TX-230H 型高空速脱硝催化剂使用说明书

The specificationservice manual forof TX-230H high

space velocity deNOx catalyst

化学品名称： 脱硝催化剂（TX-230H）
Chemical name: DeNOx catalyst (TX-230H)
西安元创化工科技股份有限公司（原西北化工研究院）
企业名称： Xi’an Origin Chemical Technologies co., Ltd. ( FormerFormerly
Enterprise Name:
Northwest Research Institute of Chemical Industry)
陕西省西安市临潼区火车站街 1 号
地址：
1 Railway Station Street, Lintong District, Xi’an City, Shaanxi
LocationAddress:
Province
邮编：
Zip code: 710600
咨询电话：
+86-29-89129883，+86-29-89129882
Tel.:
编制日期： 2018 年 11 月 15 日
Compile Date: 15.11.2018
修订日期： 2018 年 11 月 15 日
Revision Date: 15.11.2018
编号：
NO.: 20181115001

西 安
元创化工科技股份有限公司（原西北化工研究院）
Xi’an Origin Chemical Technologies co., Ltd. (FormerlyFormer Northwest Research Institute of Chemical
Industry)
TX-230H(说明书) 20181115001 2018 年 11 月 15 日
TX-230H (Specification) 20181115001 15.11.2018

1. 产品概述
Product overview
TX-230H 型高空速脱硝催化剂产品由改性二氧化钛载体负载金属氧化物五氧化
二钒及助剂组成，该产品主要应用于硝酸（盐）工业尾气中氮氧化物（ NOx）
的脱除。
The TX-230H high space velocity deNO x catalyst is composed of a modified titanium
dioxide carrier, a metal oxide pentoxide supported with vanadium pentoxide and an
promoterauxiliary agent. , This product isand is mainly applied to the removal of
nitrogen oxides (NOx) in the tail gas of nitric acid (salt) industry.
in the nitric acid (salt) industrial tail gas.
2. 工作原理
OperatWorkinging principle
主反应：
Main reaction:
4NO+4NH3+O2→4N2+6H2O
6NO2+8NH3→7N2+12H2O
2NO2+4NH3+O2→3N2+6H2O
NO+NO2+2NH3→2N2+3H2O
副反应：
Side reaction:
4NH3+5O2→4NO+6H2O
3. 使用条件
WorkingService conditions
项目 要求
ProjectItem Requirement
操作温度，℃
200-430
Operating Temperature, ℃
操作压力，MPa
≤1
Operating Pressure, MPa
体积空速，h-1
≤90000
Volume space velocity, h-1

4. 技术指标
Technical indicatorsspecification
项目 要求
ProjectItem Requirement
径向抗压强度，N/cm≥
30
Radial compressive strength , N/cm ≥
磨耗率，% ≤
6
Attrition loss, % ≤
氮氧化物转化率，% ≥
85
Nitrogen oxide conversion, % ≥

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TX-230H (Specification) 20181115001 15.11.2018

5. 使用方法
ApplicationOperation method
5.1 催化剂装填
Catalyst loading
(1) 试漏：装塔前要用压缩空气试漏，在确保无漏点时方可装塔。
Leakage: The leakage should be tested use compressed air before loading, and the
catalyst can only be loaded when there is no leakage point
.
(2) 吹扫：装塔前要将管线和反应器吹扫干净，以防杂质进入后续工段。
Purging: Before loading, the pipeline and reactor shall be purged to prevent impurities
from entering the subsequent section.

(3) 装塔：催化剂要求开包即装，在装填过程中，催化剂应分散铺开，床高均
匀，以免引起气体偏流。催化剂填装完后，人工木板刮平上表面。
Loading: The catalyst is required to be loadedinstalled as soon as it is unpacked and
should be fully spread, insuring the bed height uniform to avoidand avoiding the gas
flow deflectiondeviation. The artificial board is used for scraping the catalyst upper
surface afterwhen loading.

注意：装填时，严禁操作人员直接踩踏催化剂，以免产生碎末。
Note: when loading, trampling catalyst is forbidden in case of pulverizing.

(4) 封塔：待催化剂全部填装完毕后，封塔并且用氮气或空气试漏，确保无漏
点时，可准备开车。
Sealing: After the catalyst is completely loaded, the leakage should be tested again
use air or nitrogen. It is ready to start if there is no leakage.

5.2 开/停车操作
Startup / stop operation
(1) 开车：烟气从室温升温到 200℃时，升温速率不可过大（<15℃/min），以
免催化剂因温度突然变化而发生应力损害，待烟气温度升 200℃以上，即可配
氨气。控制烟气温度在要求范围内。
Startup: The heating rate shall not be too large (< 15 ℃ / min) when the flue gas is
heated from room temperature to 200℃,to avoid stress damage caused by sudden
temperature change of the catalyst. When the flue gas temperature rises above 200 ℃,
ammonia can be added. Flue gas temperature shall be controlled within the required
range.
(2) 停车：通氮气保护，待反应器降温至常温，关闭反应器出口阀门。
Stop: when the reactor is planned to stop and cooled to room temperature, nitrogen
should be added into the reactor to protect catalyst. Finally close the reactor outlet
valve.
注意：卸塔时应按照相关工艺规范要求进行安全操作。
Note: safe operation should be carried out in accordance with the requirements of the
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TX-230H (Specification) 20181115001 15.11.2018

relevant process specifications when unloading the catalyst.

6. 注意事项
Matters need attention
6.1 催化剂储存时存放于干燥通风的室内库房，包装件堆放时应有垫板；
Store the catalyst in cool and dry place, the packaging should be stacked with a
gasket;
6.2 催化剂应避免接触有毒气体、液体、强氧化剂等。
Catalyst should avoid exposure to toxic gases, liquids, strong oxidants, etc.
7. 安全性能说明
Safety performance specification
7.1 本催化剂活性组分为金属钒，不可用手直接接触催化剂；
The active component of the catalyst is metal vanadium, and it is forbidden to directly
touch the catalyst by handand the catalyst cannot be contacted directly by hand；
7.2 本催化剂在使用过程中，装填在密闭容器内，在发生化学反应过程中，会
略有温升（均可控）；催化剂使用温度超过 450℃的时间不能超过 30min，超过
500℃本催化剂会被烧结，失去活性；
In the deNOx chemical reaction the temperature will raise slightly which can be
controlled. The time of catalyst using over 450 ℃ can't more than 30 min, when the
temperature over 500 ℃ the catalyst can be sintered and will lose its activity;
During the use of the catalyst, the temperature will rise slightly (can be controlled);
the time when the temperature of the catalyst exceeds 450 ℃ cannot exceed 30min,
and the catalyst will be sintered and lose its activity if it exceeds 500 ℃
7.3 使用过程中催化剂不会发生明火燃烧及爆炸。
The catalyst will not burn and explode during use.

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