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ML2 T −2
= = ML−1 T −2 = Pr essure
Energy
Sol.
Volume L
3
2. (a)
Sol. In a standing wave energy of one region is always confined in that region. All particles cross their mean
position together.
3. (c)
Sol. The slope of the tangent drawn on position-time graph at any instant gives instantaneous velocity.
4. (a)
5. (c)
Sol. The forces exerted by the liquid at the bends are shown. (The liquid undergoes change of momentum
only at these points, and hence the liquid and tube exert forces on each other.) The two forces form a
couple exerting a clockwise torque.
6. (a)
Sol. The rms speed of a gas molecules at absolute temperature T is given by:
3RT
v rms =
M
( )
Sol. W = P( V) = 1 105 3.34 − 2 10−3 = 340 103 J = 340 kJ
8. (c)
Z A
Sol. = 3
Z A
9. (a)
Sol. Frequency of sound heard by the man from approaching train.
v 320
na = n = 240 = 243 Hz
v − vs 320 − 4
v 320
Frequency of sound heard by the man from receding train n r = n = 240 = 237 Hz
v + vs 320 + 4
Hence, number of beats heard by man per sec = n a.– nr = 243- 237 = 6
10. (a)
Sol. If R1 arid R2 are connected in series, then Req.= R1 + R2. = (300 ± 7)
11. (a)
Sol. During adiabatic compression the temperature of a gas increases while no heat is given to it. In
compression work is done on the gas i.e., work done is negative. Hence, internal energy of the gas
increases due to which its temperature increases.
12. (b)
Sol. The atoms when brought from infinity are attracted due to interatomic electrostatic force of attraction.
At point B, the potential energy is minimum and force of attraction is maximum. But if we bring atoms
closer than x = B, force of repulsion between two nuclei starts and P.E. increases.
13. (c)
1
Sol. Here, 0E2 represents energy per unit volume.
2
ML2 T −2
= = ML−1 T −2
Energy
0 E =
2
volume L3
14. (c)
Sol. When a particle moves on a circular path with a constant speed, then its motion is said to be a uniform
circular motion in a plane. This motion has radial acceleration whose magnitude remains constant but
whose direction changes continuously, So, a r ≠ 0 and at = 0.
FL Mg L
= = 2
A L r L
16. (c)
Sol. Given: Mass of cylinder, m = 3 kg R = 40 cm = 0.4 m,F = 30N .
Torque, = l
F R = mR2
F R 30 0.4
= =
mR2 3 (0.4)2
= 25 rad / s2
17. (d)
Sol. According to first law of thermodynamics
Q = U + W
U = Q − W
Q = 35J, W = −15J
U = 35J − ( −15J) = 50J
18. (b)
Sol. Centre of mass depends on the distribution of mass in the body. So, it may lie within, outside or on the
surface of the body.
19. (b)
d2 s 2
Sol. Acceleration = 2
=
dt 3
2
Force acting on the body = 3 = 2N
3
1 4
Displacement in 2 s = 22 = m
3 3
4 8
Work done = 2 = J
3 3
Sol.
Moment of inertia of shell 1 along diameter
2 2
Idiameter = mr
3
2 5
Moment of inertia of shell 2 = Moment of inertia of shell 3 = Itan gential = mr 2 + mr 2 = mr 2
3 3
n ( O2 ) = 2;n ( Ar ) = 4
5 3
Utotal = ( 2 ) RT + ( 4 ) RT = 11RT
2 2
23. (a)
x x 1
Sol. U = − Fdx = − kxdx = − kx 2 ,
0 0 2
It is correctly drawn in (a)
24. (d)
Sol. The static friction comes into play, the moment there is an applied force. As the applied force increases
static friction also increases, remaining equal and opposite to the applied force up to a certain limit.
But if the applied force increases so much, it overcomes the static friction and the body starts moving.
v = 5gR
26. (a)
1 1
Sol. From the law of conservation of energy, we get, mv 2 = kx 2 mv 2 = kx 2
2 2
m (1.5)2 = 50 (0.15)2
m = 0.5kg
27. (d)
Sol. Acceleration of the system
F − 4g − 2g 120 − 40 − 20
a= =
4+2 6
a = 10 m / s2
From figure,
T − 2 g = 2a
33. (b)
F 6
Therefore acceleration ( a ) = = = 6 m / s2 and final velocity ( v ) = 30 = u + at = 0 + 6 t
m 1
or t = 5 seconds
34. (d)
Sol. The wedge is given an acceleration to the right. The block has a pseudo acceleration to the left
pressing against the wedge because of which the block is not moving
g sin
mg sin = ma cos or a =
cos
Total reaction of the wedge
N = mgcos + ma sin
mg sin sin
or,N = mgcos +
cos
or, N =
(
mg cos2 + sin2 )= mg
cos cos
35. (a)
Sol. For 1 mole of gas molecule, kinetic energy = (3/2)RT.
36. (a)
Sol. According to the first law of thermodynamics,
Q = ΔU + W
In adiabatic process, ΔQ = 0
So,
ΔU = –W
38. (a)
Sol. Force F = MLT−2
= (10 g)(10 cm ) (0.1 s)−2
Changing these units into MKS system
( )( )( )
−2
F = 10−2 kg 10−1 m 10−1 s
= 10−1 N = 0.1 N
39. (b)
Sol. Given, fundamental physical quantities are force F , acceleration a and time [T].
40. (d)
Sol. Let v be the relative velocity of scooter(s) w. r. t . bus (B), then
V = Vs – V B
41. (b)
Sol. Work done by a force F , which is variable in nature in moving a particle from y1 to y 2 is given by
y2
W = F dy
y1
43. (b)
Sol. As initially both the particles were at rest therefore velocity of centre of mass was zero and there is no
external force on the system so speed of centre of mass remains constant i.e., it should be equal to
zero.
44. (c)
𝑘𝑑 𝑙𝑑 𝑀𝑟
∴ =√ ×
𝑘𝑟 𝐼𝑟 𝑀𝑑
𝑘𝑑 (5/4)𝑀𝑑 𝑅 2 𝑀𝑟 5
or =√ 2 × =√
𝑘𝑟 (3/2)𝑀𝑟 𝑅 𝑀𝑑 6
∴ 𝑘𝑑 : 𝑘𝑟 = √5: √6
45. (a)
Sol. Given,𝑎 = 1 m
As
𝑦 = 𝑎sin (𝑘𝑥 − 𝜔𝑡)
2𝜋 1
= sin ( x − 2𝜋 × 𝑡) = sin (𝑥 − 2𝑡)
2𝜋 𝜋
46. (c)
Sol. Given, 𝑦 = Asin(𝜔𝑡 − 𝑘𝑥)
As we know that wave velocity is given by
𝜆 𝜔𝜆
𝑣𝑤 = = ...(i)
𝑇 2𝜋
2𝜋
[𝑇 = ]
𝜔
and maximum particle velocity is given by 𝑣𝜌 = 𝐴𝜔 ...(ii)
𝐴 = amplitude
[ ]
𝜔 = angular frequency
So, as Eq. (i) is equal to Eq. (ii),
𝜔𝜆
𝐴𝜔 = , 𝜆 = 2𝜋A
2𝜋
47. (c)
Sol. The efficiency of Carnot engine is defined as the ratio of work done to the heat supplied i.e.
Work done 𝑊 𝑄1 − 𝑄2
𝜂 = = =
Heat supplied 𝑄1 𝑄1
𝑄2 𝑇2
=1− =1−
𝑄1 𝑇1
Here, 𝑇1 is the temperature of source, 𝑇2 is the temperature of sink, 𝑄1 is heat absorbed and 𝑄2 heat
rejected
40
As given, 𝜂 = 40% = = 0.4 and 𝑇2 = 300 K
100
𝑚1 𝑟1 − 𝑚2 𝑟2
∴ =0
𝑚1 + 𝑚2
⇒ 5𝑟1 − 10𝑟2 = 0
𝑟1
⇒ 𝑟2 =
2
Also, 𝑟1 + 𝑟2 = 100
𝑟1
⇒ 𝑟1 + = 100
2
⇒ 3𝑟1 = 200
200
⇒ 𝑟1 = ≈ 67 cm
3
49. (d)
Sol. According to work-energy theorem, the change in kinetic energy of a particle is the amount of work
done on the particle to move, i.e.
𝑊 = −Δ𝐾𝐸 = 𝐾𝐸𝑓 − 𝐾𝐸𝑖
Given, mass of cylinder, 𝑚 = 2 kg
radius of cylinder, 𝑟 = 4 cm = 4 × 10−2 m
rotational velocity, 𝜔 = 3rpm
2𝜋 𝜋
=3× = rad/s and 𝜃 = 2𝜋 revolution = 2𝜋 × 2𝜋 = 4𝜋 2 rad.
60 10
The work done in rotating an object by an angle 𝜃 from rest is given by 𝑊 = 𝜏𝜃
As the cylinder is brought to rest, so the work done will be negative.
Sol.
54. (b)
V
Sol. W = −2.303nRT log f
Vi
100
= −2.303 1 8.314 300log
10
= −2.303 8.314 300 = −5.744kJ
55. (b)
Sol. Zn(OH)2 Zn2+ + 2OH−
s M ( 2 s + 0.1) M
2s 0.1 2 s + 0.1 0.1
2
K sp = Zn2+ OH− = ( s ) (0.1)2 = 1 10 −15
s = 10−13 M
56. (c)
1
Sol. Bond order O2 = (10 − 6 ) = 2
2
1
Bond order O2+ = (10 − 5 ) = 2.5
2
1
Bond order O2− = (10 − 7 ) = 1.5
2
Correct order of bond order: O2+ O2 O2−
57. (c)
Sol. For the number of objects, significant figures are infinite.
58. (b)
%w / v 10 6 10 1
Sol. M = = = M
(mw)solute 180 3
59. (d)
Sol. Boyle’s law says Graph I PV = constant (rectangular hyperbola)
Constant
Graph II P = (straight line through origin)
V
Graph III log P = – logV + log {constant} (straight line with negative slope)
60. (a)
Sol. Elements No. of unpaired e–s
Cr 6
68. (a)
Sol.
69. (b)
1 1
Sol. X2 ( g) + Y2 ( g ) → XY ( g )
2 2
71. (d)
Sol. Mixture of weak acid and its salt with strong base can act as an acidic buffer.
72. (b)
1
Sol. Rate of diffusion
M
n n (M)SO2
t / =
He t SO2 (M)He
2.5
2 = 64
n 4
5
6.25
=4
n
nSO2 = 1.5625
w SO2 = 1.5625 64 = 100 g
73. (b)
Sol. Salts of lithium are mostly hydrated due to higher hydration enthalpy which decreases down the group
with increase in ionic size of cations.
74. (d)
Sol. An orbital can accommodate maximum two electrons with opposite spin.
75. (b)
Sol. The order of decreasing priority of the given functional groups in IUPAC nomenclature is
– COOH > – SO3H > – COCl > – CONH2
76. (c)
Sol.
Sol. pH = pK a + log
Salt
Acid
CH3COOH + NaOH → CH3COONa + H2O
200 0.1 2
Mol of CH3COOH = = mol
1000 100
100 0.1 1
Mol of NaOH = = mol
1000 100
1
Mol of CH3COONa formed = mol
100
1
Mol of CH3COOHleft = mol
100
1
100
pH = 4.7 + log = 4.7
1
100
79. (d)
Sol. ClF3 has bent T-shape and no bond angle is equal to 180°
80. (b)
20 80 + 22 20 2040
Sol. Average atomic mass = = = 20.4u
100 100
81. (a)
Sol. 5 molal aqueous solution means 5 mol urea is present in 1000 g of water
nurea 5 5
Xurea = = =
nurea + nH2O 5 + 55.5 60.5
10
Xurea =
121
82. (b)
Sol.
Selectivity ratio for monochlorination with respect to 1°, 2°, 3° carbon is 1 : 3.8 : 5 respectively
Washing soda
88. (a)
Sol. Na2[B4O5(OH)4]·8H2O
Borax
89. (d)
Sol. SO2, O3 and PAN causes irritation in the eyes.
90. (c)
Sol. Permanent hardness of water cannot be removed by boiling.
91. (d)
Sol. In H2SO4, S is present in its highest oxidation state i.e. +6 so it cannot be further oxidised.
92. (a)
Sol. Lesser is the stability of alkene, higher will be energy released on hydrogenation reaction.
Lesser is the hyperconjugative structures, lesser will be stability of alkene.
93. (d)
Sol. 188 g of AgBr contains 80 g Br
Sol. H = U + ngRT
= 2 × 103 + 1 × 2 × 300
= 2000 + 600 = 2600 = 2.6 kcal
G = H – TS = 2600 – 300 × 15 = 2600 – 4500 = – 1900 cal = –1.9 kcal mol–1
95. (d)
+H +
Sol. H2PO 4− ⎯⎯⎯ → H3PO 4
Conjugate acid
−H +
H2PO4− ⎯⎯⎯ → HPO24−
Conjugate base
96. (a)
Sol.
97. (a)
Sol. Gas which gives more deflection from Z = 1 line in Z v/s P graph gives more deviation from ideal
behavior.
98. (c)
Sol. Velocity of photon = velocity of light[3 108 ms−1]
h
=
mv
6.6 10−34
=
6.6 10−31 3 108
= 3.3 10−12 = 3.3pm
99. (b)
Sol. CaCO3 decomposes to quick lime when heated to 1200 K.
CaCO3 ⎯⎯ ⎯⎯
1200K
→ CaO + CO2
100. (b)
Sol.
101. (d)
Sol. One NADH + W produced in link reaction and 3NADH + W and one FADH + W produced in Krebs
cycle.
102. (c)
Sol. In bundle sheath cells. RuBisCO has higher concentration of CO2.
150. (c)
Sol. Sorghum is C4 plant in which double CO2 fixation occurs. Rice, potato and wheat are C3 plants.
151. (a)
Sol. Reptiles are cold blooded animals. Water tight shell is present in both birds & reptiles.
152. (b)
Sol. Fatty acids and glycerol, being water insoluble, are first incorporated into micelles.
153. (b)
Sol. In coelenterates, skeletal system is absent except anthozoans or corals which have a calcium
carbonate skeleton known as corallite.
154. (a)
Sol. Pancreatic enzymes include trypsinogen, chymotrypsinogen, lipase, amylase, nucleases, and