Asap Cair 1

Logged on User: LAB Terpadu IPB
Page 1 of 37
Instrument: GCMS_ISQLT_Manual
10/19/2021 00:24:57
Sequence: 04102021
Peak Integration Report
Sample Name: Asap Cair 1 Inj. Vol.: 10.00

Injection Type: Unknown Dilution Factor: 1.0000
Instrument Method: ASAP CAIR PENELITIAN Operator: LAB Terpadu IPB
Inj. Date / Time: 04-Oct-2021 / 12:03 Run Time: 32.01
No. Time Peak Name Peak Type Area Height Rel.Area

min counts*min counts %
1 1.40 Methyl formate BM 7252955.204 295361499.993 2.69
2 1.44 Acetic acid M 18696177.113 609267784.944 6.92
3 1.51 Propanoic acid MB 8727407.871 128392844.263 3.23
4 1.69 Propanedinitrile, Rd 5931594.908 92276113.919 2.20
5 1.96 Furfural BM 9600573.826 225750345.839 3.55
6 2.02 2-Furanmethanol MB 3000122.356 60981662.537 1.11
7 2.37 4,4-Dimethyl-2-c BM 2736297.284 55834967.033 1.01
15.448
8 2.43 2H-Pyran, tetrah MB 1085865.150 28438049.996 0.40
- -13.941
9 2.70 2-Butanone, 1-(ac BMB 871225.648
9.054
16034909.500
8.465 0.32
10 2.88 Phenol BM * 134170442.427 2483431950.937 49.67
11 3.14 Phosphonic acid, M* 842198.745 5.966- 9.666 18427674.690 0.31
5.006
12 3.25 Cyclohexanol, 3, MB* 3665660.493 44308920.547 1.36
13 3.56 1,2-Cyclopentane BMB 1468367.648 26243640.797 0.54
2.428
14 3.78 2-Cyclopenten-1- BMB 1146310.648 27230834.013 0.42

4.643
6.986
-7.669 -
3.775
15 3.89 Phenol, 2-methyl BMB 8302305.026 170732109.397 3.07

3.139
3.564
butoxide
1,2,3-trimethoxy-5-methyl- -
16 4.22 Phenol, 3-methyl BM 14700699.900 279149009.684 5.44

2-Tridecyl-2-oxazoline
3,5-Dimethoxy-4-hydroxytoluene 2.371
17 4.37 2,4-Heptadienal, MB 816185.610 15994294.330 0.30

5.632
-
3.248
18 4.58 Phenol, 2-methox BM 14198846.451

5.374
357404003.634 5.26
4.585
Homosyringaldehyde -4.826
--4.370
30 - Eugenol - 7.741
1.690
19 4.64 1-Ethyl-2-hydrox M 731583.890 20002961.762 0.27

3-ethyl-2-hydroxy-
2.697
-5.608
-
20 4.83 Phenol, 2,3-dimet MB 780767.242 9687872.829 0.29

4.224
- 5.214
ydro-2-(12-pentadecynyloxy)-
--3.894 -
- -
21 5.01 2-Cyclopenten-1- BMB 630307.076 16174013.390 0.23

6.013
yl-2-hydroxymethylimidazole
4-ethyl-2-methoxy-
2,6-dimethoxy-
2,3-dimethyl-
22 5.21 Phenol, 2-ethyl- BMB 814837.865 25394736.922 0.30

- -2.024
(p-hydroxyphenyl)-
3-methyl- -
23 5.37 Phenol, 2,4-dimet BMB 2517455.549 57950219.444 0.93

ethyl-2-cyclopenten-1-one -
24 5.61 Phenol, 4-ethyl- BM 1587845.201 59528576.183 0.59

-Piperonyl
- 1.510
1.401
-
-3,4-dimethyl-
10 - Phenol - 2.884
-
2,3-dimethyl-
25 5.63 Phenol, 2,3-dimet MB 1842211.856 56363105.019 0.68

3,5-dimethyl-
2,4-dimethyl-
2-methoxy-
-2,3-dimethyl-
(E,E)- -
26 5.97 Phenol, 3,4-dimet BM 707083.322 18081457.865 0.26

(acetyloxy)methyl- 1.439
1.959
1-(acetyloxy)-
-4-ethyl- -
27 6.01 Creosol MB 5532236.519 206995313.268 2.05

3-methyl-
2-ethyl-
2-methyl-
28 6.99 Phenol, 4-ethyl- BMB 3373554.532 149887038.618 1.25

Creosol
29 7.67 Phenol, 2,6-dime BM 6502022.229 302377359.479 2.41

2-Furanmethanol
30 7.74 Eugenol MB 580976.593 19896348.592 0.22

-
31 8.47 3,5-Dimethoxy-4 BMB 3048292.162 135865271.998 1.13

acid
clopentanedione,
2,4-Heptadienal, formate
-
32 9.05 Benzene, 1,2,3-t BMB 1999296.082 109589443.226 0.74

33 9.67 Homosyringalde BMB 649154.029 31290305.678 0.24
acid
Furfural
34 13.94 2-Tridecyl-2-oxaz BMB 500275.649 10645735.640 0.19

Phenol,
penten-1-one,
-Phenol, 35
35 15.45 Piperonyl butoxi BMB 1086019.607 40382707.343 0.40

Propanoic
Phenol,
TOTAL: 270097155.71 6205373083.31 100.00

nten-1-one,
Phenol,
04102021
Asap
#3 [manually
Cair 1 TICintegrated]
TIC
Phenol,
- Phenol,
3.0e9
Phenol,
Phenol, -27
Acetic
lohexanol,
Phenol,
counts
-Phenol, 34
Methyl
Phenol,
utanone, 5--33
acid,
2.5e9
nzene,
-24
itrile, -
---22
-
Chromeleon (c) Dionex 1996-2009

550648646.xlsx/Integration
2.0e9
-
-
Version 7.2.10.23925
29
nic
-16
18 2
15
63356
-
Sequence: 04102021
10 - P
0.0e0
5.0e8
1.0e9
1.5e9
2.0e9
2.5e9
3.0e9
counts
-5.0e8
04102021
8 - 2H-Pyran, tetrahydro-2-(12-p
2 - Acetic
Asap
421 - 32 -
31Benzene,
2-Cyclopenten-1-one,
-
Propanedinitrile,
-1114
713 Phosphonic
--19 29
18 -
2-Cyclopenten-1-on
-4,4-Dimethyl-2-cyclo
28 - -
Phenol,
- -1,2-Cyclopentaned
1-Ethyl-2-hydroxy 1,2,
Phenol
3,5-Dimeth
Phenol,
(acetyl
acid, (p-
4-
12 - 116 - -
Cyclohexanol,
15
9 - 2-Butanone, - Phenol,
Methyl
Phenol, for
1-(
23
25
-26
1720 -
- Phenol,
Phenol,
2,4-Heptadi
-Phenol,
Propanoi
2-Furanm
24
63 --22 5--3334
Phenol,
FurfH
-27
Phen
-Phen -2
3
#3 [manually TIC

Version 7.2.10.23925
10/19/2021 00:24:57
Page 2 of 37
min
0.0 5.0 10.0 15.0 20.0 25.0 30.0
Cair 1 TICintegrated]
32.0
Page 3 of 37
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Sequence: 04102021
C
grated]

Version 7.2.10.23925
C
grated]
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Sequence: 04102021
min
0 30.0
32.0

Version 7.2.10.23925
Page 5 of 37
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Sequence: 04102021
Calibration Batch Report
Sequence: 04102021 Injection Volume: 10.00

Calibration Summary
Peak Name Eval.Type Cal.Type Points Offset Slope Curve Coeff.Det.
(C0) (C1) (C2) %
Methyl formate Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Acetic acid Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Propanoic acid Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Propanedinitrile, (acetyloxy)met Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Furfural Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2-Furanmethanol Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
4,4-Dimethyl-2-cyclopenten-1- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2H-Pyran, tetrahydro-2-(12-pen Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2-Butanone, 1-(acetyloxy)- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phosphonic acid, (p-hydroxyphe Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Cyclohexanol, 3,5-dimethyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
1,2-Cyclopentanedione, 3-meth Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2-Cyclopenten-1-one, 2,3-dimet Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 2-methyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 3-methyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2,4-Heptadienal, (E,E)- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 2-methoxy- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
1-Ethyl-2-hydroxymethylimidaz Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 2,3-dimethyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2-Cyclopenten-1-one, 3-ethyl-2 Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 2-ethyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 4-ethyl- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Creosol Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 4-ethyl-2-methoxy- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Phenol, 2,6-dimethoxy- Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Eugenol Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
3,5-Dimethoxy-4-hydroxytolue Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Benzene, 1,2,3-trimethoxy-5-me Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Homosyringaldehyde Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
2-Tridecyl-2-oxazoline Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
Piperonyl butoxide Area Lin, WithOffset 0.000 n.a. n.a. n.a. n.a.
AVERAGE: #DIV/0! #DIV/0! #DIV/0! #DIV/0!
Injection Name Ret.Time Area Height Amount

min counts*min counts
Methyl formate
2 calibration level(s) are/is required,
Average
TIC
#DIV/0!
TIC TIC TIC
Methyl formate Methyl formaMethyl format Methyl formate
Rel. Std. Dev. #DIV/0!
Acetic acid
alibration level(s) are/is required, bu
550648646.xlsx/Calibration
Version 7.2.10.23925
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Sequence: 04102021
Acetic acid
TIC TIC TIC TIC
Acetic acid Acetic acid Acetic acid Acetic acid
Average #DIV/0!
Propanoic acid
TIC TIC TIC TIC
Propanoic acid Propanoic acPropanoic aci Propanoic acid
Average #DIV/0!
Propanedinitrile
east 2 calibration level(s) are/is requ
TIC TIC TIC TIC
Propanedinitrile PropanedinitrPropanedinitriPropanedinitrile, (acetyloxy)methyl-
Average #DIV/0!
Furfural
libration level(s) are/is required, but
TIC TIC TIC TIC
Furfural Furfural Furfural Furfural
Average #DIV/0!

2-Furanmethan
2 calibration level(s) are/is required
Average
TIC
#DIV/0!
TIC TIC TIC
2-Furanmethano2-Furanmeth2-Furanmetha2-Furanmethanol

4,4-Dimethyl-2
least 2 calibration level(s) are/is req
Average
TIC
#DIV/0!
TIC TIC TIC
4,4-Dimethyl-2- 4,4-Dimethyl4,4-Dimethyl- 4,4-Dimethyl-2-cyclopenten-1-one

2H-Pyran, tetra
d.At least 2 calibration level(s) are/is
Average
TIC
#DIV/0!
TIC TIC TIC
2H-Pyran, tetra 2H-Pyran, te2H-Pyran, tet 2H-Pyran, tetrahydro-2-(12-pentadecynyloxy)-

2-Butanone, 1-
st 2 calibration level(s) are/is requir
Average
TIC
#DIV/0!
TIC TIC TIC
2-Butanone, 1-(a2-Butanone, 2-Butanone, 1-2-Butanone, 1-(acetyloxy)-

Version 7.2.10.23925
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Sequence: 04102021
Phenol
TIC TIC TIC TIC
Phenol Phenol Phenol Phenol
Average #DIV/0!
Phosphonic ac
t least 2 calibration level(s) are/is re
TIC TIC TIC TIC
Phosphonic acidPhosphonic aPhosphonic acPhosphonic acid, (p-hydroxyphenyl)-
Average #DIV/0!
Cyclohexanol,
ast 2 calibration level(s) are/is requir
TIC TIC TIC TIC
Cyclohexanol, 3CyclohexanolCyclohexanol,Cyclohexanol, 3,5-dimethyl-
Average #DIV/0!

1,2-Cyclopenta
Average
TIC
#DIV/0!
TIC TIC TIC
1,2-Cyclopentan1,2-Cyclopen1,2-Cyclopent1,2-Cyclopentanedione, 3-methyl-

2-Cyclopenten
Average
TIC
#DIV/0!
TIC TIC TIC
2-Cyclopenten-12-Cyclopente2-Cyclopenten2-Cyclopenten-1-one, 2,3-dimethyl-

Phenol, 2-meth
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 2-methyPhenol, 2-mePhenol, 2-metPhenol, 2-methyl-

Phenol, 3-meth
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 3-methyPhenol, 3-mePhenol, 3-metPhenol, 3-methyl-
2,4-Heptadiena
t 2 calibration level(s) are/is required
Version 7.2.10.23925
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Sequence: 04102021
2,4-Heptadiena
TIC TIC TIC TIC
2,4-Heptadienal,2,4-Heptadien
2,4-Heptadiena
2,4-Heptadienal, (E,E)-
Average #DIV/0!
Phenol, 2-meth
TIC TIC TIC TIC
Phenol, 2-methoPhenol, 2-mePhenol, 2-metPhenol, 2-methoxy-
Average #DIV/0!
1-Ethyl-2-hydro
TIC TIC TIC TIC
1-Ethyl-2-hydro 1-Ethyl-2-hy 1-Ethyl-2-hyd 1-Ethyl-2-hydroxymethylimidazole
Average #DIV/0!
Phenol, 2,3-dim
TIC TIC TIC TIC
Phenol, 2,3-dimePhenol, 2,3- Phenol, 2,3-diPhenol, 2,3-dimethyl-
Average #DIV/0!

2-Cyclopenten
At least 2 calibration level(s) are/is r
Average
TIC
#DIV/0!
TIC TIC TIC
2-Cyclopenten-12-Cyclopente2-Cyclopenten2-Cyclopenten-1-one, 3-ethyl-2-hydroxy-

Phenol, 2-ethy
calibration level(s) are/is required, b
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 2-ethyl-Phenol, 2-ethPhenol, 2-ethyPhenol, 2-ethyl-

Phenol, 2,4-dim
Average
TIC
#DIV/0!
TIC TIC TIC

Phenol, 4-ethy
calibration level(s) are/is required, b
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 4-ethyl-Phenol, 4-ethPhenol, 4-ethyPhenol, 4-ethyl-

Version 7.2.10.23925
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Sequence: 04102021
Phenol, 2,3-dim
TIC TIC TIC TIC
Average #DIV/0!
Phenol, 3,4-dim
TIC TIC TIC TIC
Average #DIV/0!
Creosol
TIC TIC TIC TIC
Creosol Creosol Creosol Creosol
Average #DIV/0!

Phenol, 4-ethy
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 4-ethyl Phenol, 4-et Phenol, 4-eth Phenol, 4-ethyl-2-methoxy-

Phenol, 2,6-dim
st 2 calibration level(s) are/is require
Average
TIC
#DIV/0!
TIC TIC TIC
Phenol, 2,6-dimPhenol, 2,6- Phenol, 2,6-d Phenol, 2,6-dimethoxy-

Eugenol
Average
TIC
Eugenol
#DIV/0!
TIC
Eugenol
TIC
Eugenol
TIC
Eugenol

3,5-Dimethoxy
Average
TIC
#DIV/0!
TIC TIC TIC
3,5-Dimethoxy-43,5-Dimethox3,5-Dimethoxy3,5-Dimethoxy-4-hydroxytoluene
Benzene, 1,2,3
Version 7.2.10.23925
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Sequence: 04102021
Benzene, 1,2,3
TIC TIC TIC TIC
Benzene, 1,2,3-Benzene, 1,2Benzene, 1,2,Benzene, 1,2,3-trimethoxy-5-methyl-
Average #DIV/0!
Homosyringald
TIC TIC TIC TIC
HomosyringaldeHomosyringaHomosyringalHomosyringaldehyde
Average #DIV/0!
2-Tridecyl-2-ox
TIC TIC TIC TIC
2-Tridecyl-2-oxa2-Tridecyl-2-2-Tridecyl-2-o2-Tridecyl-2-oxazoline
Average #DIV/0!
Piperonyl butox
TIC TIC TIC TIC
Piperonyl butox Piperonyl buPiperonyl butoPiperonyl butoxide
Average #DIV/0!

Version 7.2.10.23925
(acetyloxy)methy
-4,4-Dimethyl-2-cyclopenten-1-o
3,4-dimethyl
3-ethyl-2-h
4-ethyl-2-meth
2.
6.
2,3-dime
3,5-dimethy
2,3-dimethyl
2,3-dimethyl-
2-methoxy-
- Eugenol -
1,2,3-trimethoxy
(p-hydroxyph
2,4-dimethyl
- 1.439
-
3-me-
2-Tridecyl-2-o
1-(acetyloxy)- 1.5
2,6-dimeth
10 - Phenol - 2.88
(E,E)-
Piperonyl 1.4
1-Ethyl-2-hydroxymethylimi
-
-
3,5-Dimethoxy-4-hydro
tetrahydro-2-(12-pentadecy
Homosyringal 1.959
4-ethyl-
3-methyl-
2-methyl-
2-ethyl-
-
Page 11 of 37
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Sequence: 04102021
2-Furanmethanol
2730- Creosol -
-
Peak Analysis Report
acid
formate
-1,2-Cyclopentanedione,
6132,4-Heptadienal,
Sample Name: Asap Cair 1 Injection Volume: 10.00
-
acid
Injection Type: Unknown Dilution Factor: 1.0000
- Furfural
Phenol,
Propanoic
5- Phenol, -
04102021
Asap#3
Cair
[manually
1TIC TICintegrat
Phenol,
Phenol,
3.0e9
2---Phenol,
Cyclohexanol, Phenol, 35
Acetic
Phenol,
counts
Phenol,
-Phenol,
-Phenol,
Methyl
2.5e9 acid,
2-Butanone,
Phenol,
3334 - -
Benzene,
2.0e9
Propanedinitrile,
--24
--22 -
-Phosphonic -
1.5e9
16
29
- 18
-15
26
25
23
1.0e9
-
20
- 28
9 - 17
5.0e8
31
-
32
0.0e0
-12
8 - 2H-Pyran,
-19
-5.0e8 min
713
0.0 5.0 10.015.020.025.030.032.0

1114-
No. Time Peak Name Width Height Resol. Resol. Plates Plates Asymmetry
min min counts (USP) (EP) (USP) (EP)
421
-
1 1.401 Methyl formate n.a. ### n.a. n.a. n.a. n.a. n.a.
2 1.439 Acetic acid 0.042 ### 1.079 n.a. 19163 n.a. n.a.
3 1.510 Propanoic acid 0.091 ### 5.768 5.409 4427 3641 n.a.
4 1.690 Propanedinitrile, ( n.a. ### n.a. n.a. n.a. n.a. n.a.
5 1.959 Furfural 0.065 ### n.a. n.a. 14592 13958 n.a.
6 2.024 2-Furanmethanol n.a. ### n.a. n.a. n.a. n.a. n.a.
7 2.371 4,4-Dimethyl-2-cy 0.083 ### n.a. n.a. 13158 13284 n.a.
8 2.428 2H-Pyran, tetrahyd n.a. ### n.a. n.a. n.a. n.a. n.a.
9 2.697 2-Butanone, 1-(ace 0.094 ### 2.172 2.218 13205 14946 1.252
10 2.884 Phenol 0.078 ### n.a. n.a. 21653 20338 1.215
11 3.139 Phosphonic acid, ( n.a. ### n.a. n.a. n.a. n.a. n.a.
12 3.248 Cyclohexanol, 3,5- 0.107 ### 3.710 2.914 14720 10262 n.a.
13 3.564 1,2-Cyclopentaned 0.063 ### 3.338 2.693 50536 25405 0.902
14 3.775 2-Cyclopenten-1-on 0.063 ### 1.776 1.705 57592 49935 1.096
15 3.894 Phenol, 2-methyl- 0.071 ### 4.429 4.409 48000 46274 1.219
16 4.224 Phenol, 3-methyl- 0.078 ### n.a. 1.840 47094 47363 1.563

550648646.xlsx/Peak Analysis
Version 7.2.10.23925
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Sequence: 04102021
17 4.370 2,4-Heptadienal, ( n.a. ### n.a. 3.011 n.a. 45771 n.a.

18 4.585 Phenol, 2-methoxy 0.060 ### n.a. n.a. 93139 90407 n.a.
19 4.643 1-Ethyl-2-hydroxy n.a. ### n.a. n.a. n.a. n.a. n.a.
20 4.826 Phenol, 2,3-dimeth 0.068 9687872.829 2.777 2.719 81545 73637 n.a.
21 5.006 2-Cyclopenten-1-on 0.062 ### 3.627 3.679 103534 104991 1.154
22 5.214 Phenol, 2-ethyl- 0.052 ### 2.720 2.692 159896 165323 1.169
23 5.374 Phenol, 2,4-dimeth 0.065 ### n.a. n.a. 108126 100590 1.007
24 5.608 Phenol, 4-ethyl- n.a. ### n.a. n.a. n.a. n.a. n.a.
25 5.632 Phenol, 2,3-dimeth n.a. ### n.a. n.a. n.a. n.a. n.a.
26 5.966 Phenol, 3,4-dimeth n.a. ### n.a. n.a. n.a. n.a. n.a.
27 6.013 Creosol 0.039 ### 26.241 26.299 384299 363429 1.078
28 6.986 Phenol, 4-ethyl-2- 0.035 ### 20.116 20.605 625289 664752 1.248
29 7.669 Phenol, 2,6-dimet 0.033 ### 1.926 n.a. 884010 904335 1.374
30 7.741 Eugenol 0.042 ### 20.096 n.a. 555412 n.a. n.a.
31 8.465 3,5-Dimethoxy-4-h 0.031 ### 20.131 20.349 1228642 1272511 1.781
32 9.054 Benzene, 1,2,3-tri 0.028 ### 20.089 20.466 1683880 1676814 1.040
33 9.666 Homosyringaldehy 0.033 ### 86.107 102.480 1369433 1458251 1.268
34 13.941 2-Tridecyl-2-oxazo 0.066 ### 29.207 34.393 708297 1166151 2.796
35 15.448 Piperonyl butoxide 0.037 ### n.a. n.a. 2802154 2911826 1.640
AVERAGE: 0.059 ### 14.184 15.169 443,672 468,508 1.341

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Cintegrated]
min
030.0
32.0

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Sequence: 04102021
Anion Summary Report
No. Name Time Area Rel.Area

min counts*min %
TIC TIC TIC
Methyl formate Methyl formate Methyl formate
1 Asap Cair 3 n.a. n.a. n.a.
3 Asap Cair 1 1.401 7252955.2043 2.69
4 Batok Kelapa n.a. n.a. n.a.
5 STANDBY n.a. n.a. n.a.
Sum: 1.401 7252955.204 2.685
Average: 1.401 7252955.204 2.685
Rel.Std.Dev: #DIV/0! #DIV/0! #DIV/0!

min counts*min %
TIC TIC TIC
Acetic acid Acetic acid Acetic acid
3 Asap Cair 1 1.439 18696177.1131 6.92
Sum: 1.439 18696177.113 6.922
Average: 1.439 18696177.113 6.922

min counts*min %
TIC TIC TIC
Propanoic acid Propanoic acid Propanoic acid
1 Asap Cair 3 1.524 9304821.5673 1.07
3 Asap Cair 1 1.510 8727407.8709 3.23
Sum: 3.034 18032229.438 4.298
Average: 1.517 9016114.719 2.149
Rel.Std.Dev: 0.639 % 4.528 % 71.200 %

min counts*min %
TIC TIC TIC
Propanedinitrile, (acetyloxy)methyl-
3 Asap Cair 1 1.690 5931594.9081 2.20
Sum: 1.690 5931594.908 2.196
Average: 1.690 5931594.908 2.196

550648646.xlsx/Summary - INJ. vs ANION
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min counts*min %
TIC TIC TIC
Furfural Furfural Furfural
1 Asap Cair 3 1.966 46210469.8978 5.30
2 Asap Cair 2 1.962 10697256.8385 2.91
3 Asap Cair 1 1.959 9600573.8257 3.55
Sum: 5.887 66508300.562 11.760
Average: 1.962 22169433.521 3.920
Rel.Std.Dev: 0.176 % 93.946 % 31.590 %

min counts*min %
TIC TIC TIC
2-Furanmethanol 2-Furanmethanol 2-Furanmethanol
1 Asap Cair 3 2.034 17206567.8905 1.97
2 Asap Cair 2 2.027 8680001.5475 2.36
3 Asap Cair 1 2.024 3000122.3555 1.11
Sum: 6.085 28886691.793 5.442
Average: 2.028 9628897.264 1.814
Rel.Std.Dev: 0.259 % 74.262 % 35.202 %

min counts*min %
TIC TIC TIC
4,4-Dimethyl-2-cyclopenten-1-one
3 Asap Cair 1 2.371 2736297.2842 1.01
Sum: 2.371 2736297.284 1.013
Average: 2.371 2736297.284 1.013

min counts*min %
TIC TIC TIC
2H-Pyran, tetrahydro-2-(12-pentadecynyloxy)-
3 Asap Cair 1 2.428 1085865.1500 0.40
Sum: 2.428 1085865.150 0.402
Average: 2.428 1085865.150 0.402

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min counts*min %
TIC TIC TIC
2-Butanone, 1-(acetyloxy)-
3 Asap Cair 1 2.697 871225.6483 0.32
Sum: 2.697 871225.648 0.323
Average: 2.697 871225.648 0.323

min counts*min %
TIC TIC TIC
Phenol Phenol Phenol
1 Asap Cair 3 2.918 377180825.5378 43.26
2 Asap Cair 2 2.894 122996242.1273 33.41
3 Asap Cair 1 2.884 134170442.4268 49.67
Sum: 8.697 634347510.092 126.341
Average: 2.899 211449170.031 42.114
Rel.Std.Dev: 0.604 % 67.930 % 19.457 %

min counts*min %
TIC TIC TIC
Phosphonic acid, (p-hydroxyphenyl)-
3 Asap Cair 1 3.139 842198.7446 0.31
Sum: 3.139 842198.745 0.312
Average: 3.139 842198.745 0.312

min counts*min %
TIC TIC TIC
Cyclohexanol, 3,5-dimethyl-
3 Asap Cair 1 3.248 3665660.4933 1.36
Sum: 3.248 3665660.493 1.357
Average: 3.248 3665660.493 1.357

min counts*min %
TIC TIC TIC

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1,2-Cyclopentanedione,
1,2-Cyclopentanedione,
3-methyl- 1,2-Cyclopentanedione,
3-methyl- 3-methyl-
3 Asap Cair 1 3.564 1468367.6476 0.54
Sum: 3.564 1468367.648 0.544
Average: 3.564 1468367.648 0.544

min counts*min %
TIC TIC TIC
2-Cyclopenten-1-one, 2,3-dimethyl-
1 Asap Cair 3 3.796 4039578.0360 0.46
2 Asap Cair 2 3.785 1236917.0233 0.34
3 Asap Cair 1 3.775 1146310.6485 0.42
Sum: 11.356 6422805.708 1.224
Average: 3.785 2140935.236 0.408
Rel.Std.Dev: 0.271 % 76.831 % 15.998 %

min counts*min %
TIC TIC TIC
Phenol, 2-methyl- Phenol, 2-methyl- Phenol, 2-methyl-
1 Asap Cair 3 3.908 28987365.8983 3.32
2 Asap Cair 2 3.908 10659728.4737 2.90
3 Asap Cair 1 3.894 8302305.0256 3.07
Sum: 11.710 47949399.398 9.294
Average: 3.903 15983133.133 3.098
Rel.Std.Dev: 0.202 % 70.847 % 6.960 %

min counts*min %
TIC TIC TIC
1 Asap Cair 3 4.248 53399584.3885 6.12
2 Asap Cair 2 4.238 16309956.3268 4.43
3 Asap Cair 1 4.224 14700699.8997 5.44
Sum: 12.710 84410240.615 15.997
Average: 4.237 28136746.872 5.332
Rel.Std.Dev: 0.283 % 77.809 % 15.988 %

min counts*min %
TIC TIC TIC
2,4-Heptadienal, (E,E)- 2,4-Heptadienal, (E,E)-2,4-Heptadienal, (E,E)-

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Sequence: 04102021

3 Asap Cair 1 4.370 816185.6103 0.30
Sum: 4.370 816185.610 0.302
Average: 4.370 816185.610 0.302

min counts*min %
TIC TIC TIC
Phenol, 2-methoxy- Phenol, 2-methoxy- Phenol, 2-methoxy-
1 Asap Cair 3 4.598 55781393.3944 6.40
2 Asap Cair 2 4.595 15185003.3657 4.12
3 Asap Cair 1 4.585 14198846.4507 5.26
Sum: 13.778 85165243.211 15.779
Average: 4.593 28388414.404 5.260
Rel.Std.Dev: 0.155 % 83.584 % 21.609 %

min counts*min %
TIC TIC TIC
1-Ethyl-2-hydroxymethylimidazole
3 Asap Cair 1 4.643 731583.8896 0.27
Sum: 4.643 731583.890 0.271
Average: 4.643 731583.890 0.271

min counts*min %
TIC TIC TIC
Phenol, 2,3-dimethyl- Phenol, 2,3-dimethyl- Phenol, 2,3-dimethyl-
1 Asap Cair 3 4.840 1182641.7382 0.14
3 Asap Cair 1 4.826 780767.2421 0.29
Sum: 9.666 1963408.980 0.425
Average: 4.833 981704.490 0.212
Rel.Std.Dev: 0.201 % 28.946 % 51.091 %

min counts*min %
TIC TIC TIC
2-Cyclopenten-1-one, 3-ethyl-2-hydroxy-
1 Asap Cair 3 5.044 1195903.4026 0.14
3 Asap Cair 1 5.006 630307.0757 0.23

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Sequence: 04102021

Sum: 10.050 1826210.478 0.371
Average: 5.025 913105.239 0.185
Rel.Std.Dev: 0.528 % 43.800 % 36.720 %

min counts*min %
TIC TIC TIC
Phenol, 2-ethyl- Phenol, 2-ethyl- Phenol, 2-ethyl-
1 Asap Cair 3 5.224 2551970.6624 0.29
2 Asap Cair 2 5.224 1222311.1880 0.33
3 Asap Cair 1 5.214 814837.8654 0.30
Sum: 15.662 4589119.716 0.926
Average: 5.221 1529706.572 0.309
Rel.Std.Dev: 0.114 % 59.387 % 6.670 %

min counts*min %
TIC TIC TIC
1 Asap Cair 3 5.384 8757884.5160 1.00
2 Asap Cair 2 5.384 4102592.3687 1.11
3 Asap Cair 1 5.374 2517455.5492 0.93
Sum: 16.142 15377932.434 3.051
Average: 5.381 5125977.478 1.017
Rel.Std.Dev: 0.110 % 63.279 % 9.024 %

min counts*min %
TIC TIC TIC
3 Asap Cair 1 5.608 1587845.2011 0.59
Sum: 5.608 1587845.201 0.588
Average: 5.608 1587845.201 0.588

min counts*min %
TIC TIC TIC
1 Asap Cair 3 4.840 1182641.7382 0.14
3 Asap Cair 1 5.632 1842211.8557 0.68

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Sequence: 04102021
Sum: 10.472 3024853.594 0.818

Average: 5.236 1512426.797 0.409
Rel.Std.Dev: 10.700 % 30.837 % 94.504 %

min counts*min %
TIC TIC TIC
1 Asap Cair 3 5.643 6131120.4061 0.70
2 Asap Cair 2 5.642 3670224.3554 1.00
3 Asap Cair 1 5.966 707083.3217 0.26
Sum: 17.251 10508428.083 1.962
Average: 5.750 3502809.361 0.654
Rel.Std.Dev: 3.244 % 77.535 % 56.581 %

min counts*min %
TIC TIC TIC
Creosol Creosol Creosol
3 Asap Cair 1 6.013 5532236.5193 2.05
Sum: 6.013 5532236.519 2.048
Average: 6.013 5532236.519 2.048

min counts*min %
TIC TIC TIC
Phenol, 4-ethyl-2-methoxy-
1 Asap Cair 3 6.993 9361594.4596 1.07
2 Asap Cair 2 6.993 5469263.8698 1.49
3 Asap Cair 1 6.986 3373554.5315 1.25
Sum: 20.971 18204412.861 3.808
Average: 6.990 6068137.620 1.269
Rel.Std.Dev: 0.057 % 50.075 % 16.282 %

min counts*min %
TIC TIC TIC
Phenol, 2,6-dimethoxy-Phenol, 2,6-dimethoxy-Phenol, 2,6-dimethoxy-
1 Asap Cair 3 7.680 13312398.0344 1.53
2 Asap Cair 2 7.676 9165424.0096 2.49
3 Asap Cair 1 7.669 6502022.2288 2.41
Sum: 23.026 28979844.273 6.424
Average: 7.675 9659948.091 2.141

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Sequence: 04102021
Rel.Std.Dev: 0.068 % 35.528 % 24.924 %

min counts*min %
TIC TIC TIC
Eugenol Eugenol Eugenol
1 Asap Cair 3 7.744 1215597.7023 0.14
2 Asap Cair 2 7.741 1034133.5208 0.28
3 Asap Cair 1 7.741 580976.5927 0.22
Sum: 23.226 2830707.816 0.635
Average: 7.742 943569.272 0.212
Rel.Std.Dev: 0.026 % 34.641 % 33.424 %

min counts*min %
TIC TIC TIC
3,5-Dimethoxy-4-hydroxytoluene
1 Asap Cair 3 8.472 5518909.3336 0.63
2 Asap Cair 2 8.469 4577716.3303 1.24
3 Asap Cair 1 8.465 3048292.1615 1.13
Sum: 25.406 13144917.825 3.005
Average: 8.469 4381639.275 1.002
Rel.Std.Dev: 0.041 % 28.458 % 32.387 %

min counts*min %
TIC TIC TIC
Benzene, 1,2,3-trimethoxy-5-methyl-
1 Asap Cair 3 9.057 4184602.6876 0.48
2 Asap Cair 2 9.054 3406134.9900 0.93
3 Asap Cair 1 9.054 1999296.0822 0.74
Sum: 27.165 9590033.760 2.145
Average: 9.055 3196677.920 0.715
Rel.Std.Dev: 0.022 % 34.649 % 31.278 %

min counts*min %
TIC TIC TIC
Homosyringaldehyde Homosyringaldehyde Homosyringaldehyde
1 Asap Cair 3 9.669 1264737.8959 0.15
2 Asap Cair 2 9.669 1128768.1841 0.31
3 Asap Cair 1 9.666 649154.0285 0.24
Sum: 29.005 3042660.109 0.692
Average: 9.668 1014220.036 0.231
Rel.Std.Dev: 0.021 % 31.885 % 35.204 %

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Sequence: 04102021

min counts*min %
TIC TIC TIC
2-Tridecyl-2-oxazoline 2-Tridecyl-2-oxazoline2-Tridecyl-2-oxazoline
3 Asap Cair 1 13.941 500275.6488 0.19
Sum: 13.941 500275.649 0.185
Average: 13.941 500275.649 0.185

min counts*min %
TIC TIC TIC
Piperonyl butoxide Piperonyl butoxide Piperonyl butoxide
1 Asap Cair 3 15.451 46872238.3066 5.38
2 Asap Cair 2 15.448 3237030.6864 0.88
3 Asap Cair 1 15.448 1086019.6069 0.40
Sum: 46.347 51195288.600 6.657
Average: 15.449 17065096.200 2.219
Rel.Std.Dev: 0.013 % 151.398 % 123.667 %

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Sequence: 04102021
Height Rel.Height Amount

counts %
TIC TIC TIC
Methyl formate Methyl formate Methyl formate
n.a. n.a. n.a.
n.a. n.a. n.a.
295361499.99 4.76 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
295361499.993 4.760 0.000
295361499.993 4.760 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
Acetic acid Acetic acid Acetic acid
n.a. n.a. n.a.
n.a. n.a. n.a.
609267784.94 9.82 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
609267784.944 9.818 0.000
609267784.944 9.818 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
Propanoic acid Propanoic acid Propanoic acid
217687154.46 1.21 n.a.
n.a. n.a. n.a.
128392844.26 2.07 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
346079998.722 3.281 0.000
173039999.361 1.641 #DIV/0!
36.489 % 36.923 % #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
92276113.92 1.49 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
92276113.919 1.487 0.000
92276113.919 1.487 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

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Sequence: 04102021

counts %
TIC TIC TIC
Furfural Furfural Furfural
921472654.08 5.13 n.a.
275822032.97 3.54 n.a.
225750345.84 3.64 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
1423045032.887 12.305 0.000
474348344.296 4.102 #DIV/0!
81.803 % 21.785 % #DIV/0!

counts %
TIC TIC TIC
2-Furanmethanol 2-Furanmethanol 2-Furanmethanol
287043664.20 1.60 n.a.
118863998.36 1.52 n.a.
60981662.54 0.98 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
466889325.100 4.105 0.000
155629775.033 1.368 #DIV/0!
75.455 % 24.557 % #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
55834967.03 0.90 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
55834967.033 0.900 0.000
55834967.033 0.900 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
28438050.00 0.46 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
28438049.996 0.458 0.000
28438049.996 0.458 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

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Sequence: 04102021
counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
16034909.50 0.26 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
16034909.500 0.258 0.000
16034909.500 0.258 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
Phenol Phenol Phenol
4518251651.80 25.16 n.a.
2482289699.52 31.82 n.a.
2483431950.94 40.02 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
9483973302.251 97.001 0.000
3161324434.084 32.334 #DIV/0!
37.172 % 23.017 % #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
18427674.69 0.30 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
18427674.690 0.297 0.000
18427674.690 0.297 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
44308920.55 0.71 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
44308920.547 0.714 0.000
44308920.547 0.714 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC

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Sequence: 04102021
1,2-Cyclopentanedione,1,2-Cyclopentanedione,
3-methyl- 1,2-Cyclopentanedione,
3-methyl- 3-methyl-
n.a. n.a. n.a.
n.a. n.a. n.a.
26243640.80 0.42 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
26243640.797 0.423 0.000
26243640.797 0.423 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
93767734.18 0.52 n.a.
29039320.67 0.37 n.a.
27230834.01 0.44 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
150037888.869 1.333 0.000
50012629.623 0.444 #DIV/0!
75.788 % 16.910 % #DIV/0!

counts %
TIC TIC TIC
590452397.82 3.29 n.a.
178398813.83 2.29 n.a.
170732109.40 2.75 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
939583321.046 8.326 0.000
313194440.349 2.775 #DIV/0!
76.675 % 18.061 % #DIV/0!

counts %
TIC TIC TIC
957700018.57 5.33 n.a.
304783364.54 3.91 n.a.
279149009.68 4.50 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
1541632392.791 13.739 0.000
513877464.264 4.580 #DIV/0!
74.838 % 15.655 % #DIV/0!

counts %
TIC TIC TIC
2,4-Heptadienal, (E,E)- 2,4-Heptadienal, (E,E)- 2,4-Heptadienal, (E,E)-
n.a. n.a. n.a.

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Sequence: 04102021
n.a. n.a. n.a.

15994294.33 0.26 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
15994294.330 0.258 0.000
15994294.330 0.258 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
Phenol, 2-methoxy- Phenol, 2-methoxy- Phenol, 2-methoxy-
1325392418.92 7.38 n.a.
375036908.05 4.81 n.a.
357404003.63 5.76 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
2057833330.611 17.948 0.000
685944443.537 5.983 #DIV/0!
80.742 % 21.755 % #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
20002961.76 0.32 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
20002961.762 0.322 0.000
20002961.762 0.322 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
34328700.18 0.19 n.a.
n.a. n.a. n.a.
9687872.83 0.16 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
44016573.014 0.347 0.000
22008286.507 0.174 #DIV/0!
79.169 % 14.277 % #DIV/0!

counts %
TIC TIC TIC
35039898.85 0.20 n.a.
n.a. n.a. n.a.
16174013.39 0.26 n.a.

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Sequence: 04102021
n.a. n.a. n.a.

n.a. n.a. n.a.
51213912.240 0.456 0.000
25606956.120 0.228 #DIV/0!
52.096 % 20.324 % #DIV/0!

counts %
TIC TIC TIC
80477307.75 0.45 n.a.
31461616.39 0.40 n.a.
25394736.92 0.41 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
137333661.060 1.261 0.000
45777887.020 0.420 #DIV/0!
65.978 % 5.806 % #DIV/0!

counts %
TIC TIC TIC
186761479.43 1.04 n.a.
69965902.33 0.90 n.a.
57950219.44 0.93 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
314677601.202 2.871 0.000
104892533.734 0.957 #DIV/0!
67.836 % 7.773 % #DIV/0!

counts %
TIC TIC TIC
n.a. n.a. n.a.
n.a. n.a. n.a.
59528576.18 0.96 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
59528576.183 0.959 0.000
59528576.183 0.959 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
34328700.18 0.19 n.a.
n.a. n.a. n.a.
56363105.02 0.91 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.

Version 7.2.10.23925
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Sequence: 04102021
90691805.203 1.099 0.000

45345902.602 0.550 #DIV/0!
34.360 % 92.239 % #DIV/0!

counts %
TIC TIC TIC
190857927.99 1.06 n.a.
87622007.77 1.12 n.a.
18081457.87 0.29 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
296561393.625 2.477 0.000
98853797.875 0.826 #DIV/0!
87.942 % 56.163 % #DIV/0!

counts %
TIC TIC TIC
Creosol Creosol Creosol
n.a. n.a. n.a.
n.a. n.a. n.a.
206995313.27 3.34 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
206995313.268 3.336 0.000
206995313.268 3.336 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
367196972.25 2.04 n.a.
192463910.27 2.47 n.a.
149887038.62 2.42 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
709547921.139 6.927 0.000
236515973.713 2.309 #DIV/0!
48.689 % 9.969 % #DIV/0!

counts %
TIC TIC TIC
Phenol, 2,6-dimethoxy-Phenol, 2,6-dimethoxy- Phenol, 2,6-dimethoxy-
631823708.74 3.52 n.a.
345197535.69 4.42 n.a.
302377359.48 4.87 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
1279398603.906 12.816 0.000
426466201.302 4.272 #DIV/0!

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Sequence: 04102021
42.003 % 16.147 % #DIV/0!

counts %
TIC TIC TIC
Eugenol Eugenol Eugenol
44216891.05 0.25 n.a.
30463878.49 0.39 n.a.
19896348.59 0.32 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
94577118.133 0.957 0.000
31525706.044 0.319 #DIV/0!
38.683 % 22.601 % #DIV/0!

counts %
TIC TIC TIC
260775989.50 1.45 n.a.
196663166.84 2.52 n.a.
135865272.00 2.19 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
593304428.331 6.163 0.000
197768142.777 2.054 #DIV/0!
31.584 % 26.625 % #DIV/0!

counts %
TIC TIC TIC
237754151.01 1.32 n.a.
185816408.17 2.38 n.a.
109589443.23 1.77 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
533160002.399 5.472 0.000
177720000.800 1.824 #DIV/0!
36.273 % 29.123 % #DIV/0!

counts %
TIC TIC TIC
Homosyringaldehyde Homosyringaldehyde Homosyringaldehyde
61213714.93 0.34 n.a.
52562763.06 0.67 n.a.
31290305.68 0.50 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
145066783.659 1.519 0.000
48355594.553 0.506 #DIV/0!
31.845 % 32.870 % #DIV/0!

Version 7.2.10.23925
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Sequence: 04102021

counts %
TIC TIC TIC
2-Tridecyl-2-oxazoline 2-Tridecyl-2-oxazoline 2-Tridecyl-2-oxazoline
n.a. n.a. n.a.
n.a. n.a. n.a.
10645735.64 0.17 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
10645735.640 0.172 0.000
10645735.640 0.172 #DIV/0!
#DIV/0! #DIV/0! #DIV/0!

counts %
TIC TIC TIC
Piperonyl butoxide Piperonyl butoxide Piperonyl butoxide
2374257682.27 13.22 n.a.
136522579.90 1.75 n.a.
40382707.34 0.65 n.a.
n.a. n.a. n.a.
n.a. n.a. n.a.
2551162969.510 15.623 0.000
850387656.503 5.208 #DIV/0!
155.292 % 133.700 % #DIV/0!

Version 7.2.10.23925
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Sequence: 04102021
3 Asap Cair 1 Audit Trail
Sample Name: Asap Cair 1 Injection Volume: 10.00

Vial Position: 2 Channel: TIC
Injection Type: Unknown Wavelength: n.a.
Instrument Method: ASAP CAIR PENELITIAN Bandwidth: n.a.
Processing Method: MS Quantitative(2) Dilution Factor: 1.0000
Recording Time: 04-Oct-21 12:03 Sample Weight: 1.0000
Run Time (min): 31.97 Int STD Amount: 1.0000
Day Time Ret. Time Command/Message

(UTC+07:00) min
12:02:14 Audit trail of injection "chrom://desktop-n5mlfne/ChromeleonLocal/GCMSISQLT/LJPKS IPB/2021/10-OKTOBER/041020
12:02:14 Start of injection 3 "Asap Cair 1", using instrument method "ASAP CAIR PENELITIAN".
12:02:15 0.000 Entered stage "Instrument Setup"
12:02:15 0.000 GC.FrontInlet.FlowMode = FlowCtrl
12:02:15 0.000 GC.PrepRunTimeout = 999.00 min
12:02:15 0.000 GC.EquilibrationTime = 0.10 min
12:02:15 0.000 GC.ReadyDelay = 0.00 min
12:02:15 0.000 GC.FrontInlet.SplitMode = Split
12:02:15 0.000 GC.FrontInlet.SplitFlow.Nominal = 20.0 ml/min
12:02:15 0.000 GC.FrontInlet.SplitFlowCtrl = On
12:02:15 0.000 GC.FrontInlet.PurgeFlow.Nominal = 3.000 ml/min
12:02:15 0.000 GC.FrontInlet.PurgeFlowCtrl = On
12:02:15 0.000 GC.FrontInlet.VacuumCorrection = On
12:02:15 0.000 GC.FrontInlet.GasSaverFlow = 5.0 ml/min
12:02:15 0.000 GC.FrontInlet.GasSaverTime = 5.00 min
12:02:15 0.000 GC.FrontInlet.GasSaverCtrl = On
12:02:15 0.000 GC.FrontInlet.Temperature.Nominal = 260 °C
12:02:15 0.000 GC.FrontInlet.TempCtrl = On
12:02:15 0.000 GC.FrontColumn.Description = "TG5MS"
12:02:15 0.000 GC.FrontColumn.Length = 30.00 m
12:02:15 0.000 GC.FrontColumn.NominalID = 0.250 mm
12:02:15 0.000 GC.FrontColumn.FilmThickness = 0.25 µm
12:02:15 0.000 GC.FrontInlet.FlowCtrl = On
12:02:15 0.000 GC.TempCtrl = On
12:02:15 0.000 Entered stage "Equilibration"
12:02:15 0.000 GC.FrontInlet.Flow.Nominal = 1.000 ml/min
12:02:15 0.000 GC.Temperature.Nominal = 100.0 °C
12:02:15 0.000 Entered stage "Inject Preparation"
12:02:15 0.000 Wait MSDevice.Ready And GC.Ready
12:02:16 0.000 Log RunState: NotReady
12:02:16 0.000 New detailed run state: Waiting for equilibration time.
12:02:19 0.000 Log Ready: Ready
12:02:19 0.000 The analysis is starting.
12:02:22 0.000 Log RunState: StandBy
12:02:22 0.000 New detailed run state: Waiting for prep-run key
12:02:22 0.000 Prep-run command sent to GC.
12:02:22 0.000 Log RunState: PrepRun

550648646.xlsx/Audit Trail
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Sequence: 04102021
12:02:23 0.000 New detailed run state: Executing prep-run events

12:02:40 0.000 Log RunState: Ready
12:02:40 0.000 New detailed run state: Waiting for start key
12:02:40 0.000 Wait finished
12:02:40 0.000 Entered stage "Inject"
12:02:40 0.000 InjectValve.Inject
12:02:40 0.000 Log Position: 2
12:02:40 0.000 Log Volume: 10.0 [µl]
12:02:40 0.000 Waiting for inject response on TRACE_1300.Run1.
12:03:26 0.000 The analysis has been started.
12:03:27 0.000 Log RunState: Run
12:03:27 0.000 Log Ready: NotReady
12:03:27 0.000 Got inject response.
12:03:27 0.000 Entered stage "Run"
12:03:28 0.014 New detailed run state: Running
12:07:27 4.000 GC.Temperature.Nominal Gradient Start = 100.0 °C, End = 200.0 °C, Duration = 5.000 min
12:14:27 11.000 GC.Temperature.Nominal Gradient Start = 200.0 °C, End = 300.0 °C, Duration = 5.000 min
12:35:27 32.000 Entered stage "Stop Run"
12:35:27 32.000 GC.FrontInlet.Flow.Nominal = 1.000 ml/min
12:35:27 32.000 Terminating instrument method chrom://desktop-n5mlfne/ChromeleonLocal/GCMSISQLT/LJPKS IPB/2021/10-OKTOBE
12:35:27 32.000 The analysis is stopping.
12:35:31 32.062 OK to terminate instrument method chrom://desktop-n5mlfne/ChromeleonLocal/GCMSISQLT/LJPKS IPB/2021/10-OKTO
12:35:31 32.062 Terminating instrument method chrom://desktop-n5mlfne/ChromeleonLocal/GCMSISQLT/LJPKS IPB/2021/10-OKTOBE
12:35:31 32.077 Log RunState: Cool
12:35:31 32.077 OK to terminate instrument method chrom://desktop-n5mlfne/ChromeleonLocal/GCMSISQLT/LJPKS IPB/2021/10-OKTO
12:35:31 End of injection "Asap Cair 1".

Version 7.2.10.23925
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Sequence: 04102021
S IPB/2021/10-OKTOBER/04102021.seq/102.smp". Executed 04/10/2021 on instrument GCMS_ISQLT_Manual (instrument controller DESKTOP-N5MLFNE).

Version 7.2.10.23925
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Sequence: 04102021
LT/LJPKS IPB/2021/10-OKTOBER/04102021.seq/ASAP CAIR PENELITIAN.instmeth. Waiting for instrument to finish processing of current injection ...
SISQLT/LJPKS IPB/2021/10-OKTOBER/04102021.seq/ASAP CAIR PENELITIAN.instmeth.

LT/LJPKS IPB/2021/10-OKTOBER/04102021.seq/ASAP CAIR PENELITIAN.instmeth. Waiting for instrument to finish processing of current injection ...
SISQLT/LJPKS IPB/2021/10-OKTOBER/04102021.seq/ASAP CAIR PENELITIAN.instmeth.

Version 7.2.10.23925
Page 36 of 37
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Sequence: 04102021
ler DESKTOP-N5MLFNE).

Version 7.2.10.23925
Page 37 of 37
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Sequence: 04102021
of current injection ...
of current injection ...

Version 7.2.10.23925

Asap Cair 1

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Asap Cair 1

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Peak Integration Report

Sample Name: Asap Cair 1 Inj. Vol.: 10.00

No. Time Peak Name Peak Type Area Height Rel.Area

14 3.78 2-Cyclopenten-1- BMB 1146310.648 27230834.013 0.42

15 3.89 Phenol, 2-methyl BMB 8302305.026 170732109.397 3.07

16 4.22 Phenol, 3-methyl BM 14700699.900 279149009.684 5.44

17 4.37 2,4-Heptadienal, MB 816185.610 15994294.330 0.30

18 4.58 Phenol, 2-methox BM 14198846.451

19 4.64 1-Ethyl-2-hydrox M 731583.890 20002961.762 0.27

20 4.83 Phenol, 2,3-dimet MB 780767.242 9687872.829 0.29

21 5.01 2-Cyclopenten-1- BMB 630307.076 16174013.390 0.23

22 5.21 Phenol, 2-ethyl- BMB 814837.865 25394736.922 0.30

23 5.37 Phenol, 2,4-dimet BMB 2517455.549 57950219.444 0.93

24 5.61 Phenol, 4-ethyl- BM 1587845.201 59528576.183 0.59

25 5.63 Phenol, 2,3-dimet MB 1842211.856 56363105.019 0.68

26 5.97 Phenol, 3,4-dimet BM 707083.322 18081457.865 0.26

27 6.01 Creosol MB 5532236.519 206995313.268 2.05

28 6.99 Phenol, 4-ethyl- BMB 3373554.532 149887038.618 1.25

29 7.67 Phenol, 2,6-dime BM 6502022.229 302377359.479 2.41

30 7.74 Eugenol MB 580976.593 19896348.592 0.22

31 8.47 3,5-Dimethoxy-4 BMB 3048292.162 135865271.998 1.13

32 9.05 Benzene, 1,2,3-t BMB 1999296.082 109589443.226 0.74

34 13.94 2-Tridecyl-2-oxaz BMB 500275.649 10645735.640 0.19

35 15.45 Piperonyl butoxi BMB 1086019.607 40382707.343 0.40

TOTAL: 270097155.71 6205373083.31 100.00

Chromeleon (c) Dionex 1996-2009

Chromeleon (c) Dionex 1996-2009

Chromeleon (c) Dionex 1996-2009

Chromeleon (c) Dionex 1996-2009

Calibration Batch Report

Sequence: 04102021 Injection Volume: 10.00

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Chromeleon (c) Dionex 1996-2009

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Injection Name Ret.Time Area Height Amount

Rel. Std. Dev. #DIV/0!