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(0999DJA111521010) Test Pattern

)0999DJA111521010)
DISTANCE LEARNING PROGRAMME JEE(Advanced)
TEST # 09
(Academic Session : 2021 - 2022) 19-12-2021
JEE(Main + Advanced) : LEADER TEST SERIES / JOINT PACKAGE COURSE (PHASE-II)
12th Undergoing/Pass Students

Test Type : Unit Test # 08


Time : 3 Hours Maximum Marks : 252
READ THE INSTRUCTIONS CAREFULLY

GENERAL INSTRUCTIONS %

1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.

2. Use the Optical Response sheet (ORS) provided separately for answering the questions.

3. Blank spaces are provided within this booklet for rough work.

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


4. Write your name, form number and sign in the space provided on the back cover of this booklet.

5. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the
20 questions in each subject and along with the options are legible. If not, contact the invigilator for
replacement of the booklet.

6. You are allowed to take away the Question Paper at the end of the examination.

OPTICAL RESPONSE SHEET :

7. The ORS will be collected by the invigilator at the end of the examination.

8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.

9. Write your name, form number and sign with pen in the space provided for this purpose on the ORS.
Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble
under each digit of your form number.

DARKENING THE BUBBLES ON THE ORS

10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.

14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
"un-darken" a darkened bubble.

15. Take g = 10 m/s2 unless otherwise stated. / g = 10 m/s2

QUESTION PAPER FORMAT

16. The question paper has three parts : Physics, Chemistry and Mathematics.
Leader Test Series/Joint Package Course/Phase-II/19-12-2021
ALLEN

BEWARE OF NEGATIVE MARKING

PART-1 : PHYSICS
SECTION-I (i) : (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer. 
For each question, choose the option corresponding to the correct answer. 
Answer to each question will be evaluated according to the following marking scheme :
          Full Marks          :    +3   If ONLY the correct option is chosen.

         Zero Marks          :     0     If none of the options is chosen (i.e. the question is unanswered)

         Negative Marks   :   –1    In all other cases


1. The graph shown is the extension of wire of length 1m suspended from the top of a  roof at one end and
with a load W connected to the other end. If the cross sectional area of the wire is 1 mm2, then the
Young's modulus of the material of the wire.

1
(A) 2 × 1011 Nm–1 (B) 2 × 1010 Nm–2 (C)  × 1011 Nm–2 (D) None of these
2

Space for Rough Work

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−−−−
4gR
2. A particle is projected with a velocity √  vertically upward from the surface of the earth, R being the
3
radius of the earth & g being the acceleration due to gravity on the surface of the earth. The velocity of the
particle when it is at half the maximum height reached by it is
−−− −−− −−−−
gR gR −−
− 2gR
(A) √ (B) √ (C) √gR (D) √
2 3 3

3. A thin oil film of refractive index 1.2 floats on the surface of water (µ = 4 ). When a light of wavelength
3
λ = 9.6 × 10–7
m falls normally on the film from air, then  it appears dark when seen normally. The
minimum change in its thickness for which it will appear bright in normally reflected light by the same
light is :-
(A) 10–7 m (B) 2 × 10–7 m (C) 3 × 10–7 m (D) 5 × 10–7 m
4. A rectangular tank is filled completely with water. A hole at its bottom is unplugged. The graph between
the velocity of efflux (through a small hole) vs depth of water h from the top of tank.

(A) (B) (C) (D)

Space for Rough Work

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ALLEN
SECTION-I (ii) : (Maximum Marks: 16)
This section contains FOUR (04) questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks             :    +4    If only (all) the correct option(s) is (are) chosen.

         Partial Marks        :    +3     If all the four options are correct but ONLY three options are chosen.

        Partial Marks         :    +2     If three or more options are correct but ONLY two options are chosen and
both of which are correct.

        Partial Marks         :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

        Zero Marks            :     0      If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks      :    –1     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –1 marks.

5. A man is sitting in a boat floating in water. There are heavy stones placed in the boat.
(A) When the man throws the stones in water, the level of boat goes down.
(B) When the man throws the stones in water, the level of boat rises up.
(C) When the man drinks some water, the level of boat goes down
(D) When the man drinks some water, the level of boat remains unchanged.
6. In a YDSE arrangement, white light is used to illuminate the slits. At point on the screen directly in front
of the slits, which of these wavelengths is/are missing ?

(λ = wavelength of light used, d = distance between the slits, D = separation between the slits and the
screen, d << D) :-
d2 d2 d2 d2
(A) (B) (C) (D)
D 3D 4D 8D

Space for Rough Work

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7. A tube of small uniform cross section is used to siphon the water from the vessel. Then choose correct
alternative(s) : (ρwater = 103 kg/m3, g = 10 m/s2, Patm = 105 Pa)

−−
(A) Water will come out from section B with a velocity of √80  m/s

(B) Water will come out from section B with a velocity of 10 √ 2 m/s

(C) The greatest value of h1 for which the siphon will work is 20 m
(D) The greatest value of h1 for which the siphon will work is 12 m
8. In the figure shown a rod is kept on floor and applied some forces. The area of cross-section is A and
Young’s modulus is Y (Assume all forces are applied uniformly distributed throughout cross section of
rod) :-

(A) Stress at P & Q are equal


(B) Stress at P is 3  times stress at Q
2

(C) Elongation of rod under the forces is  5 Fℓ


2 AY
2F
(D) Strain at Q is 
AY

Space for Rough Work

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SECTION-I (iii) : (Maximum Marks: 6)
This section contains TWO (02) questions.
This section contains ONE paragraph.
Based on paragraph, there are TWO questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks            :    +3    If ONLY the correct option is chosen.

        Zero Marks           :     0    If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks     :    –1    In all other cases.


Paragraph for Questions 9 and 10
A cylindrical container of length L is full to the brim with a liquid which has mass density ρ. It is placed
on a weight-scale; the scale reading is w. A light ball which would float on the liquid if allowed to do so,
of volume V and mass m is pushed gently down and held beneath the surface of the liquid with a rigid
rod of negligible volume as shown on the left.

9. What is the reading of the scale when the ball is fully immersed
(A) w – ρVg (B) w (C) w + mg – ρVg (D) none of these
10. If instead of being pushed down by a rod, the ball is held in place by a thin string attached to the bottom
of the container as shown on the right. What is the tension T in the string?
(A) (ρV–m)g (B) ρVg (C) mg (D) none of these

Space for Rough Work

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ALLEN
SECTION-I (iv) : (Maximum Marks: 8)
This section contains TWO (02) questions.
This section contains ONE paragraphs.
Based on paragraph, there are TWO questions
Each question has Four options (A), (B), (C) and (D) ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:

Full Marks          :    +4     If only (all) the correct option(s) is (are) chosen.

Partial Marks      :    +3     If all the four options are correct but ONLY three options are chosen.

Partial Marks      :    +2     If three or more options are correct but ONLY two options are chosen, both
of which are correct options.

Partial Marks      :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

Zero Marks         :     0      If none of the options is chosen (i.e. the question is unanswered).

Negative Marks  :    –2     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –2 marks.

Paragraph for Questions 11 and 12


A 4.0 kg mass is hung from a vertical light steel wire 2.0 m long and 5.0 × 10–3 cm2 in cross-sectional
area. The wire is securely fastened to the ceiling. (Young's modulus = 2 × 1011 N/m2)
11. Choose the correct statement(s) :-
(A) The amount the wire is stretched by the hanging mass is 8 × 10–4 m
(B) The amount the wire is stretched by the hanging mass is 3.92 × 10–4 m
(C) Stress is a vector quantity
(D) Strain is a vector quantity
12. Now assume that the mass is very slowly pulled downward 0.06 cm from its equilibrium position by an
external force F .
⃗ 

(A) The work done by gravity approximately is 0.024 J


(B) The work done by gravity approximately is 0.048 J
(C) The work done by external force on the block is 0.009 J
(D) The change in elastic potential energy is 0.033 J
Space for Rough Work

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SECTION-I (v) : (Maximum Marks: 6)
This section contains TWO (02) questions.
Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of
which ONLY ONE is correct
For each question, marks will be awarded in one of the following categories :
         Full Marks            :    +3   If ONLY the correct option is chosen.

        Zero Marks            :     0    If none of the options is chosen (i.e. the question is unanswered)

        Negative Marks     :    –1   In all other cases


13. Water which wets the wall of a vertical capillary tube rises to a height H within it. Four ‘gallows’ (a), (b),
(c) and (d) are made from the same tubing and one end of each is placed into a large dish filled with
water, as shown in figure.

Match with correct List I with List II of correct shape of meniscus. 


  List-I   List-II

(P) (1) Concave up

(Q) (2) Concave down

(R) (3) Flat horizontal

(S) (4) Water will flow out

(A) P → 1;Q → 2;R → 3;S → 4 (B) P → 2;Q → 3;R → 4;S → 1


(C) P → 4;Q → 3;R → 2;S → 1 (D) P → 1;Q → 2;R → 4;S → 3

Space for Rough Work

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14. List-I gives different situations in which bodies are floating in liquid. List-II gives corresponding time
periods of small oscillations. The value of H is 5m.
  List-I   List-II

(P) (1) π

A solid cylinder floating in liquid



(Q) (2) –
√3

A solid cone floating in liquid



(R) (3) –
√6

A solid sphere floating in liquid


π
(S) (4) –
√6

A solid cube of side H floating in liquid


(A) P → 3;Q → 4;R → 2;S → 1 (B) P → 1;Q → 3;R → 4;S → 2
(C) P → 2;Q → 3;R → 1;S → 4 (D) P → 1;Q → 4;R → 3;S → 2
Space for Rough Work

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SECTION-III : (Maximum Marks: 20)
This section contains FIVE (05) questions.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
For each question, enter the correct integer value of the answer in the place designated to enter the
answer.
For each question, marks will be awarded in one of the following categories :
         Full Marks      :    +4    If ONLY the correct answer is chosen.

         Zero Marks    :     0    In all other cases.


1. In a YDSE experiment two slits S1 and S2 have separation of d = 2 mm. The distance of the screen is
D = 8/5 m. Source S starts moving from a very large distance towards S2 perpendicular to S1S2 as
shown in figure. The wavelength of monochromatic light is 500 nm. The number of maximas
observed on the screen at point P as the source moves towards S2 is 3995 + n. Find the value of n.

2. A sphere of diameter 12 cm and density 500 kg/m3 is under water of density 1000 kg/m3. The acceleration
of the sphere is 9.80 m/s2 upward. Viscosity of water is 1.0 centipoise. If g = 9.81 m/s2, the velocity of the
sphere is given as ‘v’ m/s. Find the value of 10v. 
3. A cube of sponge rubber with edge length 5 cm has a force of 2N applied horizontally to the top face
parallel to an edge while the bottom face is held fixed. Top face gets displaced horizontally through a
distance of 1mm. If shear modulus or modulus of rigidity for the sponge rubber is given by x × 104 N/m2
then fill value of x ?

Space for Rough Work

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ALLEN
4. A hemispherical shell is fixed. The mass distribution of the shell is uniform. At a point on the symmetry
axis, which is exactly at a distance of the radius measured from the centre of the hemisphere O, a small
bead is released. The speed of the bead is v0 when it reaches the centre O. The speed of the bead be when
it reaches the shell is √−
x− v0. Find x (Neglect the effect of gravity.)

5. We have a vessel in shape of a cuboid partially filled with water . It's base is square with an area of 5 dm2
and vessel contains water upto 20 cm height. Then we place a wooden cube inside water. The wood has
mass of 4kg and specific gravity 0.5. The base of wooden cube is horizontal. The height of water level
H
above the base is H cm. Then find the value of 
4

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SECTION-IV : (Maximum Marks: 16)
This section contains TWO (02) questions.
Each question contains two columns, Column-I and Column-II.
Column-I has four entries (A), (B), (C) and (D)
Column-II has five entries (P), (Q), (R), (S) and (T)
Match the entries in Column-I with the entries in Column-II.
One or more entries in Column-I may match with one or more entries in Column-II. 
For each entry in Column-I, darken the options of all the matching entries. For example, if entry (A) in
Column-I matches with entries (Q), (R) and (T), then chosen these three options. Similarly, for entries
(B), (C) and (D).
For each question, marks will be awarded in one of the following categories :
         For each entry in Column-I

         Full Marks            :    +2    If only the option(s) corresponding to all the correct match(es) is (are) chosen

         Zero Marks           :     0    In all other cases


1. Consider the figure below. A tank of water (height of water column b) is kept on a electronic weighing
scale. A metal cube (side a and density ρ) is hung from a spring balance and the  spring balance is slowly
lowered into the tank till the cube reaches the bottom of the tank. The distance between the  bottom of the
tank and bottom of the cube, at any instant, is denoted by h with initial value h0.

  Column-I   Column-II

(A) Reading of spring balance vs h (P)

(B) Reading of electronic scale vs h (Q)

(C) Force of buoyancy vs h (R)

Sum of the reading of spring balance and  the


(D) (S)
reading of electronic scale vs h

    (T)

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ALLEN
2. In the standard YDSE apparatus shown in figure ; Δx is the path difference between S2P & S1P. Now a
glass slab is introduced in front of S2. Then match the following :-

  Column-I   Column-II
(A) Δx at P will (P) Increases
(B) Fringe width will (Q) Shift downward
(C) Fringe pattern will (R) Remain same
(D) Number of fringes between O & P will (S) Shift upward
    (T) Decreases

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ALLEN
PART-2 : CHEMISTRY
SECTION-I (i) : (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer. 
For each question, choose the option corresponding to the correct answer. 
Answer to each question will be evaluated according to the following marking scheme :
          Full Marks          :    +3   If ONLY the correct option is chosen.

         Zero Marks          :     0     If none of the options is chosen (i.e. the question is unanswered)

         Negative Marks   :   –1    In all other cases

1.
  

(A) Major product is a meso compound


(B) Major product is a threo compound
(C) Mechanism for the formation of major product is SN2
(D) Mechanism for the formation of major product is SNNGP
2. Which of the following represent correct reactivity order for SN1 as well as SN2 mechanism 

(A)  >  (B) CH2 = CHCl  >  CH3CH2–Cl

(C)  >  (D) CH2 = CHCl  >  CH2 = CH–CH2Cl

3. Correct order of increasing freezing point of solution-I 0.1m KCl. solution-II : 0.2 m HA 

(α = 0.5) & solution-III : 0.1m C6H12O6 


(A) I < II < III (B) III < II < I (C) III < I < II (D) II < I < III
4. Which of the following ore is concentrated by chemical leaching :
(A) Galena (B) Copper pyrite (C) Argentite (D) Cinnabar

Space for Rough Work

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ALLEN
SECTION-I (ii) : (Maximum Marks: 16)
This section contains FOUR (04) questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks             :    +4    If only (all) the correct option(s) is (are) chosen.

         Partial Marks        :    +3     If all the four options are correct but ONLY three options are chosen.

        Partial Marks         :    +2     If three or more options are correct but ONLY two options are chosen and
both of which are correct.

        Partial Marks         :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

        Zero Marks            :     0      If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks      :    –1     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –1 marks.

5. Reaction A : 

Reaction B : 

Which of the following statement is/are incorrect


(A) Products are same and mechanism is also same
(B) Products are same but mechanism is different
(C) Products are different but mechanism is same
(D) Products are different and mechanism is also different

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ALLEN

6.
Incorrect statement regarding product.
 (A) Only one alkene is produced
(B) Non resolvable major product
(C) Major product shows geometrial isomerism
(D) Product is optically inactive

7. For electrolysis of aq.Na2SO4 using Hg cathode & Pt anode. Select correct statement -
(A) Na+ will be reduced at anode
(B) H2O will be reduced at cathode
(C) SO42– will be oxidised at higher concentration of Na2SO4
(D) H2O will be oxidised at lower concentration of Na2SO4

8. Select ore in which oxidation number of metal is +2 and produce carbondioxide on calcination 
(A) Galena (B) Fool's gold (C) Siderite (D) Malachite

Space for Rough Work

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ALLEN
SECTION-I (iii) : (Maximum Marks: 6)
This section contains TWO (02) questions.
This section contains ONE paragraph.
Based on paragraph, there are TWO questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks            :    +3    If ONLY the correct option is chosen.

        Zero Marks           :     0    If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks     :    –1    In all other cases.


Paragraph for Questions 9 and 10
Resistance of a conductivity cell filled with 0.01 M HA (aq.) solution is 200 Ω at 300K. 

(HA is weak monoprotic acid). If cell constant is 4 cm–1 & Λ0m (HA) is 2 Ω–1m2mol–1. (R = 0.08 bar/mol-
k)
9. Molar conductivity of 0.01M HA (Ω–1cm2mol–1)
(A) 2 × 103 (B) 2 × 102 (C) 4.0 × 103 (D) 4.0 × 102
10. Osmotic pressure of 0.01M HA(aq.) at 300K is -
(A) 2.64 bar (B) 0.264 bar (C) 0.24 bar (D) 0.48 bar

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ALLEN
SECTION-I (iv) : (Maximum Marks: 8)
This section contains TWO (02) questions.
This section contains ONE paragraphs.
Based on paragraph, there are TWO questions
Each question has Four options (A), (B), (C) and (D) ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:

Full Marks          :    +4     If only (all) the correct option(s) is (are) chosen.

Partial Marks      :    +3     If all the four options are correct but ONLY three options are chosen.

Partial Marks      :    +2     If three or more options are correct but ONLY two options are chosen, both
of which are correct options.

Partial Marks      :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

Zero Marks         :     0      If none of the options is chosen (i.e. the question is unanswered).

Negative Marks  :    –2     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –2 marks.

Paragraph for Questions 11 and 12


Aluminium is the most abundant metal in earth crust. It exist in combined state like oxide, fluoride,
sulphates, silicates, phosphate etc. Aluminium is mainly extracted by bauxite ore which is generally
contaminated by ferric oxide (red bauxite) and silica (white bauxite). 
11. If white bauxite is treated with conc. solution of sodium hydroxide then silica which present in bauxite is -
(A) affected (B) form soluble silicate
(C) form insoluble silicate (D) none of the above
12. Which of the following step is involved in the metallurgy of aluminium form red bauxite.
(A) Electrolysis of aq. salt (B) Leaching
(C) Electrolytic refining (D) Fused electrolysis

Space for Rough Work

0999DJA111521010 E-17/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-I (v) : (Maximum Marks: 6)
This section contains TWO (02) questions.
Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of
which ONLY ONE is correct
For each question, marks will be awarded in one of the following categories :
         Full Marks            :    +3   If ONLY the correct option is chosen.

        Zero Marks            :     0    If none of the options is chosen (i.e. the question is unanswered)

        Negative Marks     :    –1   In all other cases


13.   List-I   List-II

(P) (1)

(Q) (2)

(R) (3) PhCH = CH–CH3

(S) (4)

(A) P → 2;Q → 3;R → 4;S → 1 (B) P → 2;Q → 1;R → 3;S → 4


(C) P → 3;Q → 4;R → 2;S → 1 (D) P → 3;Q → 2;R → 1;S → 4

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ALLEN
14. Match the following column :-
List-I List-II
   
(Metallurgical change) (Properties)
(P) CaCO3 → CaO + CO2 (1) Non-redox change
(Q) ZnS + O2 → ZnO + SO2 (2) Endothermic process
(R) C + O2 → CO2 (3) Exothermic process
Δ
(S) Fe2O3 . xH2O  →  Fe2O3 (4) Redox change

(A) P → 2,4;Q → 2,3;R → 1,3;S → 1,2


(B) P → 3,4;Q → 1,2;R → 2,4;S → 1,3
(C) P → 2,3;Q → 1,4;R → 2,3;S → 3,4
(D) P → 1,2;Q → 3,4;R → 3,4;S → 1,2

Space for Rough Work

0999DJA111521010 E-19/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-III : (Maximum Marks: 20)
This section contains FIVE (05) questions.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
For each question, enter the correct integer value of the answer in the place designated to enter the
answer.
For each question, marks will be awarded in one of the following categories :
         Full Marks      :    +4    If ONLY the correct answer is chosen.

         Zero Marks    :     0    In all other cases.


1.
   Product mixture.

Number of alcohols formed in product mixture as major product.


2.
 Product mixture.

Number of possible alkenes formed in product mixture.

3. During electrolysis 40 mA current is passed through 100ml of 0.2M Fe2(SO4)3 solution for certain time.
If 30 ml of 0.01M KMnO4 is decolourised by solution in cell then find time of electrolysis in hours.
(Given F = 96000C) 

4. If 1 gm of solute dimerise upto 75% in 100 gm of H2O & depression in freezing point 0.093°C. Find
average molecular weight of solute after dimerisation K f H 2 O 1.86 .
( ( )
= )

5. Find the number of curves which are wrongly presented in the Elingham diagram.

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Leader Test Series/Joint Package Course/Phase-II/19-12-2021
ALLEN
SECTION-IV : (Maximum Marks: 8)
This section contains TWO (02) questions.
Each question contains two columns, Column-I and Column-II.
Column-I has four entries (A), (B), (C) and (D)
Column-II has five entries (P), (Q), (R), (S) and (T)
Match the entries in Column-I with the entries in Column-II.
One or more entries in Column-I may match with one or more entries in Column-II. 
For each entry in Column-I, darken the options of all the matching entries. For example, if entry (A) in
Column-I matches with entries (Q), (R) and (T), then chosen these three options. Similarly, for entries
(B), (C) and (D).
For each question, marks will be awarded in one of the following categories :
         For each entry in Column-I

         Full Marks            :    +2    If only the option(s) corresponding to all the correct match(es) is (are) chosen

         Zero Marks           :     0    In all other cases


1. Match the column :
  Column-I   Column-II
(A) ZnCO3 —→ Zn (P) calcination
(B) ZnS —→ ZnO (Q) roasting
(C) PbS(high grade) —→ Pb (R) self reduction
(D) Cu2S —→ Cu2O (S) carbon reduction
    (T) no change in oxidation number of metal

Space for Rough Work

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ALLEN
2. Column - I
Column - II

   
(Reactions) (Characteristics)
HBr
(A) CH3CH2CH = CH2  −− → (P) Bimolecular
HBr, Peroxide
(B) CH3CH2CH = CH2  −−−−−−−−− → (Q) Carbocation intermediate
SOCl2
(C) PhCH(CH3)OH −−−− → (R) Regioselective
HBr
(D) PhCH(CH3)OH −− → (S) Racemic modification
    (T) Stereospecific reaction

Space for Rough Work

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ALLEN
PART-3 : MATHEMATICS
SECTION-I (i) : (Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer. 
For each question, choose the option corresponding to the correct answer. 
Answer to each question will be evaluated according to the following marking scheme :
          Full Marks          :    +3   If ONLY the correct option is chosen.

         Zero Marks          :     0     If none of the options is chosen (i.e. the question is unanswered)

         Negative Marks   :   –1    In all other cases


1. Let z1, z2, z3 are three complex number satisfying  |z| = 1 and 4z3 = 3(z1 + z2), then |z1 – z2| is equal to :-
2 – 3 –
√ 5 2√5
(A) (B) (C) (D)
3 3 2 3
2. Vector equation of the line passing through (–1, 1, 3) and perpendicular to lines 
x−1 y+2 z+3 x−1 y+1 z+1
= =  and  = =  is :-
1 −1 2 1 2 2

(A) r ⃗  = i
^
(− +
^
+ j 3k^) + λ ( 2^i − 3^j − 4k^)

(B) r ⃗  = i
(−^ + ^ + j 3k^) + λ 3i
( ^ − 2^j − 4k^)

(C) r ⃗  = i
^
(− +
^
+ j 3k^) + λ (2^i − k^)

(D) r ⃗  = i
^
(− +
^
+ j 3k^) + λ ( 3^i − 4^j − 3k^)

3. π
The direction ratios of a normal to the plane passing through (1,0,0), (0,1,0) and making an angle   with
4
plane x + y = 3 can be :–
– –
(A) 0,1,0 (B) 1, 1, √2 (C) 1,0,0 (D) 2 1, 1
√ ,

4. In complex plane the centre of a square ABCD is at z = 0. If A is z1, then the centroid of ΔABC is :-
z1
(A) z1 (cos π ± i sin π) (B) (cos π ± i sin π)
3
π π z1 π π
(C) z1 (cos ± i sin ) (D) (cos ± i sin )
2 2 3 2 2

Space for Rough Work

0999DJA111521010 E-23/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-I (ii) : (Maximum Marks: 16)
This section contains FOUR (04) questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are) correct
answer(s).
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks             :    +4    If only (all) the correct option(s) is (are) chosen.

         Partial Marks        :    +3     If all the four options are correct but ONLY three options are chosen.

        Partial Marks         :    +2     If three or more options are correct but ONLY two options are chosen and
both of which are correct.

        Partial Marks         :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

        Zero Marks            :     0      If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks      :    –1     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –1 marks.

1 + z̄
5. If 'z' is a complex number such that Arg(z.|z|2) + Arg ( ) = 0  , then :
z − |z 2 |
1+z 1+z
(A)   is purely imaginary (B)  is purely real 
1−z 1−z
(C) |z| < 1 (D) |z| > 1

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Leader Test Series/Joint Package Course/Phase-II/19-12-2021
ALLEN
6. x−α y z+β y z+α
Consider Lines  L1 : = = , L 2 : x = α, = ,  plane  P : 2x + 2y + z + 7 = 0   .
1 −2 2 −α 2−β
Let line L2 lies in plane P, then
(A) α = –7
(B) α=7
(C) minimum distance between line L1 and plane P is 11.
23
(D) minimum distance between line L1 and plane P is 
3
7. π 2π
Let P(α) is a variable point on the curve |z – i| = 1 in argand plane such that  ⩽ amp (α) ⩽ . 
3 3

√ 3 i
Q( + )  be another point and area swept out by segment PQ is S (in square units), then :-
2 2

(A) α|
| = √3 (B) |α| = 1
min min

– –
π √3 2π √3
(C) S= + (D) S= +
3 4 3 4
8. Let P(α, β, γ) is a variable point on a plane which is parallel to x-axis & passes through points A(5, 3, 4)
& B(4, 2, 0). Identify the correct options :- 
64
(A) Minimum value of α2 + β2 + γ2 is 4 (B) Minimum value of α2 + β2 + γ2 is 
17
(C) Minimum value of β2 + γ is –12 (D) Sum of intercepts of plane on axes is –6

Space for Rough Work

0999DJA111521010 E-25/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-I (iii) : (Maximum Marks: 6)
This section contains TWO (02) questions.
This section contains ONE paragraph.
Based on paragraph, there are TWO questions
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
         Full Marks            :    +3    If ONLY the correct option is chosen.

        Zero Marks           :     0    If none of the options is chosen (i.e. the question is unanswered).

       Negative Marks     :    –1    In all other cases.


Paragraph for Questions 9 and 10
x−6 y − 12 z−8
Let L be the line  = = .

2 4 2
Let A be the point of intersection of the plane π1 : x + y + z = 6 & L. Let P be the point of intersection of
the plane π2 : x + y + z = 10 & L. AP is produced to Q such that AP = PQ. Let R be the image of Q in
π2.
9. co-ordinates of R is :-
1 10 7 1 10 5
(A) (− , , ) (B) (− ,− , )
3 3 3 3 3 3
1 10 7 1 10 7
(C) ( , ,
3 3 3
) (D) (
3
,−
3
,−
3
)

10. Let S be a point on the plane π2 such that PQSR is a parallelogram then its area is-
– – –
6 3√3 8√2
(A) √ (B) 6 (C) (D)
3

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E-26/32 0999DJA111521010
Leader Test Series/Joint Package Course/Phase-II/19-12-2021
ALLEN
SECTION-I (iv) : (Maximum Marks: 8)
This section contains TWO (02) questions.
This section contains ONE paragraphs.
Based on paragraph, there are TWO questions
Each question has Four options (A), (B), (C) and (D) ONE OR MORE THAN ONE of these four
option(s) is(are) correct.
For each question, choose the option(s) corresponding to (all ) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:

Full Marks          :    +4     If only (all) the correct option(s) is (are) chosen.

Partial Marks      :    +3     If all the four options are correct but ONLY three options are chosen.

Partial Marks      :    +2     If three or more options are correct but ONLY two options are chosen, both
of which are correct options.

Partial Marks      :    +1     If two or more options are correct but ONLY one option is chosen and it is a
correct option.

Zero Marks         :     0      If none of the options is chosen (i.e. the question is unanswered).

Negative Marks  :    –2     In all other cases.


For Example : If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option), without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in –2 marks.

Paragraph for Questions 11 and 12


For complex number z, consider sets A = {z ∈ C : |z – 2 – 2i| < 2} and

B = {z ∈ C : i (z − z̄ ) − (z + z̄ ) + 4 ⩽ 0}
11. Area of the region traced by points in set A ∩ B (in sq. units) is -
(A) 3π – 2 (B) 3π + 2 (C) π+2 (D) π + 3
12. The minimum value of |z + 2| (z ∈ A ∩ B) is greater than :-
– 1 –
(A) √ 2 (B) – (C) 2√2 (D) 2
√2

Space for Rough Work

0999DJA111521010 E-27/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-I (v) : (Maximum Marks: 6)
This section contains TWO (02) questions.
Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of
which ONLY ONE is correct
For each question, marks will be awarded in one of the following categories :
         Full Marks            :    +3   If ONLY the correct option is chosen.

        Zero Marks            :     0    If none of the options is chosen (i.e. the question is unanswered)

        Negative Marks     :    –1   In all other cases


13. If z1, z2, z3, z4 are the roots of the equation z4 + z3 + z2 + z + 1 = 0 then match List-I with List-II and select
the correct answer using the code given below the list.
List-I List-II
∣ 4 ∣
(P) ∣

∑ zi 4 ∣∣ is equal to (1) 0
∣i = 1 ∣

4
(Q) ∑ zi 5  is equal to (2) 4
i = 1

4
(R) ∏ ( zi + 2)  is equal to (3) 1
i = 1

least value of [|z1 + z2|]

(S) (Where [.] represents greatest integer (4) 11


function)
(A) P → 3;Q → 2;R → 4;S → 1 (B) P → 2;Q → 4;R → 3;S → 2
(C) P → 4;Q → 1;R → 2;S → 3 (D) P → 1;Q → 3;R → 1;S → 4

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ALLEN
14. OAB is an equilateral Δ lying on plane P ≡ 2x – y – z = 0 where O is origin. D(1,1,1) be the foot of
perpendicular from origin on line AB. Let C ≡ (1,0,1). It is given that CA > CB. Match List-I with List-II
and select the correct answer using the code given below the list.
List-I List-II
x−1 y−1 z−1
If equation of AB is  = =  , then

(P) α 1 γ (1)  2
4(α – γ) is equal to
–y –z
x √ 2 √ 2
(Q) If equation of OA is  = =  , then α – β is  (2)  6
1 α β
– –
x √ 2y √ 2z 2 2
(R) If equation of OB is  = = , then λ + μ is  (3) 4
1 λ μ
If a plane passing through A and B & perpendicular to  plane
(S) (4) 3
P has equation x + y + z = k, then k is
(A) P → 3;Q → 2;R → 1;S → 4 (B) P → 2;Q → 1;R → 4;S → 3
(C) P → 3;Q → 1;R → 2;S → 4 (D) P → 1;Q → 3;R → 2;S → 2

Space for Rough Work

0999DJA111521010 E-29/32
Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
SECTION-III : (Maximum Marks: 20)
This section contains FIVE (05) questions.
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
For each question, enter the correct integer value of the answer in the place designated to enter the
answer.
For each question, marks will be awarded in one of the following categories :
         Full Marks      :    +4    If ONLY the correct answer is chosen.

         Zero Marks    :     0    In all other cases.


x−1 y z+1 x y−1 z
1. A line from origin meets the lines  = =  and  = =  at A and B, then length of
1 2 2 2 3 1
AB is equal to :-
2i π
2. If z1 & z2 are two complex numbers such that z1 + z2 = z12 + z22 =  –  and |Re(z1)| =  sin
( )  (where 
√3 k
i = √−
−−
−1)  , then value of k is :-

x y−1 z−1 x y−1 z−1


3. The projection of line  = =   on a plane 'P' is  = =  . If the plane P passes
2 2 1 1 1 −1

through (k, –2, 0), then value of k is :-


(− 4 + 7i) (83 − i) (1 + 83i)
4. Let x + iy =  ; (x, y ∈ R)  then (x2 + y2) is :-
4 + 7i) (−1 + 83i) (83 + i)
(

81
5. Let volume of a tetrahedron ABCD is   sq. unit and volume of parallelopiped whose three coterminous
2
edges are line segments joining centroid of any face of tetrahedron with centroids of its other three faces
is 3λ, then λ is 

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E-30/32 0999DJA111521010
Leader Test Series/Joint Package Course/Phase-II/19-12-2021
ALLEN
SECTION-IV : (Maximum Marks: 16)
This section contains TWO (02) questions.
Each question contains two columns, Column-I and Column-II.
Column-I has four entries (A), (B), (C) and (D)
Column-II has five entries (P), (Q), (R), (S) and (T)
Match the entries in Column-I with the entries in Column-II.
One or more entries in Column-I may match with one or more entries in Column-II. 
For each entry in Column-I, darken the options of all the matching entries. For example, if entry (A) in
Column-I matches with entries (Q), (R) and (T), then chosen these three options. Similarly, for entries
(B), (C) and (D).
For each question, marks will be awarded in one of the following categories :
         For each entry in Column-I

         Full Marks            :    +2    If only the option(s) corresponding to all the correct match(es) is (are) chosen

         Zero Marks           :     0    In all other cases


1. Consider the following linear equations 

2(a + b)x + 3(b + c)y + 4(c + a)z = 0,

2(b + c)x + 3(a + c)y + 4(a + b)z = 0 and

2(a + c)x + 3(a + b)y + 4(b + c)z = 0, a, b, c, x, y, z ∈ R.


Column-I Column-II
the equations represent planes
(A) (P) a + b + c ≠ 0 and a2 + b2 + c2 = ab + bc + ca
meeting only at  a single point
the equations represent
(B) (Q) a + b + c = 0 and a2 + b2 + c2 ≠ ab + bc + ca
identical planes
the equations represent the
(C) (R) a + b + c ≠ 0 and  a2 + b2 + c2 ≠ ab + bc + ca
line 2x = 3y = 4z
The equations represent the
(D) (S) a + b + c = 0 and  a2 + b2 + c2 = ab + bc + ca
whole of the xy-plane
    (T) a2 + b2 + c2 + ab + bc + ca < 0

Space for Rough Work

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Target : JEE(Main + Advanced) 2022/19-12-2021
ALLEN
n
2. The complex numbers  z1 , z2 . . . . . . . . . zn , ∑ zi ≠ 0,  represents the vertices of a regular polygon of n
i=1

sides in order, inscribed in a circle of unit radius and  z3 zn Az1 A z2  Then the values of [|A|] in
+ = +
¯¯
¯¯
,

column-II for prescribed values of n in column-I (where [x] be the greatest integer  ≤ x).
Column-I Column-II
(A) 4 (P) 0
(B) 6 (Q) 1
(C) 8 (R) 2
(D) 12 (S) 3
    (T) 4

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