should have developed a deeper understanding of the properties and behavior of food macromolecules during post-harvest handling, preparation, processing, storage and distribution. Specific Objectives: Upon completion of the course, the student should be able to: 1. Relate food chemistry with the other areas of food science and technology; 2. Describe the role played by food chemistry in food science and technology, and discuss its role in the promotion of the welfare of the individual, the family and the society; 3. Discuss the properties and behavior of the macromolecules in food under varied conditions; 4. Describe the major chemical reactions occurring in food during processing and storage; 5. Discuss the effects of various methods and conditions of processing on major food components, and on the quality and storage properties of foods; 6. Explain the role of each macromolecule in the manufacture and storage of foods; 7. Relate properties and behavior of the macromolecules with sensory and nutritional attributes of foods; and 8. Assess the impact of recent advances in food chemistry on the family, the society and the local food industry. Course Requirements
Quizzes and Long Exams
Periodic Exams Research Work Laboratory Reports Overview of the Course
Food Chemistry – concerned with the
composition of food and the changes that it undergoes during processing and under storage. The topics includes basic chemical composition, structure and properties of foods and the chemistry of changes occurring during food preparation, processing, storage and utilization. Nature of Food Chemistry •Concerned about food that exist throughout the world In underdeveloped regions – population is involved in food production In developed regions – food production is highly mechanized and efficient oSmall portion of the population is involved in food production oFood is available in abundance; much of it is processed or has been altered by addition of chemicals. oConcern is directed mainly to the effects of processing and added chemicals on the wholesomeness, nutritive value, and quality of food. Food Science – an interdisciplinary subject involving primarily, bacteriology, chemistry, and engineering.
Food chemistry – science that deals with
the composition, structure, and properties of foods and the chemical changes it undergo. - Intimately related to chemistry, biochemistry, physiological chemistry, botany, zoology, and molecular biology. Food chemist •Relies on his knowledge of the aforementioned sciences •Concerned primarily with biological substances that are dead or dying ( post harvest physiology of plants, post mortem physiology of muscle) and are exposed to a wide range of environmental conditions. •Concerned with the chemical properties of disrupted food tissues, single-cell sources of food. Grading System (Passing Grade, 50%) Lecture Quizzes 40% Periodic Exams 30% Attitude/Attendance 10% Research Work/Project 20% Laboratory Experiments/Written Reports 30% Periodic Exams 30% Pre/Post Lab Quizzes 30% Manipulative Skills 10% Mid-Term/Final Term Grade = 70% Lec + 30%Lab Final Grade = 50% MTG + 50% FTG History of Food Chemistry
•Acquired identity only in 20th century
1. Carl Wilhelm Scheel (1742-1786) – Swedish pharmacist; discovered chlorine, glycerol and oxygen; isolated and studied the properties of lactic acid (1780); prepared mucic acid by oxidation of lactic acid; devised a means of preserving vinegar by heat (1782); isolated citric acid from lemon juice (1784) and goose berries (1785); isolated malic acid from apples (1785); tested20 common fruits for citric, malic, and tartaric acids (1785). 2. Antoine Laurent Lavoisier (1743-1792) – French chemist; established the fundamental of combustion organic analysis; first to show a balanced equation for fermentation process; made the first attempt to determine the elemental composition of alcohol (1784); presented one of the first papers on organic acid of various fruits (1786). 3. (Nicolas) Theodore de Sausure (1767- 1845) – French chemist; formalized and clarified the principle of agricultural and food chemistry; studied CO2 and O2 changes during plant respiration (1804); studied the mineral contents of plants by ashing, and made the first accurate elemental analysis of alcohol (1807). 3. (Nicolas) Theodore de Sausure (1767- 1845) – French chemist; formalized and clarified the principle of agricultural and food chemistry; studied CO2 and O2 changes during plant respiration (1804); studied the mineral contents of plants by ashing, and made the first accurate elemental analysis of alcohol (1807). 4. Joseph Louis Gay-Lussac (1778-1850) & Louis-Jacques Thenard (1777-1857) - devised the first method for quantitatively determining the percentages of carbon, hydrogen, and nitrogen in dry vegetable substances; (their oxidative combustion technique, however, did not provide a procedure for estimating the quantity of water formed. 5. Humpry Davy (1778-1829) – isolated the elements K, Na, Ba, Sr, Ca, and Mg in the years 1807 and 1808. Author of the book “Elements of Agricultural Chemistry”, 1813.
6.Jacob Berzelius (1779-1848): Swedish
chemist & Thomas Thomson (1773-1852): Scottish Chemist – their works resulted in the beginnings of organic formulas, “without which organic analysis would be a trackless desert and food analysis an endless task”. 7. Von Liebig (1803-1873); studied vinegar fermentation and showed that acetaldehyde was an intermediate between alcohol and acetic acid. He classified food as either nitrogenous or non nitrogenous. He perfected the methods for quantitative analysis of organic substances.
8. William Beaumont (1785-1853) – American
Army Surgeon. Performed classic experiments on gastric digestion Review of basic biochemical concepts
A.Percent Composition – is an expression of
composition which gives the number of parts per hundred of the sample. This can be express in the following: a.Mass Percent (w/w) = mass solute X 100% mass solution b. Vol Percent (v/v) = volume solute X 100% volume solution c. Mass/Vol Percent = mass solute, g X 100% (w/v) volume soln, mL B. Molar Concentration or Molarity – number of moles of solute in one Liter of solution or millimoles solute per milliliter of solution.
Molarity (M) = amount (mol) of solute
volume (L) of solution n mass M = ------- n = ------------- v Molar Mass C. Molality (m) – the number of moles of solute dissolved in 1 kg (1000 g) of solvent – that is,
Molality (m) = amount (mol) of solute
mass (Kg) of solvent D. Density and Specific Gravity Density – The mass of a substance per unit volume. In SI units, density is expressed in units of kg/L or g/mL. mass d = ------------ volume Specific Gravity – The ratio of the density of the substance to the density of water at the same temperature. Dimensionless (not associated with units of measure). density of substance Sp. gravity = ---------------------------------- density of water E. Neutralization – involves the reaction of acids with bases. One equivalent weight of acid will neutralize one equivalent weight of base. Na x Va = Nb x Vb