Mass and Heat Transfer - Aula 02 02 23

Chemical Engineering Program
COPPE – Federal University of Rio de Janeiro
January / 2023
Module I: Fundamentals of Chemical

Engineering
Heat and Mass Transfer
Prof. Cristiano Borges

Mass transfer in two dimensions
Mass Transfer in two dimensions

Following liquid film in laminar flow
Liquid B # Gas A has low solubility in liquid B
# Developed velocity profile

Gas A
# Equilibrium at gas/liquid interface
Liquid B Momentum balance:
Gas A
Liquid B
Gas A
Mass balance:
Liquid B
Mass balance:
Gas A
Liquid B
Mass balance:
Gas A
Solution (maths):

DAB= 1 x 10-5 cm/s2

Umax = 10 cm/s
Molar flux of A: Interface (x=0)

Mass transfer in unsteady state

Unsteady state evaporation in stagnant gas
Corrente de gás B
Gas stream (B) Assumptions:
- Ideal Gas (T and P known, c = P/RT)
- Gas B is unsoluble in liquid A
- Boundary conditions:
Impermeable z = Z2 XA= XA,2 (known = 0)

plate
z = Z1
Liquid A

Corrente de gás B
Gas stream (B) Assumptions:
- Ideal Gas (T and P known, c = P/RT)
t2 - Gas B is unsoluble in liquid A
- Boundary conditions:
t1 z = Z2 XA= XA,2 (known = 0)
z = Z1 Thermodynamic equilibrium G - L
Liquid A

Gas stream B Mass balance:

ΔV= S. Δz
XA = f (z,t)
Dividing by ΔV = S.Δz Δz→0
Liquid A

Gas stream B
Direction z
XA = f (z,t) Model (FICK):
Liquid A NBz = ???


Gas stream B
Mass balance:
XA = f (z,t)
Liquid A

Gas stream B
Mass balance:
XA = f (z,t)
Liquid A

Gas stream B
Mass balance:
XA = f (z,t)
Liquid A

Gas stream B
Mass balance:
XA = f (z,t)
NA + NB = constante
constant
Liquid A

Gas stream B
NA + NB = constante
constant in any z
(NA + NB ) z=0 = constante

constant
XA = f (z,t)
Liquid A

Gas stream B
NA + NB = constante
constant in any z

constant
XA = f (z,t)
mas,
but,
Liquid A

Gas stream B
NA + NB = constante
constant in any z

constant
XA = f (z,t)
mas,
but,
Liquid A

Gas stream B
NA + NB = constante
constant in any z

constant
XA = f (z,t)
but,
Liquid A

Gas stream B
Model (FICK):
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
t=0 XA = 0 any z
XA = f (z,t)
z=0 XA = XAo
z→∞ XA = 0
Liquid A

Gas stream B
t=0 XA = 0 any z
XA = f (z,t)
z=0 XA = XAo
z→∞ XA = 0
XA z
X= Z=
Liquid A XAo 4.DAB.t

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t) Z=0 X=1
Z→∞ X= 0
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t) Z=0 X=1
Z→∞ X= 0
Liquid A

Gas stream B
XA = f (z,t)
considering,
Liquid A

Gas stream B
XA = f (z,t)
XAo j
0,00 0,0000
0,25 0,1562
0,50 0,3578
0,75 0,6618
Liquid A
1,00 

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
Evaporation rate: dVA / dt
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
but,
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Gas stream B
XA = f (z,t)
Liquid A

Mass transfer in a plate
+l
z x
y
-l L
W

Recipient with
fluid A
+l
z x
y
-l L
W

Recipient with
fluid A
+l
z x
y
-l L
# Gas A has low solubility in the plate
W
# Flux is preferencial in direction z
# Diffusion coeffient is constant
# Themodynamic equilibrium at
interface fluid / plate
Dz Mass balance:
+l z
Dz ΔV=W. L. Δz
x
-l L
y
W
Dividing by ΔV = W.L.Δz Δz→0


Dz Mass balance:
+l z
Dz
x
-l L
y
W
Direction z
Model (FICK):

Dz Mass balance:
+l z
Dz
x
-l L
y
W
Direction z
Model (FICK):

Dz Mass balance:
+l z
Dz
x
-l L
y
W
Direction z
Model (FICK):

Dz
+l z
Dz
x
-l L
y
W
z=l CA = CA1 t>0
z=0 NAz= 0 any t
t=0 CA = CAo - l < z < +l


Dz
+l z
Dz
x
-l L CA1 - CA
y q=
W dimensionless:
Admensionalizar: CA1 - CAo

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
z=l q=0 t>0
z=0 any t
t=0 q=1 - l < z < +l


Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q = f (z,t) = z(z).t(t)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q = f (z,t) = z(z).t(t)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q = f (z,t) = z(z).t(t)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q = f (z,t) = z(z).t(t)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q = f (z,t) = z(z).t(t)
constant

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
t (t) = K.exp(a.DAP.t)
a> 0 t ®¥ t (t) ® ¥

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
dt (t)
= a.DAP.dt t (t) = K.exp(a.DAP.t)
t (t)
a= 0 t (t) = K q = f(z)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
dt (t)
= a.DAP.dt t (t) = K.exp(a.DAP.t)
t (t)
a< 0 a = -l 2
t (t) = K.exp(-l 2.DAP.t)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
z (z) = K1sen(l z)+ K2 cos(l z)


Dz
+l z
Dz
x
-l L
y
W
q = f (z,t) = z(z).t(t)
q (z, t) = [K1sen(l z) + K 2 cos(l z)].K.exp(-l 2 .DAP.t)
q (z, t) = [A.sen(l z) + B.cos(l z)].exp(-l 2 .DAP.t)


Dz
+l z
Dz
x
-l L
y
W
q = f (z,t) = z(z).t(t)
q (z, t) = [K1sen(l z) + K 2 cos(l z)].K.exp(-l 2 .DAP.t)
q (z, t) = [A.sen(l z) + B.cos(l z)].exp(-l 2 .DAP.t)


Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
q (z, t) = [A.sen(l z)+ B.cos(l z)].exp(-l 2.DAP.t)
z=0 sen(0)=0
A=0
cos(0)=1

Dz
+l z
Dz
x
-l L
y
W
q (z, t) = B.cos(l z).exp(-l 2.DAP.t)

B≠0
z=l q=0 B.cos(l. ) = 0
cos(l.l) = 0

Dz
+l z
Dz
x
-l L
y
W
q (z, t) = B.cos(l z).exp(-l 2.DAP.t)
(2n+1).p (2n+1).p
cos(l.l) = 0 l. = l=
2 2.

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
(2n+1).p
q (z, t) = B.cos(l z).exp(-l .DAP.t) 2 l=
2.

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
t=0 q=1

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
Orthogonality
t=0 q=1 theorem

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo
4.(-1)n
t=0 q=1 Bn =
p .(2n+1)

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo

Dz
+l z
Dz
x CA1 - CA
-l
y L q=
W CA1 - CAo

0,9
0,8
(D.t/lˆ2)
0,7
(CA - CAo)/(CA1-CAo)
0,6 0,001
0,01
0,5
0,04
0,4 0,2
0,8
0,3
1,5
0,2
0,1
0
0 0,2 0,4 0,6 0,8 1
Z/l

Mass and Heat Transfer - Aula 02 02 23

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Chemical Engineering Program

COPPE – Federal University of Rio de Janeiro

Module I: Fundamentals of Chemical

Heat and Mass Transfer

Prof. Cristiano Borges

Mass Transfer in two dimensions

Liquid B # Gas A has low solubility in liquid B

# Developed velocity profile

Following liquid film in laminar flow

Liquid B Momentum balance:

Following liquid film in laminar flow

Following liquid film in laminar flow

Following liquid film in laminar flow

Following liquid film in laminar flow

Following liquid film in laminar flow

DAB= 1 x 10-5 cm/s2

Following liquid film in laminar flow

Molar flux of A: Interface (x=0)

Mass transfer in unsteady state

- Ideal Gas (T and P known, c = P/RT)

- Gas B is unsoluble in liquid A

Impermeable z = Z2 XA= XA,2 (known = 0)

Mass transfer in unsteady state

- Ideal Gas (T and P known, c = P/RT)

t2 - Gas B is unsoluble in liquid A

t1 z = Z2 XA= XA,2 (known = 0)

Mass transfer in unsteady state

Gas stream B Mass balance:

Dividing by ΔV = S.Δz Δz→0

Mass transfer in unsteady state

Liquid A NBz = ???

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

(NA + NB ) z=0 = constante

Mass transfer in unsteady state

(NA + NB ) z=0 = constante

Mass transfer in unsteady state

(NA + NB ) z=0 = constante

Mass transfer in unsteady state

(NA + NB ) z=0 = constante

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

XA = f (z,t) Z=0 X=1

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

XA = f (z,t) Z=0 X=1

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Mass transfer in unsteady state

Evaporation rate: dVA / dt