Sangamner Nagarpalika Arts, D.J. Malpani Commerce & B.N.

Sarda Science College (Autonomous),

Sangamner.
T.Y.B.Sc.-Chemistry
Organic Chemistry-II (CH-3976)
Tutorial No.-01 (Sem-VI) Date:27/02/23
2. Ultra Violet and Visible Spectroscopy
Q.1) Answer the following: (1M) (Solve any 3 questions)
a) Define the term ‘Chromophore’.
b) Define the term ‘Auxochrome’.
c) Define the term ‘Hypsochromic Shift’.
d) Define the term ‘Hyperchromic Shift’.
e) Define the term ‘Hypochromic Shift’.
f) Write the name of radiation used and nature of excitation in UV Spectroscopy.

Q.2) Answer the following: (3M) (Solve any 4 questions)

a) What is bathochromic shift? Trans stilbene absorbs at higher wavelength than cis. Explain.
b) What is bathochromic shift? P-nitrophenol shows red shift in alkaline medium. Explain.
c) Explain the electronic transitions in UV spectroscopy.
d) Write/ Give applications of UV spectroscopy.
e) Explain n→π* transition and π→π* transition with suitable example.
f) What is bathochromic shift? Trans-cinnamic acid absorption at longer wavelength than cis-cinnamic
acid. Explain.

Q.3) Answer the following: (2M)

a) Aniline shows hypsochromic shift in acidic medium. Or Aniline shows blue shift in acidic medium.
Explain.
b) Explain Beer-Lamberts Law.

Q.4) Calculate λmax values for the following: (4M) (Solve any 5 questions)

a)

b)

c)
 d)

e)

f)

g)

h)

i)

Subject Incharge
Asst. Prof. Bhoye M.R.

• Last Date of Submission: 08-03-2023