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76. Which 112. Consider following two reactions 119. Geometrical isomerism is not shown by:
of the following is a redox reaction? 84. Acetylene reacts with hypochlorous acid to form:
(a) Naci + KNO, NaNO + KC1 A Product - k ,[AJ° (a) 1, 1-dichloro-1-pentene
(b) CaC,O4 +2HCl CaCl2 + HC04 (a) CCHGHO (b) CICHcoOH
(b) 1, 2-dichloro-1-pentene
(C) CHCO (d) ciCH,CHO
() Ca(OH)}h + 2NH,CI Caclh + 2NH
85. On heating benzyl amine with chloroform and B Product - k [B] (c) 1, 3-dichloro-2-pentene
21H,0 (d) 1, 4-dichloro-2-pentene
(d) 2K[Ag(CN),] + Zn 2Ag ethanolic KOH, product obtained is: k and k are expressed in terms
n s of molariy
molarity
120. Number of atoms in the unit cell of Na (BCC
(a) L)and time (s-1a
(c) benzyl alcohol (b) benzaldehyde mol
+Ka[Zn(CN),] benzonitrile (d) benzyl isocyanide Ypecrystal) and Mg (FCC ype crystal)
are
77. For an ideal gas, number of mol per litre in (a) s,Ms( 6 ) M s", Ms
respectively:
terms of its pressure P, temperature T and gas 86. Which of the following reaction is possible at ) s , Ms (d) Ms",s
(a) 4,4
constant R is: anode
(a) ?
F +2 2F
113. RNA contains (C) 2, 4
(a) (6) PRT a) ribose sugar and thymine 121. Which of the following compounds has
(6) nibose sugar and uracil
6) 2H° +O2 + 2e HO incorrect IUPACnomenclature ?
C) deoxyribose sugar and uracil
RT ( 205+7H0 Co} (d) deoxyribose sugar and thymine
78. Number of P-O bonds in P,O10 is +14H+6e 114. For a cell given below: (a) CHCHCH,COC,H,
(a) 17 (b):16 (d)Fe F+e Ag lAg"||Cu*"| Cu
(c)1 (d) 6
87. Which of the following concentration factor is (b) CH,CHCH,CHO
79. E°-X
KO2 is used in space and submarines because it:
(a) absorbs CO2 and increases O, Concentration
afected by change in temperature ? Ag + Ag H
(6) absorbs moisture
(a) Molarity (b) Molality Cu22e Cu, E°=y L.mcthyl butanal
3-mcthyi butanal
(c) Mole fraction (d) Weight fraction
() absorbs CO2 E° cell is
88. Cyanide process is used for the extraction of (a)x+ 2y
(d) produces ozone 6) 2x+ (e) CH,CHCCHCH
80. Which of the following ions has the maximum (a) bariumm silver ()y- (a) y - 2x
() boron () zine 115. Based on kinetic theory of gases following laws
magnetic moment ? CH3
(a).Mn2* (b) Fe2* 89. Following reaction can be proved: 2-methyl 3-pentanone
(CH,)CBr + H,0 (CH3)%COH + HBr (a) Boyle's law (b) Charles law
Ti2 d)C2
(c) Avogadro's law (d) all of these
(d) CH,CHCHCH,
is an example of:
81. Acetylene does not react with:
(a) elimination reaction
116. MnO is a good oxidising agent in different H.C OH
(a) Na
HCI
(b) NaOH
(d) ammoniacal AgNO
AgNO (6) free radical substitution
medium changing to -2-methyl-3-butanod
MnO4 Mn* 122. End product of the following reaction is:
82. Compound A given below is : () nucleophilic substitudon
(d) electrophilic substitution Mnog
OcOCH 90. A metal M forms water soluble MSo, and inert MnO2 alcobolic KoH
CH,CHCOOH
coOH MO. MO in aqueous solution forms insoluble Mn0
MOH% soluble in NaoH. Metal M is: Changes in oxidation number respectively are:
(a) 1,3,4, 5 (b) 5, 4,3,2 (a) CH,CHCOOH (b) CH,CH,CoOH
(a) Be
() Ca
(6) Mg
(d) Si
c5, 1,3, 4 (d) 2, 6, 4,3 OH OH
the
(a) antiseptic (b) antibiotic 91.
Half-life of asubstance A following first order 117.For the reaction: H + l2 2H1, (CH,=CHCOOH () CH,CHCOOH
(c) analgesic (d) pesticide kinetics is 5 days. Starting with 100g of A, differential rate l2
83. For the following cell with hydrogen electrodes amount lefk after 15 days is:
(a)- =-al_2 d[HI) OH
123. For the following reaction in gaseous phase
at two different presSures P and P2
(a) 25 8
()12.5g (b) 50g
(d) 6.25 g
b)-2d.-2dl.d[HI)
Pt(H)| H°ag)| Pt{H;) CO +02 o2 K,/K, is i
IM P2
92. The most stable ion is: ()- =- dt
(a)[Fe(OH)s1 (a) (RT2 (0) (RT)V2
emfis given by: (b)[FeC,1 a)-d-d. d[Hn
(a)log. (b)log, P2 ([Fe(CN)% (d)[Fe(H,O)J*
118. Number of atoms in 560g of Fe (atomic mass
(C)(RT) (RT)
93. A substance forms Zwitter ion. It can have 124. Energy of H-atom in the ground state
() 2F log, P functional groups 568mo that
a) twice
?5 70 N
of g -13.6 ev, hence energy in the second excited
(a)-NH2-COOH (b)-NH2,-SOH
(c) both (a) and (6) (d) none of these (b) half that of 20 g
state15:
(b) - 3.4 e
c) both (a) and (b) (a)-6.8 eV
(C)- 1.51 eV (d) -4.53 eV
(d) none of the above
https://www.gofacademy.in AIEEE 2002 Old Question Paper by GOF Academy
125. A square planar complex is formed by (c<o <0 <02 1.Ifa Band a = Sa -3, =5ß-3, then the 10. cor (cos a) - tan (Wcos a )- x, then
hybridisation of the following atomic orbitals:
equation having a/ß and B/a as its roots, is: sin x is equal to:
(a) s, Pa Py» Pa» d
PPy
133. Most common oxidation states of Ce (Cerium) (a 3x 19x + 3= 0 (b) 3x -19x +3=0
are:
c) d, (c) 3x 19x -3-0 (d)x*-16x+ 1=0
) s, Pa* , d, dd
s, Prs Py» Pa» d,
(a) +3, +4 b +2, 3
+ 2 , +4 (a) +3,t+5
126. Type of isomerism shown by[CrONHGs NO2}da 134.ce*, La*, Pm* and Yb" have ionic radii in
2.If y =(x+ y1+ x*y, then tan a
the increasing order as: 11. The order and degree of the differential
a) optical (b) ionisation (a) La*" < Ce* < Pm < Yb*
(C) geometrical (d) linkagee - ny
127. One of thefollowing equilibria is not affected by (6)Yb**< Pm*" < Ce* < La* a))n'y
()-y (d) 2xy equation1+3 4 are :
Cprotonanon of monomers
(d) (CH,CO andCH,(CO0OH)% (d) neither right angled nor isosceles a))256 (b) 512
(d) none of the above (d) none of these
140. In the following benzy/allyl system 9. In a class of 100 students there are 70 boys c) 1024
132. Increasing, order of bond strength of 10
O2, 0z Oz and O is whose average marks in a subject are 75. If the 18. sin x| dx is:
R-CH CH or
average marks of the complete class is 72, then
(R is alkyl group) what is the average of the girls? (a) 20 (b) 8
decreasing order of inductive effect is : (a) 73 (D) 55 ) 10 (a) 18
(C) 68 (d) 14
(c) (CH,CH->CH,CH-> (CH,),C -- (d) NaNH2 +H2 https://www.gofacademy.in AIEEE 2002 Old Question Paper by GOF Academy
(d) (CEl,),C-> CH,CH-> (CH3hCH- 147. Maximum dehydration takes place that of 19.1,-tan"x dr, then lim ntat I 28. The greatest value of
141. PCl3 and PCls both exist; NCI, exists but NCls fx)=(x + 1 ° -(x-19 on [0, 1] is :
does not exist. It is due to: (b) 2
(a) lówer electronegativity of P than N (b) 1 (d) 1/3
(6) lower tendency of N to fornm covalent bond (c) (d) zero 29. Evaluate
sin X dx
. c) availability of vacant d-obital in P but not in OH Sin x + VCOs X
20.Ctdr is:
N
(d) statement is itself incorrect QH
a 2-2 (6)222 ( (b)
142. Pollowing vypes of compounds (as L, ) ( ) v2-1 d)-2-3+S (C) zero (a) 1
149. Oxidation number of Cl in CaOClh (bleaching 32. The differential equation of all non-vertical
144. A heat engine absorbs heat 4 from a source at 24. If sin y x sin (a + y), then i s
lines in a plane is :
temperature T, and heat 2 from a source at powder) is
temperature T2- Work done is found to be
(a) zero, since it contains Gla (a)Sina (b)sin (at sin a
(a)
iin
(G + 2) This is in accordancewith (6)-1, since it contains C
(c) +1, since it contains ClO
(a) first law ofthermodynamics (c) sin a sin (a+ y) (d)
(d) +1 and-1 since it contains Cl0" and CI
(5) second law of themodynamics
() Joules equivalent law 150.Picric acid is: 25. Ifx - , thenis 33. Given two vectors are i - j and i +2j the unit
(a) 2
4
b)-2
(d) 3 7(i+ 2+ 2k)=15 and |F -+2k)| =4 ( tan zero
(6) 2
is:
54.Three
2 4 * + 7 ystraightlines 2x -+11y-5=0,
- 20 = 0 and 4x - 3y 2 0: 7. i dog is equal to :
aCo 1,2 , 3,4
(a) none of these
(d) 4
(a) fom a triangle
(b) are only concurrent
(),3,4 (a) log, * (b) x
(d) none of these
() are concurrent with one linc bisecting the 62.The value of is () los
angle between the other two
1+tan 15° -1-t-1. . .
equal t
(d) none of the above (a) 1 (b)3
55. A sraight line through the point (2, 2) intersects
the lines 3x + y = 0 and v3r-y =0 at the (d) 2
points A and B. The equation to the linc AB so
that the triangle OAB is equilateral, is : 63.If tan 9=-then sin Ois:
72 a(c)
(c) no solution 62. 53.
57. ( 66. (a 59. (a) 60. a) 70
(d) none of the above 67. (b) 68. (C)
65. (d)
73. (d) 74. (d) 5. ()