find H5

Compound ammonia
Conditions
Temp (K) 313.15
Pressure (bar) 49
Tref 298.15
Constants
R (cc*bar/molK) 83.14
Omega 0.253
Tc 405.4
Pc 113
Alpha 1.19
K 0.75
Cp 32.203551313
H0 -45362.21243 7945.113381 7407.325814
Parameter in eqn 2
A 0.40
B 0.04

A' -0.95633
B' 0.30227
C' -0.01528

P' -0.002580664

Q' 0.0162948263

Δ 6.63797E-05

Δ>0 1 real root ln φ φ f V

Z 0.0618597289 -1.22223811 0.294570149 14.43393728 32.86808252

H5 -65705.49434 -8762544.02 0.020428778 -47804.6879

eqn 1

Parameter in eqn 1
a 4596775.582
b 23.20571307

eqn 2
find H4
Compound ammonia
Conditions
Temp (K) 361.36196757
Pressure (bar) 49.5
Tref 298.15
Constants
R (cc*bar/molK) 83.14
Omega 0.253
Tc 405.4
Pc 113
Alpha 1.09
K 0.75
Cp 34.615171889
Ho -43589.20778 9718.118033 7407.325814
Parameter in eqn 2
A 0.27
B 0.04

A' -0.96177
B' 0.19279
C' -0.00894

P' -0.115544789

Q' -0.013037742

Δ -1.463736E-05

Δ>0 1 real root ln φ φ f V

Z #NUM! #NUM! #NUM! #NUM! #NUM!
H4 #NUM! -8369599.65 #NUM! #NUM!
Δ<0 3 real root
Z1 0.18722098608
Z2 0.067578
Z3 0.706967

Z ln φ φ f V H4
vapor 0.70696709762 -0.25851198 0.772199781 38.22388915 429.0880953 -46323.3213
liquid 0.067578 -0.25851182 0.772199903 38.22389519 41.01599368 -60776.7384
0.0000
H4 -60776.73844
 eqn 1

Parameter in eqn 1
a 4596775.582
b 23.20571307

eqn 2

-8369599.65 0.002214845 -44469.5851

-8369599.65 0.017188632 -46390.542
find H3
Compound ammonia
Conditions
Temp (K) 613.04131507
Pressure (bar) 50
Tref 298.15
Constants
R (cc*bar/molK) 83.14
Omega 0.253
Tc 405.4
Pc 113
Alpha 0.69
K 0.75
Cp 44.668086364
Ho -33118.26898 20189.05684 7407.325814
Parameter in eqn 2
A 0.06
B 0.02

A' -0.97724
B' 0.01355
C' -0.00085

P' -0.304774873

Q' -0.065564556

Δ 2.6165E-05

Δ>0 1 real root ln φ φ f V

Z 0.9640905686 -0.03691194 0.963761001 48.18805004 982.7602776
H3 -33962.6416 -6650580.29 0.000994422 -33301.2931
Δ<0 3 real root
Z1 #NUM!
Z2 #NUM!
Z3 #NUM!

Z ln φ φ f V H3
vapor #NUM! #NUM! #NUM! #NUM! #NUM! #NUM!
liquid #NUM! #NUM! #NUM! #NUM! #NUM! #NUM!
#NUM!
 eqn 1

Parameter in eqn 1
a 4596775.582
b 23.20571307

eqn 2

-6650580.29 #NUM! #NUM!

-6650580.29 #NUM! #NUM!
find H2
Compound ammonia
Conditions
Temp (K) 673.15
Pressure (bar) 295
Tref 298.15
Constants
R (cc*bar/molK) 83.14
Omega 0.253
Tc 405.4
Pc 113
Alpha 0.61
K 0.75
Cp 46.700292448
Ho -30316.59984 22990.72597 7407.325814
Parameter in eqn 2
A 0.27
B 0.12

A' -0.87768
B' -0.02358
C' -0.01574

P' -0.280352617

Q' -0.0727176

Δ 0.0005058497

Δ>0 1 real root ln φ φ f V

Z 0.9217820667 -0.11148565 0.894504228 263.8787473 174.8751536

H2 -33962.6417 -6296429.05 0.005095412 -30754.3519

eqn 1

Parameter in eqn 1
a 4596775.582
b 23.20571307

eqn 2
find H1
Compound ammonia
Conditions
Temp (K) 773.15
Pressure (bar) 300
Tref 298.15
Constants
R (cc*bar/molK) 83.14
Omega 0.253
Tc 405.4
Pc 113
Alpha 0.51
K 0.75
Cp 49.856473384
H0 -25413.84743 27893.47838 7407.325814
Parameter in eqn 2
A 0.17
B 0.11

A' -0.89170
B' -0.08140
C' -0.00545

P' -0.346442229

Q' -0.082168534

Δ 0.0001478887

Δ>0 1 real root ln φ φ f V

Z 0.9803998176 -0.04030128 0.960500015 288.1500044 210.0659911

H1 -28017.26189 -5740801 0.004315469 -25539.8368

eqn 1

Parameter in eqn 1
a 4596775.582
b 23.20571307

eqn 2
Tc/K 405.4 a/J m3 mol 4596775.582 K
Pc/Pa 113 b/m3 mol-1 23.20571307
Omega 0.253 Hf J/mol -45900

T/K 773.15 Alpha 0.51

P/Pa 300

A B A' B' C' P' Q'

0.17 0.11 -0.89169652 -0.08140133 -0.00545432 -0.34644223 -0.08216853

T/K 673.15 Alpha 0.61

P/Pa 295

A B A' B' C' P' Q'

0.27 0.12 -0.87768068 -0.02357816 -0.01573824 -0.28035262 -0.0727176

T/K 613.0413151 Alpha 0.69

P/Pa 50

A B A' B' C' P' Q'

0.06 0.02 -0.97723513 0.013554627 -0.0008504 -0.30477487 -0.06556456

T/K 361.3619676 Alpha 1.09

P/Pa 49.5

A B A' B' C' P' Q'

0.27 0.04 -0.96176618 0.192786608 -0.00894457 -0.11554479 -0.01303774

T/K 313.15 Alpha 1.19

P/Pa 49

A B A' B' C' P' Q'

0.40 0.04 -0.95632544 0.302272117 -0.01527569 -0.00258066 0.016294826

T3/°K 613.0413
T4/°K 361.3620
E-101 E-102 E-103
Heat duty/J mol-1 -5945.37981 -26814.0968 -4928.7559
 0.75

Δ Z ln φ φ f V Cp
0.000147889 0.980399818 -0.04030128 0.960500015 288.1500044 210.0659911 49.85647338

Δ Z ln φ φ f V Cp
0.00050585 0.921782067 -0.11148565 0.894504228 263.8787473 174.8751536 46.70029245

Δ Z ln φ φ f V Cp
2.6165E-05 0.964090569 -0.03691194 0.963761001 48.18805004 982.7602776 44.66808636

Δ Z1 Z2 Z3 ln φ φ f
-1.4637E-05 0.187221 0.0675781 0.706967098 -0.25851182 0.772199903 38.22389519

Δ Z ln φ φ f V Cp
6.63797E-05 0.061859729 -1.22223811 0.294570149 14.43393728 32.86808252 32.20355131
H0 H1
-25413.8474 -28017.2619

H0 H2
-30316.5998 -33962.6417

H0 H3
-33118.269 -33962.6416

V Cp H0 H4
41.01599368 34.61517189 -43589.2078 -60776.7384

H0 H5
-45362.2124 -65705.4943