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  • 9 Equilibrios de Formación de Complejos (2) - Valoraciones Complejométricas y Aplicaciones

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    Daniela Landinez
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    This document discusses complexation reactions between metal ions (Mn+) and ligands such as EDTA (Y4-). 1) Equations are provided to calculate formation constants (Kf') of complexes such as MYn-4 based on known constants and concentrations. 2) Graphs show how the formation of complexes varies with pH and can be used to determine the pH at which a metal will completely form complexes. 3) Several examples of metal-ligand complexes are given to illustrate the general principles discussed.

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    9 Equilibrios de formación de complejos (2) -Valoraciones complejométricas y aplicaciones (2)

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    This document discusses complexation reactions between metal ions (Mn+) and ligands such as EDTA (Y4-). 1) Equations are provided to calculate formation constants (Kf') of complexes such as MYn-4 based on known constants and concentrations. 2) Graphs show how the formation of complexes varies with pH and can be used to determine the pH at which a metal will completely form complexes. 3) Several examples of metal-ligand complexes are given to illustrate the general principles discussed.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    7 views19 pages

    9 Equilibrios de Formación de Complejos (2) - Valoraciones Complejométricas y Aplicaciones

    Uploaded by

    Daniela Landinez
    This document discusses complexation reactions between metal ions (Mn+) and ligands such as EDTA (Y4-). 1) Equations are provided to calculate formation constants (Kf') of complexes such as MYn-4 based on known constants and concentrations. 2) Graphs show how the formation of complexes varies with pH and can be used to determine the pH at which a metal will completely form complexes. 3) Several examples of metal-ligand complexes are given to illustrate the general principles discussed.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 19

    29/07/2022

    Mn+

    1
    29/07/2022

    Mn+ + Y 4− ⇌ MY n−4
    [MY n−4 ]
    MY n−4 𝐾f′ = 𝐾f 𝛼Y4− = n+ (𝟏)
    M CEDTA
    α
    ℃ 𝜇 = 0.10 𝑀
    • 𝛼Y4−
    pH 𝛼Y4− pH 𝛼Y4−
    –18 –3
    1 1.9×10 8 5.6×10
    –14 –2
    2 3.4×10 9 5.4×10
    –11
    3 2.6×10 10 0.37
    –9
    4 3.8×10 11 0.85
    –7
    5 3.7×10 12 0.98
    –5
    6 2.4×10 13 1.00
    –4
    7 5.0×10 14 1.00

    Y 4− MY n−4
    M 2+

    MnY 2− .

    ~ ~
    ~

    2
    29/07/2022

    Zona 3
    𝐩𝐌 = −𝐋𝐨𝐠[𝐌𝒏+ ]

    𝑲′𝒇 𝑲′′
    𝒇
    Zona 1

    Zona 2
    Ca2+

    Log 𝐾f CaY 2− = 10.70 𝛼Y4− =


    0.37 (a pH = 10.00)
    Volumen de EDTA añadido (mL)

    3
    29/07/2022

    𝐌𝐧+
    ′ n+ − C ′
    𝐾f′ M n+ 2 + 𝐾f′ CEDTA
    ′
    − CM n+ + 1 M Mn+ = 0
    (𝟐)
    Ca2+

    V V
    [Ca2+] pCa2+ [Ca2+] pCa2+
    EDTA EDTA
    0 0.0500 1.30 25.00 1.4 × 10−6 5.87
    5.00 0.0364 1.44 25.05 2.8 × 10−8 7.56
    10.00 0.0250 1.60 25.10 1.4 × 10−8 7.86
    15.00 0.0154 1.81 25.50 2.8 × 10−9 8.56
    20.00 0.0071 2.15 26.00 1.4 × 10−9 8.86
    24.00 0.0014 2.87 30.00 2.8 × 10−10 9.56
    24.50 6.7 × 10−4 3.17 35.00 1.4 × 10−10 9.86
    24.90 1.3 × 10−4 3.87 40.00 9.2 × 10−11 10.03
    24.95 6.7 × 10−5 4.18

    4
    29/07/2022

    𝐋𝐚𝐮𝐱
    Laux
    ◦
    𝐾f MY n−4 ≫ 𝐾f MLaux
    Laux
    n−4
    Laux MY
    Laux
    MY n−4
    Laux
    [MY n−4 ]
    𝐾f′′ = 𝐾f 𝛼Mn+ 𝛼Y4− = (𝟑)
    CMn+ EDTA

    Demostración 29
    (𝟒)

    (𝟓)

    (𝟔)

    Dem. 30
    (𝟕)

    (𝟖)
    (𝟗)

    𝐋𝐚𝐮𝐱 𝑲′′
    𝒇 𝐌 𝒏+ = 𝐌 𝒏+ ′𝜶𝐌𝒏+ ^_^

    10

    5
    29/07/2022

    Zn(NO3 )2
    NH4 Cl
    NH3 Log 𝐾f ZnY 2− = 16.50

    Zn2+ + Y 4− ⇌ ZnY 2−

    11

    12

    6
    29/07/2022

    Zn2+

    𝐾f′′ =
    𝐾f 𝛼Mn+ 𝛼Y4−

    ′ 2 ′ ′ ′
    𝟐+ 𝐾f′′ Zn2+ + 𝐾f′′ CEDTA
    ′
    − CZn2+ + 1 Zn
    2+
    − CZn2+ = 0
    𝐙𝐧 𝐍𝐇𝟑 ′
    Zn2+ = Zn2+ 𝛼Zn2+ (𝟏𝟎)

    13

    MY n−4 MIn

    MY n−4 MIn
    𝐾f M(OH)n ≪ 𝐾f MLaux ≪ 𝐾f MIn− ≪ 𝐾f MY n−4

    14

    7
    29/07/2022

    15

    16

    8
    29/07/2022

    𝐇𝟐 𝐈𝐧− 𝐇𝐈𝐧𝟐−
    𝐈𝐧𝟑−

    17

    𝐌𝐈𝐧− + HY 3− ⇌ 𝐇𝐈𝐧𝟐− + MY 2−

    Cu2+ , Ni2+ , Co2+ , Cr 3+ , Te3+ , Al3+

    18

    9
    29/07/2022

    Log 𝐾f MgIn− = 7.0 Log 𝐾f CaIn− = 5.398

    𝐌𝐈𝐧 Si se conoce 𝐾f′ pH MIn,

    (𝟏𝟖) ∆pM = Log 𝐾f′ ± 1.


    (𝟏𝟗)

    19

    Mg 2+ Ca2+

    6.45 𝐇𝐈𝐧𝟐−

    4.45
    𝐌𝐈𝐧− 4.85 𝐇𝐈𝐧𝟐−

    2.85
    𝐌𝐈𝐧−

    Mg 2+ Ca2+

    20

    10
    29/07/2022

    21

    22

    11
    29/07/2022

    •
    •
    • ▪
    • Laux

    23

    MY 2−
    ⇌

    MY 2− ⇌
    Zn2+ Co2+
    ZnY 2−
    CoSO4 CoSO4

    24

    12
    29/07/2022

    BrO3− Br −

    K 2 Ni(CN)4 Ni2+ BrO3−


    Br − As 3+
    Ni2+
    NaBrO3
    −
    Ni(CN)42− + 2AgBr s ⇌ 2Ag CN 2 + Ni2+ + 2Br −

    25

    Ni(CN)42− + 2AgBr s ⇌ 2Ag CN 2


    −
    + Ni2+ + 2Br −

    31.48%

    26

    13
    29/07/2022

    Ni(CN)42− + 2AgBr s ⇌ 2Ag CN 2


    −
    + Ni2+ + 2Br −

    27

    𝑲𝐟 𝐌𝐀𝐄 > 𝑲𝐟 𝐌𝐘 𝐧−𝟒 .

    →
    Cd2+ , Zn2+ , Hg 2+ , Co2+ Cu2+ , Ag + , Ni2+ Pd2+
    Pt 2+ Fe2+ Fe3+ Ca2+ , Mg 2+ Mn2+ ni Pb2+
    Al3+ , Fe3+ , Ti4+ y Be2+
    Al3+ Fe3+ Mn2+
    Bi3+ Cd2+ Cu2+ Hg 2+ ,
    Pb2+
    𝐾f M(OH)n ≪ 𝐾f MLaux ≪ 𝐾f MIn− ≪ 𝐾f MY n−4 ≪ 𝐾f MAE

    28

    14
    29/07/2022

    𝐾f M(OH)n ≪ 𝐾f MLaux ≪ 𝐾f MIn− ≪ 𝐾f MY n−4 ≪ 𝐾f MAE ⇇ ADE

    29

    30

    15
    29/07/2022

    31

    32

    16
    29/07/2022

    33

    >; <

    34

    17
    29/07/2022

    35

    https://http2.mlstatic.com/D_NQ_NP_970694-
    MLA46683380650_072021-O.jpg

    36

    18
    29/07/2022

    Mg 2+

    Tarea 10, toda.


    37

    38

    19

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