MSE 304

Assignment 2
-

= =

190907
Tejas shingle
-

1 stainless Stell → 18% Cr

,
8% Mi
, ¥741 Fe
.

( wt 1.)
-

For 1m06 :

Cr wt =
52g
Ni wt = 58 7g
.

WE
Fe = 55
8g
.

Assuming 100g of
steel

18g 8g → Fe
→ er
,
→ Hi
, 74g
Moles ( Cr )
¥-2 = 35
=
o .

( )
=¥y
Moles Hi = 0-14

Moles ( Fe)
=¥ 1-33

Total moles =
035+014+1-33 = 1.82

9%1×100 19.23
= T .

'
1- mole Cv =

7.69 I -

÷Y
T .
Mole Ni = ✗ 100 =

73.08%
% mole
1¥ ✗ 100
=
Fe =
,
 19.23% Cry 769% Mi , -73 -08% Fe
Mole % =

2- Air → 21% 02 ,
78% Mz 1% Ar
,
( Volume 't )

Assuming 100L
of Air

Oz → 21L

NL -0 78L

pro 1L

ideal 4 STP
Assuming gas
.

1m06 = 224L

¥y
1L =
mole

Oz → 21 ✗ 1- = O '

9375 moles
22.4

moles
Nz
78K¥ 3.4821
→ =

Ar 0-0446 molls
→ I
¥
=

.
u

wt
of :
Oz =
322
1- mole MI
Nz =
28g
AV Hog
=
 wtof
:

9375×32
30g
=
0
'

=
oh

Nh= 3-4821×28 =

979988g
Ar= 00446×40 1
784g
=
.

Total weight = 30+97-4988+1784=129 -283g

wtt -2%
.

02 =
I =
23

129.283
Ans
-

Nh = 75.42%

Ar = I '

38%

3- Gefesz + Fesz + cuz S

a-
Cus 30% Fc 40%5
30-1 .

✗
wtt
→
Assuming
.

cute { → n2
let
weight of
Fes → yg
cures →*
s
 If total weight is assumed to

De
loog

wt often
=
302
wt
offer 3oz
=

wtog s
uog
=

Molar wt 183-522
of cutesy
.
=

Fesz =

120g
cases
159g
=

wt
from cuFe{ 4ft cures
of Cee =
-

63.5×1 635×2
}=g
✗
①
+
-
30 =

183-52 ,

wt
of Fe =
from cutesy Fe 5-
-

30 +56 ✗ 2-
② - = 56 ✗ 2-
183.52 120

from are
wf.gs 3
:

40 =
32×2×2 +32×2×3
Ito
183.52
32T¥
+
 ,z§÷n ¥g8z
+ ° + =
30

%÷k ¥02 30
=
+ +0

☒÷zk -1%1-+9%2=40

2--54
27g y 30.46g , 2=15 19g
.
=
,

Hn :
En ,y,z =
9992g I 100g
as assumed

wt % Cute 5<=54-27-1 .

Ub T
Fesz 30
-

% = .

T -
Ceezs =
15.
lqy.tt#
 loolonnes →
2h 0C ? )
4. 2ns G- 5)
Pbs (s )
→
Roasting →
Pbo ( ? )

Fe{ ( s ) Fezoycz )

Basi b
5oz +
So
]
Tent 65 6% 2%

Pbtsot 2ns → 75T ; → 75-0=7.73 ly mole .

5032 97

Fet 56
mole
Pbs 5t=
g 0.209kg
t = -

/ mole
Fela
-054--5,20-0=0416 g.

7.73+0-201+0 avoid
input
-

Moles of S =

mousgsoitput ⇐ F.)
+ n
-

where his leg .mn of gaster irytshsfom

-
 8. 771 = 0-08 n

2=109 .
64kg .
mole

6- 58kg mob
502 109.69
= .

÷
= ✗
.

109.69=2-19 kgmok
503 ÷ ✗
=

4%(142+02) =
100.87 tfgmok
Let Nz flue
y be mole
of in gag

: mousy on =
(100-87 -

g) tkgmole

ftp.gmoleN2-oj.tn#Yttgmo60aFIfRoastinf2no--
Air contains :

mole
7.73kg -

=
Pbo =
0.209 kg mob .

Mok
Fez 04=0.27+19
-
 onygenbabnu-gzns-r.roµpbs→Pb° FESTER
✗

21 ] 0-201 0-277×2
0
7.2-a3
+
-

I
¥
+ 6-58 + 2.19×12
a
son % ]

+ 100-87 -

J og,mole

lemurs 02
91 -113 kg
y= mole
-

(a) Rate of blowing air __%¥×;÷×÷•%

=
2- 99 miss-1

(b) excess air

=enun I 51.34.x
stoichometne
amount
 →
6" moles
(c) Son
= 109.64 mob
$03 →
21 .

4=109.64
" <
→ 83-91-1
.

+22.4ms
02 → 8- 19%

(d) Song + KOH - kasoyttezo /

MY
yesnob
oysrsg
502+1202-503
or or no moles
GSR
i. Total moles
ofkzsoy
=
Miles of 5026503
= 100-87 kg -

mole
 → steel ( Ms )
5 Hot metal →
ffpen-w.in
furnace

Ff
sum
↳
slag (d)
one

ringtone
Balanuiylanbon
00001
¥ Mg ✗
¥
120×004%+80×00001
=
✗

(C) Ms = 4880 tonne

"YjI?×ooi=n ✗
I
' ✗ 1-
56

(A) N = 12.77 tonnes

6385 tonnes
From this 1h
77×12
= =

mask
.

, ,

④mq -77×0045=0-575 tonnes

SIM, , 1h
=
.

Balancing Alumina
( let y be the unknown %)
of silly
6- 005 = N ✗
Y /too Miro
1305
 349%
7--2
-

(d) Hence
sickly .

) + Mn 00 .
) -1139-1%1
__ 28.15%

Mate
of
6- 50 t

chemicdkenn-i.RS +
Sitz -110g
→ Feo +
Sign +5oz

Blister production : Ghs ton → Nee +

son

Lee → 0.4×50 f- =
20T
(mass)

20,1yd
317-46
=
ly =
kg .
Mole

(moles )

Crab
3T¥ 158-73 kg.mn
= =

(mown

:
cuds man = 15873×158--25079.365 1g

Remaining mass =
50,000 -25079.365
(Fel ) 24920.96635
=

Now , let us assume man

of slag as kkg
& man
of flunasykg
Balaneiyt.edu
9h0 -635
÷
+

01b¥,¥g×y
✗ 6
=
07×51 ✗ u

56-116
from from
matte flynn
9
from
slag
15859
1018g 0.5445W
=
t o
-

Balancing
-
£02
epomthen ☒ from slang
8g 0.3W
o =
-

Solving for n&y

(a) y =

11745.925kg
(b) Us 31322.512kg
How set the blister as m

of
man

Balancing
4969.8376%4,3×+2-32=0
-985m
20,000 +

M = 20684.962
(C)
 (d) Onvegd
224%0.96635×3-2 ✗ 22.4 Mm}
.

]
3 Nm
5233
•

Blowing time 5233.3 -

S =
830476s

021 3
=
2.31 hrs

(e) .
02 =/ 58-73×22.4 Hms
nqd
.

Blowing line
352,551€
59.256min
=
=

7.
softened -

leadtonnes )
( Uo
As / tonne
85kt As
= 340 kg
unsaturated 2h → n tonnes
?⃝
 t
7- n tonne Pb
2n lg Ag , 0 -

1-

4$00 -
tan ) 1g zn

this is equivalent to
y
tonne bed containing
1kg 2h per 05kg Ag
"

veal + ( rust ( 70% Pb Aging)

chemicals ,

hag -132h Agin ]

Many
of
2h → (300-12) n -

5.2g kg
-
: Mass
of Ag
=

2gx(-
Massy Agzznz =

§
✗ ( -1-1

Since crust contains 701 Pb -

total
mass
of bed =
¥ y
balance
Ag
340 -11.2h =
00026g +2,4298 -8m
-52g)
① 198-3-46442=340
-
 Pb balance

40,000 -1700m
y (0.0052+0--00252×2)
= -

¥ told
+ ✗

may
g
467 -6N
lmt
② 988
-156g +40,000=0
-
-

From ① & ②

2=2.44569 tonne

(a) I = 41.6367 tonne

(b) weight of first

µ
yvemoued
,
=/ 71.41 kg

(c) weight 92h LAH

3g
= ✗ M

nyd
( pure
2h ) = D- 163 tonne
8. one →
Ffurnace

☒
-
piqiron
coke

Basis ltonne gases

Égivm -

1000kg It
iron
coke Ratio
=
pig
It iron
flan uoolg pig
=

Dalanciyfe
,÷×¥×n= 1000×9*-0
e
pomme
Eprom iron
one

(A) N= 1696^42
1cg
( iron one )

Si one
Balancing
Siinslag =
1696.92×-12×2-0
pig iron
( unknown) 100 60
b
+

I
1052*4%1201 -1000×1--4
100
coke
 069 kg
130
Slag
-

Since moles
of
convened
Algo } are

A
1203 1203
1696.42/1,8-0
= A =

,
↳ lag ) ( one )

=
13571 kg
GO KO
slag law] ? ↳
→
in =
3801g

100dg
→
56kg
380 212.3kg
59¥80
i.
kg = =

(b) Slag = 130.069+212-3

mass = 978-579 kf

(c)
 red mud rely
mass
of
=

9. Assume

1000kg Daniele =
Home
given :
of
(d) From mass balance
of, Fei }

0-26 ✗ N = 0-06 ✗ 1000

NZ230.769l@
red
present in mad -_ 0.14×230.79
(b) Ngo
= 32 306
.

kg

For insoluble compounds

*
Moly Moles
§ moly
= =

Na ,
Sion
, AGO]
( lost /

total weight
of sign
:
__
004×1000

40
kg
=

i. total Alnoz present Bansi b- = 058%00

in
= 580 kf

we have ,
Mobs Na oxmol wt Abo}
Alzo , lost
-

of
.

=
weiiut ,
 =3h¥n ✗ 10h 53 155kg
= -

lost
i. weight of Aho,
5¥55 32s
= - 1-

% lost
5%-55×100=9
= -

17%

C) Total loss
of D-
120] content =

5316kg
( Banik )
1m06 4m06
(d) Of insoluble ago,
=

compound
Total Naoh =
2×32.31×40
lost
-62
= 41 .

69

lost
4%90=1042
total NaOH
1g sign
=
12 .

Atsumi
Al
'
iron in burden enters hot
metal

1m06 Fe moles
203 → 2 Fe

( in burden)

158 69g of Fezo]

→ 110
beg Fe
of
-
-

160 ✗ 103 Fez 0 ] I 111 604

kf Fe
g of of
-

Fe is
present 95% A =

111.6041g of
Fe

: mass of =
"" ✗ too

compound 95

=
117.478 kf

: yy .
C = 4699 kg

2% Si = 1.175 kf
-778 -469s
removing
= 73 30L-

Laf
 252 Si
541g of silat kg of
I 1748
=L 5. 2
-

remaining
-

.
: Si
= 24-0252 kg

mom
of Si
=

LA✗É 41.957 mobs

83-914 moles
028yd
: - .
=

( → 02 & Cto → to
→
v02

-
:
C moles =

23×8391955-943 =

}
( 2 73-301-55-94] 12×15
removing ✗

= 72 .
⑥ 297 kg

160197 Fero]
0,13512¥ 160kg
✗ 0

= 48 .

396kg 0
 from
0
48.4317 C
kfof
- -

Now amount
of
0
present in remains
Sion
=L 4. OR 52 ✗ 2×16
-

28
=
27.4573 1g
Total sioz Mcweeney =
24.0282 + At 4573
= 51-4825 kg

Cato → Go +
coz

1g of GW ] kg
100 56
of 60
→

& 44kg of ↳
2

of slag
56
1g -60
lomposition :

484317 1g
→
C

20 hey → A 1202

51
-48261g si 02
-
e

175.91421¥ slag