077.23 [psi]


Sample Name: blanco 1 Inj. Vol.: 500.00

Injection Type: Blank Dilution Factor: 1.0000
Inj. Date / Time: 22-jun-2016 / 09:47 Run Time: 13.00

min µS*min µS n.a.
TOTAL: 0.00 0.00 0.00
062116-CATIONES #6 blanco 1 ECD_1

0.0100
µS
0.0000
-0.0100
-0.0200
-0.0300
-0.0400
-0.0500
-0.0600
-0.0700
min
-0.0800
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: blanco 1 Injection Volume: 500.00


0.0100
µS
0.0000
-0.0100
-0.0200
-0.0300
-0.0400
-0.0500
-0.0600
-0.0700
min
-0.0800
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
n.a. n.a. Lithium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
n.a. n.a. Sodium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
n.a. n.a. Ammonium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
n.a. n.a. Magnesium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
n.a. n.a. Calcium n.a. n.a. n.a. n.a. n.a. n.a. n.a.
AVERAGE: #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0! #DIV/0!

6 blanco 1 Audit Trail

Injection Type: Blank Wavelength: n.a.
Recording Time: 22-jun-16 09:47 Sample Weight: 1.0000

(UTC-06:00) min
09:47:19 Start of injection 6 "blanco 1", using instrument method "SODIO".
09:49:02 0.500 Log Pressure: 1093.01 [psi]
10:01:34 End of injection "blanco 1".


Sample Name: V1 Inj. Vol.: 500.00

Injection Type: Unknown Dilution Factor: 10.0000

1 4.21 Sodium BM 8.758 58.643 309.3756
2 5.80 Potassium M 0.354 1.817 n.a.
3 7.62 Magnesium M 0.295 0.777 n.a.
4 8.96 Calcium MB 1.617 3.863 n.a.
TOTAL: 11.02 65.10 309.38
062116-CATIONES #7 V1 ECD_1
70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.957
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: V1 Injection Volume: 500.00

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.957
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 58.643 6.197 6.273 5535 5661 1.143
2 5.804 Potassium 0.289 1.817 4.334 4.385 6448 6553 1.289
3 7.620 Magnesium 0.549 0.777 2.295 2.322 3080 3140 n.a.
4 8.957 Calcium 0.616 3.863 n.a. n.a. 3386 3446 1.324
AVERAGE: 0.420 16.275 4.275 4.327 4,612. 4,700. 1.252

7 V1 Audit Trail

Injection Type: Unknown Wavelength: n.a.

(UTC-06:00) min
20:12:50 Start of injection 7 "V1", using instrument method "SODIO".
20:14:44 0.500 Log Pressure: 1046.00 [psi]
20:27:17 End of injection "V1".




1 4.21 Sodium BM 8.933 59.930 316.2553
2 5.79 Potassium M 0.415 2.149 n.a.
3 7.65 Magnesium M 0.307 0.826 n.a.
4 8.98 Calcium MB 1.752 4.199 n.a.
TOTAL: 11.41 67.10 316.26
70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.981
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0


70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.981
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 59.930 6.162 6.239 5567 5691 1.150
2 5.787 Potassium 0.287 2.149 4.481 4.532 6493 6607 1.274
3 7.647 Magnesium 0.543 0.826 2.307 2.333 3175 3230 1.644
4 8.981 Calcium 0.613 4.199 n.a. n.a. 3431 3491 1.324
AVERAGE: 0.417 16.776 4.316 4.368 4,667. 4,755. 1.348

8 V2 Audit Trail


(UTC-06:00) min
20:29:12 0.500 Log Pressure: 1033.76 [psi]


Sample Name: V3 UPS Inj. Vol.: 500.00


TOTAL: 0.00 0.00 0.00
062116-CATIONES #9 V3 UPS ECD_1

0.0300
µS
0.0250
0.0200
0.0150
0.0100
0.0050
0.0000
min
-0.0050
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: V3 UPS Injection Volume: 500.00

062116-CATIONES #9 V3 UPS ECD_1

0.0300
µS
0.0250
0.0200
0.0150
0.0100
0.0050
0.0000
min
-0.0050
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

9 V3 UPS Audit Trail
Sample Name: V3 UPS Injection Volume: 500.00


(UTC-06:00) min
20:41:45 Start of injection 9 "V3 UPS", using instrument method "SODIO".
20:43:38 0.500 Log Pressure: 1029.68 [psi]
20:56:10 End of injection "V3 UPS".




1 4.21 Sodium BM 8.882 59.555 314.2647
2 5.79 Potassium MB 0.336 1.755 n.a.
3 7.66 Magnesium BM 0.304 0.809 n.a.
4 8.99 Calcium MB 1.636 3.923 n.a.
TOTAL: 11.16 66.04 314.26

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.991
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.991
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 59.555 6.159 6.236 5549 5678 1.160
2 5.787 Potassium 0.287 1.755 4.497 4.552 6497 6608 1.273
3 7.661 Magnesium 0.546 0.809 2.295 2.323 3151 3214 n.a.
4 8.991 Calcium 0.613 3.923 n.a. n.a. 3441 3503 1.314
AVERAGE: 0.418 16.511 4.317 4.370 4,660. 4,751. 1.249

10 V4 Audit Trail


(UTC-06:00) min
20:58:05 0.500 Log Pressure: 1029.87 [psi]




1 4.21 Sodium BM 8.862 59.412 313.4445
2 5.79 Potassium M 0.338 1.729 n.a.
3 7.66 Magnesium M 0.308 0.815 n.a.
4 8.99 Calcium MB 1.630 3.896 n.a.
TOTAL: 11.14 65.85 313.44

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.991
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.991
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 59.412 6.151 6.225 5547 5672 1.150
2 5.787 Potassium 0.288 1.729 4.481 4.535 6470 6574 1.277
3 7.657 Magnesium 0.547 0.815 2.299 2.326 3138 3200 n.a.
4 8.991 Calcium 0.613 3.896 n.a. n.a. 3438 3500 1.309
AVERAGE: 0.418 16.463 4.310 4.362 4,648. 4,737. 1.245

11 V5 Audit Trail


(UTC-06:00) min
21:12:32 0.500 Log Pressure: 1030.30 [psi]




1 4.21 Sodium BM 8.912 59.752 315.4196
2 5.79 Potassium M 0.327 1.680 n.a.
3 7.66 Magnesium M 0.292 0.771 n.a.
4 8.99 Calcium MB 1.551 3.709 n.a.
TOTAL: 11.08 65.91 315.42

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.991
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.991
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 59.752 6.150 6.225 5550 5672 1.148
2 5.787 Potassium 0.288 1.680 4.470 4.524 6465 6575 1.275
3 7.657 Magnesium 0.549 0.771 2.295 2.322 3115 3176 n.a.
4 8.991 Calcium 0.613 3.709 n.a. n.a. 3439 3499 1.302
AVERAGE: 0.419 16.478 4.305 4.357 4,642. 4,731. 1.241

12 V6 Audit Trail


(UTC-06:00) min
21:26:59 0.500 Log Pressure: 1030.99 [psi]




1 4.21 Sodium BM 8.880 59.520 314.1681
2 5.79 Potassium MB 0.325 1.687 n.a.
3 7.66 Magnesium BM 0.299 0.804 n.a.
4 8.99 Calcium MB 1.642 3.947 n.a.
TOTAL: 11.15 65.96 314.17

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.987
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.987
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 59.520 6.150 6.224 5541 5665 1.155
2 5.787 Potassium 0.288 1.687 4.499 4.548 6472 6574 1.287
3 7.657 Magnesium 0.543 0.804 2.301 2.327 3176 3229 n.a.
4 8.987 Calcium 0.612 3.947 n.a. n.a. 3447 3508 1.314
AVERAGE: 0.417 16.490 4.317 4.366 4,659. 4,744. 1.252

13 V7 Audit Trail


(UTC-06:00) min
21:41:26 0.500 Log Pressure: 1031.03 [psi]




1 4.21 Sodium BM 9.046 60.586 320.6986
2 5.79 Potassium M 0.344 1.766 n.a.
3 7.66 Magnesium M 0.310 0.821 n.a.
4 8.99 Calcium MB 1.711 4.099 n.a.
TOTAL: 11.41 67.27 320.70

70.0
1 - Sodium - 4.211
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.987
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.211
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.987
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.211 Sodium 0.226 60.586 6.139 6.212 5543 5667 1.133
2 5.791 Potassium 0.289 1.766 4.472 4.524 6445 6544 1.272
3 7.661 Magnesium 0.548 0.821 2.286 2.313 3129 3190 n.a.
4 8.987 Calcium 0.613 4.099 n.a. n.a. 3441 3502 1.311
AVERAGE: 0.419 16.818 4.299 4.350 4,640. 4,726. 1.239

14 V8 Audit Trail


(UTC-06:00) min
21:55:53 0.500 Log Pressure: 1031.41 [psi]




1 4.21 Sodium BM 9.009 60.384 319.2574
2 5.79 Potassium M 0.351 1.798 n.a.
3 7.66 Magnesium M 0.306 0.809 n.a.
4 8.99 Calcium MB 1.690 4.055 n.a.
TOTAL: 11.36 67.05 319.26

70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
20.0
4 - Calcium - 8.987
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



70.0
1 - Sodium - 4.207
µS
60.0
50.0
40.0
30.0
4 - Calcium - 8.987
20.0
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.207 Sodium 0.226 60.384 6.159 6.232 5544 5661 1.155
2 5.790 Potassium 0.288 1.798 4.467 4.521 6461 6567 1.271
3 7.657 Magnesium 0.548 0.809 2.293 2.320 3129 3191 n.a.
4 8.987 Calcium 0.613 4.055 n.a. n.a. 3442 3504 1.303
AVERAGE: 0.419 16.762 4.306 4.358 4,644. 4,731. 1.243

15 V9 Audit Trail


(UTC-06:00) min
22:10:19 0.500 Log Pressure: 1032.18 [psi]


Sample Name: BLANCO 2 Inj. Vol.: 500.00


TOTAL: 0.00 0.00 0.00
062116-CATIONES #16 BLANCO 2 ECD_1

0.0200
µS
0.0150
0.0100
0.0050
0.0000
-0.0050
-0.0100
min
-0.0150
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: BLANCO 2 Injection Volume: 500.00


0.0200
µS
0.0150
0.0100
0.0050
0.0000
-0.0050
-0.0100
min
-0.0150
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

16 BLANCO 2 Audit Trail


(UTC-06:00) min
22:22:53 Start of injection 16 "BLANCO 2", using instrument method "SODIO".
22:24:46 0.500 Log Pressure: 1031.45 [psi]
22:37:19 End of injection "BLANCO 2".


Sample Name: F1-3 Inj. Vol.: 500.00


1 4.18 Sodium BMB 0.015 0.101 n.a.
2 5.83 Potassium BMB* 0.000 0.003 n.a.
3 7.64 Magnesium BMB* 0.003 0.010 n.a.
4 9.02 Calcium BMB 0.121 0.287 n.a.
TOTAL: 0.14 0.40 0.00
062116-CATIONES #17 [manually integrated] F1-3 ECD_1

0.350
4 - Calcium - 9.021
µS
0.300
0.250
1 - Sodium - 4.184
0.200
0.150
0.100
0.050
0.000
-0.050
-0.100
-0.150
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: F1-3 Injection Volume: 500.00


0.350
4 - Calcium - 9.021
µS
0.300
1 - Sodium - 4.184
0.200
0.100
0.000
-0.100
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.184 Sodium 0.225 0.101 6.854 6.801 5526 5625 1.210
2 5.827 Potassium 0.254 0.003 5.238 5.132 8395 7951 1.211
3 7.637 Magnesium 0.437 0.010 2.627 2.627 4893 4695 1.339
4 9.021 Calcium 0.616 0.287 n.a. n.a. 3426 3496 1.337
AVERAGE: 0.383 0.100 4.906 4.853 5,560. 5,442. 1.274

17 F1-3 Audit Trail


(UTC-06:00) min
22:37:19 Start of injection 17 "F1-3", using instrument method "SODIO".
22:39:13 0.500 Log Pressure: 1030.99 [psi]
22:51:45 End of injection "F1-3".




1 3.61 Lithium BMB 0.310 1.715 n.a.
2 4.50 Sodium Ru* 148.645 616.647 581.2599
4 5.03 Ammonium Rd* 7.251 31.446 192.0899
6 6.00 Potassium Rd* 96.859 493.084 283.1533
7 7.62 Magnesium Rd* 47.342 123.198 94.6569
8 9.25 Calcium Rd* 8.799 21.071 20.7680
TOTAL: 309.21 1287.16 1171.93

700
2 - Sodium - 4.501
µS
600
500
400
300
200
8 - Calcium - 9.247
1 - Lithium - 3.614
100
3 - 4.751
5 - 5.424
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



700
2 - Sodium - 4.501
µS
600
500
400
300
8 - Calcium - 9.247
1 - Lithium - 3.614
200
3 - 4.751
5 - 5.424
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.614 Lithium 0.285 1.715 1.692 n.a. 2577 2595 1.141
3 4.751 1.059 9.530 1.005 n.a. 322 n.a. n.a.
5 5.424 0.282 6.101 n.a. n.a. 5922 n.a. n.a.
AVERAGE: 0.542 162.849 1.348 #DIV/0! 2,940. 2,595. 1.141

18 F2-3 Audit Trail


(UTC-06:00) min
11:39:57 Audit trail of injection "chrom://lenovo-pc/ChromeleonLocal/cationes/062116-CATIONESxxxxx.seq/108.smp". Execut
11:41:42 0.500 Log Pressure: 1109.07 [psi]

ESxxxxx.seq/108.smp". Executed 22/06/2016 on instrument ICS1100 (server Lenovo-PC).



1 3.61 Lithium BMB 0.320 1.772 n.a.
2 4.49 Sodium Ru* 143.953 605.453 562.8047
3 5.00 Ammonium Ru* 6.562 29.178 173.4943
5 5.99 Potassium Rd* 77.142 404.249 225.0424
6 7.60 Magnesium Rd* 46.057 123.624 92.0141
7 9.19 Calcium Rd* 12.173 30.104 32.1185
TOTAL: 286.21 1194.38 1085.47

700
2 - Sodium - 4.494
µS
600
500
400
300
200
7 - Calcium - 9.187
1 - Lithium - 3.607
100
4 - 5.444
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



700
2 - Sodium - 4.494
µS
600
500
400
300
7 - Calcium - 9.187
1 - Lithium - 3.607
200
4 - 5.444
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.607 Lithium 0.280 1.772 1.990 1.379 2653 2679 1.226
4 5.444 1.565 4.561 n.a. n.a. 194 83 1.040
AVERAGE: 0.923 171.277 1.990 1.379 1,424. 1,381. 1.133

19 F3-3 Audit Trail


(UTC-06:00) min
12:41:43 0.500 Log Pressure: 1116.11 [psi]




1 4.18 Sodium BMB 0.016 0.110 n.a.
2 5.82 Potassium BMB* 0.006 0.035 n.a.
3 7.65 Magnesium BMB* 0.006 0.021 n.a.
4 9.01 Calcium BMB 0.061 0.152 n.a.
TOTAL: 0.09 0.32 0.00

0.200
4 - Calcium - 9.014
µS
1 - Sodium - 4.184
0.150
0.100
0.050
0.000
-0.050
-0.100
min
-0.150
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.200
1 - Sodium - 4.184
4 - Calcium - 9.014
µS
0.150
0.100
0.050
0.000
-0.050
-0.100
min
-0.150
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.184 Sodium 0.226 0.110 6.438 6.452 5490 5554 1.210
2 5.821 Potassium 0.283 0.035 4.790 4.880 6790 6715 1.152
3 7.651 Magnesium 0.482 0.021 2.504 2.559 4039 4277 1.199
4 9.014 Calcium 0.607 0.152 n.a. n.a. 3525 3603 1.225
AVERAGE: 0.399 0.079 4.578 4.630 4,961. 5,037. 1.196

20 F4-3 Audit Trail


(UTC-06:00) min
22:52:15 0.000 Error cleared: Attempt to deliver an invalid vial.
22:53:53 0.500 Log Pressure: 1030.83 [psi]


Sample Name: E1-090616 Inj. Vol.: 500.00


1 4.28 Sodium Ru* 1.990 13.171 431.3167
3 4.86 Ammonium Rd 0.423 2.178 776.3121
4 6.04 Potassium MB 1.168 5.804 112.9162
5 7.82 Magnesium BMB* 0.807 1.857 n.a.
6 9.27 Calcium Rd* 3.517 8.343 299.3537
TOTAL: 7.91 31.35 1619.90
062116-CATIONES #21 [manually integrated] E1-090616 ECD_1

14.0
1 - Sodium - 4.284
µS
12.0
6 - Calcium - 9.274
10.0
8.0
6.0
4.0
2.0
2 - 4.581
0.0
min
-2.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: E1-090616 Injection Volume: 500.00

062116-CATIONES #21 [manually integrated] ECD_1

14.0
1 - Sodium - 4.284
µS
6 - Calcium - 9.274
12.0
10.0
8.0
6.0
4.0
2 - 4.581
2.0
0.0
min
-2.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
2 4.581 0.570 0.165 3.347 1.943 1033 230 n.a.
4 6.044 Potassium 0.304 5.804 4.142 4.183 6313 6403 1.251
5 7.824 Magnesium 0.555 1.857 n.a. n.a. 3177 3224 1.242
AVERAGE: 0.477 5.253 3.745 3.063 3,508. 3,286. 1.247

21 E1-090616 Audit Trail


(UTC-06:00) min
12:54:17 Start of injection 21 "E1-090616", using instrument method "SODIO".
12:56:11 0.500 Log Pressure: 1116.27 [psi]
13:08:43 End of injection "E1-090616".




1 4.18 Sodium BMb* 0.015 0.100 n.a.
2 4.75 Ammonium bMB* 0.000 0.002 n.a.
3 5.82 Potassium BMB* 0.006 0.035 n.a.
4 7.64 Magnesium BMB* 0.006 0.021 n.a.
5 9.00 Calcium BMB* 0.022 0.061 n.a.
TOTAL: 0.05 0.22 0.00
062116-CATIONES #22 [manually integrated] E2-090616 ECD_1

0.120
1 - Sodium - 4.181
µS
0.100
5 - Calcium - 9.001
0.080
0.060
0.040
0.020
0.000
-0.020
-0.040
min
-0.060
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.120
1 - Sodium - 4.181
µS
5 - Calcium - 9.001
0.100
0.080
0.060
0.040
0.020
0.000
-0.020
-0.040
min
-0.060
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.181 Sodium 0.226 0.100 2.052 2.119 5478 5567 1.199
2 4.751 Ammonium 0.330 0.002 3.475 3.563 3323 3632 1.209
3 5.817 Potassium 0.284 0.035 4.904 4.874 6702 6662 1.194
4 7.644 Magnesium 0.461 0.021 2.641 2.633 4403 4297 1.098
5 9.001 Calcium 0.567 0.061 n.a. n.a. 4036 4033 1.076
AVERAGE: 0.373 0.044 3.268 3.297 4,788. 4,838. 1.155



(UTC-06:00) min
23:08:26 0.500 Log Pressure: 1031.49 [psi]


Sample Name: BLANCO 3 Inj. Vol.: 500.00


TOTAL: 0.00 0.00 0.00

0.0200
µS
0.0175
0.0150
0.0125
0.0100
0.0075
0.0050
0.0025
0.0000
-0.0025
-0.0050
-0.0075
min
-0.0100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.0200
µS
0.0150
0.0100
0.0050
0.0000
-0.0050
min
-0.0100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

23 BLANCO 3 Audit Trail


(UTC-06:00) min
23:20:58 Start of injection 23 "BLANCO 3", using instrument method "SODIO".
23:22:52 0.500 Log Pressure: 1032.49 [psi]
23:35:25 End of injection "BLANCO 3".




1 4.28 Sodium BM 0.780 5.051 n.a.
2 4.85 Ammonium M 0.049 0.227 n.a.
3 6.05 Potassium M 0.509 2.495 n.a.
4 7.83 Magnesium Ru 0.278 0.771 n.a.
5 9.31 Calcium MB 0.721 1.573 n.a.
TOTAL: 2.34 10.12 0.00
062116-CATIONES #24 E14-1 ECD_1

6.00
1 - Sodium - 4.277
µS
5.00
4.00
3.00 5 - Calcium - 9.314

2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0


062116-CATIONES #24 E14-1 ECD_1

6.00
1 - Sodium - 4.277
µS
5.00
4.00
5 - Calcium - 9.314
3.00
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.277 Sodium 0.237 5.051 2.146 2.179 5210 5293 1.188
2 4.851 Ammonium 0.297 0.227 3.974 4.032 4262 4402 n.a.
3 6.047 Potassium 0.305 2.495 6.804 6.884 6286 6385 1.240
5 9.314 Calcium 0.655 1.573 n.a. n.a. 3234 3297 1.259
AVERAGE: 0.374 2.023 4.308 4.365 4,748. 4,844. 1.229



(UTC-06:00) min
13:10:38 0.500 Log Pressure: 1114.57 [psi]




1 4.27 Sodium BM 0.773 5.007 n.a.
2 4.85 Ammonium MB 0.050 0.234 n.a.
3 6.04 Potassium BM 0.515 2.545 n.a.
4 7.81 Magnesium M 0.289 0.775 n.a.
5 9.30 Calcium MB 0.686 1.580 n.a.
TOTAL: 2.31 10.14 0.00
062116-CATIONES #25 E14-2 ECD_1

6.00
1 - Sodium - 4.274
µS
5.00
4.00
3.00 5 - Calcium - 9.301

2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0


062116-CATIONES #25 E14-2 ECD_1

6.00
1 - Sodium - 4.274
µS
5.00
4.00
5 - Calcium - 9.301
3.00
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.274 Sodium 0.237 5.007 2.149 2.181 5210 5294 1.187
2 4.847 Ammonium 0.297 0.234 3.979 4.034 4273 4401 n.a.
3 6.044 Potassium 0.305 2.545 4.087 4.129 6289 6383 1.243
4 7.814 Magnesium 0.561 0.775 2.451 2.478 3101 3148 1.275
5 9.301 Calcium 0.652 1.580 n.a. n.a. 3256 3317 1.243
AVERAGE: 0.410 2.028 3.167 3.205 4,426. 4,509. 1.237



(UTC-06:00) min
13:25:06 0.500 Log Pressure: 1117.54 [psi]




1 4.27 Sodium BM 0.638 4.137 n.a.
2 4.85 Ammonium MB 0.053 0.252 n.a.
3 6.05 Potassium BM 0.375 1.868 n.a.
4 7.81 Magnesium M 0.223 0.599 n.a.
5 9.30 Calcium MB 0.633 1.464 n.a.
TOTAL: 1.92 8.32 0.00
062116-CATIONES #26 E16-1 ECD_1

5.00
1 - Sodium - 4.271
µS
4.00
3.00
5 - Calcium - 9.297
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0


062116-CATIONES #26 E16-1 ECD_1

5.00
1 - Sodium - 4.271
µS
4.00
5 - Calcium - 9.297
3.00
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.271 Sodium 0.237 4.137 2.175 2.207 5194 5280 1.200
2 4.847 Ammonium 0.293 0.252 4.017 4.071 4370 4501 n.a.
3 6.047 Potassium 0.304 1.868 4.070 4.115 6321 6410 1.223
4 7.811 Magnesium 0.562 0.599 2.451 2.479 3087 3145 1.279
5 9.297 Calcium 0.651 1.464 n.a. n.a. 3266 3319 1.233
AVERAGE: 0.410 1.664 3.178 3.218 4,448. 4,531. 1.234



(UTC-06:00) min
13:39:33 0.500 Log Pressure: 1118.85 [psi]




1 4.27 Sodium BM 0.668 4.327 n.a.
2 4.85 Ammonium M 0.049 0.227 n.a.
3 6.05 Potassium M 0.353 1.735 n.a.
4 7.81 Magnesium Ru 0.216 0.597 n.a.
5 9.29 Calcium MB 0.709 1.551 n.a.
TOTAL: 2.00 8.44 0.00
062116-CATIONES #27 E16-2 ECD_1

5.00
1 - Sodium - 4.274
µS
4.00
3.00
5 - Calcium - 9.294
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0


062116-CATIONES #27 E16-2 ECD_1

5.00
1 - Sodium - 4.274
µS
4.00
5 - Calcium - 9.294
3.00
2.00
1.00
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.274 Sodium 0.237 4.327 2.167 2.200 5206 5289 1.188
2 4.851 Ammonium 0.295 0.227 4.008 4.065 4320 4456 n.a.
3 6.054 Potassium 0.305 1.735 6.759 6.834 6296 6386 1.222
5 9.294 Calcium 0.653 1.551 n.a. n.a. 3236 3295 1.244
AVERAGE: 0.373 1.687 4.312 4.366 4,765. 4,857. 1.218



(UTC-06:00) min
13:54:00 0.500 Log Pressure: 1120.73 [psi]


Sample Name: S14-1 Inj. Vol.: 500.00


1 4.18 Sodium BMB 0.015 0.101 n.a.
2 4.74 Ammonium BMB* 0.000 0.001 n.a.
3 5.84 Potassium BMB* 0.001 0.003 n.a.
4 7.63 Magnesium BMB* 0.003 0.010 n.a.
5 9.01 Calcium BMB 0.100 0.249 n.a.
TOTAL: 0.12 0.36 0.00
062116-CATIONES #28 [manually integrated] S14-1 ECD_1

0.300
5 - Calcium - 9.011
µS
0.250
0.200
1 - Sodium - 4.184
0.150
0.100
0.050
0.000
-0.050
-0.100
-0.150
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: S14-1 Injection Volume: 500.00


0.300
5 - Calcium - 9.011
µS
0.200 1 - Sodium - 4.184
0.100 3 - Potassium - 5.844
0.000
-0.100
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.184 Sodium 0.225 0.101 2.895 2.776 5524 5612 1.215
2 4.737 Ammonium 0.157 0.001 4.691 4.570 14543 11547 1.166
3 5.844 Potassium 0.315 0.003 4.518 4.510 5518 5712 1.273
4 7.631 Magnesium 0.476 0.010 2.545 2.542 4107 3959 1.088
5 9.011 Calcium 0.608 0.249 n.a. n.a. 3511 3567 1.233
AVERAGE: 0.356 0.073 3.662 3.600 6,641. 6,079. 1.195

28 S14-1 Audit Trail


(UTC-06:00) min
23:36:02 Start of injection 28 "S14-1", using instrument method "SODIO".
23:37:40 0.500 Log Pressure: 1032.22 [psi]
23:50:12 End of injection "S14-1".




1 4.19 Sodium BMB 0.025 0.173 n.a.
2 4.74 Ammonium BMB* 0.002 0.012 n.a.
3 5.82 Potassium BMB* 0.008 0.044 n.a.
4 7.64 Magnesium BMB* 0.011 0.021 n.a.
5 9.01 Calcium BMB 0.048 0.123 n.a.
TOTAL: 0.09 0.37 0.00

0.200
1 - Sodium - 4.187
µS
5 - Calcium - 9.007
0.175
0.150
0.125
0.100
0.075
0.050
0.025
0.000
-0.025
-0.050
-0.075
min
-0.100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.200
1 - Sodium - 4.187
5 - Calcium - 9.007
µS
0.150
0.100
0.050
0.000
-0.050
min
-0.100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.187 Sodium 0.227 0.173 2.337 2.349 5430 5519 1.201
2 4.744 Ammonium 0.249 0.012 4.009 4.002 5806 5775 1.200
3 5.817 Potassium 0.286 0.044 3.961 4.225 6602 6522 1.205
4 7.644 Magnesium 0.636 0.021 2.205 2.328 2311 2790 0.700
5 9.007 Calcium 0.601 0.123 n.a. n.a. 3599 3660 1.182
AVERAGE: 0.400 0.075 3.128 3.226 4,750. 4,853. 1.098



(UTC-06:00) min
23:52:07 0.500 Log Pressure: 1031.72 [psi]


Sample Name: CO14-1 Inj. Vol.: 500.00


1 3.60 Lithium BM 0.115 0.776 n.a.
2 4.38 Sodium Ru* 53.071 308.119 5131.6765
3 4.95 Ammonium Ru* 5.505 23.903 3624.1348
5 5.98 Potassium Rd* 33.682 171.376 2423.8603
6 7.69 Magnesium Ru* 17.663 49.377 839.9679
7 9.21 Calcium M* 6.890 15.045 358.6003
TOTAL: 116.93 568.60 12378.24
062116-CATIONES #30 [manually integrated] CO14-1 ECD_1

350
2 - Sodium - 4.381
µS
300
250
200
150
100
7 - Calcium - 9.211
1 - Lithium - 3.604
50
8 - 10.861
4 - 5.387
min
-50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: CO14-1 Injection Volume: 500.00


350
2 - Sodium - 4.381
µS
300
250
200
150
7 - Calcium - 9.211
1 - Lithium - 3.604
100
8 - 10.861
4 - 5.387
50
min
-50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.604 Lithium 0.229 0.776 2.089 1.633 3952 4019 1.247
4 5.387 1.478 3.234 3.591 2.940 212 121 1.142
7 9.211 Calcium 0.651 15.045 1.968 n.a. 3205 3258 1.346
8 10.861 1.026 0.151 n.a. n.a. 1793 n.a. n.a.
AVERAGE: 0.846 71.498 2.549 2.286 2,291. 2,466. 1.245

30 CO14-1 Audit Trail


(UTC-06:00) min
14:06:33 Start of injection 30 "CO14-1", using instrument method "SODIO".
14:08:27 0.500 Log Pressure: 1120.54 [psi]
14:21:00 End of injection "CO14-1".




1 3.60 Lithium BM 0.116 0.781 n.a.
2 4.38 Sodium Ru* 53.443 309.819 5168.2921
3 4.95 Ammonium Ru* 5.521 23.982 3634.6200
5 5.98 Potassium Rd* 33.907 172.380 2440.4768
6 7.69 Magnesium Ru* 17.377 48.342 825.2626
7 9.25 Calcium M* 3.573 7.344 79.5987
TOTAL: 113.94 562.65 12148.25

350
2 - Sodium - 4.381
µS
300
250
200
150
100
7 - Calcium - 9.247
1 - Lithium - 3.604
50
8 - 10.871
4 - 5.387
min
-50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



350
2 - Sodium - 4.381
µS
300
250
200
150
7 - Calcium - 9.247
1 - Lithium - 3.604
100
8 - 10.871
4 - 5.387
50
min
-50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.604 Lithium 0.229 0.781 2.087 1.631 3955 4019 1.236
4 5.387 1.480 3.260 3.621 2.965 212 120 1.144
7 9.247 Calcium 0.652 7.344 2.052 n.a. 3220 3281 1.237
8 10.871 0.931 0.118 n.a. n.a. 2183 n.a. n.a.
AVERAGE: 0.823 70.753 2.586 2.298 2,393. 2,473. 1.206



(UTC-06:00) min
14:22:54 0.500 Log Pressure: 1120.54 [psi]




TOTAL: 0.00 0.00 0.00

0.0200
µS
0.0175
0.0150
0.0125
0.0100
0.0075
0.0050
0.0025
0.0000
-0.0025
-0.0050
-0.0075
min
-0.0100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.0200
µS
0.0150
0.0100
0.0050
0.0000
-0.0050
min
-0.0100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



(UTC-06:00) min
00:06:46 0.500 Log Pressure: 1032.18 [psi]


Sample Name: AG14-1 Inj. Vol.: 500.00


1 3.60 Lithium Ru* 0.308 1.783 n.a.
3 4.52 Sodium Ru* 189.299 704.970 741.1960
4 4.99 Ammonium Ru* 5.087 24.702 133.6642
5 5.99 Potassium Ru* 112.508 569.166 329.2747
6 7.54 Magnesium Ru* 55.066 142.664 110.5465
7 9.14 Calcium Rd* 13.693 32.689 37.2340
TOTAL: 375.96 1475.97 1351.92
062116-CATIONES #33 [manually integrated] AG14-1 ECD_1

800
3 - Sodium - 4.520
µS
700
600
500
400
300
7 - Calcium - 9.137
200
1 - Lithium - 3.597
100
2 - 8.694
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: AG14-1 Injection Volume: 500.00


800
3 - Sodium - 4.520
µS
700
600
500
400
300
7 - Calcium - 9.137
1 - Lithium - 3.597
200
2 - 8.694
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
2 8.694 5.431 0.646 n.a. n.a. 41 13 0.675
AVERAGE: 5.431 210.946 #DIV/0! #DIV/0! 41. 13. 0.675

33 AG14-1 Audit Trail


(UTC-06:00) min
14:35:27 Start of injection 33 "AG14-1", using instrument method "SODIO".
14:37:22 0.500 Log Pressure: 1120.04 [psi]
14:49:54 End of injection "AG14-1".




1 4.18 Sodium BMB 0.013 0.089 n.a.
3 5.83 Potassium BMB* 0.001 0.004 n.a.
4 7.63 Magnesium BMB* 0.007 0.012 n.a.
5 9.01 Calcium BMB 0.088 0.212 n.a.
TOTAL: 0.11 0.32 0.00

0.250
5 - Calcium - 9.007
µS
0.200
1 - Sodium - 4.184
0.150
0.100
0.050
2 - 4.707
0.000
-0.050
-0.100
-0.150
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.250
5 - Calcium - 9.007
µS
1 - Sodium - 4.184
0.200
0.150
0.100
2 - 4.707
0.050
0.000
-0.050
-0.100
-0.150
min
-0.200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.184 Sodium 0.223 0.089 2.611 2.185 5612 5645 1.192
2 4.707 0.178 0.001 5.262 4.180 11250 5340 3.000
3 5.831 Potassium 0.249 0.004 4.029 2.756 8740 6875 1.439
4 7.627 Magnesium 0.642 0.012 2.201 1.695 2255 884 0.715
5 9.007 Calcium 0.612 0.212 n.a. n.a. 3471 3531 1.276
AVERAGE: 0.381 0.064 3.526 2.704 6,266. 4,455. 1.524



(UTC-06:00) min
00:21:18 0.500 Log Pressure: 1031.95 [psi]


Sample Name: A14-1 Inj. Vol.: 500.00


1 3.60 Lithium BMB 0.317 1.726 n.a.
2 4.49 Sodium Ru* 155.973 632.450 610.0921
3 5.01 Ammonium Ru* 6.919 29.635 183.1321
5 5.98 Potassium Rd* 94.100 481.836 275.0216
6 7.56 Magnesium Ru* 48.020 126.009 96.0509
7 9.12 Calcium MB* 16.525 36.673 46.7608
TOTAL: 321.85 1308.33 1211.06
062116-CATIONES #35 [manually integrated] A14-1 ECD_1

700
2 - Sodium - 4.494
µS
600
500
400
300
200
7 - Calcium - 9.120
1 - Lithium - 3.597
100
4 - 5.454
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: A14-1 Injection Volume: 500.00


700
2 - Sodium - 4.494
µS
600
500
400
300
7 - Calcium - 9.120
1 - Lithium - 3.597
200
4 - 5.454
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.597 Lithium 0.290 1.726 1.943 1.375 2453 2470 1.116
4 5.454 1.620 5.065 3.213 2.392 181 81 n.a.
7 9.120 Calcium 0.662 36.673 n.a. n.a. 3033 3094 1.516
AVERAGE: 0.858 187.628 2.578 1.883 1,889. 1,882. 1.316

35 A14-1 Audit Trail


(UTC-06:00) min
14:49:55 Start of injection 35 "A14-1", using instrument method "SODIO".
14:51:49 0.500 Log Pressure: 1120.77 [psi]
15:04:21 End of injection "A14-1".




1 4.18 Sodium BMB 0.011 0.078 n.a.
2 4.72 Ammonium BMB* 0.000 0.001 n.a.
3 5.82 Potassium BMB* 0.001 0.003 n.a.
4 7.20 Magnesium BMB* 0.004 0.006 n.a.
5 9.01 Calcium BMB* 0.020 0.052 n.a.
TOTAL: 0.04 0.14 0.00

0.100
1 - Sodium - 4.181
µS
5 - Calcium - 9.007
0.080
0.060
0.040
0.020
0.000
-0.020
-0.040
-0.060
min
-0.080
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.100
1 - Sodium - 4.181
5 - Calcium - 9.007
µS
0.080
0.060
0.040
0.020
0.000
-0.020
-0.040
-0.060
min
-0.080
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.181 Sodium 0.224 0.078 2.412 2.195 5580 5671 1.190
2 4.721 Ammonium 0.224 0.001 4.149 3.845 7110 4847 1.372
3 5.821 Potassium 0.306 0.003 2.189 1.788 5780 5923 1.245
4 7.197 Magnesium 0.952 0.006 2.342 1.982 915 537 1.434
5 9.007 Calcium 0.594 0.052 n.a. n.a. 3681 3736 1.132
AVERAGE: 0.460 0.028 2.773 2.452 4,613. 4,143. 1.275



(UTC-06:00) min
00:35:49 0.500 Log Pressure: 1033.18 [psi]


Sample Name: Z14-1 Inj. Vol.: 500.00


1 4.18 Sodium BMB 0.011 0.079 n.a.
2 4.74 Ammonium BMB* 0.000 0.002 n.a.
3 5.81 Potassium BMB* 0.001 0.004 n.a.
4 7.21 Magnesium BMB* 0.007 0.009 n.a.
5 8.98 Calcium BMB* 0.011 0.030 n.a.
TOTAL: 0.03 0.12 0.00
062116-CATIONES #37 [manually integrated] Z14-1 ECD_1

0.100
1 - Sodium - 4.180
µS
0.080
0.060
5 - Calcium - 8.984
0.040
0.020
0.000
-0.020
-0.040
min
-0.060
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: Z14-1 Injection Volume: 500.00


0.100
1 - Sodium - 4.180
µS
0.080
5 - Calcium - 8.984
0.060
0.040
0.020
0.000
-0.020
-0.040
min
-0.060
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 4.180 Sodium 0.226 0.079 2.425 2.308 5490 5601 1.201
2 4.737 Ammonium 0.234 0.002 4.178 3.928 6585 5301 1.355
3 5.807 Potassium 0.279 0.004 1.896 1.720 6948 6595 1.561
4 7.207 Magnesium 1.198 0.009 2.022 1.862 579 458 1.304
5 8.984 Calcium 0.559 0.030 n.a. n.a. 4136 4022 1.106
AVERAGE: 0.499 0.025 2.630 2.455 4,748. 4,395. 1.306

37 Z14-1 Audit Trail


(UTC-06:00) min
00:48:22 Start of injection 37 "Z14-1", using instrument method "SODIO".
00:50:17 0.500 Log Pressure: 1033.41 [psi]
01:02:49 End of injection "Z14-1".




1 4.19 Sodium Ru* 0.732 4.978 n.a.
2 4.75 Ammonium Ru* 0.056 0.327 n.a.
3 5.80 Potassium Ru* 0.384 2.046 n.a.
4 7.64 Magnesium Ru* 0.183 0.540 n.a.
5 8.99 Calcium BMB* 0.133 0.212 n.a.
TOTAL: 1.49 8.10 0.00

6.00
1 - Sodium - 4.194
µS
5.00
4.00
3.00
2.00
5 - Calcium - 8.994
1.00
0.00
min
-1.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



6.00
1 - Sodium - 4.194
µS
5.00
4.00
3.00
5 - Calcium - 8.994
2.00
1.00
0.00
min
-1.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
5 8.994 Calcium 0.604 0.212 n.a. n.a. 3549 3616 1.163
AVERAGE: 0.604 1.621 #DIV/0! #DIV/0! 3,549. 3,616. 1.163



(UTC-06:00) min
01:04:44 0.500 Log Pressure: 1033.61 [psi]


Sample Name: CA14-1 Inj. Vol.: 500.00


1 3.58 Lithium BMB 0.014 0.099 n.a.
2 4.21 Sodium Ru* 9.076 61.850 32.1862
3 4.76 Ammonium Ru* 0.595 3.241 12.3913
5 5.77 Potassium Rd* 6.219 33.280 16.0146
6 7.63 Magnesium Ru* 1.515 4.440 0.3784
8 8.99 Calcium Rd* 0.304 0.810 n.a.
TOTAL: 17.72 103.72 60.97
062116-CATIONES #39 [manually integrated] CA14-1 ECD_1

70.0
2 - Sodium - 4.211
µS
60.0
50.0
40.0
30.0
20.0
8 - Calcium - 8.991
1 - Lithium - 3.584
10.0
4 - 5.301
7 - 8.587
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0

Sample Name: CA14-1 Injection Volume: 500.00


70.0
2 - Sodium - 4.211
µS
60.0
50.0
40.0
30.0
8 - Calcium - 8.991
1 - Lithium - 3.584
20.0
4 - 5.301
7 - 8.587
10.0
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.584 Lithium 0.218 0.099 2.147 1.327 4315 4376 1.203
4 5.301 1.381 0.093 2.764 1.417 236 80 0.976
7 8.587 0.998 0.043 n.a. n.a. 1185 228 0.993
AVERAGE: 0.866 12.982 2.455 1.372 1,912. 1,561. 1.057

39 CA14-1 Audit Trail


(UTC-06:00) min
01:17:16 Start of injection 39 "CA14-1", using instrument method "SODIO".
01:19:11 0.500 Log Pressure: 1034.38 [psi]
01:31:43 End of injection "CA14-1".




1 3.58 Lithium BMB 0.009 0.064 n.a.
2 4.20 Sodium Ru* 6.226 42.501 20.9772
4 4.75 Ammonium Rd* 0.401 2.274 7.1752
5 5.76 Potassium Ru* 9.313 51.094 25.1326
8 7.64 Magnesium Rd* 0.818 2.398 n.a.
9 8.99 Calcium Rd* 0.209 0.550 n.a.
TOTAL: 16.98 98.88 53.28

60.0
µS
2 - Sodium - 4.204
50.0
40.0
30.0
20.0
9 - Calcium - 8.991
1 - Lithium - 3.584
10.0
6 - 6.251
3 - 4.567
7 - 6.907
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



60.0
2 - Sodium - 4.204
µS
50.0
40.0
30.0
20.0
9 - Calcium - 8.991
1 - Lithium - 3.584
10.0
6 - 6.251
3 - 4.567
7 - 6.907
0.0
min
-10.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.584 Lithium 0.218 0.064 1.890 1.328 4319 4405 1.193
3 4.567 0.823 0.325 2.061 1.546 493 207 1.148
6 6.251 0.811 0.539 1.050 n.a. 950 747 n.a.
7 6.907 0.440 0.065 n.a. n.a. 3942 n.a. n.a.
AVERAGE: 0.573 11.090 1.667 1.437 2,426. 1,786. 1.171



(UTC-06:00) min
01:33:37 0.500 Log Pressure: 1034.80 [psi]




TOTAL: 0.00 0.00 0.00

0.0100
µS
0.0000
-0.0100
-0.0200
-0.0300
-0.0400
-0.0500
-0.0600
min
-0.0700
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



0.0100
µS
0.0000
-0.0100
-0.0200
-0.0300
-0.0400
-0.0500
-0.0600
min
-0.0700
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



(UTC-06:00) min
15:06:17 0.500 Log Pressure: 1119.35 [psi]




1 4.27 Sodium Ru* 0.604 4.002 n.a.
2 4.85 Ammonium Ru* 0.154 0.824 126.0993
3 6.04 Potassium Ru* 0.363 1.827 n.a.
4 7.80 Magnesium Ru* 0.245 0.682 n.a.
6 9.29 Calcium Rd* 0.525 1.245 n.a.
TOTAL: 1.89 8.58 126.10

5.00
1 - Sodium - 4.267
µS
4.00
3.00
6 - Calcium - 9.291
2.00
1.00
5 - 8.694
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



5.00
1 - Sodium - 4.267
µS
4.00
6 - Calcium - 9.291
3.00 2 - Ammonium - 4.851
2.00
1.00
5 - 8.694
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
5 8.694 2.989 0.016 n.a. n.a. 135 134 0.698
AVERAGE: 2.989 1.432 #DIV/0! #DIV/0! 135. 134. 0.698



(UTC-06:00) min
15:20:44 0.500 Log Pressure: 1119.15 [psi]




1 4.27 Sodium Ru* 0.641 4.242 n.a.
2 4.85 Ammonium Rd* 0.151 0.812 106.7508
4 6.04 Potassium Rd* 0.368 1.849 n.a.
5 7.80 Magnesium Ru 0.240 0.668 n.a.
7 9.29 Calcium Rd* 0.579 1.368 n.a.
TOTAL: 1.98 8.94 106.75

5.00
1 - Sodium - 4.271
µS
4.00
3.00
7 - Calcium - 9.287
2.00
1.00
3 - 4.634
6 - 8.704
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



5.00
1 - Sodium - 4.271
µS
4.00
7 - Calcium - 9.287
3.00 2 - Ammonium - 4.851
2.00
1.00
3 - 4.634
6 - 8.704
0.00
-1.00
min
-2.00
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
3 4.634 2.048 0.035 1.396 1.409 82 153 n.a.
6 8.704 3.783 0.020 n.a. n.a. 85 66 n.a.
AVERAGE: 2.916 1.285 1.396 1.409 84. 110. #DIV/0!



(UTC-06:00) min
15:35:11 0.500 Log Pressure: 1119.50 [psi]




1 3.61 Lithium BMB 0.387 2.004 0.0732
2 4.52 Sodium Ru* 179.518 687.645 702.7175
3 4.99 Ammonium Ru* 5.094 24.905 133.8609
4 5.98 Potassium Ru* 100.252 512.296 293.1534
5 7.57 Magnesium Ru* 51.309 134.170 102.8186
7 9.13 Calcium Rd* 14.058 36.024 38.4593
TOTAL: 350.62 1397.04 1271.08

800
2 - Sodium - 4.520
µS
700
600
500
400
300
7 - Calcium - 9.134
200
1 - Lithium - 3.607
100
6 - 8.877
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



800
2 - Sodium - 4.520
µS
700
600
500
400
300
7 - Calcium - 9.134
1 - Lithium - 3.607
200
6 - 8.877
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.607 Lithium 0.305 2.004 10.116 7.240 2238 2284 1.091
6 8.877 0.737 4.043 n.a. n.a. 2322 941 0.880
AVERAGE: 0.521 200.155 10.116 7.240 2,280. 1,613. 0.986



(UTC-06:00) min
17:30:07 0.500 Log Pressure: 1107.37 [psi]




1 3.60 Lithium BMB 0.368 1.936 0.0498
2 4.51 Sodium Ru* 172.150 670.560 673.7312
3 4.99 Ammonium Ru* 5.865 26.209 154.6807
4 5.97 Potassium Ru* 98.595 505.092 288.2705
5 7.57 Magnesium Ru* 49.151 129.259 98.3780
7 9.11 Calcium Rd* 16.902 41.681 48.0299
TOTAL: 343.03 1374.74 1263.14

800
2 - Sodium - 4.510
µS
700
600
500
400
300
7 - Calcium - 9.114
200
1 - Lithium - 3.604
100
6 - 8.830
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



800
2 - Sodium - 4.510
µS
700
600
500
400
300
7 - Calcium - 9.114
1 - Lithium - 3.604
200
6 - 8.830
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.604 Lithium 0.301 1.936 9.697 6.451 2291 2318 1.069
6 8.830 0.777 2.379 n.a. n.a. 2068 710 0.648
AVERAGE: 0.539 196.731 9.697 6.451 2,180. 1,514. 0.858



(UTC-06:00) min
17:44:42 0.500 Log Pressure: 1109.57 [psi]




2 4.57 Sodium Ru* 284.339 851.108 1115.0893
3 5.00 Ammonium Ru* 4.023 21.516 104.9597
4 6.01 Potassium Ru* 169.749 802.094 497.9791
5 7.48 Magnesium Ru* 79.848 194.470 161.5307
6 9.16 Calcium Rd* 12.683 30.591 33.8343
TOTAL: 550.64 1899.78 1913.39

1,000
2 - Sodium - 4.574
µS
900
800
700
600
500
400
300
6 - Calcium - 9.160
200
1 - 8.744
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



1,000
2 - Sodium - 4.574
µS
875
750
625
500
375
6 - Calcium - 9.160
250
1 - 8.744
125
0
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 8.744 6.132 0.551 n.a. n.a. 33 13 0.650
AVERAGE: 6.132 316.722 #DIV/0! #DIV/0! 33. 13. 0.650



(UTC-06:00) min
16:18:31 0.500 Log Pressure: 1116.30 [psi]




1 3.60 Lithium BMB 0.306 1.677 n.a.
2 4.49 Sodium Ru* 154.777 630.187 605.3858
3 5.01 Ammonium Ru* 6.945 29.617 183.8337
5 5.98 Potassium Rd* 94.096 483.559 275.0106
6 7.57 Magnesium Ru* 48.231 125.294 96.4854
7 9.14 Calcium MB* 15.120 33.617 42.0346
TOTAL: 319.47 1303.95 1202.75

700
2 - Sodium - 4.494
µS
600
500
400
300
200
7 - Calcium - 9.144
1 - Lithium - 3.601
100
4 - 5.454
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



700
2 - Sodium - 4.494
µS
600
500
400
300
7 - Calcium - 9.144
1 - Lithium - 3.601
200
4 - 5.454
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.601 Lithium 0.288 1.677 1.949 1.380 2505 2520 1.112
4 5.454 1.615 5.087 3.248 2.420 183 82 n.a.
7 9.144 Calcium 0.658 33.617 n.a. n.a. 3093 3151 1.485
AVERAGE: 0.853 187.005 2.598 1.900 1,927. 1,918. 1.299



(UTC-06:00) min
16:32:59 0.500 Log Pressure: 1114.57 [psi]




1 3.61 Lithium Ru* 0.356 1.624 0.0367
3 4.97 Ammonium Ru* 0.942 6.618 21.7749
4 5.98 Potassium Ru* 111.441 565.362 326.1312
5 7.61 Magnesium Ru* 40.239 106.549 80.0445
7 9.17 Calcium Rd* 10.917 27.722 27.8919
TOTAL: 163.90 707.88 455.88

1,000
2 - 4.621
µS
900
800
700
600
500
400
300
7 - Calcium - 9.167
1 - Lithium - 3.611
200
6 - 8.877
100
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



1,000
2 - 4.621
µS
875
750
625
500
375
7 - Calcium - 9.167
1 - Lithium - 3.611
250
6 - 8.877
125
0
min
-100
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
2 4.621 n.a. 908.841 n.a. n.a. n.a. n.a. n.a.
6 8.877 0.757 2.005 n.a. n.a. 2201 768 0.641
AVERAGE: 0.757 231.246 #DIV/0! #DIV/0! 2,201. 768. 0.641



(UTC-06:00) min
16:47:26 0.500 Log Pressure: 1112.76 [psi]




1 3.58 Lithium BM 0.007 0.047 n.a.
2 4.20 Sodium Ru* 4.642 31.765 14.7431
3 4.75 Ammonium Ru* 0.343 1.939 5.6106
4 5.76 Potassium Ru* 7.389 40.625 19.4638
7 7.64 Magnesium Rd* 0.566 1.659 n.a.
8 8.99 Calcium Rd* 0.144 0.381 n.a.
TOTAL: 13.09 76.42 39.82

45.0
µS
2 - Sodium - 4.201
40.0
35.0
30.0
25.0
20.0
15.0
8 - Calcium - 8.991
10.0
1 - Lithium - 3.584
5 - 6.244
5.0
6 - 6.914
0.0
min
-5.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



45.0
2 - Sodium - 4.201
µS
40.0
30.0
20.0
8 - Calcium - 8.991
1 - Lithium - 3.584
10.0
5 - 6.244
6 - 6.914
0.0
min
-5.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.584 Lithium 0.218 0.047 5.115 4.568 4343 4434 1.250
5 6.244 0.823 0.469 0.939 n.a. 922 688 n.a.
6 6.914 0.605 0.074 n.a. n.a. 2092 n.a. n.a.
AVERAGE: 0.548 9.620 3.027 4.568 2,452. 2,561. 1.250



(UTC-06:00) min
01:48:45 0.500 Log Pressure: 1034.76 [psi]




1 4.19 Sodium Ru* 0.291 1.977 n.a.
2 4.75 Ammonium Ru* 0.026 0.152 n.a.
3 5.80 Potassium Ru* 0.380 2.021 n.a.
4 7.64 Magnesium BMB* 0.074 0.166 n.a.
TOTAL: 0.77 4.32 0.00

2.50
1 - Sodium - 4.194
µS
2.25
2.00
1.75
1.50
1.25
1.00
0.75
0.50
0.25
0.00
-0.25
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



2.50
1 - Sodium - 4.194
µS
2.00
1.50
1.00
0.50
0.00
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
4 7.644 Magnesium 0.528 0.166 n.a. n.a. 3356 3422 1.082
AVERAGE: 0.528 1.079 #DIV/0! #DIV/0! 3,356. 3,422. 1.082



(UTC-06:00) min
02:03:11 0.500 Log Pressure: 1035.07 [psi]




1 3.61 Lithium BMB 0.165 0.887 n.a.
2 4.48 Sodium Ru* 145.913 607.012 570.5129
3 4.94 Ammonium Ru* 3.249 16.114 84.0643
4 6.12 Potassium Ru* 320.599 1185.337 942.5723
7 7.77 Magnesium Rd* 14.565 42.195 27.2260
8 9.27 Calcium MB 5.639 13.389 10.1359
TOTAL: 490.13 1864.93 1634.51

1,400
µS 4 - Potassium - 6.124
1,200
1,000
2 - Sodium - 4.481
800
600
400
8 - Calcium - 9.267
1 - Lithium - 3.607
200
5 - 6.574
6 - 7.264
min
-200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



1,400
µS
1,200
2 - Sodium - 4.481
1,000
800
600
8 - Calcium - 9.267
1 - Lithium - 3.607
400
5 - 6.574
6 - 7.264
200
min
-200
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
1 3.607 Lithium 0.298 0.887 4.687 4.354 2351 2328 1.070
5 6.574 0.968 15.032 0.927 n.a. 738 607 n.a.
6 7.264 0.520 2.774 3.458 n.a. 3125 n.a. n.a.
8 9.267 Calcium 0.639 13.389 n.a. n.a. 3367 3416 1.344
AVERAGE: 0.606 235.342 3.024 4.354 2,395. 2,117. 1.207



(UTC-06:00) min
17:01:52 0.500 Log Pressure: 1111.84 [psi]




1 4.19 Sodium Ru* 0.413 2.809 n.a.
2 4.75 Ammonium Ru* 0.031 0.182 n.a.
3 5.80 Potassium Ru* 0.546 2.904 n.a.
5 7.64 Magnesium Rd* 0.073 0.222 n.a.
6 8.99 Calcium BMB* 0.017 0.049 n.a.
TOTAL: 1.08 6.17 0.00

3.50
1 - Sodium - 4.194
3.00
2.50
2.00
1.50
1.00
6 - Calcium - 8.987
0.50
4 - 7.257
0.00
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



3.50
1 - Sodium - 4.194
µS
3.00
2.50
2.00
1.50
6 - Calcium - 8.987
1.00
4 - 7.257
0.50
0.00
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
4 7.257 1.330 0.007 1.841 1.388 476 221 0.681
6 8.987 Calcium 0.550 0.049 n.a. n.a. 4278 4279 1.199
AVERAGE: 0.940 1.029 1.841 1.388 2,377. 2,250. 0.940



(UTC-06:00) min
02:17:44 0.500 Log Pressure: 1035.15 [psi]




1 4.19 Sodium Ru* 0.379 2.575 n.a.
2 4.75 Ammonium Ru* 0.027 0.156 n.a.
3 5.80 Potassium Ru* 0.463 2.461 n.a.
5 7.64 Magnesium Rd* 0.071 0.212 n.a.
6 8.99 Calcium BMB* 0.016 0.047 n.a.
TOTAL: 0.96 5.45 0.00

3.00
1 - Sodium - 4.194
2.50
2.00
1.50
1.00
6 - Calcium - 8.987
0.50
4 - 7.097
0.00
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0



3.00
1 - Sodium - 4.194
µS
2.50
2.00
1.50
6 - Calcium - 8.987
1.00
0.50
4 - 7.097
0.00
min
-0.50
0.0 2.0 4.0 6.0 8.0 10.0 12.0 13.0
4 7.097 2.569 0.007 1.213 1.615 122 250 0.933
6 8.987 Calcium 0.548 0.047 n.a. n.a. 4304 4273 1.093
AVERAGE: 1.558 0.910 1.213 1.615 2,213. 2,262. 1.013



(UTC-06:00) min
02:32:11 0.500 Log Pressure: 1035.30 [psi]
02:41:35 9.899 Eluent level is below 200 milliliters.
02:41:39 9.976 Error cleared: Eluent level is below 200 milliliters.


Sample Name: BLANCO Inj. Vol.: 500.00

Program: Apagado Operator: Lenovo
Inj. Date / Time: 22-jun-2016 / 17:57 Run Time: n.a.

min n.a. n.a. n.a.
TOTAL: 0.00 0.00 0.00
Channel ECD_1 is not available for injection #54 - BLANCO .

Sample Name: BLANCO Injection Volume: 500.00

Instrument Method: Apagado Operator: Lenovo
Inj. Date / Time: 22-jun-2016 / 17:57 Run Time: n.a.
Channel ECD_1 is not available for injection #54 - BLANCO .
min min n.a. (USP) (EP) (USP) (EP)

54 BLANCO Audit Trail
Sample Name: BLANCO Injection Volume: 500.00

Vial Position: 50 Channel: n.a.
Instrument Method: Apagado Bandwidth: n.a.
Run Time (min): n.a. Int STD Amount: 1.0000

(UTC-06:00) min
17:57:15 Start of injection 54 "BLANCO ", using instrument method "Apagado".
17:57:15 0.000 Pump_ECD.%A.Equate = "%A"
17:57:15 0.000 Sampler.DeliverSample
17:57:15 0.000 The total volume has been reduced to 5000 µL.
17:57:40 0.000 Attempt to deliver an invalid vial.
17:57:40 0.000 Injection aborted (because an error has occurred).
17:57:40 End of injection "BLANCO ".



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Logged on User: Lenovo Page 1 of 216

Instrument: ICS1100 22/6/2016 6:37 p.m.

Peak Integration Report

Sample Name: CAL1 Inj. Vol.: 500.00

No. Time Peak Name Peak Type Area Height Amount

062116-CATIONES #1 [manually integrated] CAL1 ECD_1

Chromeleon (c) Dionex 1996-2009

Peak Analysis Report

Sample Name: CAL1 Injection Volume: 500.00

062116-CATIONES #1 [manually integrated] CAL1 ECD_1

10.0 4 - Ammonium - 4.834

Chromeleon (c) Dionex 1996-2009

1 CAL1 Audit Trail

Sample Name: CAL1 Injection Volume: 500.00

Day Time Ret. Time Command/Message

Chromeleon (c) Dionex 1996-2009

ES.seq/528.smp". Executed 31/05/2016 on instrument ICS1100 (server Lenovo-PC).

Chromeleon (c) Dionex 1996-2009

Peak Integration Report

Sample Name: CAL2 Inj. Vol.: 500.00

No. Time Peak Name Peak Type Area Height Amount

062116-CATIONES #2 [manually integrated, 2 peak(s) manually assigned] ECD_1

Chromeleon (c) Dionex 1996-2009

Peak Analysis Report

Sample Name: CAL2 Injection Volume: 500.00

062116-CATIONES #2 [manually integrated, 2 peak(s) manually assigned] ECD_1

25.0 1 - Lithium - 3.591

Chromeleon (c) Dionex 1996-2009

2 CAL2 Audit Trail

Sample Name: CAL2 Injection Volume: 500.00

Day Time Ret. Time Command/Message

Chromeleon (c) Dionex 1996-2009

ES.seq/122.smp". Executed 31/05/2016 on instrument ICS1100 (server Lenovo-PC).

Chromeleon (c) Dionex 1996-2009

Peak Integration Report

Sample Name: CAL3 Inj. Vol.: 500.00

No. Time Peak Name Peak Type Area Height Amount

062116-CATIONES #3 [manually integrated] CAL3 ECD_1

Chromeleon (c) Dionex 1996-2009

Peak Analysis Report

Sample Name: CAL3 Injection Volume: 500.00

062116-CATIONES #3 [manually integrated] CAL3 ECD_1

Chromeleon (c) Dionex 1996-2009

3 CAL3 Audit Trail

Sample Name: CAL3 Injection Volume: 500.00

Day Time Ret. Time Command/Message

Chromeleon (c) Dionex 1996-2009

ES.seq/906.smp". Executed 31/05/2016 on instrument ICS1100 (server Lenovo-PC).

Chromeleon (c) Dionex 1996-2009

Peak Integration Report

Sample Name: CAL4 Inj. Vol.: 500.00

No. Time Peak Name Peak Type Area Height Amount

062116-CATIONES #4 [manually integrated, 1 peak(s) manually assigned] ECD_1

Chromeleon (c) Dionex 1996-2009

Peak Analysis Report

Sample Name: CAL4 Injection Volume: 500.00

062116-CATIONES #4 [manually integrated, 1 peak(s) manually assigned] ECD_1

Chromeleon (c) Dionex 1996-2009

4 CAL4 Audit Trail

Sample Name: CAL4 Injection Volume: 500.00

Day Time Ret. Time Command/Message

Chromeleon (c) Dionex 1996-2009