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CHEMISTRY 2
TABLE OF CONTENTS
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL KINETIC MOLECULAR THEORY
CHEMISTRY 2
OF LIQUIDS AND SOLIDS
INSTANT TASK
Put all the items in the correct box according to their state of matter.
From the lists in Activity 1, fill up the table below and mark the
relationship to you of each.
Characteristic
Relatives Grand Aunt Mother
Cousin Sibling
Parent / Uncle or Father
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
1
DIRECT TALK
The
The kinetic
kinetic molecular
molecular theory
theory explains the properties
explains the properties ofof gases
gases byby assuming
assuming that
that gas
gas particles
particles act
act
independently
independently of
of each
each other.
other. Due
Due to
to the very weak
the very weak attractive
attractive forces
forces between
between them,
them, the
the particles
particles are
are free
free totomove
moveabout
about
at
at random
random and
and fill
fill their
their containers.
containers. Gases
Gases are
are compressible
compressible and
and they
they diffuse
diffuse through
through one
one another
another easily.
easily.
The particles of a liquid are close together because of strong attractive forces between them. Like gas
particles, liquid particles also collide with each other and with the walls of their containers. However, since the particles
are close together, they can move only at short distances. This type of movement allows liquids to flow and take the
shape of their container without filling it completely as gases do. This also explains why liquids compress only very
slightly, have higher densities than gases, and diffuse more slowly than gases.
In solids, the attractive forces between the particles are stronger than those in liquids and gases. These result
to an ordered arrangement of particles in which the particles are not free to move around. The movement of the particles
is limited to vibrations while they remain in their fixed positions. Thus a solid has a fixed volume and shape. Solids
compress even less than liquids and hardly diffuse.
The three phases of matter. Notice that the spacing between atoms or molecules increases as we move from a
description of the solid phase to the gaseous one.
Intermolecular Forces
nnkh
Intermolecular forces (IMF) or (secondary forces) are the forces which intimidate the reaction between particles
between molecules, including forces of attraction or repulsion which act between atoms and other types of neighboring
particles, e.g. atoms or ions. Intermolecular forces are weak relative to intramolecular forces – the forces which hold a
molecule together. They are ion-dipole, dipole-dipole, dipole-induced dipole, and London dispersion forces. Another
more specific intermolecular forces that affects only certain kinds of molecules is the hydrogen bond.
Intermolecular Forces
2 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Ion - Dipole Forces
Comparison of Molecular Weights, Dipole Moments, and Boiling Points The more polar the substance, the
stronger its dipole-dipole
interactions. The higher the dipole
moment, the stronger the
intermolecular forces that must be
overcome for a substance to boil,
and the higher the boiling point.
London - Dispersion
Forces
It is rather easy to understand intermolecular forces among charged and polar
particles, but it is not so among atoms or nonpolar molecules. Nonpolar molecules such
as Cl2 and CH4 exhibit attractive forces. These nonpolar substances can be condensed
to liquid and even solid if cooled enough to low temperature. The origin of this attraction
was explained in 1930 by Fritz London (1900-1954), a German-American physicist.
On the average, the electrons in a nonpolar molecule or atom are distributed uniformly around the nucleus.
However, at certain instances, the electrons may be on one side of the nucleus. The molecule becomes temporary dipole or
momentary dipole or instantaneous dipole. An instantaneous dipole exerts an influence on nearby particles. It causes the
distortion of the electron clouds of neighboring molecules. As a result, the neighboring molecules also become dipoles.
They are called induced dipoles because they are caused by the formation of the first dipole. This kind of attraction is called
instantaneous dipole-induced dipole attraction or London forces. They are short-lived attractions because electrons
keep on moving which causes the dipole to vanish as quickly as they are formed.
The ease with which a dipole can be induced is called polarizability. Polarizability increases with increased
molecular mass. In large molecules, the electrons are less firmly held and therefore easier to be polarized. As polarization
and London forces increase, the boiling and melting points of covalent substances generally increase with increasing
molecular mass.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
3
.
The ease with which a dipole can be Molar Mass, Melting Points, and Boiling Points of Halogen
induced is called polarizability.
Polarizability increases with increased
molecular mass. In large molecules, the
electrons are less firmly held and
therefore easier to be polarized. As
polarization and London forces
increase, the boiling and melting points
of covalent substances generally
increase with increasing molecular
mass.
Hydrogen Bond
4 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
FLASH CHECK
C. HF and CH3__________________________________________________________
3F
____________________________________________________________________
____________________________________________________________________
D. BaCl2 and PCl3
QUICK REFERENCES
CONNECT • Breaking through chemistry pp. 313 - 323
• World of chemistry pp. 516 - 522
You only have to think about water to • https://www.liveworksheets.com/os987191op
appreciate how different the three • https://cscsdashaicechem.weebly.com/chapter-
states of matter are. Flying, swimming, 4---chemical-bonding.html
and ice skating are all done in contact • http://brainfuse.com/curriculumupload/12240578
with water in its various states. We 98133.html
swim in liquid water and skate on water • https://chem.libretexts.org/Courses/University_of
in its solid form (ice). Airplanes fly in an _Arkansas_Little_Rock/Chem_1403%3A_Gener
atmosphere containing water in the al_Chemistry_2/Text/11%3A_Intermolecular_For
gaseous state (water vapor). To allow ces_and_Liquids/11.03%3A__Dipole-
Dipole_Forces
these various activities, the
• https://irp-
arrangements of the water molecules
cdn.multiscreensite.com/89a70595/files/uploade
must be significantly different in their d/Liga%C3%A7%C3%B5es%20intermoleculares
gas, liquid, and solid forms. _.pdf
• https://legacy.chemgym.net/environmental_chem
istry/topic_3c/page_4.html
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
5
GENERAL
CHEMISTRY 2 PROPERTIES OF LIQUIDS
INSTANT TASK
NOTE: There are
10 terms you need
Encircle the term that are related to the to find.
properties of liquids
I N T E R M O L E C U L A R R
L E T E R O F E N E O U S H R
O N B P O M B H R O Q I C U S
I N T E R M O L E C U L A R S
M O O E M Q O M U C Y Q K E D
Q F V E M Q R M U C Y E K E T
O I I Y E H H H T O M U N R E
U S I Y E H C H T O M V N C N
L S L U R E T T A M T I I U C
I N S U R H E A T M T F I N I
A N I E S A V J R P N D J S R
D E C E S Y S J R R N F J A O
R E N T A T I I E O G S N S E
S T O T A I D S A O G E N T P
E T G F G H S L S U H G I E A
E E S F G H O L P U H G I S G
O E P R B G C N M C X S H R S
O C I R B G O N M N X S H B N
U C O G C M O A E D O T D P L
U A T G C M G A E D U T D U I
S A I S E R S P T S F S S R I
S F Y S E R D P T S F J S S L
R F N N W I I S F S E C R O F
R R N O I T A Z I R O P A V I
C R T B L R T I Q B V C Q P U
C U T B L R Z I Q B V C Q R O
N U X O D B Y S Z C Z X B A Y
S U R F A C E T E N S I O N B
I S N O I T A Z I R O P A V D
I S S I Y F E R U T X I M P D
6 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
DIRECT TALK
VISCOSITY
Some liquids such as water or alcohol flow easily. They are fluid. Others such as
molasses or motor oil take longer time to flow (they are viscous). Viscosity is related to the
Viscosity can be movement of the molecules in the liquid, and thus to the intermolecular forces present. Nonpolar
measured using a
molecules like benzene (C6H6), pentane (C5H12), and carbon tetrachloride (CCl4) experience
only weak intermolecular forces (dispersion forces) and low viscosities. More polar molecules
viscometer. It
like glycerol (C3H5C (OH)3) and aqueous sugar solution (syrup) have high viscosities because
measures the time it
of H-bonding among many -OH groups and dispersion forces at many points along the chain.
takes for a known
volume of a liquid to The viscosity of a liquid decreases with increasing temperature because at higher
flow through the temperatures, the average kinetic energy of the molecules that overcomes the attractive forces
small neck. between molecules is greater.
CAPILLARITY
When you go for This phenomenon is called capillarity or capillary action. This results from a
simple blood tests, a competition between the intermolecular forces within the liquid molecules (cohesive forces) and
sample may be those between the liquid molecules and the walls of the tube (adhesive forces).
obtained by pricking
your finger with a When a capillary tube is placed in water, the surface or meniscus takes a U-shape
needle. A narrow (concave) because the adhesive forces are greater than cohesive forces. In mercury, the
tube called capillary meniscus is curved downward (convex) because the cohesive forces (metallic bonding are
tube is placed on stronger than adhesive forces.
the skin opening
and the blood rises Capillarity is also observed in the transport of water from the roots to the other parts of
up through the tube. plants.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
7
VAPOR PRESSURE
BOILING POINT
The temperature at which boiling point occurs at a pressure of 1 atm is called the
normal boiling point of the liquid. This property changes as pressure changes. If the
atmospheric pressure is below 1 atm, especially at high altitudes like in Baguio City, liquids
boil at lower than normal temperatures. At an altitude of 1600 m, atmospheric pressure is
about 640 torr and water boils at 95 0C. This is because particles in the liquid need less
kinetic energy to escape. Cooking under these conditions takes longer than at sea level. The
effect of high altitudes and lower boiling temperature can be counteracted by using a
pressure cooker. In a pressure cooker, water boils at higher temperature and higher
pressure. The increased heat content of the boiling water allows the food to absorb heat from
the water faster than at 100 0C. A rise of about to 10 0C inside a pressure cooker cooks food
twice as fast as in 100 0C.
8 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
4
FLASH CHECK
Identify
Explainthe why
dominant
eachintermolecular
of the following forces for the following
occurs:
substances. Select the substance with the higher boiling point in each
pair.
1. A freely falling drop of water is spherical in shape.
A. Ne and Ar
__________________________________________________________________________________
__________________________________________________________________________________
____________________________________________________________________
____________________________________________________________________
__________________________________________________________________________________
B. CHarm
33OH and CH33CH22OH
2. Your feels cool when alcohol evaporates from your skin.
____________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
C. HF and CH33F
__________________________________________________________________________________
____________________________________________________________________
____________________________________________________________________
3. On a warm day, water droplets form outside the bottle of carbonated beverage.
D. BaCl22 and PCl33
__________________________________________________________________________________
__________________________________________________________________________________
_____________________________________________________________________
__________________________________________________________________________________
QUICK REFERENCES
CONNECT • Breaking through chemistry pp. 323 - 328
• World of chemistry pp. 516 - 522
• Pin by Nitza I Marin on DYK? | Did you know,
Surface tension, Fun facts (pinterest.ph)
The hair on a gecko's foot are so tiny • Learn Boiling vs Evaporation in 3 minutes.
that it can form intermolecular forces (toppr.com)
of attraction with most surfaces and • Surfact Active Agents, Surfactants (ncsu.edu)
thus making the gecko adhere even • Chapter 13 Solids and Liquids. - ppt video online
on glass without the use of liquids or download (slideplayer.com)
surface tension. • a steel needle floating on water to illustrate
surface tension Stock Photo - Alamy
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
9
GENERAL STRUCTURE AND PROPERTIES OF
CHEMISTRY 2 WATER
INSTANT TASK
WATER Complete the diagram about the concept of water by writting the correct terms
SOLID from the box.
LIQUID
GAS I N T E R M O L E C U L A R R
1. A clear, odorless
SHAPE O N B P O M liquid B that H
has no R
taste. O Q I C U S
FREEZING POINT
BOILING POINT M O O E M Q O M U C Y Q K E D
O I I Y E H H H T O M U N R E
L S L U R3. TheEtemperature
2. The temperature
T T A M T I I U C
8. A hard substance 9. A free flowing
atAwhichN a liquidI E Sat which A a Vliquid J R that P has N three D Jsubstance.
S R
R E N T A T I I dimensions.
turns into a solid. boils.
E O G S N S E
E T G4. AnFobjectGform H S L S U H G I E A
O E Por figure. R B G C N M C 10. X A SsubstanceH R S
such as air that is
U C O G C M O A E D not O solidTor liquid.
D P L
5. A ___ has and keeps 6. A ___ borrows the
S shape.
its own A I S E shape Rof itsScontainer.
P T S F S S R I
R F N N W I I S F S E C R O F
C R T7. A ___Bhas noLfixedR T I Q B V C Q P U
shape.
N U X O D B Y S Z C Z X B A Y
I S N O I T A Z I R Note: O Answers
P A mayVbe D
repeated
10 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
DIRECT TALK
The high boiling point of water is a Water is the only substance that contracts
consequence of its strong intermolecular forces of when cooled. For most substances, their solid form is
attraction caused by the formation of the H-bond. It also, denser than their liquid form. This is because the H-
explains why water is liquid at room temperature. bond is more extensive in its solid state (ice) than in
its liquid state. Ice has an open structure because the
hydrogen bonds could not get inside the hexagonal
ring structure.
2. High specific heat
Specific heat refers to the amount of heat needed to 4. High surface tension
change the temperature of 1 gram of a substance by
1 0C. For water, its specific heat is 1cal/g 0C. It
means that water can absorb and release large The hydrogen bond formation among water
quantities of heat without change in temperature. molecules causes water to have high surface tension,
This is the reason why body temperature remains as described earlier. This high surface tension causes
370C even when there's a change in the surrounding. water to move from the roots of a tree to the top of
This also explains why oceans and lakes exert an very tall trees and explains why water moves into the
influence on the climate. If there were no longer fibers of a towel. This phenomenon is called
bodies of water that surround the earth, the earth capillarity.
would experience great temperature variations.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
11
FLASH CHECK
__________________________________________________________________________________
B. CH33OH and CH33CH22OH
__________________________________________________________________________________
____________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
C. HF and CH33F
__________________________________________________________________________________
__________________________________________________________________________________
____________________________________________________________________
____________________________________________________________________
__________________________________________________________________________________
__________________________________________________________________________________
D. BaCl22 and PCl33
__________________________________________________________________________________
_____________________________________________________________________
QUICK REFERENCES
CONNECT
• General Chemistry 2 pp. 12 - 14
• https://www.pinterest.com.au/pin/657244139356
993388/
12 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL TYPES AND PROPERTIES OF
CHEMISTRY 2
SOLIDS
INSTANT TASK
Metallic
Crystalline
Molecular
Hydrogen bond
Ionic
Polar
Amorphous
Non-polar
Covalent
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 13
DIRECT TALK
Crystalline Solids
Crystalline solids are those whose atoms, ions,
or molecules are ordered in well-defined arrangements.
They usually have flat surfaces or faces and sharp
angles. These solids have regular shapes. Ice, sugar,
salt, and gems are examples of crystalline solids.
Amorphous Solids
TAKE
NOTE
Crystalline solids have particles that are arranged in a definite geometric pattern.
Amorphous solids have particles that are not located in any particular position.
14 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
TYPES OF CRYSTALS
The physical properties of solids depend on the kind of particles that make up the solid. They are also
dependent on the strength of the attractive forces between the particles. Solids are classified based on the
kind or nature of the particles that make them up.
For the melting and boiling points, it is important to note that the energy required is that needed to break
the intermolecular forces of attraction and not the intramolecular.
A. IONIC SOLIDS
The particles of ionic solids are positive and negative ions. Since
oppositely charged particles are present, the forces between the ions are
electrostatic in nature. The crystal arrangement in ionic solids maximizes
attractions and simultaneously minimizes repulsion making the compound
possess a high degree of stability. These solids are hard, they are brittle, have
high melting points, and have poor electrical and thermal conductivity.
B. COVALENT SOLIDS
This type of solids are made up of atoms and are joined by covalent
bonds. Some solids form covalent bonds resulting in the formation of
molecules. In some solids, however, molecules are not formed. Rather, a
covalent network is formed extending throughout the solid crystal. They are
very hard, have very high melting points, and often have poor thermal and
electrical conductivity.
C. MOLECULAR SOLIDS
The particles in molecular solids can be either atoms or molecules held
together by intermolecular forces like dispersion forces, dipole-dipole forces,
and hydrogen bonds. Solids with dispersion forces that are also large are solids
at room temperature. This is true for solids that are highly polar. This type of
solids are soft, have low to moderately high melting points, and have poor
electrical and thermal conductivity. They are poor conductors of heat and
electricity because there are no free moving electrons and no charge particles.
D. METALLIC SOLIDS
These are joined by metallic bonds. Metallic bonds are characterized
by the presence of mobile electrons around the positive metal ion. The force
that binds the atoms together is the force attraction between the mobile
valence electrons and the fixed positive metal ion. The strength of the force
depends on the metal and, depending on the nature of the metal, they can be
soft to hard, and melting points range from low to high. These solids are good
electrical conductors (because of the mobile electrons), good thermal
conductors, and are malleable and ductile.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
15
4
FLASH CHECK
QUICK REFERENCES
CONNECT
• Breaking through chemistry pp. 330 - 332
• General Chemistry 2 pp. 14 - 17
• E School (apsacwestridge.edu.pk)
• Classification of solids (brainkart.com)
Quartz glass forms from silica • Crystalline Solids | Crystalline solid, Solid,
Intermolecular force (pinterest.ph)
(SiO2) heated above 1600 0C. It
then evolves to form amorphous
solids like window glass (with
CaCO3 and Na2CO3), colored glass
(with metal ions), and barosilicate
glass in pyrex (B2O3).
16 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL
CHEMISTRY 2
The Temperature Curve and
The Phase Changes of Water and CO2
INSTANT TASK
The diagram below shows the cooling curve for a gas. Draw the diagram and
write/draw the correct word/figure in each number.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 17
Heating and Cooling Curves Explained
What happens when you let a glass of ice sit out on the counter for several
minutes? It melts, of course! The increase in temperature causes the water to
change from solid to liquid.
What happens when you pour that cup of water into a pot
on the stove and let it cook for several minutes? It boils! Once
again, the increase in temperature causes the water to change
phases, this time from a liquid state to a gaseous state.
In the science world, we use heating and cooling curves to model such physical changes. A
heating or cooling curve is a simple line graph that shows the phase changes a given substance
undergoes with increasing or decreasing temperature.
T
E
M
P
E
R
A
T
U
R
E
HEAT ADDED
Fig. 1.1 Heating and Cooling Curve of Water. Temperature is
measured on the vertical y-axis and the amount of heat added over
time is measured on the horizontal x-axis. Changes of state occur
during plateaus because the temperature is constant.
The change of state behavior of all substances can be represented with a heating and cooling
curve of this type. The melting, boiling, freezing, and condensing points of the substance can be
determined by the horizontal lines or plateaus on the curve.
Phase changes happen when you reach certain special points. Sometimes a liquid wants to
become a solid. Scientists use something called a freezing point or melting point to measure the
temperature at which a liquid turn into a solid.
Melting - or Fusion, is a physical process that results in
the phase transition of a substance from a solid to a
liquid. This occurs when the internal energy of the solid
increases,
18 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Boiling - is the process by which a liquid turn into a vapor when it is heated to its boiling point.
Condensation - is the process of a substance that is in its gaseous state converting into a
liquid state. This change is brought about by a change in pressure and temperature of the
substance.
Sublimation - refers to the phase transition in which matter changes state from a solid
immediately into a gas, without passing through an intermediate liquid phase.
Deposition - refers to the phase transition in which matter changes state from a gas
immediately into a solid, without passing through an intermediate liquid phase.
Using the phase diagram for water given in the graph, determine the state of water at the
following temperatures and pressures:
(a) 50 °C and 40 kPa (b) 80 °C and 5 kPa (c) −10 °C and 0.3 kPa
Solution: Using the phase diagram for water, we can determine that the state of water at
each temperature and pressure given are as follows: (a) liquid; (b) gas; (c) solid.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
19
You already know about solids melting and becoming liquids. Some of you may have also seen
a solid become a gas. It's a process called sublimation. The easiest example of sublimation
might be dry ice. Dry ice is solid carbon dioxide (CO2). Amazingly, when you leave dry ice
out in a room, it just turns into a gas. Have you ever heard of liquid carbon dioxide? It can be
made, but not in normal situations. Coal is another example of a compound that will not melt
at normal atmospheric pressures. It will sublimate at very high temperatures.
Can you go from a gas to a solid? Sure. Deposition occurs when a gas becomes a solid
without going through the liquid state of matter. Those of you who live near the equator may
not have seen it, but closer to the poles we see frost on winter mornings. Those little frost
crystals on plants build up when water vapor from the air becomes a solid on the leaves of
plants.
Consider the phase diagram for carbon dioxide shown in the figure as another example. The
solid-liquid curve exhibits a positive slope, indicating that the melting point for CO2 increases with
pressure as it does for most substances (water being a notable exception as described previously).
Notice that the triple point is well above 1 atm (101.325 kPa), indicating that carbon dioxide cannot
exist as a liquid under ambient pressure conditions. Instead, cooling gaseous carbon dioxide at 1
atm results in its deposition into the solid state. Likewise, solid carbon dioxide does not melt at 1
atm pressure but instead sublimes to yield gaseous CO2. Finally, notice that the critical point for
carbon dioxide is observed at a relatively modest temperature and pressure in comparison to water.
20
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Instructions: Answer the following questions. Write your answer in a separate sheet of
paper.
Using the phase diagram for water, determine the state of water at the following
temperatures and pressures:
(a) −10 °C and 50 kPa (b) 25 °C and 90 kPa (c) 50 °C and 0.3 kPa
Using the phase diagram for carbon dioxide, determine the state of water at the following
temperatures and pressures:
(d) 20 °C and 1500 kPa (e) 0 °C and 100 kPa (f) 20 °C and 2 atm
Answer to The steamboats got their power from steam – liquid water converted to a gas at
START-UP high temperatures. The steam would push the pistons of the engine, causing the
paddle wheels to turn and propel the boat.
References:
QUICK
CONNECT • http://www.chem4kids.com/
• https://study.com/academy/le
sson
Gases under Pressure • https://www.ck12.org/
If you have a propane (C3H8) • https://opentextbc.ca/
barbecue, you have probably seen •
those cylinders filled with fuel. In
the cylinder, the propane
molecules are in a liquid state at a
high pressure. When the
molecules are released from the
cylinder, they immediately become
a gas and you can cook your food.
Pressure differences make the
phase change.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
21
GENERAL
CHEMISTRY 2
Concentration of Solutions
INSTANT TASK
Solve the following problems. Write your solutions in a separate sheet of paper.
1.) There are 200 apples. 30 apples are considered bad and will be not for sale. How
many percent of apples are bad?
3.) A skateboard is on sale that has a 25% discount of its price. The skateboard’s
original price is Php 750.00. Find the new price.
22 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
The key difference
between solvent and
solute is that the solute is Concentration is the measure of how much of a given
the one to be dissolved substance is mixed with another substance. Solutions are said to
while, the solvent is be either dilute or concentrated. When we say that vinegar is 5%
responsible for dissolving acetic acid in water, we are giving the concentration. If we said
it. the mixture was 10% acetic acid, this would be more
concentrated than the vinegar solution.
A concentrated solution is one in which there is a large
amount of solute in a given amount of solvent. A dilute solution
is one in which there is a small amount of solute in a given
amount of solvent. A dilute solution is a concentrated solution
that has been, in essence, watered down. Think of the frozen
juice containers you buy in the grocery store. To make juice, you
have to mix the frozen juice concentrate from inside these
Fig. 1: The solution on the left is more containers with three or four times the container size full of
concentrated than the solution on the water. Therefore, you are diluting the concentrated juice. In
right because there is a greater ratio of terms of solute and solvent, the concentrated solution has a lot of
solute (red balls) to solvent (blue balls) solute versus the dilute solution that would have a smaller
particles. The solution particles are closer
amount of solute. Therefore: Concentration of a solution is the
together. The solution on the right is more
dilute (less concentrated). mass or volume of the solute present in a given amount of
solvent or solution.
Example: What is the molar concentration of a solution of 22.4 g of HCl dissolved in 1.56 L?
STEP 2 Convert the mass of solute to moles using STEP 3 Now, we can use the definition of
the molar mass of HCl. molarity to determine a concentration.
*Remember! If the quantity of the solute is given in mass units, you must convert mass units to
mole units before using the definition of molarity to calculate concentration.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
23
There are several ways of expressing the concentration of a solution using a percentage. The
mass/mass percent (% m/m) is defined as the mass of a solute divided by the mass of a solution times 100:
*Remember! If you can measure the masses of the
mass of solute solute and the solution, determining the mass/mass
% m/m = X 100% percent is easy. Each mass must be expressed in the
mass of solution
same units to determine the proper concentration.
STEP 1 Find the mass of the solution. mass of solution = 25.0 g sugar + 100.0 g water = 125.0 g
25.0 g sugar
STEP 2 Calculate the percent by mass. Percent by Mass = X 100% = 20% sugar
125.0 g solution
The percent solutions can be in the form volume/volume percentage. In each case, the concentration
in percentage is calculated as the fraction of the volume of the solute related to the total volume of the
solution.
volume of solute
Volume Percent = x 100%
volume of solution
25 mL
Volume Percent = x 100%
200 mL
= 12.5%
24 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Number of moles of solute
m=
Mass of solvent in kilograms
Example: Calculate the molality of a solution where 5.0 grams of toluene (C7H8) is
dissolved in 225 grams of Benzene (C6H6). Calculate the moles of given solute.
STEP 1 Find the molar mass of Toluene. C7H8 = (7 x 12 g/mol) + (8 x 1.008 g/mol) = 92 g/mol
Mole fraction is a unit of concentration, defined to be equal to the number of moles of a component
divided by the total number of moles of a solution. Because it is a ratio, mole fraction is a unitless
expression. The mole fraction of all components of a solution, when added together, will equal 1.
Example: In a solution of 1 mol benzene, 2 mol carbon tetrachloride, and 7 mol acetone,
the mole fraction of the acetone is ______.
Total number of Moles in Solution = 1 mole (benzene) + 2 moles (carbon tetrachloride) + 7 moles (acetone)
Total number of Moles in Solution = 10 moles
Similarly, the mole fraction of benzene would be 1/10 or 0.1 and the mole fraction of carbon
tetrachloride would be 2/10 or 0.2.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 25
Instructions: Perform the different ways of calculating the concentrations of solutions.
Write your answer in a separate sheet of paper.
Answer to By looking at percentages, it is easier to tell if one recipe is drier, sweeter, saltier,
etc. than another recipe. It also makes predicting what the final product will look
START-UP like easier. Baker’s % can be used to quickly and easily convert between batch
sizes as well.
QUICK
References:
CONNECT
• https://chem.libretexts.org/
Anyone who has made instant coffee
• https://byjus.com/
or lemonade knows that too much • https://www.thoughtco.com/
powder gives a strongly flavored, • https://byjus.com/
highly concentrated drink, whereas
too little results in a dilute solution
that may be hard to distinguish from
water. In chemistry, the
concentration of a solution is the
quantity of a solute that is contained
in a particular quantity of solvent or
solution. Knowing the concentration
of solutes is important in controlling
the stoichiometry of reactants for
solution reactions.
26 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL
CHEMISTRY 2
Stoichiometric Calculations for
Reactions in Solutions
INSTANT TASK
200 grams of flour + 2 eggs + 200 grams of butter + 1 cup of sugar = 10 cookies
But it turns out that the ingredients are incomplete because you only have one (1)
egg. A new equation is made, where everything is cut in half to achieve a result:
1. Fill in the blanks the right amount of ingredients and the cookies to be made
with just one egg.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 27
Introduction to Stoichiometry
The coefficients in the equation tell us that 1 mole of Fe2O3 reacts with 2 moles of Al, forming 2
moles of Fe and 1 mole of Al2O3. We can write the relationship between the Fe2O3 and the Al as the
following mole ratio:
Using this ratio, we could calculate how many moles of Al are needed to fully react with a
certain amount of Fe2O3, or vice versa. To illustrate, let's walk through an example where we use a
mole ratio to convert between amounts of reactants.
3
reactant side product side
Question: How many grams of NaOH are required to fully consume 3.10 grams of H 2SO4?
start text, F, e, end text, start subscript, 2, end subscript, start text, O, end text, start
subscript, 3,First
endthings first:orwe
subscript, need
vice to balance the equation! In this case, we have 1 Na atom and
versa.
3 H atoms on the reactant side, and 2 Na atoms and 2 H atoms on the product side. We can
balance the equation by placing a 2 in front of NaOH (so there are 2 Na atoms on each side)
and another 2 in front of H2O (so that there are 6 O atoms and 4 H atoms on each side.) Doing
so gives the following balanced equation:
Now that we have the balanced equation, let's get to problem solving. To review, we
want to find the mass of NaOH that is needed to completely react 3.10 grams of H2SO4. We
can tackle this stoichiometry problem using the following steps: (See next page)
28 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Step 1: Convert known reactant mass to moles
In order to relate the amounts H2SO4 and NaOH using a mole ratio, we first need
to know the quantity of H2SO4 in moles. We can convert the 3.10 grams of H2SO4 to
moles using the molar mass of H2SO4.
H2SO4= 2 H atoms + 1 S atom + 4 O atoms
Atomic Mass of H = 2 x 1.008 g/mol = 2.016 g/mol
Atomic Mass of S = 1 x 32 g/mol = 32 g/mol
Atomic Mass of O = 4 x 16 g/mol = 64 g/mol (add)
Molar Mass of H2SO4 = 98.02 g/mol
Proceed to conversion of 3.10 grams of H2SO4 to moles:
Now that we have the quantity of H2SO4 in moles, let's convert from moles of
H2SO4 to moles of NaOH using the appropriate mole ratio. According to coefficients in
the balanced chemical equation, 2 moles of NaOH are required for every 1 mole of
H2SO4, so the mole ratio is:
Multiplying the number of moles of H2SO4 by this factor gives us the number of
moles of NaOH needed:
Notice how we wrote the mole ratio so that the moles of H2SO4 cancel out,
resulting in moles of NaOH as the final units.
We were asked for the mass of NaOH in grams, so our last step is to convert the
6.32 x 10-2 moles of NaOH to grams. We can do so using the molar mass of NaOH:
Molar Mass of NaOH = (1 x 23 g/mol) + (1 x 16 g/mol) + (1 x 1.008 g/mol) = 40 g/ mol
So, 2.53 grams of NaOH are required to fully consume 3.10 grams of
H2SO4 in this reaction.
Shortcut! We could have combined all three steps into a single calculation, as shown in the
following expression:
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
29
Instructions: Solve the problem stated below. Write your solution in a separate sheet
of paper.
Answer to With stoichiometry, you can know how much nitrogen gas must be produced in a
START-UP matter of seconds for the bag to inflate by impact and can save the life of the
driver or passengers.
References:
QUICK
CONNECT 1. http://www.chem4kids.com/
2. https://study.com/academy/le
sson
Stoichiometry is at the heart of the 3. https://www.ck12.org/
production of many things you use 4. https://opentextbc.ca/
in your daily life. Soap, tires,
fertilizer, gasoline, deodorant, and
chocolate bars are just a few
commodities you use that are
chemically engineered, or
produced through chemical
reactions. Chemically engineered
commodities all rely on
stoichiometry for their production.
30 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL BOILING POINT ELEVATION AND
CHEMISTRY 2 FREEZING POINT DEPRESSION
INSTANT TASK
Unscramble the letters to form the term that describes the given phrase. Write the
letters on the blanks provided.
1. L O N G B I I T I P N O
__ __ __ __ __ __ __ __ __ __ __ __
2. R I N G Z E E F O T N I P
__ __ __ __ __ __ __ __ __ __ __ __ __
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
31
DIRECT TALK
Where K is the molal boiling point elevation constant of the solvent and m is the molal concentration
of the solution.
The K of water is 0.52 0C/m, so 1 m aqueous Molal Boiling Point Constant
solution of a nonvolatile solute like sucrose will boil at
0.52 0C higher than pure water. The boiling point
elevation is proportional to the number of solute particles
in the solution. When 1 mole of NaCl dissolves in water,
2 moles of solute are formed 1 mole of Na and 1 mole
Cl. Therefore, a 1 m solution of NaCl in water causes a
boiling point elevation twice as large as a 1 m solution of
sucrose.
Calculate the boiling point of a solution containing 3.5 g sugar (molar mass = 342 g)
Example dissolved in 150 g of water. The mass of solute (3.5 g) is given which is dissolved in
150 g of solvent, water.
STEP 1: Solve for the molality of the solution, the unit of which is STEP 2: Solve for boiling point elevation
mole solute/kilogram solvent. Using the dimensional analysis, the first
𝚫𝐓𝐛 = 𝐊𝐛 𝐱 𝐦
factor converts mass to mole, then divide with the mass of solvent, and
the last factor converts the mass in grams to kilogram. 0.513 °C
x 0.068 m = 𝟎. 𝟎𝟑𝟓 °𝑪
1m
mole solute
𝐌𝐨𝐥𝐚𝐥𝐢𝐭𝐲 (𝑚) =
kg solvent
1 mole 1 1 000 g
STEP 3: Solve for boiling point of the solution
𝐌𝐨𝐥𝐚𝐥𝐢𝐭𝐲 (𝑚) = 3.5 g sugar x x x
342 g 150 g water 1 kg Boiling point of solution = boiling point of solvent +
ΔTb
3500 mole
𝐌𝐨𝐥𝐚𝐥𝐢𝐭𝐲 (𝑚) = = 𝟎. 𝟎𝟔𝟖 𝐦𝐨𝐥𝐞/𝐤𝐠
51300 kg 62.8 0C = 61.2 0C + ΔTb
32 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
FREEZING POINT DEPRESSION
The freezing point of a substance is the temperature at which the solid and liquid phases coexist and their
vapor pressures are the same. If a nonvolatile solute is added to a solvent, the freezing point of the solvent is lowered
and the reduction in the freezing point depends on the number of moles of solute present. Again, the effect of
electrolytes as solutes is greater than nonelectrolytes because electrolytes ionize in solution and as such contain a
greater number of particles. The greater the number of solute particles, the greater the effect on the reduction of the
freezing point.
If one mole of nonelectrolyte solute is dissolved in one kilogram of water, the freezing point of water is
reduced by 1.86 °C. If two moles of nonelectrolyte solute dissolved in one kg of water, then the freezing point is
reduced by 3.72 °C. In other words, the freezing point depression constant for water (Kf) is 1.86 °C/1 molal solution
and Kf varies depending on the solvent. The identity of the solute does not have any effect on the freezing point just
like in the vapour pressure and boiling point. The freezing point depression then is equal to
What is the freezing point depression when 155 g of Iodine (I2) crystals is added to 1200 g of
Example benzene? Kf benzene = 5.12 0C/m FP benzene = 5.51 0C
STEP 1: Solve for the molality of benzene STEP 2: Solve for freezing point
depression
1 mole I2 1 1000 g benzene
155 g I2 x x x
254 g 1200 g benzene 1 kg benzene 𝚫𝐓𝐟 = 𝐊𝐟 𝐱 𝐦
𝟎. 𝟓𝟎𝟗 𝐦𝐨𝐥𝐞
= 5.12 °C
𝐤𝐠 = x 0.509 m = 𝟎𝟐. 𝟔𝟏 °𝐂
1m
SCIENCE
OVERLOAD
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
33
4
FLASH CHECK
PROBLEM
PROBLEMSOLVING
SOLVING
1. What is the molality of a solution dissolved in chloroform that boils at 62.8 0C? Boiling
point of chloroform is 61.2
62.2 0C? Kb chloroform 3.63 0c/m
2. A solution prepared from 0.3 g of an unknown nonvolatile solute and 30 g CCl 4 has a
boiling point of 0.392 0C higher than that pure CCl4. What is the molecular weight of the
solute?
QUICK REFERENCES
CONNECT
• Breaking through chemistry p. 336 - 370
• General Chemistry 2 pp. 50 - 52
The greatest application of boiling point
elevation is in the preparation of candies. Sugar
and flavours are added to water and boil for a
long time to make the solution concentrated. As
the solution becomes more concentrated, the
vapor pressure is reduced and the boiling point is
increased. A candy thermometer determines if the
candy is ready for the next procedure. Syrup is
prepared in the same manner. A dilute sugar
solution is boiled for a long time to make it very
concentrated. The temperature is monitored to
determine when the desired concentration of the
syrup has been attained.
34 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL THERMODYNAMICS vs.
CHEMISTRY 2
THERMOCHEMISTRY
INSTANT TASK
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 35
DIRECT TALK
TAKE
Enthalpy of Chemical Reactions NOTE
The term enthalpy, from the Greek word, enthalpein, meaning "to
THERMOCHEMISTRY
warm" refers to the energy transferred under constant pressure. It is represented
by the symbol, H. It is often referred to, as heat content. Like E (internal energy), Is the study of this heat
enthalpy, H, is also a state function, and therefore, not path dependent. Enthalpy exchange and work on
cannot be measured, but, it is possible to measure the change in enthalpy or heat chemical reactions. The law of
content, ΔH. conservation of energy states
that the total energy of universe
Internal energy (E) is the sum of the kinetic and potential energy found in
is constant.
the system. It is the total energy found on the system being studied. However, this
is not quantifiable. But internal energy also changes as the system changes. Energy univ = constant
Hess's Law
According to Germain Hess, a Russian chemist, the enthalpy change is the
same whether a reaction takes place in one step or a series of steps. For a chemical
For any chemical reaction at reaction that takes place using different pathways, overall enthalpy change is the
standard conditions, the same regardless of the route, so long as initial and final conditions are the same.
standard enthalpy change is Hess's Law states that the enthalpy change of an overall reaction is the sum of the
the sum of the standard enthalpy change of its individual steps. Since enthalpy is a state function where the
molar enthalpies of formation final and initial states are the only important states, the individual equations and their
of the products (each known enthalpy can be manipulated to determine the enthalpy of the reaction.
multiplied by its coefficient in
the balanced chemical A thermochemical equation can be expressed as the sum of two or more
equation) minus the equations, overall equation = equation 1 + equation 2 + ………..and, ΔH0 for the
corresponding sum for the overall equation is the sum of the ΔH0 for the individual equations:
reactants.
ΔH0 = ΔH1 + ΔH2 + …..
36 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Example:
1.) S (s) + O2 (g) → SO2 (g) ΔH0 = -296.8 kJ
STEP 1
Identify the net equation whose ΔH0 is unknown. Make sure that the reaction is balanced.
STEP 2
Manipulate equations where ΔH0 is known so that the correct moles of reactants and products are
on correct sides. Remember that reversing the direction of the reaction will give a ΔH0 of the same
magnitude but with different sign. Multiplying or dividing the reaction by a factor should be done to both the
ΔH0 value and the reaction.
STEP 3
Add these individual reactions to get the net reaction. The value of the unknown ΔH0 is the sum of
the individual manipulated ΔH0.
STRATEGY
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
37
4
FLASH CHECK
PROBLEM SOLVING
1.) Calculate the standard enthalpy of formation, ΔH0 for methane gas, CH4, produced from graphite
and hydrogen gas according to the following reaction:
Analysis: Since this reaction that forms methane gas does not take place as written, ΔH0 of methane
is determined indirectly by using the following set of reaction whose ΔH0 values have been accurately
determined and applying Hess's Law.
A. Write equation (1) as is.
2.) H2 (g) + 1/2O2 (g) → H2O (l) ΔH0 = -285.8 kJ C. Rewrite reaction (3) in the reverse
direction and change the sign of ΔH0
3.) CH4 (g) + 2O2 (g) → CO2 (g) + 2HO2 (l) ΔH0 = -890.4 kJ from - to +.
QUICK REFERENCES
CONNECT • Breaking through chemistry pp. 410 - 420
• World of chemistry pp. 72 - 83
• Applications - Thermodynamics- Enthalpy/Hess's
Law (google.com)
Hess's Law can be applied to sever
• Coffee Cup Vector PNG & Download
every day factors, such as the engine in
Transparent Coffee Cup Vector PNG Images for
your car which turns the heat Free - NicePNG
of combustion of the fuel, through several
steps, into the energy which is translated to
the movement of the car. This can be
applied industrially as the engineers
creating the cars can use it to determine if
new fuels would heat the engine more or
less and how they would affect the ability of
movement and speed of the car.
38 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL
CHEMISTRY 2
Colligative Properties of Solutions
INSTANT TASK
Study the disorganized letters. Try to organize or rearrange the letters to form
the exact word based on the supported description.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
39
A colligative property is a property of a solution that is dependent on the ratio between the
total number of solute particles (in the solution) to the total number of solvent particles. Colligative
properties are not dependent on the chemical nature of the solution’s components. We can observe
the colligative properties of solutions by going through the following examples. If we add a pinch of
salt to a glass full of water, its freezing temperature is lowered considerably than the normal
temperature. Similarly, if we add alcohol to water, the solution’s freezing point goes down below the
normal temperature that is observed for either pure water or alcohol.
In the picture on the left (pure solvent), the surface is entirely occupied by liquid molecules,
some of which will evaporate and form a vapor pressure. On the right (solution), a nonvolatile solute
has been dissolved into the solvent. Nonvolatile means that the solute itself has little tendency to
evaporate. Because some of the surface is now occupied by solute particles, there is less room for
solvent molecules. This results in less solvent being able to evaporate. The vapor pressure of a
solvent is lowered by the addition of a non-volatile solute to form a solution. By definition, a
non-volatile substance does not evaporate.
40 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
take up spaces at the surface of the liquid. As we know, to vaporize, solvent
molecules must be present at the surface of the solution. Adding about 68.5 grams of salt to
1 liter of water lowers its freezing point by 1.86 degrees Celsius (3.4 degrees Fahrenheit).
When salt is added to an icy road, it dissolves into water above the ice and keeps it from
freezing even though the temperature of the road is lower than 0 degrees Celsius -- the
freezing point of water.
Electrolytes are chemical compounds that can break down into ions when dissolved in
water. These ions can conduct electricity through this aqueous solution. There are two types of
electrolytes: strong electrolytes and weak electrolytes. Strong electrolytes readily produce ions when
they are soluble. For example, strontium hydroxide, Sr(OH)2 is partially dissolved in water. But it is a
strong electrolyte since the amount that is dissolved is completely ionized. Moreover, salts such as
NaCl, MgCl2 are also strong electrolytes since they are ionic compounds with a high degree of ionic
characteristics. Nonelectrolytes are chemical compounds whose aqueous solutions cannot conduct
electricity through the solution. These compounds do not exist in ionic form. Most nonelectrolytes are
covalent compounds. When dissolved in water, these compounds do not form ions at all. Sugars,
fat, and alcohols are examples of nonelectrolytes.
Different Types of Colligative Properties of Solution
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
41
1. Identify whether the following statements are TRUE or FALSE.
_________________ 1. Salt water solution will boil faster than just water alone.
_________________ 2. The higher the temperature, the higher the vapor pressure.
_________________ 3. A glass of water will evaporate faster than a glass of soda.
_________________ 4. A dissolved sugar in H2O can conduct electricity but will
evaporate slowly.
_________________ 5. The effect of electrolytes on colligative properties is very low
compared to nonelectrolytes.
2. Observe from your surroundings. Pick one from the different types of colligative
properties and cite one example that best exhibits it. Explain.
Example: When we soak resins in water they swell up. This happens due to
osmotic pressure. Water travels from high concentration to low concentration and
keeps moving by osmosis until the equilibrium is reached, that is when the
concentration of both solutions is the same.
Answer to We tend to drink lots of water after consuming salty foods because salt is a solute and
after consuming lots of salt, our cells become concentrated with salt, which triggers the
START-UP process of thirst. So, our cells absorb water and we feel thirsty, and hence, we start
drinking water.
References:
QUICK
CONNECT 1. http://www.chem4kids.com/
2. https://study.com/academy/le
Salt water helps you get sson
relieved from sore throat 3. https://www.ck12.org/
In case you have a sore throat, 4. https://opentextbc.ca/
cells and tissues surrounding the
throat are swollen because of the
excess of water. The salt water
which we use for gargles has a
lower concentration of water than
the cells of the throat. So, water
molecules move from the swollen
cells of the throat to the salt
water; reducing pain and swelling.
42 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL
CHEMISTRY 2
Rates of Reaction
INSTANT TASK
LET’S DO THE NAKED EGG EXPERIMENT! Prepare these materials for this fun and
interesting activity. You will need:
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
43
The rate of reaction or reaction rate is the
speed at which reactants are converted into
products. When we talk about chemical reactions, it is
a given fact that rate at which they occur varies by a
great deal. Some chemical reactions are nearly
instantaneous, while others usually take some time to
reach the final equilibrium.
Example:
Wood combustion has a high reaction rate since the process is fast and rusting of iron has a
low reaction rate as the process is slow.
Nature of the Reactants. The rate of reaction highly depends on the type and nature of the
reaction. As mentioned earlier, few reactions are naturally faster than others while some reactions
are very slow. The physical state of reactants, number of reactants, complexity of reaction and other
factors highly influence the reaction rate as well. The rate of reaction is generally slower in liquids
when compared to gases and slower in solids when compared to liquids. Size of the reactant also
matters a lot. The smaller the size of reactant, the faster the reaction.
The Temperature. According to collision theory, a chemical reaction that takes place at a higher
temperature generates more energy than a reaction at a lower temperature. This is because colliding
particles will have the required activation energy at high temperature and more successful collisions
will take place.
Physical State of Reactants. Gases and liquids tend to react faster than solids because of the
increase in surface area of the gases and liquids versus the solid. If the size of a particle is small, the
surface area will be more and this increases the speed of heterogeneous chemical reactions.
Catalysts. A catalyst can be defined as a substance that increases or decreases the rate of the
reaction without actually participating in the reaction. The definition itself describes its effect on
chemical reactions. With a helping hand from a catalyst, molecules that might take years to interact
can now do so in seconds. All reactants need to overcome certain energy, better known as activation
energy in order to form products.
44 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
and how it affects the
chemical reaction
Types of Catalysts
Activation Energy
Activation energy and catalyst are closely related because the function of the catalyst is to lower down
the activation energy so that more particle has enough energy to react. Activation energy is defined as the
minimum amount of extra energy required by a reacting molecule to get converted into product. It can also be
described as the minimum amount of energy needed to activate or energize molecules or atoms so that they
can undergo a chemical reaction or transformation.
Examples of Chemical reactions that require Activation energy:
✓ The combustion reaction requires activation energy. Carbon and oxygen combine to form carbon
dioxide and transformed the energy.
✓ Lighting a match which creates friction and turns to heat. The heat thus liberated then produce enough
activation energy that allows the chemical on the match to react and ignite the flame.
45
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Answer the following questions below. Write your answer in a separate sheet of paper.
1. Enumerate the five factors that affects the rate of chemical reaction.
2.
1. a.
b.
c.
d.
e.
2. Why does a chemical reaction that takes place at a higher temperature
generates more energy?
Answer to The rusting process of an iron is pretty much fast, not to mention if it’s in rough
START-UP climate, but we don’t want the process to occur, or at least we want to delay the
process, so we paint it, or cover it with a substance that slows down the process.
References:
QUICK
CONNECT 1. http://www.chem4kids.com
/
2. https://study.com/academy
/lesson
3. https://www.ck12.org/
In wildlife, a wood could
decompose in over 300 years if it 4. https://opentextbc.ca/
exposed to open air, but we want
the process faster to get heat out
of it, so we light the wood by
adding extra energy to fasten the
process.
46 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
GENERAL
CHEMISTRY 2
Molecular Collisions
and the Orders of Reaction
INSTANT TASK
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
____________________________________________________
________
____________________________________________________________________
____________________________________________________________________
____________________________________________________________________
____________________________________________________________________
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
47
What is Collision Theory?
The more molecules are present, the more collisions will happen.
The molecules must collide with energies greater than or equal to the activation energy of the reaction. If
this does not happen the reaction will not take place. The molecules need the energy to break their existing bonds
and form new bonds. This is the kinetic energy that the molecules possess. If this energy is not equal to or
greater than the activation energy, the reaction will not proceed.
As the temperature rises, molecules move faster and collide more vigorously,
greatly increasing the likelihood of bond cleavages and rearrangements.
Most reactions involving neutral molecules cannot take place at all until they have
acquired the activation energy needed to stretch, bend, or otherwise distort one or
more bonds.
48 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Orders of Reaction Explained
The order of the reaction is a relationship between the rate of a chemical reaction and the
concentration of the species.
But remember! Orders of reaction are always found by doing experiments. You can't deduce
anything about the order of a reaction just by looking at the equation for the reaction. This topic
will introduce you the basic concept of the orders of the reaction. First, let us discuss the
relationship of the reaction orders to the Rate Law.
The term k is the rate constant, which is specific for a given reaction at a given
temperature.
The exponents m and n are reaction orders and are determined by experiment. The value
of m and n are not necessarily related in any way to the coefficients a and b.
A reaction has an individual order ““with respect to” or “in” each reactant.
✓ If the rate doubles when [A] doubles, the rate depends on [A]1 and the reaction is
first order with respect to A.
✓ If the rate quadruples when [A] doubles, the rate depends on [A]2 and the reaction
is second order with respect to A.
✓ If the rate does not change when [A] doubles, the rate does not depend on [A], and
the reaction order is zero order with respect to [A].
Answer: The reaction order is second order with respect to NO, first order with respect to H2
and third order overall (addition of all exponents).
Note that the reaction order is first order with respect to H2 even though the coefficient for H2 in
the balanced equation is 2. This is because as stated from above, that the value of m and n are not
necessarily related in any way to the coefficients a and b.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 49
Answer the following questions. Write your answer in a separate sheet of paper.
a.)
b.)
Answer to Molecules with greater kinetic energy diffuse faster; in other words, the rate of
START-UP diffusion increases as kinetic energy increases. For example, the food coloring
will spread out faster in the warmer water because of greater kinetic energy.
QUICK References:
CONNECT
1. http://www.chem4kids.com/
2. https://study.com/academy/le
The game of pool provides an sson
example of a collision in which one 3. https://www.ck12.org/
object, the cue ball, is moving, 4. https://opentextbc.ca/
while the other—known as the
object ball—is stationary. Due to
the hardness of pool balls, and
their tendency not to stick to one
another, this is also an example of
an almost perfectly elastic
collision—one in which kinetic
energy is conserved.
Read more:
http://www.scienceclarified.com/e
veryday/Real-Life-Chemistry-Vol-3-
50 Physics-Vol-1/Momentum-Real-life-
applications.html#ixzz6ng39JSBT
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
The Temperature Curve and START - UP
The Phase Changes of Water and
CO2 - THEIR SIMILARITIES ARE NOT BASED
ON THE COMPOSITION OR STRUCTURE
INSTANT TASK
OF THE CONTAINER. THEIR
1. Gas SIMILARITIES ARE BASED ON THEIR
2. C
SURROUNDINGS IN THE FORM OF
3. Liquid
4. B HEAT AND ON THEIR ABILITY TO DO
5. Solid
WORK ON THE SURROUNDINGS.
6. A
7. Gas - Liquid
8. Liquid – Solid
INSTANT TASK
FLASH CHECK
1. CRYSTALLINE
a. Solid 2. AMORPHOUS
b. Liquid 3. MOLECULAR
c. Gas 4. IONIC
d. Liquid 5. METALLIC
e. Gas 6. COVALENT
f. Gas 7. POLAR
8. NON-POLAR
9. HYDROGEN BONDED
FLASH CHECK
- ANSWERS MAY VARY
SCIENCE POCKET LESSON 5 SCIENCE POCKET LESSON 4
START - UP START-UP START-UP
- SURFACE TENSION - ANSWERS MAY VARY
- ICE IS ACTUALLY ABOUT 9% LESS DENSE
THAN WATER. SINCE THE WATER IS INSTANT TASK
INSTANT TASK *SOLID
HEAVIER, IT DISPLACES THE LIGHTER ICE,
1. ICE
CAUSING THE ICE TO FLOAT TO THE TOP. 1. INTERMOLECULAR 2. BOOK
2. SURFACE TENSION 3. WOOD
INSTANT TASK 4. BLOCK
3. BOILING POINT 5.
1. WATER 4. VISCOSITY *LIQUID
5. LIQUIDS 1. MILK
2. FREEZING POINT 2. WATER
3. BOILING POINT 6. VAPORIZATION 3. JUICE
4. SHAPE 7. MOLAR 4. COFFEE
5. SOLID 8. FORCES 5. PAINT
9. HEAT *GAS
6. LIQUID 1. BALLOON
7. GAS 10. VAPOR 2. CLOUD
8. SOLID 3. TORNADO
FLASH CHECK 4. AIR
9. LIQUID 5. BOILING
10. GAS 1.
2. ANSWERS MAY VARY FLASH CHECK
FLASH CHECK 3. 1. LONDON DISPERSION FORCES (Ar)
2. DIPOLE-DIPOLE, H-BOND (CH3CH2OH)
- ANSWERS MAY VARY 3. DIPOLE-DIPOLE, H-BOND (HF)
4. DIPOLE-DIPOLE (BaCl2)
SCIENCE POCKET LESSON 3 SCIENCE POCKET LESSON 2 SCIENCE POCKET LESSON 1
ANSWER KEY
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Colligative Properties of Solutions START-UP START-UP
INSTANT TASK - ANSWERS MAY VARY - ANSWERS MAY VARY
1. Colligative Property INSTANT TASK INSTANT TASK
2. Sugar
3. Sodium Chloride -THERMOCHEMISTRY 1. BOILING POINT
4. Universal Solvent 2. FREEZING POINT
FLASH CHECK
FLASH CHECK FLASH CHECK
- C (graphite) + 2H2 (g) → CH4 (g)
A. ΔH0 = -74.7 kJ 1. 0.441 m
1. TRUE 2. 128 g/mol
2. TRUE
3. TRUE
4. FALSE
5. FALSE
B. (Answers may vary.)
SCIENCE POCKET LESSON 10 SCIENCE POCKET LESSON 9 SCIENCE POCKET LESSON 8
Stoichiometric Calculations for Concentrations of Solutions
Reactions in Solutions
INSTANT TASK
INSTANT TASK 1. 15% apples are bad.
2. 25%
1. 5 grams of flour, 100 3. Php 562.50
grams of butter, ½ cup of
FLASH CHECK
sugar, 5 cookies
2. 2NaN3 → 2Na + 3N2 a. (2 x 12) + (5 x 1.008) + (1 x 14) + (2 x 16) = 75.04 g/mol →
molar mass
FLASH CHECK [0.000889 g C2H5NO2 x (1 mol C2H5NO2 / 75.04 g C2H5NO2) =
1.18 x 10-5 mol HCl
1. a. 200g C3H8 = 4.54 mol Convert 1.05mL to L = 0.00105 L
C3H8 M = 1.18 x 10-5 mol HCl / 0.00105 L = 0.0112 M C2H5NO2
b. (ratio of H2O to C3H8= b. (36.5 g / 355 g)(100%) = 10.3%
4:1); for every 4.54 mol c. (0.6 g Pb / 277 g solution)(1000000) = 2166 ppm
C3H8 there are 18.18 mol d. (90mL / 3000mL)(100%) = 3%
e. 25 g KBr x (1 mol KBr / 120 g KBr) x (1 / 0.75 L) = 0.278 M
H2O
f. (25 g / 46.07 g/mol) = 0.543 moles ethanol
c. 18.18 mol H2O is equal (25 g / 18 g/mol) = 1.389 moles water
to 327.27 g H2O. Total number of moles in the solution = 0.543 + 1.389 = 1.932
moles
Mole fraction of ethanol = (0.543 / 1.932) = 0.281
Mole fraction of water = (1.389 / 1.932) = 0.718
SCIENCE POCKET LESSON 7 SCIENCE POCKET LESSON 6
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Molecular Collisions and the Orders of Reactio Rates of Reaction
INSTANT TASK INSTANT TASK
1. (Answers may vary.) (Answers may vary.)
FLASH CHECK
FLASH CHECK
1. Five factors:
1. (Answers may vary.) a. Nature of the
2. (Answers may vary.) Reactants
3. a. The exponent of [NO] is 2 and the b. Temperature
exponent of [O2] is 1, so the reaction order c. Concentration of
is second order with respect to NO, first Reactants
order with respect to O2, and third order d. Physical State of
overall. Reactants
b. The reaction is first order in H2O2, first e. Catalysts
order in I-, and second order overall. The
reactant H+ does not appear in the rate 2 – 4. (Answers may vary based on
law, so the reaction is zero order with student’s interpretation.)
respect to H+.
SCIENCE POCKET LESSON 12 SCIENCE POCKET LESSON 11
ANSWER KEY