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This course is designed to teach students the basic concepts necessary to understand fire and how to
effectively extinguish incipient stage fires. A basic understanding of these concepts can aid workers in
handling emergency situations involving fires. The course is designed to meet the requirements of OSHA
regulation 29 CFR 1910.157. Other standards referenced in the course are NFPA 10 and NFPA 30.
Table of Contents
Theory of Fire Page 3
1.3 Flash Point- is the lowest temperature at which a flammable substance gives off
vapors that will burn when a flame or spark is applied.
2 Fire Tetrahedron
A tetrahedron is simply a shape which has four parts.
We will use this model to describe fire. This is the
most important concept to understand when it comes
to understanding fire. The model states that it takes
four components for a fire to occur. The old model
used to be called the fire triangle which said that it
took the following for a fire to occur.
Fuel
Heat
Oxygen
We know now that in order for a substance to
continue to burn, one additional component must take
place, thus we get the tetrahedron.
2.1 Fuel- also called a reducing agent, is found in three physical states.
Solids
Liquids
Gases
2.1.1 Solids- Must first go through a process before the substance will burn. It must
go through pyrolysis.
As this ratio increases, the fuel particles become smaller (more finely divided)
increasing their ignitability. As the surface area increases, more of the material is
exposed to the heat and thus generates more burnable gases due to pyrolysis.
A solid fuels actual position also affects the way it burns. If a solid fuel is in a vertical
position, fire spread will be more rapid than if it is in horizontal position. The rapid
fire spread is due to increased heat transfer through convection as well as
conduction and radiation.
Vaporization- is the transformation of a liquid to its vapor or gaseous state. The rate
of vaporization is determined by the substance and the amount of heat energy
applied to it.
For example water left in a pan eventually evaporates. The energy required for this
process comes from the sun or surrounding environment. Water in the same pan
placed on a stove and heated to boiling vaporizes much more rapidly because there
is more energy being applied to the system. The rate of vaporization is determined
by the substance and the amount of heat applied to it.
2.1.3 Gases- Gaseous fuels can be the most dangerous of all fuel types because they
are already in the natural state required for ignition. No pyrolysis or vaporization is
needed to ready the fuel and less energy is required for ignition.
For combustion to occur after a fuel has been converted into a gaseous state, it must
be mixed with air (oxidizer) in the proper ratio. The range of concentrations of the
fuel vapor and air is called the Flammable Range.
Lower Flammable Limit (LFL)- is the minimum concentration of fuel vapor and air
that supports combustion. Concentrations that are below the LFL are said to be too
lean to burn.
Upper Flammable Limit (UFL)- is the concentration above which combustion cannot
take place. Concentrations that are above the UFL are said to be too rich to burn.
LEL/LFL UEL/UFL
Remember that Gases is are the most dangerous type of fuel because they are already in
the phase of matter that burns. For this reason we store most gases that are used in
industry and residentially as a liquid under pressure. It is important to remember that
the only thing keeping the gas in its liquid form is it being under pressure. If a tank
ruptures during a fire, all the liquid will vaporize and expand which can cause a very big
explosion. It is commonly referred to as a BLEVE ( Boiling Liquid Expanding Vapor
Explosion).
2.2 Oxygen/Oxidizers
Oxygen is one of the more common elements in our atmosphere. Oxidizers are
those materials that yield oxygen or other oxidizing agents during the course of a
chemical reaction. Oxidizers themselves are not combustible, but they support
combustion when combined with a fuel. Oxygen is the most common oxidizer. The
following are some common oxidizers:
1. Causes the pyrolysis or vaporization of solid and liquid fuels and the production
of ignitable vapors or gases.
2. Provides the energy necessary for ignition
3. Causes the continuous production and ignition of fuel vapors or gases so that the
combustion reaction can continue.
For discussion on fire behavior, chemical, electrical, and mechanical energy are the
most common sources of heat that result in the ignition of a fuel.
2.3.1 Chemical
Chemical heat energy is the most common source of heat in combustion reactions.
When any combustible is in contact with oxygen, oxidation occurs. This process is
almost always results in the production of heat. The heat generated when a
common match burns is an example of chemical heat energy.
Heat of Friction- is created by the movement of two surfaces against each other. This
movement results in heat and/or sparks being generated.
Heat of Compression- is generated when a gas is compressed. Diesel engines use this
principle to ignite fuel vapor without a spark plug. The principle is also the reason that
SCBA cylinders feel warm to the touch after they have been filled.
2.3.3 Electrical
Electrical heat energy can generate temperatures high enough to ignite any combustible
materials near the heated area. Electrical heating can occur in several ways including
the following:
When all the components come together flaming combustion occurs. Heat produced by the
initial fire package is transmitted to additional fuel packages. The initial package creates a
plume of hot gases. Outside fires are spread primarily by winds, terrain, and other exposed
fuel packages. An enclosed fire is very complex and tends to be fuel or oxygen controlled.
When the existing reducing agents have been utilized, the fire is then fuel controlled. In a
fire that is ventilation controlled there is a limited source of oxygen.
When no intervention is taken the fire will develop through five stages
Another hazardous situation can occur during this time. If the fire consumes enough
oxygen to reduce the level below 14%, and there isn’t an available source of oxygen,
the flames will go out and the fire begins to smolder. The heat is continuing to cause
the fuel to emit flammable vapors which gather in the space. If oxygen is rapidly
introduced back into the space, the flame will return and ignite the unburned
flammable gases causing a backdraft.
Low Oxygen
High Heat
Smoldering fire
High fuel vapor
concentrations
4 Classification of Fires
Fires are classified according to the nature of the combustibles or fuels involved. The
classification of any particular fire is important, since it determines the manner in which the
fire must be extinguished. Fires are classified as Class A, Class B, Class C, Class D, and Class
K.
USA UK
4.2 Class B
These are fires that occur in a vapor-air mixture over the surface of flammable
liquids such as gasoline, jet fuels, diesel oil, paints, thinners, solvents, lubricating oils,
and grease. Dry chemical, foam, light water, carbon dioxide, or water fog can be
used to extinguish Class B fires. The choice of agents depends on the circumstances
of the fire.
USA UK
In The USA the classification consists of flammable liquids and gases. They are classified
together as most flammable gases are stored as a liquid under pressure. The UK system
splits these into two separate classes, Class B being flammable liquids and Class C being
Flammable gases. It is split in the UK as there are certain techniques which can be used
to fight these types of fires and they have some characteristics which are unique to
flammable gas fires.
USA UK
4.4 Class D
These fires are those occurring in combustible metals such as magnesium, titanium,
zirconium, sodium, potassium, calcium, lithium and Zinc. Special techniques have
been developed for the control of this type of fire. Class D fires have extremely high
temperatures, in excess of 2000 0F. Most combustible metals are reactive to water.
USA UK
5 Principles of Extinguishment
Overall, Fires may be extinguished by removing a component of the fire tetrahedron (fuel,
heat, oxygen or chemical chain reaction) or by slowing the rate of combustion. The method
of extinguishment used in any specific instance depends on the classification of the fire and
the circumstances surrounding the fire.
If enough heat can be removed by cooling the fire to a temperature below that at
which it will support combustion, the fire will go out. Water is the most commonly
used cooling agent. Water may be applied as a solid stream, as fog, or incorporated as
foam. The way in which the water or other cooling agent is applied depends on the
nature of the fire.
If fire occurs in a closed space, it can be extinguished by diluting the air with Carbon
Dioxide (CO2) gas. This dilution of the air must reach a certain point before the flames
are extinguished. A large volume of CO2 must be used to reduce the oxygen content to
15 % or less. Oxygen’s normal concentration in the atmosphere is 21%.
6.1 Water
Cooling is the most common method of fire extinguishment, and water has the
greatest capacity for heat absorption. Most burning substances can be cooled below
their ignition points by the application of water.
With two fire fighters or more the following technique should be used.
Carbon dioxide is a dry, non-corrosive gas that is inert when in contact with most
substances. Carbon dioxide does not damage machinery or other equipment. Since it
is a non-conductor of electricity, carbon dioxide can safely be used in fighting fires that
might present electric shock hazards. However, the frost that collects on the horn of a
carbon dioxide cylinder is a conductor of electricity.
6.5 Halon
Halon is an excellent extinguishing agent that extinguishes by interrupting the
chemical reaction. Halon has an ozone-depletion potential and has been phased out
of production. The only exception that has been made is if no other alternatives are
available. Halon 1211 and Halon 1301 are the two most common halogenated
compounds used for fire extinguishment. Halogenated vapor is nonconductive and is
effective in extinguishing Class B and Class C fires.
7 Fire Extinguishers
A fire extinguisher is an active firefighting device used to extinguish or control small fires,
often in emergency situations. They are effective in the incipient or ignition phase of a fire.
There are two main types of extinguishes, the stored pressure and the cartridge operated
types.
Multi-Purpose Dry
Breaks Chain Reaction
Chemical
Isolating
Foam
Fuel/Cooling/Smothering
To extinguish a fire with a portable extinguisher, a person must have immediate access to
the extinguisher, know how to actuate the unit, and know how to apply the agent
effectively. Attempting to extinguish even a small fire carries some risk. Fires can increase in
size and intensity in seconds, blocking the exit path of the fire fighter and creating a
hazardous atmosphere. In addition, portable fire extinguishers contain a limited amount of
extinguishing agent and can be discharged in a matter of seconds. Therefore, individuals
should attempt to fight only very small or incipient stage fires.
Prior to fighting any fire with a portable fire extinguisher you must perform a risk
assessment that evaluates the fire size, the fire fighters evacuation path, and the
atmosphere in the vicinity of the fire.
The fire is limited to the original The fire involves flammable solvents,
material ignited, it is contained (such as has spread over more than 60 square
Is the fire too big? in a waste basket) and has not spread feet, is partially hidden behind a wall or
to other materials. The flames are no ceiling, or cannot be reached from a
higher than the firefighter's head. standing position.
The fire has not depleted the oxygen in Due to smoke and products of
the room and is producing only small combustion, the fire cannot be fought
Is the air safe to breathe?
quantities of toxic gases. No respiratory without respiratory protection.
protection equipment is required.
Heat is being generated, but the room The radiated heat is easily felt on
temperature is only slightly increased. exposed skin making it difficult to
Smoke may be accumulating on the approach within 10-15 feet of the fire
Is the environment too hot or ceiling, but visibility is good. No special (or the effective range of the
smoky? personal protective equipment is extinguisher). One must crawl on the
required. floor due to heat or smoke. Smoke is
quickly filling the room, decreasing
visibility.
There is a clear evacuation path that is The fire is not contained, and fire, heat,
Is there a safe evacuation
behind you as you fight the fire. or smoke may block the evacuation
path?
path.
Sound the fire alarm and call the fire department, if appropriate
Identify a safe evacuation path before approaching the fire. Do not allow the fire,
heat, or smoke to come between you and your evacuation path
Select the appropriate type of fire extinguisher
Discharge the extinguisher within its effective range using the P.A.S.S Technique
(PULL, Aim, Squeeze, Sweep)
Back away from an extinguished fire in case it flames up again
Evacuate immediately if the extinguisher is empty and the fire is not out
Evacuate immediately if the fire progresses beyond the incipient stage
11 Fire Safety
Fire prevention is the best way to prevent loss of property and life. A big part of prevention
is the identification of fire hazards.
11.1 Fire hazards
A fire hazard is a condition that encourages a fire to start or increases the extent or severity
of a fire. Basic fire chemistry suggests a fire cannot survive without a fuel supply, sufficient
heat source, oxygen supply, and a self-sustained chemical reaction. Therefore, hazardous
fire conditions can be prevented by eliminating one or all of these elements.
Control of the oxygen supply hazard is only practical under special circumstances because
21 percent oxygen is normally present in air. Control of the hazards associated with fuel
supply and heat sources are the most manageable.
Flammable and combustible gases such as natural gas, liquefied petroleum gas
(LPG), and compressed natural gas (CNG). (NFPA 30 for storage info)
Mechanical heat energy- Moving parts on machines, such as belts and bearings,
are a source of mechanical heating
11.1.3 Common Fire Hazards
A common fire hazard is a condition that is prevalent in almost all occupancies and
encourages a fire to start. Be alert for the following common hazards:
13 Summary
With an effective knowledge of the theory presented in the course along with practical
training, employees can reduce the number of severe injuries or even deaths that occur in
industrial settings every year. Students should remember the fire tetrahedron and it is the
basis for all operations from firefighting to fire prevention.