Example 6.

(HR)0/RTc Pr 1.731
Pr 1.5 1.731 2 Tr 1.127
Tr ω 0.191
1.10 -2.203 -2.555 -2.965 Tc 420
1.127 -2.293
1.15 -1.719 -2.070 -2.479
(HR)/RTc -2.429
R 1 R
(H ) /RTc (H )/RTc -8482.96 J mol-1
Pr 1.5 1.731 2
Tr
1.10 -0.617 -0.915 -1.261
1.127 -0.713
1.15 -0.487 -0.541 -0.604
 (SR)0/R
Pr 1.5 1.731 2
Tr
1.10 -1.557 -1.799 -2.081
1.127 -1.566
1.15 -1.126 -1.368 -1.649
R
(S )/R -1.705
R
(S )/R -14.17 (SR)1/R
J mol-1 K-1 Pr 1.5 1.731 2
Tr
1.10 -0.618 -0.906 -1.241
1.127 -0.726
1.15 -0.502 -0.572 -0.654
 Pressure (kPa) Temperature (K) y1 y2
25 323.15 0.5 0.5

Tc (K) Pc (bar) Vc Zc ω
1 2
535.5 41.5 267 0.249 0.323

Set k ij = 0

ij Tc ij (K) Pc ij Vc ij (cm3
Zci j ωi j
(bar) mol-1)

11 535.5 41.5 267 0.249 0.323

22 591.8 41.1 316 0.264 0.262
12 562.95 41.2811 290.81 0.2565 0.293

Tr ij (K) B^ ij B ij
ij B0
B1 3
(cm mol ) -1
(cm3 mol-
1
)
11 0.60345 -0.864 -1.296 -1.282 -1376
22 0.54605 -1.028 -2.045 -1.564 -1872
12 0.57403 -0.943 -1.631 -1.420 -1610
Tc (K) Pc (bar) Vc Zc ω
591.8 41.1 316 0.264 0.262

δ12 = 28.421

ϕ1 = 0.987
ϕ2 = 0.983
 Pressure (kPa) Pressure (bar) Temperature (K)
170 1.7 333.15

Tc (K) Pc (bar) Vc Zc ω
1
535.5 41.5 267 0.249 0.323

Set k ij = 0

Tc ij (K) Pc ij Vc ij (cm3
Zci j
ij
(bar) mol-1)

11 508.2 47 209 0.233

22 417.9 40 238.9 0.275
12 460.84 43.520366 223.62 0.2540

Tr ij (K) B^ ij
0 1
ij B B (cm3 mol-1)

11 0.65555 -0.746 -0.874 -1.015

22 0.7972 -0.523 -0.307 -0.582
12 0.72291 -0.626 -0.533 -0.759

B= -602.76 Z= 0.963 V=
dB0/dTr = 1.5692 HR/RTc = -0.1013284 HR =

dB1/dTr = 3.90201 SR/R = -0.0991731 SR =

-2462.6

Tpc = 443.184 Tpr = 0.7517194

Ppc= 41.96 0.0405148
w= 0.22276
 y1 y2
0.28 0.72

Tc (K) Pc (bar) Vc Zc ω
2
591.8 41.1 316 0.264 0.262

ωi j

0.307
0.19
0.249

δ12 = 81.74925

B ij ϕ1 0.948
(cm mol )
3 -1
ϕ2 0.970
-912
-505
-668

15690.2 cm3 mol-1

-388.24

-0.825
Estimate the fugacity of Liquids

T 383.15 Tr Pr(sat) B0 B1
P 275 0.748632 0.116992 -0.58763 -0.44123
ϕ= 0.900

Psat 5.267
Tc 511.8
Pc 45.02
Zc 0.273
Vc 258
w 0.196
Tn 322.4

sat
V = 107.54578

f= 11.784183

At normal boiling point means Temperature of the system = Tn

and Psat = 1.01325 bar = 1 atm

T 309.2 Tr Pr(sat) B0 B1
P 200 0.658293 0.030067 -0.740839 -0.856793
ϕ= 0.957

Psat 1.01325
Tc 469.7
Pc 33.7 Vsat = 119.43816
Zc 0.27
Vc 313
w 0.252
f= 2.445
Tn 309.2
 Pressure (kPa) Temperature (K) y1 y2 y3
3500 373.15 0.21 0.43 0.36

Tc (K) Pc (bar) Vc Zc ω
1 2
190.6 45.9644 98.6 0.286 0.012

Tc (K) Pc (bar) Vc Zc
3
369.8 42.4283 200 0.276

Set k ij = 0

Pc ij Vc ij (cm3
ij Tc ij (K) Zci j ωi j
(bar) mol-1)

11 190.6 45.9644 98.6 0.286 0.012

22 305.3 48.6779 145.5 0.279 0.1
33 369.8 42.4283 200 0.276 0.152
12 241.226 47.0052 120.533497 0.2825 0.056
13 265.488 43.2591 143.378469 0.281 0.082
23 336.006 45.2525 171.30781 0.2775 0.126
 Tr ij (K) B^ ij B ij (cm3
ij B0 B1
(cm3 mol-1) mol-1)

11 1.95776 -0.061 0.129 -0.059 -20.51

22 1.22224 -0.223 0.065 -0.217 -112.95
33 1.00906 -0.333 -0.027 -0.337 -244.20
12 1.54689 -0.127 0.111 -0.121 -51.51
13 1.40552 -0.162 0.098 -0.154 -78.45
23 1.11055 -0.274 0.028 -0.270 -166.84
Tc (K) Pc (bar) Vc Zc ω
305.3 48.6779 145.5 0.279 0.1

ω
0.152

δ12 = 30.428
δ13 = 107.810
δ23 = 23.469
ϕ1 = 0.994 ʄ1 7.3056
ϕ2 = 0.896 ʄ2 13.478
ϕ3 = 0.772 ʄ3 9.7306