Hydrogen Quick Inorganic

Hydrogen Quick Inorganic

Hydrogen Quick Inorganic
Hydrogen Quick Inorganic
Hydrogen Quick Inorganic

Some Physical Characteristics of H2O2 :

Melting point (K) 272.4 Density (liquid at 298 K) (g cm–3) 1.4425
Boiling point
423 Viscosity at 298 K (Centipoise) 1.245
(extrapolated) (K)
Vapour pressure at 298
1.9 Dielectric constant of 298 K 70.7
K (mm Hg)
Density (solid at 268.5)
1.6434 15.1 × 10–8
(g cm–3)
Hydrogen Quick Inorganic
Hydrogen Quick Inorganic
Hydrogen Quick Inorganic
s-Block Elements Quick Inorganic

Metal Li Na K Rb Cs
Crimson Yellow Pale violet Red violet Blue
670.8 589.2 766.5 780.0 455.5
s-Block Elements Quick Inorganic
s-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic

Inert pair effect : Al3+ > Ga3+ > In3+ > Tl3+
Electron deficient act as Lewis acids : BX3 > AlX3 > GaX3 > InX3
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic

Positive oxidation states :

NO2 or
Compound NH3 NH2NH2 NH2OH N2 N2O NO N2O3 N2O5
N2O4
Oxidation
–3 –2 –1 0 +1 +2 +3 +4 +5
state

Ionization enthalpy :
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic

Bond angle : NH3 > PH3 > AsH3 > SbH3 > BiH3
Basic character : NH3 > PH3 while AsH3, SbH3 and BiH3
Boiling point : PH3 < AsH3 < NH3 < SbH3 < BiH3
Melting point : PH3 < AsH3 < SbH3 < NH3
Thermal stability : NH3 > PH3 > AsH3 > SbH3 > BiH3
Reducing character : NH3 < PH3 < AsH3 < SbH3 < BiH3
Acidic strength : N2O < NO < N2O3 < N2O4 < N2O5
Lewis bases : NF3 < NCl3 < NBr3 < NI3
p-Block Elements Quick Inorganic

Boiling point : H2S < H2Se < H2Te << H2O

Volatility : H2S > H2Se > H2Te > H2O
Bond angle : H2O > H2S > H2Se > H2Te
Acidic character : H2O < H2S < H2Se < H2Te
Thermal stability : H2O > H2S > H2Se > H2Te
Reducing power : H2Te > H2Se > H2S > H2O
Enthalpy of dissociation : Cl2 > Br2 > F2 > I2
Oxidising power : F2 > Cl2 > Br2 > I2
p-Block Elements Quick Inorganic

Reducing power : I– > Br– > Cl– > F–

Hydrogen halides : F2 > Cl2 > Br2 > I2
Boiling points : HF > HI > HBr > HCl
Melting points : HI > HF > HBr > HCl
Dipole moments : HF > HCl > HBr > HI
Bond lengths : HI > HBr > HCl > HF
Thermal stability : HF > HCl > HBr > HI
Acid strength : HI > HBr > HCl > HF
Reducing power : HI > HBr > HCl > HF
p-Block Elements Quick Inorganic
p-Block Elements Quick Inorganic

XeF6 + H2O XeOF4 + 2HF

XeF6 + 2H2O XeO2F2 + 4HF

XeF6 + 3H2O XeO3 + 6HF

2XeF2 + 2H2O 2Xe + 4HF + O2

6XeF4 + 12H2O 4Xe + 2XeO3 + 24HF + 3O2

d- and f-Block Elements Quick Inorganic

General valence shell configuration : (n – 1) d2 4s2 (n = 4 to 6)

Characteristics : TiCl4, ZrCl4, HfCl4 or TiO2, ZrO2 and HfO2
General Electronic configuration : (n – 2) f1–14 (n – 1) d0–1 ns2
Transition Series :
1st transition series : (3d series) for n = 4 (21Sc – 30Zn)
2nd transition series : (4d series) for n = 5 (39Y – 48Cd)
3rd transition series : (5d series) for n = 6 (57La, 72Hf – 80Hg)
4th transition series : (6d series) for n = 7 (89Ac, 104Ku onwards)
d- and f-Block Elements Quick Inorganic

Complex formation : K4 [Fe(CN)6], [Cu(NH3)4] SO4

Complete E.C. of 1st lanthanoid : [Xe]54 4f1 5d1 6s2
Complete E.C. of 2nd lanthanoid : [Xe]54 4f7 5d0 6s2
Oxidation states of 1st lanthanoid : +2 (4f 2), + 3 (4f 1), + 4 (4f 0)
Oxidation states of 2nd lanthanoid : +2 (4f 7) and +3 (4f 6)
Electronegativity of halogens decreases : F > Cl > Br
Halides decreases : M – F > M – Cl > M – Br
Noble gas configuration : 21Sc = [Ar] 3d1 4s2, Sc3+ = [Ar]
Completely filled configuration : 30Zn = [Ar] 3d10 4s2, Zn2+ = [Ar] 3d10
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