UDC 678. 743. 22-462: 628. 143.2 This standard was revised in 5, 1977 JAPANESE INDUSTRIAL STANDARD Unplasticized Polyvinyl Chloride Pipes for Water Works Service © JIS K 6742-101 This English version does not give the numerical values in terms of SI units which, in the recently issued Japanese text, are given in braces after the values in customary units as a transitional step. Reference to the original Japanese text is recommended if necessary. Translated and Published by Japanese Standards Association 8s Printed in JapanUDC 678.743.22-462:628.143.2 @) JAPANESE INDUSTRIAL STANDARD SIs Unplasticized Polyvinyl Chloride Pipes for Water Works Service K 6742-1971 (Reaffirmed: 1975) + Scope This Standard specifies rigid polyvinyl chloride pipes for water works service which are used under conditions of hydrostatic head not more than 75 mm, hereinafter referred to as the "pipes". 2, Method of Manufacture and Material 2.1 The pipes shall be manufactured from the materials based on polyvinyl chloride resins by means of extruding machines properly heated. 2.2 The polymers and stabilizors used in manufacturing the pipes shall be of good quality and the product shall be uniform in quality, resisting to water and any substance which affects the quality of water shall not be extracted. ions and Tolerances and Reference Weight 3. Appearance, Shape, Dimens 3.1 The colour of the pipes shall be grey, and the pipes shall have smooth surfaces outside and inside and be free from injurious flaws, streaks, cracks, twists and other defects. 3.2 The pipes shall be of practically straight in the longitudinal direction and shall be perfect round in their sections with both ends cut exactly at right angles to its length. 3.3. The pipe shall meet the requirements of dimensions tolerances on dimensions and reference weights indicated in Table 1. ‘Table 1 Unit mm te | Ga face's”) Seas [tenet esename fwetat nef 3 8 £0.20 | 8 0 4000 or 000 100 150 Remarkt The relerence weights of the pipos are the figures calculated on the basis of specific gravity of the product be as 1,43 and they are not a part of this standard. Applicable Standard JIS B 7502-External Micrometers JIS B 7507-Vernier Callipers JIS Z 2241-Method of Tension Test for Metallic Materials2 K 6742-1971 4. Quatity The pipes shall conform to the requirements specified in Table 2 when tested in accordance with 5. Table 2 Test Test equirements temperature Req 7 Normal Tensile strength measured at 15°C shall be not Tension tes shall be no} * | temperature less than 500 kg/em2. Hydraulic Normal ‘The specimen shall be freo from any leakage and pressure test | temperature other defects, Fiatiening Normal ‘The specimen shall be free from any cracks and test temperature erazings. Penetration _ test under - 80°C min, heating Turbidity: 0.5 degree max. Colourness: 1 degree max. KMnO , consumption: 2 ppm max. Extraction Normat test temperature Pb consumption: 0.1 ppm max. Loss of residual chlorine: 0.7 ppm max. Odor and taste:_not detectable 5. Method of Test 5.1 Appearance, Shape and Dimensions The appearance and the shape of pipes shall be visuélly examined, and their dimensions shall be measured by means of JIS B 7502-External Micrometers or JIS B 7507~Vernier Calipers. 5.2 Tension Test A test specimen as shown in Fig. 1 shall be cut from the pipe land subjected to the tension test at a tension rate of 10 mm per minute at normal room temperature in accordance with JIS Z 2241-Mothod of Tension Test for Metallic Materials, and the tensile Strength at 15°C shall be calculated by the following formula: Jah $ 9.05 1B where, f1 tensile strength at 15°C (kg/em*) tensile strength at (°C (kg/em”) a tt test temperature (°C); applicable temperature is 5 to 30°C3 K 6742-1971 Fig. 1 ‘| ~ 7 Se =f | il f = Unit: mm ny Nom 7 > | ® rataias| * * | % 1 | | and under ” et 5 | ° ” m | 8 a » |e and over | 5.9 Hydraulic Pressure Test A test specimen not shorter than 1000 mm shall be cut from the pipe and subjected to the hydraulic pressure test applying a pressure of 35 kg per square centimeter at normal room temperature and allow to stand for 1 minute. 5.4 Flattening Test A cylindrical test specimen of 50 mm in length shall be cut from thé pipe. The specimen shall be placed between two parallel plates of smooth surfaces and compressed rectangularly to the axis of the pipe under a load at the rate of 10 mm per minute until the outside diameter of the specimen is depressed to half of the original diameter. 5.5 Penetration Tost under Heating A test specimen of 15 mm in length and 10 mm in width, shall be cut from the pipe and finished to 2 mm thickness. The test specimen shall be’placed on a metal table heated up to 50°C in a closed chamber as shown in Fig. 2. A metal needle 1mm in diameter with a flat end shall be placed on the center of the fest specimen and the load of 2 kg-weight shall be applied on the needie, The temperature of the chamber shall then be elevated at a rate of 1°C per minute. The temperature of the table at which the test specimen softens to permit the needie to penetrate to the depth of 0.1 mm shall be determined. (The temperature in the closed chamber may be about 25°C higher than that of the table.) Fig. 2 Unit : mm Test specimen /4 K 6742-1971 5.6 Extraction Test_ Bach of the respective specimens shall be cut from the pipe in the length specified in Table 3 and washed for an hour in clean running water at a speed of about 30 m per minute, Upon drained off the water drops, one end of the specimen shall be plugged with a stopper covered with the polyethylene film (1), The plugged specimen shall be rinsed one time with the test water and then filled with the fresh test water, With another end closely plugged in the same manner, the specimen containing a fresh water shall be left at the zoom temperature for 24 hours. This water shall be used for test. At the same time another lot of the test water more than 500 ml shall be propared and left standing not being exposed to the light for 24 hours at the same place as above. This lot of water shall be used for the blank test. ‘The method of preparation of the test water and the procedures of the test are described in the ‘Appendix. Note (1) The polyethylene film used for this purpose shall be washed first with 5% nitric acid and then with water thoroughly. Table 3 Napa ain Length 1B~20 + 25~ 30 2 — 40~50 1 75 and over 05 Remark: The specimen 4m long may be replaced by two specimens, 2m long each. 6. Inspection 6.1 Pipes must be inspected on the test items of appearance, shape, dimensions, tension, hydraulic pressure, flatterning, penetration under heating, and dissolution tests. Ali of samples shall meet the requirements specified in clause 3 and 4 when tested in accordance with the test methods described in clause 6. 6.2 The method of sampling should be agreed between the parties concerned. 7. Marking On the outside of the pipe, the chinese character corresponding to "water", nominal diameter, name of the manufacture or his trade mark and the month and year of manufacture shall be indicated clearly in the manner not being fade away easily.my 5 K 6742-1971 ATTACHMENT 1, Solubility Test 1 a) (2) (4) (6) (6) Reagents Lime Water Take about 100 parts of the purified water in a suitable container Fad add tes parts of calcium hydroxide. ‘The container is corked tightly and Siken thorcughly. Alto the content is left still for more than 24 hours, the srebenatant Liguid is filtered using the filter paper Class 5, into another con~ sapere a Thich about 100 parts of the purified water is filled beforehand. The Hine water thus prepared fs kept corked tightly and used as a reagent, If there Eppears membrane or precipitate in the reagent, filtration shall be conducted. Tn order to analyze quantitatively the calcium in the above lime water, to about 100 mi of the purified wator taken ina 200 ml conical flask, add 1 ml of Ete magnesium cbloride (Wl) solution, 2 ml of ammonia buffer solution and five ov six drops of EBT indicator. Then further addition of drops of M/100 Bra celution shell be made until the liquid turns into blue, (Care should be taken not to add excessively.) "phon 1 ml of the lime water is correctly added to the above liquid and titration of the liquid in'a color of the wine red shall be conducted with M/100 Sere on eld ihe quantity of the calcium in the titrated Liquid shall be calculated by the following formulas Calcium in Lime water (Ca ppm) = mi count of M/100 EDTA x At 1000 Purified Water. The distilled water or the water desalted by passing through ihe iomexchange resin, with the electric conductivity below 3 #U/em ‘Ammonia Buffer Solution To 67.5 g of ammonium chloride (NH,CD taken in a Qatker and dissolved in about 300 ml of the purified water, add 570 ml of a eekania water (28%) and increase the whole liquid to 1 litre by further using the purified water. EBT Indicator Dissolve 5 g of Eriochrome Black T and 4.5 g of hydroxylamine fydrochloride in 100 mi of ethyl alcohol (95%) and preserve the Liquid ina brown boitle, (Effective about a month.) M/100 EDTA Solution 4g of ethylenediaminotetraaceticacid, disodium salt MEMCOD)N Cle Criy=N (CH,COO)sH,Noy21,9) shall be taken and increased to 1 litre by dissolving in the purified water. ‘In order to determine the factor of this liquid, 25 ml of M/100 zine chloride solution taken correctly in a 300 mi conical flask, upon adding about 75 ml of the purified water, 2 ml of ammonia buffer solution and five or six drops of EBT indicator to the solution, shall be titrated by further adding the above EDTA liquid in drops through a burette until the wine red color of the solution een ia iluce By finding the ml count (a) of the EDTA solution used in the ‘Move process, the [actor of EDTA solution shall be calculated by the following formula: Fecwr (= ‘At the next stage, 1000/F ml of the above EDTA solution taken ina 17 meacoring flask shall'be increased to 1 litre in all by adding the purified water, M/100 Zinc Chloride Solution 0,653 g of the standard reagent zine (Zn) Washed with hydrechloric acid (1 + 3), purified water and acetone in order and seat toly dzied in a calcium chloride desiccator or a sulfuric acid desiccator sro eset sere hours beforehand, shall be taken in a beaker and dissolved by Keating on water bath in an addition of about 20 mi of purified water and > mt ae yagochloric acid (35%). Then the reagent shall be removed after cooling te yee ecnuring flask, while the beaker is washed with the purified water and6 K 6742-1971 the washing liquid is also put in the measuring flask, and the whole liquid shall be increased to 1 litre by adding the purified water. At the next stage, part (one fifth to one tenth) of the above liquid is taken in another 2. Turbidity Turbidity means degree of impurity of water and impurity that 1! of water contains 1 mg of kaolin shall be designated one degree. 2.1 Reagents and Tools (1) Kaotine for Turbidimetry About 10 g of kaolin on the market is taken ina 560 ml beaker and upon adding 300 ml of purified water and 0.2 g (a) of sodium pyrophosphate ({a,P,0,-10 1,0) it is mixed up violently for three minutes by bsing a stirrer or the like. Kaolin thus prepared shall be removed to a co~ plugged measuring cylinder, together with the purified water used for thoroughly Washing the beaker and upon increasing to 1 litre in all by adding purified water, the whole liquid shall be dispersed by shaking thoroughly for one minute. ‘After {eft still for one hour in the room temperature, the liquid 250 ml deep from the top shall be thrown away by means of siphon and the lower liquid 500 ml deep (b) shall be taken on the evaporating dish, the weight of which is known beforehand. The liquid taken on the evaporating dish shall be dried by evaporation on a water bath and further dried for about three hours at 05 to 110°C, Thereafter weight (c) of kaolin for turbidimetry shall be found by measuring in the desiccator upon cooling. Then it is ground in fine power in an agate nortar and preserved in a wido~mouthed bottle. "The weight (@) of the pure kaolin thus obtained i 41.9 Wo aisaat) Accordingly it is sufficient to obtain o/d g of kaolin for turbidimetry in order to measure 1 g of the pure kaolin. (2) Standard Turbidimetrical Liquid Kaolin for turbidimetry in ¢/d g is taken in E11 measuring (lask. Upon adding 10 ml of formalin, it is increased to 11 fn all by using the purified water. This is designated as the reserved liquid. ‘This liquid is shaken thoroughly and then taken correctly ina separate 1 1 measuring flask in 100 ml, Then it is increased to 1/_ by using the purified water. 1ml of this liquid shall contain 0.1 mg of kaolin. (3) Test Tube An about 37 cm long, co-plugged and transparent test tube with polished flat bottom and with a 100 ml marked line at a 30 em height from the bottom. 2.2 Test Procedure 100 ml of test water is taken in a test tube and the standard turbidimetrical guid shaken thoroughly is quickly and correctly taken in the same Shaped test tubes in 0, 0.5, 1.0, 2.0, 3.0 .+-++. 5,0 ml in order. The respective liquids taken in the test tubes shall be increased to 100 ml by filling the purified water. By plugging the tubes, they are shaken quietly and shall be used as the standard liquid. These liquids are then placed on the black paper, and by seeing through from above, turbidity of the test water is compared with that of the standard liquid. ‘Then, upon obtaining ml count (a) of the corresponding standard turbidimetrical liquid, turbidity Shall be claculated by the following formul7 K 6742-1971 where, T: Turbidity (degree) 1: Sample water (ml count) 3. > Chromaticity Chromatocity is to show the color degree of water and the color of the standard turbidimetrical liquid which is viewed when 1 ml of the liquid is increased to 1! by filling water, is designated one degree. 3.1 Reagents and Tools (1) Standard Chromaticity Liquid 2.4912 ¢ of potassium chloroplatinate (GPC) etaing Tg ot Pi), 2,0005 F of crystalline cobalt chloride (CiCh-6th0) (contain 0.496 g of Co) and 200 mi of hydrochloric acid (35%) shall be taken ina 1/ measuring flask and increased to 1 in all by dissolving in the purified water. 1'ml of this quid contains 1 mg of platinum (Pt). (2) Test Tube Same as specified in the above item of Turbidity. 3.2 Test Procedure 100 ml of test water is taken ina test tube and the standard chromaticity Liquid is correctly taken in the same~shaped test tubes in 0, 0.1, 0.2, 0.3 cesses 1,0ml in order. The liquids taken in the test tubes shall be increased to 100 mi respectively by filling the purified water and used as the standard liquids. ‘Upon mixing by shaking, these liquids are then placed on the white paper, and by seeing through from above, chromaticity of the test water is compared with that of the Standard liquid, Then upon obtaing mi count (a) of the corresponding standard chromaticity liquid, chromaticity shall be calculated by the following formula: 1000 Cmax where, C1 Chromaticity I: Test water (m1 count) 4. Consumption of Potassium Permanganate 4.1 Reagents and Tools Reagents and tools used are specified as follows: (1) Ditute Sulphuric Acid After one part of sulphuric acid (95%) is slowly added In shaking to two paris of purified water, potassium permanganate solution (0.5%) shall be added in drops to the liquid heated on a water bath until the faint red color keeps remaining. (2) N/100 Sodium Oxalate Solution 0.670 g against 100% of sodium oxalate 0" Sofution taken na T7 “measuring flask shall be increased to 1! in all by Gissolving in the purified water. This solution shall be kept in a co-plugged, brown-colored bottle. Tl of the solution corresponds to 0.316 mg of potassium permaganate. (3) N/100 Potassium Permanganate 0.32 to 0.34 g of potassium permanganate Ghinb), shall be taken ina 27 beaker, and by adding 1050 m! of purified water it is boiled calmly for one to two hours. After that, upon standing Tani in the dark for one night, the supernatant liquid shall be filtered by the glass filter (G4), (The filter shall not be washed with water before nor alter filtration.) The liquid shall be preserved in a dark place in a brown bottle which is vapor-sterilized beforehand for 30 minutes. The factor of the liquid shall be determined in each use. Procedures of determination of the factor of the liquid are specified as below: to 300 mi of purified water taken in a clean conical flask, 5 mi of dilute sulphuric acid is added; upon adding 5 ml of potassium permanganate8 K 6742-1971 by using a brown colored burette, it is boiled by direct fire for 5 minutes; after boiling, the fire is removed, and immediately 10 ml of N/100 sodium oxalate solution is added by a separate burette; alter discoloring, potassium permanganate is again added in drops until the faint red color keeps remaining to this liquid 5 ml of dilute sulphuric acid and 5 ml of potassium permanganate are further added and after boiling for 5 minutes, by adding 10 ml of N/100 sodium oxalate solution as in the former case, the liquid shall be titrated immediately with potassium permanganate solution. Finding the total ml count (a) in the second case of previously added 5 ml of potassium permanganate solution and the potassium permanganate solution consumed in titration, the factor shall be calculated by the following formula: 10 F where, F: Factor (4) Glass Beads These are beads made of glass, with diameter of about 2 mm and of good quality. These beads are boiled in sulphuric acid (4N) for about 30 minutes, washed with purified water thoroughly until the washing water becomes neutral (which is confirmed with the litmus paper), dried at 105 to 110°C ina drier and preserved in a glass bottle. (5) Clean Conical Flask A conical flask with capacity of about 300 ml is first washed thoroughly. Then it is filled with 100 ml of purified water, 5 ml of Gilute sulphuric acid, 10 ml of N/100 potassium permanganate solution and several pieces of glass beads and boiled for about 5 minutes. ‘At the next stage, the content of the Mask shall be discolored by adding 10 ml of N/100 sodium oxalate solution, and then N/100 potassium permanganate solution shall be added in drops until the faint ved color keeps remaining. The content of the flask shail be thrown away So that the glass beads may remain in the flask and the flask shall be used for test directly. 4.2 Test Procedure Take 100 ml of sample water correctly in the clean conical flask and add 5 ml of dilute sulphuric acid. Then upon adding 10 ml of N/100 potassium permanganate solution by using a brown burette, it is boiled by direct fire for 5 minutes, Immediately upon removing the fire, 10 ml of N/100 sodium oxalate solution is added using a separate burette and the liquid is discolored. N/100 potassium per- manganate solution is directly added in drops to the above liquid which is then titrated until the faint red color keeps remaining. The total ml count (a) of the N/100 potassium permanganate solution consumed in the former and the latter procedures as above shall be found. ‘Separately, with respect to 100 mi of the blank test water, tost procedures under the same conditions as the sample water shall be exercised and the total ml count (b) of the N/100 potassium permanganate consumed for tosting the blank test water shall be found. Consumption (ppm) of the potassium permanganate shall then be calculated by the following formula: . Consumption (ppm) of potassium permanganate at ml count of X/100 potassium permanganate against 100 ml of sample water bi mi count of N/100 potassium permanganate against 100 mt of blank test water Factor of N/100 potassium permanganate 1: Measured quantity (ml count) of the sample water and the blank test water9 K 6742-1971 Lead 5.1 Reagents and Tools Reagents and tools used are specified as follows: (1) Ditnizone Primary Solution Dithizone with purity of about 957% and above is ground in power using a clean agate mortar. 0.1 g of the powder is edded to 200 ml of carbon tetrachloride, This is mixed now and then and left dissolving by standing for 24 hours and more. This mixture shall be used as the dithizone primary solution, When the dithizone contains a lot of impurities or comes to Contain increased oxidized substances, it shall be refined by the next procedures. 0.1 g of dithizone dissolved in 30 m1 of chloroform is taken in a separating funnel, Itis shaken thoroughly by adding 30 ml of ammonia water (0.15N) and stood still. When a water layer is caused, it shall be separated. This pro- cedure is repeated further two times and the water layers separated are Combined in a 200 ml separating funnel. After shaking thoroughly upon adding 5 mi of carbon tetrachloride to this, the carbon tetrachloride separated in Standing still is thrown away. After the above washing operation is repeated further two times, the water layer is made faintly accidic by adding hydro~ chloric acid (3N), Dithizone is extracted three times by adding 60 ml of carbon tetrachloride each time to the above, The extracted liquids are combined and used as the dithizone primary solution, which shall be preserved in a cool and dark place. ‘Approximate measurement of concentration of the dithizone primary solution shall be made as follows: 1 ml of dithizone primary solution is taken correctly in a 100 ml measuring flask and increased to 100 ml in all by adding carbon tetrachloride. With regard to the above dilute liquid, the photo-absorption rate (E) is measured using 10 min absorption cell at 620 mm wave-length and from this, concentration of dithizone primary solution shall be measured approximately. Concentration (mg/l) of dithizone primary solution =955.3%~[-»100 Note: ©483( extinction coefficient of the molecule of dithizone carbon tetrachloride 10°) (2) Dithizone Solution for Extraction Use Dithizone primary solution is taken in an adequate quantity to which carbon tetrachloride is added so that 1 ml of the Solution may contain about 0.05 mg of dithizone, Tin use, a necessary quantity shall be taken in a separating funnel and after shaking upon adding dilute nitric acid (abt. 0.15N) in half quantity, it shall be used upon removing the water layer. Standard Lead Solution 0.1599 g of lead nitrate ‘Pb(NOD) is taken ina 11 measuring flask and upon adding 1 ml of nitric acid (60%), increased to 1! in all by adding the purified water. This is designated the preservation solution. ‘On each occasion of use, 10 ml of the preservation solution shall be taken correctly in a 500 mi measuring flask and increased to 500 ml in all with purified water, 1 ml of this solution shall contain 0.002 mg of lead (Pb). (3) Standard Lead (4) Ammonium Citrate Solution 50 g of ammonium citrate, dibasic is dissolved in 700 ml of purified water; upon adding 2 or 3 drops of Thymol Blue indicator, ammonia water is further added until the liquid turns into blue. At this time, outside of the container shall be chilled with ice in care of exothermic reaction. ‘Phis liquid is then removed to a 200 mi separating funnel, and mixed by shaking upon adding each 10 ml of the dithizone solution for extraction use, so that impurities in the Liquid may be extracted and removed. This operation shall be repeated until the dithizone solution comes to keep the proper green color. ‘At the next stage, each 10 ml of carbon tetrachloride is added to the solution and by shaking the surplus dithizone shall be removed. This operation shall be repeated until color of the carbon tetrachloride comes to be plain,10 K 6742-1971 (5) Hydroxylamine-hydrochloride Solution 20 g of hydroxylamine hydrochloride is dissolved in 65 ml of purified water and upon adding 2 or 3 drops of Thymol Blue indicator, ammonia water shall be added until the solution shows blue color. At the next stage, as in the case of ammonium citrate solution, it is refined by using dithizone extraction solution and carbon tetrachloride, (6) Purified Water without Carbonic Acid The purified water that is redistilled or passed through the ion exchange resin shall be boiled so that carbonic acid gas or other volatile matters may be removed. Then it is cooled down to the Foom temperature so as not to absorb carbonic acid gas in the air. The purified water thus prepared shall be used for the test. (7) hymol Blue Indicator 0.1 g of Thymol Blue (ColhxO:S) ig taken in an agate mortar and upon dissolving completely in 10.75 ml of N/50 sodium hydroxide, it is removed to a 250 ml measuring flask. it is then increased to 240 mi in all by adding the purified water without carbonic acid, (8) Potassium Cyanide Solution 5 g of potassium cyanide increased to 50 ml by dissolving with purified water, (9) Ammoniacal Potassium Cyanide-Citric Acid Solution 10 g of potassium eyanide is dissolved in 500 ml of ammonia water (28%), and upon dissolving 10 g of citric acid in it, is increased to 1/ by using purified water. (10) Carbon Tetrachloride Refined one. (11) Glass Tools Glass tools shall be washed carefully with warmed nitric acid (GN) and further washed with purified water thoroughly before use. 5.2 Test Procedure Sample water in 50 ml (quantity that contains 0.002 to 0.015 mg of Pb) is taken in a 100 ml separating funnel and upon adding 10 ml of ammonium citrate solution, 2m of hydroxylamine hydrochloride solution and 2 to 3 drops of Thymol Blue indicator, ammonia water is added until the solution appears blue, Then after adding 4 ml of potassium cyanide, nitric acid (N/10) is further added in drops until the whole solution shows green color, (pH value: 8.5 to 9.0), To this solution, 5 ml of dithizone solution for extraction use is added, and upon standing still after shaking for 30 seconds, the layer of carbon tetrachloride shall be removed to the second 100 ml separating funnel. To the first separating funnel, 5 ml of dithizone for extraction use is added again and, upon standing still after shaking for 30 seconds, the layer of carbon tetrachloride shall be removed to the second separating funnel, To the second sepa: rating funnel, 20 ml of nitric acid (N/10) is added and upon standing still after shaking violently for one minute, the separated layer of carbon tetrachloride shall be thrown away. The water layer is increased to 50 ml by adding purified water, to which 4 ml of ammoniacal potassium cyanide-citric acid solution and 5 ml of dithizone solution for extraction use shall be added correctly. This liquid shall be mixed by shaking for one minute and upon standing still, carbon tetrachloride shall be removed. This is used as the test liquid. Separately, standard lead solution in 50 ml (Pb: 0.01 mg) is taken correctly ina 100 m1 separating funnel and increased to 50 ml by adding purified water. ‘Then same procedures as the sample water shall be conducted with the increased sulution and with 50 ml of the blank test water, and upon removing carbon tetrachloride, these are used as the standard solution and the blank test solution respectively. "At the next stage, the test liquid, the standard solution and the blank test solution shall be taken respectively in the absorbing cells and upon measuring each photo absorption rate around the wave length of 510 mm by using the electric photo-meter, ppm of lead in the sample water sball be claculated by the following formula:" K 6742-1971 where, L: ppm of lead a: Photo-absorption rate of the test liquid bi: Photo-absorption rate of the standard solution ct Photo-absorption rate of the blank test solution 1: Sample water (ml) 6. Reduction of Residual Chloride 64 (1) (2) (3) (4) (5) Reagents and Tools jolidine Solution 135 g of o-tolidine dibasic hydrochloride ((CH,CHNHD: + THCH is dissolved in about 800 mi of purified water, and upon adding 150 ml of hydrochloric acid (35%), increased to 1/ using the purified water. This shall be preserved in a brown bottle. Purified Water without Carbonic Acid Refer to 5.1 (6) in 5. Lead. Buffer Solution 22.86 g of disodium hydrogen phosphate (Na,HPO) and 46.14 of monopotassium phosphate (KIl:/0) which are previously dried and left cooled in the desiccator shall be dissolved and increased to 11 in the purified water without carbonic acid. Then, after standing still for several days, the separated precipitate shall be filtered. This is used as the primary solution. ‘At the next stage, 400 ml of the primary solution shall be increased to 2/ by adding the purified water without carbonic acid and it shall be used as the buffer solution, The pH value of this buffer solution is 6.45. romate-Potassium Bichromate Solution 4,65 g of potassium chromate’ (K:C:O,) and g of potassium te (K,Cr,0;) shall be taken §na 11 measuring flask and increased to 1/ in all by dissolving in the buffer solution. The above solution shall be corked tightly and preserved in the dark. When precipitate is caused, it shall be filtered by glass filter (G3) or filter paper (Class 5-A). The solution over 6 months old shall not be used. Standard Color Comparison Liquid of Residual Chloride The potassium Ghromate=potassium dichromate solution shall be mixed with the buffer solution in the ratios on the following list, and taken in the 100 ml color comparison tubes respectively, and the ppm values of the corresponding residual chloride shall be determined.| 12, K 6742-1971 Standard Color Comparison Liquids of Residual Chloride (Liquid layer : 20 em high) Team spare ieee a 0 ae Eg 03 rr as 7.0 aa |e a8 a0 wo oe a ar 70 og ar a 8 oy ie ine og iz Be wo 1s ae 87.0 15 a0 20 Ey Ro Tho «e a ao — oo 70 so | ae (6) 100 mi Color Comparison Tube Co-plugged, flat-bottomed and plain test tube, 35 cr Tong, With 100 mi marked line at the height of 20 2 0.3 cm trom the bottom. 6.2. Test Procedure 5 ml of o-tolidine solution is taken in @ 100 mi color compari son tube, and upon adding the sample water aa high as the marked line (pH value #1-3 and below), it shall be stood still for 5 minutes, Then, the color shown in the sample water is compared with that of the standard color comparison quid of residual chloride prepared in a color comparison tube of the same size and the ppm value of the residual Chloride in the sample water shall be determined by the corresponcing standard color comparison liquid. "AL the next stage, the pom value of the residual chloride of the blank test water shall be determined in the same procedures as above, and the difference of this value from that of the sample water shail be deemed to be the reduction of the residual chlovide 7. Odor and Taste 7.1 Test Procedure About 100 ml of sample water is taken in a co-plugged conical flask and after warming the lightly corked flask at 40 to 50 °C, odor and then taste are inspected immediately upon uncorking.Translation without guarantee In the event of any doubt arising, the original standard in Japanese is to be evidence