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ABSTRACT
Red algae cellulose is a promising feedstock for value-added industrial products because
it has a faster growth rate, thinner fiber structure, and is easier to extract fiber fromthan
wood. To evaluate red algae cellulose as a feed material for its potential applications,
CNFs were produced with bleached red algae pulp and then the CNF films were
characterized in this study. Both CNFs from the 1-stage and 3-stage bleached red algae
pulps were well fibrillated, although the CNF from 1-stage bleached red algae pulp
contained short fibrosis and fibrillated fibers due to residual non-cellulosic compounds.
The aspect ratio of the CNF from 3-stage bleached red algae pulp was higher than that of
the wood-driven CNF. Besides, the film fabricated with the 3-stage bleached red algae
CNF produced a tensile index value of 117.1 Nm/g, which was comparable to the strength
of the wood CNF film. The 3-stage bleached algae CNF film had higher elongation and
water resistance than the wood CNF film. Thus, utilization of red algae as a raw material
for CNF production can widen the choice of feedstocks for potential industrial
applications.
(d) (e)
Fig. 2. Particle size distribution of HwCNF, red algae pulp and CNF (left:
single-stage bleached, right: three-stage bleached).
(d) (e)
필름의 인장지수는 표백 과정을 거침에 따라 증가하였고 작된 필름에서 1단 표백 펄프로 제작된 필름을 제외하고
이는 표백 과정에서 근양사 표면의 피질 세포와 리그닌 HwCNF 필름 연신율의 80% 이상에 해당하는 높은 연신
9)
등의 제거로 인해 셀룰로오스 섬유 추출이 더 잘 이루어 율을 나타냈다. 또한, 3단 표백된 홍조류 CNF는 목재 펄
지고, 섬유 간 표면적이 증가하면서 섬유 간 결합이 용이 프 CNF보다 높은 연신율을 나타냈다. Seo 등23)에 따르
해 섬유 간 결합력이 높아졌음을 추측할 수 있다. 3단 표 면 홍조류 섬유의 좁은 폭으로 섬유 간 결합 면적이 넓어
백 홍조류 CNF의 경우 표백된 펄프에서 피브릴화가 효 홍조류 섬유의 강도가 목재 펄프 강도보다 낮음에도 높
과적으로 진행돼 섬유 간 표면적이 넓고, 100 μm 대 크 은 파단 길이를 가진다고 보고된 바 있다. 본 연구에서도
기의 섬유와 20 μm 대 크기의 섬유의 혼재로 미세분과 HwCNF와 3단 표백 홍조류 CNF의 연신율을 비교했을
장섬유 사이 수소 결합이 활발히 이루어져 117.1 Nm/g 때, 목재 CNF의 입자 크기가 더 작음에도 불구하고 홍조
과 같이 높은 인장지수 값을 보인 것으로 사료된다. 꺾은 류 CNF의 연신율이 더 높은 것을 확인할 수 있었다.
선 그래프에 나타낸 연신율은 홍조류 펄프와 CNF로 제
사사
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