SUHU REFERENSI 25 298

Celsius
hno3 cpl 109.9
nacl cps 10.79 + 0.0042
nano3 cps 4.56 + 0.058
h2o cpl 75.3418
cl2 cpg 8.28 + 0.0006
nocl cpg 44.7
SUHU STEAM 121
Hv 2707.7 4.1868
Hc 507.97

Heater HNO3
suhu in 303 298
komponen BM m kmol Icpdt
hno3 85 60000 705.882352941176 549.5
h2o 18 40000 2222.22222222222 376.709
total

suhu out 333 298

komponen BM m kmol Icpdt
hno3 85 60000 705.882352941176 3846.5
h2o 18 40000 2222.22222222222 2636.963
total

kebutuhan steam
T 394
Hv 2707.7 kj/kg
Hc 507.97 kj/kg
Qs = m lamda
= m 2199.73
= 2199.73 m kj/kg
Qc = 507.97
Qloss = 109.9865 m kj/kg

Hin + Qin =
1225013.46405229 + 2199.73 m =
2199.73 m =
m =
Qs 7350588.7543137 kj
Qc 507.97 kj
Qloss 367529.43771569 kj
Qtot 7718626.1620294
nerpan tot
Hin Hout
Hin 1225013.4640523 Hout 8575094.24836601
Qs 7350588.7543137 Qloss 367529.437715686
Qc 507.97
tot 8943131.6560817 tot 8943131.6560817

Reaktor
kkal/mol kj/mol
komponen dHf dHf
NaCL -98.321 -412.948
HNO3 -41.35 -173.67
NaNO3 -111.71 -469.182
NOCl 12.8 53.76
H2O -68.3174 -286.933
Cl2 0 0

Q = Hproduk + Qr
Humpan T refernsi 333 K
umpan 1 BM m kmol Icpdt
NaCl 58.5 40000 683.760683760684 1391.30653312
H2O 18 111111.1111111 6172.83950617284 2636.963
umpan 2
HNO3 85 60000 705.882352941176 63.95173454
H2O 18 40000 2222.22222222222 2636.963
total
dHm

panas reaksi dH 25 C

kj/mol
komponen koef kmol dHf H
NaCL -3 866.1 -412.948 1238.844
HNO3 -4 649.6 -173.67 694.68
NaNO3 3 433.0484330484 -469.182 -1407.546
NOCl 1 649.5726495727 53.76 53.76
H2O 2 216.5242165242 -286.933 -573.866
Cl2 1 216.5242165242 0
 3031.36951567 5.872
dHr 17800.20179601
25oC dHreaksi 17800.20179601 kJ

evaporator 0.25 to 0.62

Etot = dHf + Qs
BPR oC = 1.78 x
x1 0.31030449697
x2 0.388672683367
x3 0.52
BPR tiap efek kondisi vakum efek 3
BPR1 1.1512588434316 T3sat
BPR2 1.6314707252221 Ts1
BPR3 2.607488 sumdT

dT = sumdT x (1/Ui/((1/U1+1/U2+1/U3))
harga koefisien overall evaporasi
U1 2867.8122189379 W/m2K 0.00034869786571
U2 1608.1694533617 W/m2K 0.000621825018445
U3 1237.9393665375 W/m2K 0.000807794005935
0.00177831689009
dT1 10.904137813937 oC 283.904137813936 K
dT2 19.445102376756 oC 292.445102376756 K
dT3 25.260542240654 oC 298.260542240654 K

efek 1 efek 2 efek 3

Ts1 121 Ts2 108.944603342632 Ts3
T1 110.09586218606 T2 90.6507598093078 T3

perhitungan cp
cp feed efek 1
komp cp kj/kg m x cp rata"
NaCl 0.865 2000 0.009027081243731 0.00780842528
HNO3 1.744 5435.897435897 0.024535143893218 0.04278929095
NaNO3 1.08 55213.67521368 0.249209165959417 0.26914589924
H2O 4.19 158905.982906 0.717228608903634 3.00518787131
tot 221555.5555556 1 3.32493148677

perhitungan cp
cp L2 efek 2
komp cp kj/kg m x cp rata"
NaCl 0.865 2000 0.013102844261942 0.01133396029
HNO3 1.744 5435.897435897 0.035612858763227 0.06210882568
NaNO3 1.08 55213.67521368 0.361728093727117 0.39066634123
H2O 4.19 89989.04229673 0.589556203247714 2.47024049161
tot 152638.6149463 1 2.9343496188

V1 = 221555.5555556 - L1
V2 = L1 - L2
V3 = L2 - 115462.195924
L3 = 115462.1959237
perhitungan steam economy

F 221555.55555556 kg/jam
Cpf 3.324931486768 kj/kgK
Tf 60 oC
lamdaS1 2199.07 kj/kg
Cp1 3.1802763177644 kj/kgK
TL1 110.09586218606 oC
H1 2697.9214979782 kj/kg

evap2
Cp1 3.1802763177644
TL1 110.09586218606
lamdaS2 2238.5259573668
Cp2 2.9343496188029
TL2 90.650759809308
H2 2615.2549245541

evap3
Cp2 2.9343496188029
TL2 90.650759809308
lamdaS3 2238.5259575534
Cp3 2.530056383742
TL3 63.758746843432
H3 2664.5845920223

evap 1
F.Cp.ΔT) + (S.λs1) = (L1.Cp.ΔT) + (V1.H1)
S 260090.17 - 1.10378166348871 L1

evap 2
L1.Cp1.(T1-Tref) + V1.λs2 = L2.Cp2.(T2-Tref) + V2.H2
2422.61 L2+ 495957862.1099 = 4583.15
evap 3
L2.Cp2.(T2-Tref) + V2.λs2 = L3.Cp3.(T3-Tref) + V3.H3
L1 = 2.10 #REF! #REF!

S 51558.59 F 221555.555555556
V1 32630.89 L1 188924.67
V2 36233.03 L2 152691.64
V3 37229.44 L3 115462.195923734

F + S = L1
25782996.4957265 + 113380954.2135 = 51128371.5529
139163950.7092 = 139163950.709

L1 + V1 = L2
51128371.5529052 + 73045093.88463 = 29414865.9362
124173465.4375 = 124173465.438

L2 + V2 = L3
29414865.9362228 + 81108569.07047 = 11322432.482
110523435.0067 = 110523435

Neraca energi overall

H in Hout
Qbahan 25782996.495727 Qbahan 51128371.5529052
steam 113380954.21347 uap h2o 88035579.1562901
total 139163950.7092 total 139163950.709195

H in Hout
Qbahan 51128371.552905 Qbahan 29414865.9362228
steam 73045093.884628 uap h2o 94758599.5013102
total 124173465.43753 total 124173465.437533

H in Hout
Qbahan 29414865.936223 Qbahan 11322432.4819725
steam 81108569.070473 uap h2o 99201002.5179613
total 110523435.0067 total 110523434.999934

crystallizer

neraca energi total\

Q = H2 - Hv
sehingga Hv = 0
H2 = entalpi produk
 H1 = entalpi bahan masuk

entalpi bahan masuk H1 pada suhu 63.7587468434

komponen BM m kmol Icpdt
NaCl 58.5 2000 34.1880341880342 1437.15006407
H2O 18 47376.72583826 2632.04032434802 2920.15375293
NaNO3 85 55213.67521368 649.57264957265 4259.58627809
total 161.5 104590.4010519 3315.8010081087

the heat of solution at 25oC = -5050 kkal/mol

the heat of solution at 25oC = -152.589928057554 kj/kg crystal
panas kristalisasi = 152.5899280576 kj/kg crystal
= 153 kj/kg crystal
atau
panas kristalisasi = 1452007.190345 kj

neraca energi total

Q = Q kristalisasi - entalpi bahan masuk
Q = 1452007.190345 - 10502006.5113
= -9049999.32093 kj/jam (tanda negatif maka panas harus di hilan

kebutuhan air pendingin

suhu air pendingin masuk 30 oC
suhu air pendingin keluar 45 oC
Cp air pendingin 4.181 kj/kg K
Q = m Cp dT
m 144303.58480311 kg H2O/jam

rotary dryer
1 Cp solid = Cp NaNO3 ( diasumsikan konstan)
2 Udara panas ,TG2 masuk pada suhu 60
relative humidity H2 = 0.045
3 TG1 = 50.199 oC
4 Rate solid masuk (Ls) 9300.43821266523
5 suhu solid masuk (Ts1) 30
6 suhu solid keluar (Ts2) 50
7 kapasitas panas solid 0.262
8 kapasitas panas air permukaan 0.9987
9 suhu referen (T0) 25
10 panas laten 542.576

mirip nermas
X1 0.052744759806 kg H2O/solid kering
13 kadar air dalam produk keluar 1%
X2 1%
 X2 0.01 kg H2O/solid kering
neraca komponen air
G H2 + Ls
G 0.045 + 9300.43821267
pers 1 0.045 G + 397.544997487

komponen masuk entalpi

udara panas masuk GEANKOPLIS HAL 562
H'G2 62.552 kkal/Kg udara kering
entalpi feed masuk
H'S1 1.578 kkal/Kg solid

komponen keluar entalpi

pers 2 H'G1 = 25.3249 +

H'S2 6.800355 kkal/Kg K

neraca panas rotary dryer

G H'G2 + Ls
62.552 G + 9300.43821267
62.552 G + 14676.0914996
pers 3 37.2271 G - 48570.1900021
G
substitusi pers 1 dan pers 3
0.045 G +
0.045 G +
-0.01280066107

G
37585.416075

substitusi H1 ke pers 2
H'G1 = 25.3249 + 589.95
= 58.11261474588 kcal/kg udara kering

entalpi masuk
entalpi bahan = Ls x H's1
= 14676.09149959
entalpi udara = G x H'G2
= 2351042.946326
entalpi keluar
entalpi bahan = Ls x H's2
= 63246.28150169
entalpi udara = G x H'G1
= 951846.9035589
Qloss = 1350625.852765 kkal/jam
14%

neraca energi
masuk keluar
Q bahan 14676.091499586 Q bahan 63246.2815016891
Q udara 2351042.9463262 Q udara 951846.903558902
Q loss 1350625.8527652
total 2365719.0378258 total 2365719.03782579 0
 273
Kelvin komponen nomor aliran
J/molK 1 2
T kal/molK HNO3 60000 60000
T kal/molK NaCl
J/molK H2O 40000 40000
T kal/molK NaNO3
J/molK NOCl
394 Cl2
udara kering
uap air

Heater Mixer NaCl

suhu in 303
H komponen BM
387882.35294 nacl 58.5
837131.11111 h2o 18
1225013.4641 total

suhu out 333

H komponen BM
2715176.4706 nacl 58.5
5859917.7778 h2o 18
8575094.2484 total

kebutuhan steam
T 394
Hv 2707.7
Hc 507.97
Qs =
=
=
Qc =
Qloss =

Hout + Qout Hin +

8575094.2484 + 507.97 3027954.6475275 +
7350588.7543
3341.5868103
Qs 14201423
Qc 507.97
Qloss 710071.17
Qtot 14912003
 nerpan tot
Hin
Hin 3027954.6
Qs 14201423

tot 17939449

- Humpan

H
951320.70641
16277549.383

45142.400852
5859917.7778
23133930.268
23133930.268

298 K
entalpi produk 333 K

kj/mol
komponen BM m kmol
NaCL 58.5 2000 34.188034
HNO3 85 5435.8974358974 63.951735
NaNO3 85 55213.675213675 649.57265
NOCl 65.5 14182.336182336 216.52422
H2O 18 158905.98290598 8828.1102
Cl2 70.1 15373.219373219 219.30413
 251111.11111111
Q 2004452.245796
m 911.2264895219 kg/jam

= dHp + Qloss
+ 6.22 x^2

isi vakum efek 3 data steam

60 oC suhu steam suhu
121 oC oC
55.609782431 oc Hs1 Ts1 121
328.60978243 K Hs2 Ts2 108.9446
/((1/U1+1/U2+1/U3)) Hs3 Ts3 89.019289
Hs4 Ts4 61.151259
T1 110.095862186064
T2 90.6507598093078 perhitungan efek 1
Ts2 108.944603342632 T1 110.09586
T3 63.7587468434316 BPR1 1.1512588
Ts3 89.0192890840858 H1 2697.9215
Ts4 61.1512588434316 H2 2615.2549
H3 2664.5846

condenser
89.019289084 Ts4 61.1512588434
63.758746843

perhitungan cp
cp L1 efek 1
komp cp kj/kg m x cp rata"
NaCl 0.865 2000 0.0105365732007 0.0091141
HNO3 1.744 5435.897435897 0.0286378656223 0.0499444
NaNO3 1.08 55213.67521368 0.2908814652833 0.314152
H2O 4.19 127165.4613193 0.6699440958937 2.8070658
tot 189815.0339689 1 3.1802763

perhitungan cp
cp L3 efek 3
komp cp kj/kg m x cp rata"
NaCl 0.865 2000 0.017321686843 0.0149833
HNO3 1.744 5435.897435897 0.0470794565477 0.0821066
NaNO3 1.08 55213.67521368 0.4781969957521 0.5164528
 H2O 4.19 52812.62327416 0.4574018608571 1.9165138
tot 115462.1959237 1 2.5300564

L1
+ V1
+ 88035579.1562901
0

+ V2
+ 94758599.5013102
-2.086163E-07

+ V3
+ 99201002.5179613
0.006761536

- H1 asumsi tidak ada air yang teruapkan

 oC = 336.758746843 K
H
49133.335524
7685962.431
2766910.7447
10502006.511

= -21210 kj/kmol NaNO3.3H2O

pi bahan masuk

a negatif maka panas harus di hilangkan)

oC dan
H2O/kg udara kering

oC
oC
kkal/kg K
kkal/kg K
oC
kkal/kg K
 X1 = G H1 + Ls
0.0527447598 = G H1 + 9300.4382
= G H1

NKOPLIS HAL 562

589.95 H1

H'S1 = G H'G1 +
1.578 = 25.3249 G + 589.95
= 25.3249 G + 589.95
= 589.95 GH1
H1 = 0.05780066107 G - 83.573175

397.54499749 = G H1
397.54499749 = 0.05780066107 G - 83.573175
G = - -481.118172463
G = 37585.416075

H1 = 0.05780066107 G - 83.573175
H1 = 0.05780066107 37585.41607504 - 83.573175
H1 = 0.0555771078 kg h2o/udara kering

H1
4.1999439352 konversi

set e329 to 0 by chg a322

 3 4 5 6 7 8 9
5435.897435897
40000 40000 40000 2000 2000 2000
111111.1 111111.111111 158905.982906 47376.73 47376.73
55213.67521368 55213.68 55213.68

Qloss 5%
298
m kmol Icpdt H
40000 683.7606837607 1027.539 702590.449997
111111.111111111 6172.839506173 376.709 2325364.19753
3027954.64753

298
m kmol Icpdt H
40000 683.7606837607 1391.307 951320.706407
111111.111111111 6172.839506173 2636.963 16277549.3827
17228870.0891

kj/kg
kj/kg
m lamda
m 2199.73
2199.73 m kj/kg
507.97
109.9865 m kj/kg

Qin = Hout + Qout

2199.73 m = 17228870.0891 + 507.97
2199.73 m = 14201423.4116
m = 6455.98478522
kj
kj
kj
Hout
Hout 17228870.08912
Qloss 710071.1705798
Qc 507.97
tot 17939449.2297

Icpdt H
1391.30653312 47566.03532034
3846.5 245990.346908
1391.30653312 903754.6710865
1564.5 338752.1367521
2636.963 23279399.85565
1391.30653312 305119.2660349
 25120582.31175

3200
1950
1100 0
0
0
0
0
F
F
dHsatliq dHsatvap 221555.6
kj/kg kj/kg
509.03 2708.1
457.226568950402 2695.752526317 0
373.65527615438 2612.181233708 0
255.948593889183 2659.67208463 F
0
2 3 0
Ts2 108.9446033426 0
Ts1 121 F
kj/kg lamdas1 2199.07 kj/kg 0
kj/kg lamdas2 2238.526 kj/kg 0
kj/kg lamdas3 2238.526 kj/kg 0
jumlah air

37176.41902257
X2
0.01

Ls H'S2 + 0% (G H'G2
GH1 9300.438212665 6.800355 + 0% (G 62.552
GH1 63246.28150169 + 0G +
 10 11 12 13 14 15 16 17 18 19
1811.966 3623.932 5435.897
20 20 20
490.5494 184379.1 147202.7 110026.3
9300.438 9207.434 9207.434 93.00438 93.00438

2088.889 6857.087 37585.42

1598.339 2088.889

reaktor konversi 0.95

comp in out RX
2 6 7 25
x n x n x n x n c
hno3 0 0 0.3 952.381 0.00899 86.28409 0 -1.333333
nacl 0.099723 683.7607 0 0 0.003562 34.18803 0 -1
h2o 0.900277 6172.84 0.7 2222.222 0.919772 8828.11 0 0.666667
nano3 0 0 0 0 0.067677 649.5726 0 1
nocl 0 0 0 0 0 0.5 216.5242 0.333333
cl2 0 0 0 0 0 0.5 216.5242 0.333333
1 6856.6 1 3174.603 1 9598.155 1 433.0484
10031.2 10031.2
reaktor konversi 0.9
comp in out recycle
6 2 7 25 evap
x m x m x m x m x
hno3 0 0 0.6 60000 0.024535 5435.897 0 0
nacl 0.264706 40000 0 0 0.009027 2000 0 0.022433
h2o 0.735294 111111.1 0.4 40000 0.717229 158906 0.457369
nano3 0 0 0 0 0.249209 55213.68 0.520197
nocl 0 0 0 0 0 0 0.479853 14182.34 0
cl2 0 0 0 0 0 0 0.520147 15373.22 0
1 151111.1 1 100000 1 221555.6 1 29555.56 1
251111.1 251111.1
nermas tia 0 0 0 0 0 0 0 0 0
evap 1 0 0 0 0 0 0 0 0 evap2
F = L1 + V1 0 0 0 0 L1
221555.6 = L1 + 37176.42 0 0 0 0 184379.1
L1 = 184379.1 0 0 0 0 0 0 L2
xf = L1 x1 + V1 xv1 0 L1 x1
xf = (L1 + V1) x1 0 0 L1 xf
0.258236 = 184379.1 x1 0 0 0 0 184379.1 0.310304
x1 0.310304 0 0 0 0 0 0 0 x2

nano3 mas 55213.68 0 0 0 0 0 0 0

bahan keri 57213.68 0 0 0 0 0 0 0
bahan over 221555.6 0 0 0 0 0 0 0
xf 0.258236 0 0 0 0 0 0 0
triple effe 0 0 2 0 xv = 0 0
F = L3 + (V1 + V2) 0 0
xf = L3 + (V1 + V2) 0 0
57213.68 = L3 x3 + V2 xv 0 0
57213.68 = L3 0.52 + V2 0 0 0
L3 = 110026.3 set ao86 to 0,52 chnge m87 0 0 0
0= 111529.3 tiap efek 37176.42 V1 V2 V3 0 0 0
+ Ls H'S1 ) neraca massa aliran udara keluar produk
+ 9300.438 1.578 ) uap H2O = Feed H2O masuk
0 = #REF!
= #VALUE!
udara basah = G +
= 37585.42 +
= #VALUE!
neraca massa aliran udara keluar
1% impuritis terikut udara menuju cyclone
kristal nano3 #REF!
 20 21 22 23 24 25 26 27

1980 1980
46886.18 40367.99 6518.189
45913.24 6306.732
14182.34 14182.34 2054.41
15373.22 15373.22
37585.42
2088.889

n
866.1
649.6
433.0484
649.5726
216.5242
216.5242
0

terakumulasi
dalam reaktor
m
0
1980
40367.99
45913.24
0
0
88261.22
 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 evap 3 0
= L2 + V2 0 0 0 0 L2 =
= L2 + 37176.42 0 0 0 0 147202.7 =
= 147202.7 0 0 0 0 0 0 L3 =
= L2 V2 + 0 xv2 0 L2 X2 =
= (L2 + V2) x2 0 0 147202.7 0.388673 =
= 147202.7 x2 0 0 0 0 0 X3 =
0.388673 0 0 0 0 0 0 0 0 0
 + G H2 - H2O Produk
+ 37585.42 = - 93.00438

uap air
#VALUE!

ra menuju cyclone
 0 0 0
0 0 0
L3 + V3
L3 + 37176.42
110026.3 0 0
L3 X3 0
110026.3 X3 0
0.52 0 0
0