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Decarbonizing gas turbines

through carbon capture


A pathway to lower CO2

www.ge.com/power/future-of-energy
Executive Summary
In order to combat man-made climate change, carbon
capture, utilization, and sequestration is a necessity

In 2019, global CO2 emissions from fossil Planning for sustainability in the power
fuels amounted to 33 gigatons, with 41 Energy Trilemma sector is one of three corners in the Energy
percent of that coming from the power Trilemma: the need to balance affordable
ELECTRICITY GENERATION,
generation sector, and the remainder from energy, maintain reliable power supply,
the transportation and industrial sectors. DELIVERY & CONSUMPTION and improve sustainability. See Figure 1.
There is a lot of work to be done and time Each country is at a different point in its
is against us. According to the IPCC’s 2018 decarbonization* journey and will prioritize
special report “Global Warming of 1.5 °C,” the elements of the trilemma differently, but
we had 580 gigatons of CO2 in our remaining the most effective way is a mix of generation
carbon budget if the globe were to have a resources that complement one another.
50–50 chance of keeping global warming to
1.5 °C compared to pre-industrial levels. Bring AFFORDABLE Based on our extensive analysis and
that forward from 2018 to 2020, and if we experience across the breadth of the
continue on our current path of emissions, we global power industry, GE believes that the
have only 15 years left before the budget runs accelerated and strategic deployment of
out. The good news is that there are solutions renewables and gas power can change the
available today to enable the power sector’s RELIABLE SUSTAINABLE near-term trajectory for climate change,
rapid reduction in carbon intensity. enabling substantive reductions in emissions
quickly, while in parallel continuing to
Carbon Capture, Utilization, F I G U R E 1 : The energy trilemma advance the technologies for near zero-
is the challenge of providing affordable, carbon power generation.
and Storage (CCUS) is one of
reliable and sustainable energy.
these solutions and will play *Decarbonization in this paper is intended to mean the reduction
of carbon emissions on a kilogram per megawatt hour basis.
an integral role across multiple
sectors on the journey to
lower carbon.

As governments, countries, and companies GE believes that the accelerated


establish their charters for achieving and strategic deployment of CCUS
carbon reduction goals, CCUS should be
part of the pathway. The International and gas power can change the
Energy Agency’s Sustainable Development
Scenario (SDS), emphasizes the trajectory for climate change
contribution CCUS will play in reducing
cumulative CO2 emissions, indicating
CCUS will account for one sixth
of the needed cumulative CO2
reduction. However, in order
for CCUS to fulfill its role,
policies and regulations are
needed to both accelerate the
speed of adoption and to de-
risk public concerns around
the technology.

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 2


Introduction
As of 2020 there were ~1.6 TW of gas
turbines installed globally, and despite the
PRE- POST-
COMBUSTION COMBUSTION
effects of COVID-19 on power demand gas
generation accounted for ~22 percent of
generation globally. There are two ways
to systematically approach the task of USE A ZERO OR CARBON REMOVE CARBON FROM
turning high efficiency gas generation into NEUTRAL FUEL THE PLANT EXHAUST
a zero or near zero-carbon resource: pre • Hydrogen (blue, green, pink) • Carbon capture (liquid solvents)
and post-combustion. See Figure 2. Pre- • Synthetic (renewable) methane • Carbon capture (solid sorbents)
combustion refers to the systems and • Biofuels • Oxy-fuel cycles
processes upstream of the gas turbine. The
• Ammonia (NH3)
most common approach today to tackle
pre-combustion decarbonization is simple: F I G U R E 2 : Means of decarbonizing a gas turbine
change the fuel. The vast majority of gas
turbines burn natural gas, or methane
(CH4), to release energy which ultimately
produces the electricity we use at home and Pathway to Low or Near-Zero Carbon with Gas Turbines
Carbon Emissions Intensity (g/kWh)

for industry. An advantage of gas turbines is


that they are able to operate on many other
CAPABLE TODAY
fuels besides natural gas. Some of these
fuels, such as hydrogen (H2), do not contain RETROFITTABLE IN THE FUTURE
45%
carbon in the first place, and will therefore
not emit CO2 when combusted. Furthermore, ~1,000
60%
69%
H2 can be introduced to new gas turbines and
existing gas turbines alike, reinforcing the
concept that solutions are available today to
decarbonize assets already in the field and 97%
those waiting to be installed. The possibility COAL GAS 100%

of burning hydrogen in a gas turbine avoids HA HA HA Combined HA with


Global Global
the potential “lock-in” of CO2 emissions for Average Average Combined Combined Cycle with 100% H2 *
the entire life of the power plant. Cycle Cycle with 90% Carbon
50% H2 Capture

On the other side of the gas turbine, or F I G U R E 3 : Gas turbine decarbonization opportunity
post-combustion, there is a tool chest of *The atmosphere contains approximately 0.06% (by mass) CO2. Therefore, a gas turbine
different technologies that can remove on 100% H2 will still emit a small amount of CO2 due to the ambient air composition.

CO2 from the flue gases in a process that is


commonly referred to as carbon capture.
The general concept of carbon capture
involves introducing into the plant exhaust
stack a specialized chemical which has an
Sequestration (CCUS). Similar to introducing pre and post-combustion
hydrogen to a plant, CCUS can be applied decarbonization options for gas
engineered affinity to carbon. Once the CO2
to both new and existing gas power plants,
and the agent bond, the CO2 and specialized
again avoiding lock-in of CO2 emissions for
turbines are viable tools available
chemical are processed, the CO2 is separated, today. Both hydrogen and CCUS have their
the life of the power plant.
and taken to a compression tank as pure own merits and ideal areas of application.
CO2. This CO2 is then transported to either GE believes that in order for This paper will discuss the merits and
a geologic formation deep underground the power sector to rapidly limitations specific to carbon capture.
for permanent sequestration, or re-used See Figure 3.
in industrial process, thus completing the
decarbonize while maintaining
process of Carbon Capture and Utilization or high levels of reliability, both

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 3


WHO NEEDS CCUS?

Anthropogenic (man-made) sources of


Global cumulative captured CO2 by application, sector and
greenhouse gases (GHG) are certainly not source in the Sustainable Development Scenario, 2020–70
limited to the power generation sector. In
Application Sector Source
fact, one of the most compelling arguments
for the deployment of CCUS as a tool to 4% 4%
8% 15%
reduce CO2 emissions is that it is not limited
28% 22%
to applications in just one sector. In fact,
36%
we should think about four different value
streams for CCUS to make an impact. Those 27%

sectors are power generation, industry, 30%


92%
32% 2%
transportation fuels (blue H2 via steam
methane reforming), and direct air capture. In
Used Fuel transformation Process emissions
the IEA’s Sustainable Development Scenario Stored Industry Coal
(SDS), their hypothetical scenario that keeps Power generation Oil
Direct air capture Natural gas
global average temperatures well below 2° C Biomass
with efforts to limit it to 1.5° C, aligned Direct air capture
F I G U R E 4 : The transportation, industrial,
with the goal of the Paris Agreement, over IEA 2020. All rights reserved.
and power generation sectors will play a major
the next 50 years the power generation,
role when it comes to capturing CO2.
transportation, and industrial sectors will
play a major role in the aggregation and
sequestration of CO2 (Figure 4).

Expanding on the other sectors where Difference in global energy sector CO2 emissions reductions by
CCUS will play a role, the industrial sector abatement measure in the Sustainable Development Scenario
is a rather expansive term. Drilling down compared to the Stated Policies Scenario, 2019–70
and identifying industrial operations which
are considered “hard to abate” will bring us 0
to the iron & steel, cement, chemical, oil & Cumulative 2020–70
gas, pulp & paper sectors. These industries -10 Energy
rely on manufacturing processes in which efficiency*
GtCO2/yr

it is difficult to replace current fuels with -20


electricity, which is often referred to as Electrification,
electrification. In the case of transportation, -30 CCUS,
bioenergy
and primarily long-distance transportation,
-40
limitations in battery duration and limited 2019 2030 2040 2050 2060 2070
infrastructure to support low carbon fuels
make it a difficult sector to tackle emissions, Avoided demand Technology performance Electrification Hydrogen
Bioenergy Other renewables Other fuel shifts CCUS
but not impossible. One low carbon fuel
option today is hydrogen. Hydrogen as IEA 2020. All rights reserved.
it’s made today generally goes through an
industrial process know as steam methane F I G U R E 5 : Global energy sector CO2 emissions reductions by measure in the
reforming (SMR), which breaks up a standard IEA SDS relative to the Stated Policies scenario. Stated Policies scenario represents if
methane molecule (CH4), separating the the world’s current policies where to carry forward on its current track in addition to
carbon from the hydrogen, and emitting the announced Government intentions.
carbon into the atmosphere as CO2. Based
on a recent study, CO2 emissions from SMR
hydrogen production is ~9 Kg CO2 per Kg H2 carbon capture must (and can) be applied accounting for one-sixth of cumulative
produced.1 For many, an ideal state to create to SMR processes. Fortunately, capturing emissions reductions, according to the
hydrogen is instead using an electrolyzer carbon dioxide can be completed in a wide IEA (Figure 5).2 In order for CCUS to be an
powered from renewable energy to crack array of applications to fit the industrial, effective tool to remove a material amount of
a water molecule (H2O), making “green” mechanical, and alternative fuel processes carbon from power production and industrial
hydrogen. However, green hydrogen may (Blue H2) which produce CO2 emissions. operations, it will need to be deployed on
be a few decades away before it becomes both existing and newly constructed assets.
more economical and scalable. Thus, in CCUS is in fact expected to play a major
order for hydrogen to be effective in the role in order to reach net-zero emissions,
short term as a viable transportation fuel,
A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 4
In addition to the benefit of applying CCUS
to existing assets, it can also be deployed as
Global CO2 emissions reductions from CCUS retrofits
a modular solution, solving for incremental
amounts of carbon reduction with each
in power generation and heavy industry in the
additional module. This translates to greater Sustainable Development Scenario
optionality for plant owners, taking either
a phased approach by deploying carbon 2.5 100%
capture systems over years and spreading
out the capital expenses over a longer period, 2.0 80%
or an immediate approach by building out

GtCO2/yr
the carbon capture system to full capacity in 1.5 60%
one go. By 2050, retrofits to both the power
and heavy industry assets are expected to 1.0 40%
contribute more than 2 gigatons in annual
carbon reduction according to the IEA’s SDS. 0.5 20%
In fact, carbon capture retrofits are expected
to account for 50 percent of all CO2 capture 0.0 0%
2019 2030 2040 2050 2060 2070
projects by 2050 in their scenario (Figure 6).
Power Heavy industry Share of retrofits in total CO2 capture
IEA 2020. All rights reserved.

F I G U R E 6 : Global CO2 emission reduction from CCUS retrofits in power


generation and heavy industry in IEA’s 2020 SDS

Post-combustion carbon
capture can be installed on
both new and existing assets

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 5


WHAT IS CCUS AND
HOW DOES IT WORK?
CAPTURE USE
In its simplest sense carbon capture and Extract CO2 from power generation and Captured CO2 can be used as a
industrial sites post-combustion, or feedstock in many industrial processes.
sequestration is the process of removing CO2
directly from the air (DAC).
from the waste gas from industrial or power
generation processes. It has four central
components: (i) capture, (ii) compression, (iii)
transport, and (iv) storage or use. There is a
portfolio of options to tackle this challenge,
using liquid solvents or solid sorbents which
have an affinity towards acidic gases. Once
captured, the CO2 is compressed on site, and CH4 CO2 TRANSPORT
injected into a pipeline for transportation Once captured, the CO2 is
to a well-head for injection deep into the compressed and then transported
by either ship or pipelines. The US has
earth, or to an industrial site for use. The
about 5,000 miles of CO2 pipelines.
repurposing of carbon is generally directed to
the production of synthetic fuels, chemicals,
and building materials. However, the
majority of captured CO2 will be destined STORAGE
for sequestration and enhanced oil recovery Return the CO2.
(EOR), due to the limited volume of CO2 Permanently store CO2 safely far underground.
demanded for utilization.

When it comes to the actual process of F I G U R E 7 : Lifecycle of carbon in a CCUS application


capturing CO2, the most mature option
today, and the baseline for all other
carbon capture technologies, is a post-
combustion technology called Amine Carbon
Capture. A special chemical liquid called
monoethanolamine (MEA, or Amine for Flue Stack De-absorber
short), is literally rained down through an
Flue Gas CO2 To
exhaust stream, absorbing the CO2 from the to Stack Compression
exhaust. That CO2-rich liquid is then moved to
a second vessel, where it is heated to drive off
pure CO2. That CO2 can then be compressed
and transported to a sequestration or Lean Rich
Amine Amine
industrial site. Amine
Flow

On a more granular chemical level, MEA is a


CO2 Solvent
base that reacts with the acid by forming a
Absorption
Amine Regeneration
complex compound with the CO2 in the acid Column Solvent Column
gas, effectively removing the acid gas from Heat
the original stream (absorbing process). The Exchange/
liquid amine solution with the acidic gas is Gas
Flow
Integration
then heated to recover the amine, resulting
in a purified CO2 stream (desorbing process). Flue Gas
3–5 Steam
The heat forces the CO2 back to a vapor from the
Vol. % CO2
form, where the now pure CO2 gas can be reboiler
Rich Lean
compressed for sequestration, and the amine Amine Amine
is recycled into the stream. (Figure 8).

F I G U R E 8 : Post combustion amine process diagram

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 6


Amine-based carbon capture is the most mature
technology, though many options exist

The primary components in the basic HEAT EXCHANGER (ECONOMIZER) LEAN PUMP AND AMINE MAKEUP
MEA process are presented below.
The rich solution carries CO2 from the The regenerated “lean” amine solution travels
ABSORBER absorber to the de-absorber. The de-absorber to the heat exchanger by using a lean solution
works optimally when the rich solution pump where it cools down. A control unit
Vessel—also called tower or column—in temperature is approximately 80º C higher is designed to provide the necessary amine
which the chemical absorption reactions than that at the absorber bottom. Therefore, makeup—amine is degraded by the process to
take place. The absorption reaction chain the rich solution must travel through a heater compounds that are not effective at binding
binds the CO2 to the MEA, in its aqueous first and then to the top of the de-absorber with CO2—and set the solution flowrate. The
solution, separating it from the flue gas. tower using a pump. This heater is a heat same amine plant can accept a range of flue
After the amine solution binds with CO2, it exchanger also called an “Economizer,” that gas flowrates by regulating the flowrate of
is collected at the bottom of the absorber transfers excess energy from the hot and amine solution to maintain a balanced ratio
(CO2-rich solution) while the scrubbed lean solution exiting the regeneration (de- between molar flowrate of CO2 in the flue and
flue gas is vented through the top of the absorber) column to the relatively cold and molar flowrate of amine in contact with it.
column. The fraction of flue gas that has rich solution exiting the absorption column.
been separated from the CO2 is vented As mentioned before, amines are the most
at the top of the absorber. The geometry DE-ABSORBER (STRIPPER) commonly used chemicals, but there are
of an absorber has two main degrees of other options which are commercially
freedom: diameter and height. These two The CO2-rich amine solution is sprayed down available. While there are a variety of
parameters are tailored to ensure that the from the top of the de-absorber tower (also options, it is important to point out that
unit is not too big, heavy and expensive known as the solvent regeneration column) there are limitations to the process. The
but at the same time, the velocity of the while steam generated in the reboiler rises most significant of these limitations is the
gas ascending the column is under control. under pressure, from the bottom to the top. cost associated with achieving more than
A gas stream that is too fast induces This counter-current motion of rich solution ~90 percent carbon capture. The relationship
pressure loss along the column and results through steam creates the right environment between carbon capture percent and capital
in the need for high compression power for the equilibrium reactions to be shifted expense is not linear. To achieve a capture
to pressurize the flue gas at the bottom of towards the release of CO2 from the amine rate greater than 90 percent, the equipment
the tower. The equilibrium reactions inside solution, which becomes “lean”, or stripped gets larger and larger with small increments
the column takes place at a rate controlled of the CO2, and is collected at the bottom of in the plant’s capture rate. Additionally, there
by the kinetics of the amine chemistry, the column. As a result of the reaction and are several developments in new chemical
which means the absorber should be sized system configuration, the CO2 migrates to compositions which show promise to
according to the time required to ensure a the top of the column while the MEA solution increase the effectiveness of CCUS above 90
binding reaction occurs between the amines that is now poor in CO2 is collected at the percent, such as Metal Organic Frameworks
and the CO2. bottom of the column. The CO2 is separated (MOF) which may be able to improve on
from the water vapor that “stripped” it from amine’s current limitations.
the rich solution in the condenser/flash tank.
At the top of the condenser, the CO2 can be
accumulated or pumped away.

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 7


CARBON CAPTURE The CO2 compressor is the second largest
IN PRACTICE contributor to the power plant’s efficiency
loss. The compressor pressurizes the
IMPACTS TO THERMAL PERFORMANCE CO2 collected at the top of the solvent
regeneration column as need to prepare the
As with most things in life, rarely is there gas for injection into the pipeline system for
any free lunch. The same holds true for transport to the storage site. An important
the positive benefits that come along with factor to keep in mind is that compression
carbon capture systems. As described in the operations are volumetric. The higher the
section above, the thermodynamic cycle of CO2 capture rate, the larger the CO2 flowrate,
the amine system requires thermal energy, and therefore the efficiency loss due to CO2
which in a combined cycle power plant would compression increases with the carbon
be taken from the Heat Recovery Steam capture level.
generator (HRSG) or the steam turbine,
depending on the required conditions. The third major source of efficiency loss
Historically, the associated efficiency penalty comes from a blower unit, situated upstream
has been calculated to be rather high at of the absorber. In the absorber, lean solution
almost 10 points of combined cycle efficiency. rains down through the ascending column of
Reassessment of this topic has uncovered flue gas. The blower uses electrical power to
the possibility of reducing the penalty by create the necessary pressure to the flue gas
improving the steam and carbon capture to overcome the pressure losses through the
processes. As shown in Figure 9, absorber’s packing.
GE’s analysis of a 2 x 1 combined
cycle 7HA plant (~1,200 MWs)
indicated the efficiency penalty
MEA Plant Efficiency Losses
is closer to 6 percent at an 85
7.0%
percent carbon capture rate.

More work is being done in this area, but 6.0%


there is no avoiding an efficiency penalty
nonetheless. 5.0%
Eficiency Loss (%)

The impact of CCUS on power plant efficiency 4.0%


can be assessed by examining three key
pieces of the carbon capture system:
1) de-absorber, 2) CO2 compressor, and 3.0%
3) blower. Within the de-absorber is a
subcomponent called the steam reboiler, 2.0%
which provides two key functions. First,
it keeps steam at the pressure needed in 1.0%
order to force gases to ascend the de-
absorber tower and second, it maintains the
temperature at which the CO2 segregates 0.0%
85% 90%
from the rich amine solution, which can be as
Desorb Steam CO2 Compressor Blower DP Auxiliary Power Pumps
high as 120º C–140º C. However, when the
system is paired with a combined cycle plant,
there is no need for a dedicated reboiler,
steam is instead drawn directly from the F I G U R E 9 : Plant efficiency losses for a combined cycle plant at 90 percent
steam cycle. The impact of steam removal and 85 percent carbon capture
causes a reduction in electricity production at Source: GE Gas Power marketing analysis
the steam turbine shaft and a corresponding
reduction in plant efficiency.

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 8


RETROFITS Power plant

As discussed earlier, one of the merits of


post-combustion carbon capture is that Carbon capture plant
it can be applied to both existing and
future CO2-producing assets. However, it is
F I G U R E 1 0 : Conceptual layout of gas power plant and carbon capture plant
important to note that not every asset will be
considered a good candidate due to multiple
factors, including available land, access to
geologic storage formations, and lack of
policy/regulations to encourage deployment.

Starting with land constraints, it is important


45% of F/H plants have PLENTY of space
to point out that adding a post-combustion GLOBALLY... 22% of F/H plants have SOME space
system is a considerable expansion in the 33% of F/H plants have INSUFFICIENT space
site’s footprint, approximately doubling
the size assuming an ~90 percent carbon 100%
capture system. For a typical plant this is 90% 20%
an additional ~4 acres. In an analysis of
80% 45%
hundreds of gas power plants using GE’s F/ 54%
70% 20%
HA class gas turbines around the globe across
60%
48 countries, approximately 45 percent
50%
of existing plants had plenty of physical 25%
40%
space adjacent to the site, 22 percent of 25%
30% 60%
plants had some space, and 33 percent
20%
of sites likely had insufficient space. 30%
10% 20%
0%
An added benefit of a retrofit strategy
Americas Asia Europe, Middle East, Africa
is that it helps de-risk future carbon
regulations that impact the decision Based on a visual inspection of the sites using Google Earth, assuming carbon capture requires a doubling of
current site on at least one adjacent side. Analysis looked only for un-used property, not property ownership.
to build a gas-fired power plant today.
Furthermore, retrofits can significantly
extend the lifetime of operating assets, F I G U R E 1 1 : Available space analysis for adding carbon capture
extending their economic viability and even systems to a sample of power plants with GE gas turbines
deferring incredibly costly decommissioning Source: GE Gas Power marketing analysis
expenses with forced retirements.

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 9


ECONOMICS Indeed, when capital costs and operational at $6.82/ton in September ’20. Not only
costs are amortized over a ~20 year plant are these prices, among many other
The cost of adding a carbon capture system life, the levelized cost of energy from schemes, too low to encourage impactful
to any CO2-emitting asset has often been the asset are highly competitive when decarbonization to CO2 emitting sectors,
labeled as overly expensive and unnecessary. compared to other forms of decarbonized they often lack sustained pricing needed for
This holds true under circumstances thermal assets, and even more so when long-term planning and business certainty.
where CO2 emissions may continue an added cost of a carbon tax comes into See Figure 12 below for a global sampling
unabated. However, with the transition to a the picture. Placing a price (i.e., a tax) of established carbon pricing schemes.
decarbonized future across multiple sectors, on carbon can be a meaningful way to
this is no longer the case. In fact, given the encourage cleaner forms of power. There In analysis performed by GE, the trade-off
proper market structures and regulatory are a handful of markets that place a value between paying a carbon tax on emissions
frameworks that already exist in certain on CO2 emissions and mostly take the versus paying to capture and sequester
regions, CCUS is economical today, especially form of a cap-and-trade system. However, the carbon tips in favor of installing post-
compared to alternatives to decarbonize the markets are currently structured in combustion carbon capture in certain
thermal assets. such a manner where the price of carbon conditions starting as low as ~$35–~$50 per
remains too low to provide the price signal metric ton of sustained CO2 pricing. At this
An approximate rule of thumb for a 90 that is needed to encourage meaningful rate, a plant’s levelized cost of electricity
percent post-combustion carbon capture decarbonization. Looking across a few of comes down as the asset decarbonizes until
system is that it can double the capital the carbon pricing schemes, the European it reaches ~90 percent decarbonization. The
expense of the power plant. Nominally, this is Emissions Trading System (ETS) had a 12 relationship between carbon capture percent
certainly a significant investment. But unlike month average of ~€24/MT (Nov ’19–Nov and capital expense is not linear, and in fact,
efficiency losses, which are linear to the ’20) reaching a high of ~€30/MT and in the costs begin to increase exponentially above
amount of carbon reduction, it is important Northeast US, the Regional Greenhouse ~90 percent capture.
Gas Initiative’s (RGGI) 49th auction cleared

Most carbon prices are too low Price


to enable meaningful change Sweden carbon tax
Finland carbon tax
Norway carbon tax
France carbon tax
to keep in mind that capital expense does not
Iceland carbon tax
have a linear relationship with the percentage Ireland carbon tax
of carbon reduction. Therefore, moving down EU ETS
to an 85 percent carbon capture rate sees BC carbon tax
a very significant reduction in capital cost. Denmark carbon tax
Additionally, costs can be reduced even Portugal carbon tax
more so on new power plant builds due to New Zealand ETS
synergies of construction operations, onsite Alberta TIER
equipment and labor, etc. Switzerland ETS
Korea ETS
When looking at operational costs, the Quebec CaT
important buckets include onsite utilities California CaT
(CO2 compression, etc.), operating and Beijing pilot ETS
maintenance labor, CO2 take-away costs, and Australia ERF Safeguard Mechanism
raw materials such as the amine, to name a South Africa carbon tax
RGGI
few. Despite the fact that these raw materials
Shanghai pilot ETS
degrade over time and need to be replaced,
Shenzhen pilot ETS
the costs of these materials are incredibly
Chile carbon tax
low when looking at the overall operating
Japan carbon tax
expense of the entire plant site. Mexico carbon tax
0 20 40 60 80 100 120 140 160

F I G U R E 1 2 : Selected CO2 prices, US$/tCO2e


Source: The World Bank Carbon Pricing Dashboard https://carbonpricingdashboard.worldbank.org

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 10


TRANSPORTATION Map 2, used to bring CO2 to the Permian the scale of the standard long-haul pipeline
basin for use in enhanced oil recovery. Some systems we see today.
Once the CO2 is compressed to the of these pipelines have already demonstrated
appropriate pressure its ready leave the nearly a half-century worth of safe and The cluster & hub model is one that is likely
site and be repurposed or sequestered, reliable operations, going into service as early to be replicated given the multi-regional
there are a few modes to transport it: as the 1970s. However, CO2 pipelines have hurdles that long-haul systems face. In fact,
truck, train, ship, and pipeline. a perceived stigma among communities, large concentrations of major industrial and
despite many of these same communities power generation operations are within
accepting the day-to-day risks brought by ~300 km of areas that may hold formations
Pipeline transport is by far
existing natural gas infrastructure. With ideal for geologic storage.7 These clusters of
the lowest cost option when that in mind, it is especially important to stationary emitters are ideal for aggregating
looking at significant volumes. ensure the proper regulation, monitoring, and sufficient volumes to satisfy a pipeline’s
maintenance structures are in place for CO2 capacity, from which a modest pipeline is
The technology for transporting CO2 via pipelines in sufficient measure to overcome needed to ship the compressed CO2 to a
pipelines is fundamentally no different than public perception. nearby geologic resource. This obviously has
the technology for transporting natural gas economic implications for both the developer
and other gases, and also safely managed in While other modes of transportation can of the pipeline and the supplier of the CO2.
the same ways. Dry CO2 does not corrode the be both viable and well suited for different From a development perspective, it costs
carbon-manganese steels generally used for CCUS applications or geographies, pipeline on average anywhere from $80K–$150K per
pipelines, as long as relative humidity can be networks are the most cost-effective inch/mile (inch of pipeline diameter per mile
controlled.3 infrastructure to connect the power of pipeline) to construct a new CO2 pipeline.
generation sector to sequestration sites. From the perspective of the supplier of the
There are already millions of miles of Developing CO2 pipeline infrastructure CO2, transportation can become a significant
pipelines carrying hydrocarbons around the is a classic chicken and egg dilemma. cost if there is a great distance between CO2
globe, with established rights-of-way (routes) Because pipelines are suited for moving production and storage. In a recent National
the CO2 pipelines can follow, see Map 1, large, continuous volumes of material, their Petroleum Council study, the transportation
minimizing the potential construction impact construction for purposes of moving CO2 will costs of CO2 range from $2 USD–$38 per
associated with greenfield infrastructure depend on being able to aggregate clusters metric tonne.8
projects. In fact, there are already 5,000 of CO2 suppliers, or creating the hubs for CO2
miles (~8,000 km) of CO2 pipelines globally collection. This business model has been
(compared to ~2,800 miles of H2 pipelines5), applied in many of sequestration projects
with the majority in the United States, see that are currently in development, but not at

M A P 1 : Natural Gas Infrastructure in US/CAN4 M A P 2 : Existing CO2 Pipelines in the US6

CO2 to Canada

Great Plaines Coal


Gasification Plant

LaBarge

McElmo Dome Sheep Mountain

Ridgeway CO2 Ammonia Plant


Discovery Bravo
Dome
Jackson Dome

Terrell, Puckett
and Mitchell Gas
Plants

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 11


SEQUESTRATION AND ENHANCED In fact, it is often a misconception underground in perpetuity. While there are
OIL RECOVERY (EOR) inevitably risks with these types of operations,
that there is not enough capacity
proper regulation, monitoring, maintenance,
Today, most of the CO2 that is captured and deep below the Earth to house and implementing tools that already exist
piped to wellheads is used for a process a meaningful amount of carbon, can safely mitigate these risks. There is very
called EOR. The EOR process is generally or that resources that do exist strong evidence that we can safely store the
implemented at the final extraction phase of CO2 underground for hundreds of millions
a well, after the natural geological pressures
are far away and hard to access.
of years, just as hydrocarbons were stored
have pushed the hydrocarbons into the well. A study completed by the Global underground before being intentionally
Once these natural forces have done their Carbon Capture and Resource extracted by humans.
job, the remaining deposits need a little more Institute indicates there is ample
help to make it to the surface. One method to It’s important to point out that leakage
do this is to inject gases into the well, which
space both onshore and offshore.
can occur, as it does naturally with current
expand and push remaining hydrocarbon hydrocarbon deposits. The best way to
Afterall, the majority of the carbon in
deposits into the well stream. Using CO2 as the explain this phenomenon is the study of
the atmosphere that we need to capture
agent has been done in the US for decades. the very liquids and gases that humans use
originated from those same location.
Under this scheme, there is actually a value to create CO2: hydrocarbons. Generally,
Granted, it is not an infinite resource if one
that carbon provides in these operations to fossil fuels are created when biological
considers a millennial time scale, but the
improve the productivity of wells which would matter, mostly dead vegetation, is buried
magnitude of known resources are more
otherwise be considered “dry.” over millennia, and cooked under extreme
than enough to accommodate centuries of
sequestration, making CCUS a viable and temperature and pressure. Much of the
While EOR will continue to be a viable crust above these cooked deposits is porous
necessary tool to achieve net-zero targets.
route for utilization of carbon capture, and made of materials that are denser than
To present this in a more quantifiable
sequestration without additional oil and natural gas. As a result, buoyancy
manner, anthropogenic CO2 emissions
hydrocarbon extraction is a necessary naturally wants to drive the hydrocarbons
(excluding land use) in 2019 were ~33
activity for CCUS to make its full impact in the upward through the porous layers. If the
gigatons. On the low end, there are 2,000
energy transition. The techniques, tools, and Earth’s crust was merely made of perfectly
gigatons of storage capacity in the US alone,
geologies to do so are well known, and are cylindrical layers of porous rock, then all of
with sizable capacities in many countries
almost all born out of the oil & gas industry. the fossil fuels would have escaped to form
across the globe. See Map 3 below.
The questions become, where are these pools of oil on the surface of the Earth a long
geologic structures, and how safe is it? time ago. But this is not the case.
An additional public misconception is that
carbon sequestration is unsafe, and there Some fossil fuels do make it to the Earth’s
are fears that the carbon may not stay surface and atmosphere naturally, but the
vast majority are trapped underground.

M A P 3 : Geologic Storage Reserves: Global Carbon Capture and Resource Institute

There are
200 geologic
NORTH
SEA
300
resources to
200–430
1,210–4,130
store centuries
2,000–21,000
100
worth of
5–25 140
1–5
5–30
CO2 emissions
100
47–63 9 12 23
140
2,000
2–228 7
High Confidence
Medium Confidence
Low Confidence
Very Low Confidence 150
220–410 16

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 12


The reason for this is that there are also
non-porous layers—like granite, or salt. While
these layers are not continuous all around
Land Surface
the Earth, both porous and non-porous
layers undulate in upward and downward
slopes. Hydrocarbons and other less dense Conventional
Non-associated Coalbed Methane
gases will continue to rise upwards, along Gas
the slope of that impermeable strata until Conventional
Associated Gas
reaching a concave section—a dome—where
it is then trapped.
Seal Oil
In fact, oil and gas geologists are
exceptionally good at finding these structures Sandstone
Tight Sand Gas
and therefore pockets of oil and gas. Once we
understand that the simple geometry of the
geology provides natural places for gases and Gas-Rich Shale
liquids to reside, it’s a small step to realizing U.S. Energy Information Administration

one other fact: those fossil fuels have been


trapped in those domes for millions and F I G U R E 1 3 : Cross-sectional view of geologic formations and drilling activities.
millions of years. Re-injecting the carbon
back from where it came is nothing short
of a “bottle return” concept.

Monitoring remains a very important piece infrastructure development. acting as the “bottle return” concept
of this puzzle in order to properly manage for the hydrocarbon industry. However,
the risks. Items such as injection rates, An outcome of good and sound policy is that if the world is to achieve meaningful
well pressures, seismic profiling, and even it lays the framework for a structured and safe decarbonization, policies need to be
satellite monitoring are a few of the critical economic activity, which is needed in order to structured to ensure the long-term
tools that will play a role in monitoring attract investment capital. viability of projects and infrastructure.
the CO2 to ensure it does not leak into the
atmosphere. It is important to structure An important part of thoughtful policymaking Because CCUS projects have such a long
international regulatory and monitoring is to structure regulations and incentives operational life and require significant
standards in a manner that gains the trust in a manner that decouples the existing amounts of investment, billions of dollars
of the public and ensures effective long- economic relationship between EOR and worth, policy must bring stability and
term success of CCUS applications. CCUS. That is to say, ensure CCUS is viable business certainty to developers and
without being tied to the price of a barrel of investors alike. Characteristics that will
oil. The CO2 projects that are active today bring about certainty include nation-wide
POLICIES and the corresponding infrastructure and emission reduction targets across all
operations are generally stimulated by the economic sectors, a firm and sustained price
Policy and regulatory statutes commercial opportunity to use the CO2 on carbon, programs to encourage and fund
for EOR and maximize withdrawal from innovation in CCUS applications, defining long
remain somewhat fractured
existing wellheads. This places an inherent term liabilities for storage, and establishing
between countries and even their goals or targets for CCUS deployment in
vulnerability on the project, as is evidenced
constituent regions when it comes by the Petra Nova facility in Texas, which the field. Some regions are more advanced
to many of the facets required for idled starting in March 2020 due to low oil when it comes to providing this certainty,
prices.9 At lower oil prices, EOR is no longer but in most cases, many of these facets
successful deployment of CCUS
economical, so the CO2 that would otherwise have yet to be defined. Many governments
across the full value stream. These are still struggling to provide the right mix
have been captured and routed to a storage
facets include a sustained value site is emitted into the atmosphere. of regulations to create the change that is
placed on CO2, uniform standards needed in order for CCUS to play its needed
It needs to be understood that use of role in decarbonization.
and procedures for monitoring
captured CO2 for EOR is an acceptable
and safety, tax incentives,
and necessary action as long as the
assignment of long-term world continues to demand fossil fuels,
storage liability, and significant

A Pathway to Lower CO2: Decarbonizing Gas Turbines Through Carbon Capture 13


Conclusion Going beyond the power sector,
governments must establish impactful
AUTHORS

In order for the Nationally Determined Contributions


(NDCs) under the Paris Agreement. In
John Catillaz
Dr. Jeffrey Goldmeer

world to avoid the support of these NDCs there needs to


be well thought out policies that:

negative impacts 1. incentivize the reduction


of carbon emissions
CONTRIBUTORS

that accompany
Rinaldo Miorini
Albert Stella
2. foster the creation of new market
climate change,
GE Gas Power Marketing
structures that properly value
decarbonized assets
it must become a REFERENCES
3. provide stability and business
global priority and certainty for decision makers.
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Updates of Hydrogen Production from SMR Process in
GREET®, 2019, Argonne Nat Lab.
IEA Energy Technology Perspectives 2020, Special
involve all carbon
2

Report on Carbon capture and Utilisation and Storage


One of the most effective economic 3
IPCC Special Report on Carbon Dioxide
mechanisms that support these
emitting sectors.
Capture and Storage, CH. 4, pg 181.
4
S&P Global Market Intelligence
three outcomes is placing a price 5
S&P Global Platts, "Hydrogen Transportation: moving
on a unit of carbon. molecules a core challenge for H2 market growth", Jan
Continued investment in a combination 21, 2020 https://www.spglobal.com/platts/en/market-
insights/blogs/lng/012120-hydrogen-transport-moving-
of wind, solar, batteries, and gas-fired molecules-a-core-challenge-for-h2-market-growth
power is critical to the enablement of coal
GE as a company is uniquely 6
Pacific Northwest National Laboratory, Comparing
generation retirements while maintaining positioned to play a key role Existing Pipeline Networks with the Potential
Scale of Future US CO2 pipeline networks
grid reliability. In fact, renewables and gas through its scale, breadth, and 7
IPCC Special Report on Carbon Dioxide Capture
power have the capability to quickly make and Storage, Summary for Policymakers, pg 7.
technological depth. We have 8
NPC, Carbon Capture, Use, and Storage
meaningful and long-lasting reductions (CCUS) report, CH 2, pg. 22.
to CO2 emissions in the power sector.
been a key player in the power 9
“Petra Nova Status Update,” August 26, 2020 by NRG
industry since its inception and Energy, Inc https://www.nrg.com/about/newsroom/2020/
petra-nova-status-update.html#:~:text=Given%20
Within the power generation sector, the have a suite of complementary the%20current%20status%20of,online%20
when%20economic%20conditions%20improve
technologies and capabilities to remove technologies including gas-fired
carbon from critical generation equipment
already exist, but still face economic
power with hydrogen and CCUS
headwinds. Increased R&D funding will help capability, onshore and offshore
with cost declines, efficiency improvements, wind, hydro, small modular
and will accelerate the deployment of reactors, battery storage, hybrids
hydrogen and carbon capture solutions
for assets that provide the electric grid
and grid solutions needed for
with the dependable capacity it requires. the energy transformation.

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