2- 25% EXAM -- ( REPEATER BATCH)

ANSWER KEY (13.03.2023 -- MONDAY) -- 720 MARKS

PHYSICS CHEMISTRY BOTANY ZOOLOGY
Q NO KEY Q NO KEY Q NO KEY Q NO KEY Q NO KEY Q NO KEY Q NO KEY Q NO KEY
1 B 36 B 51 C 86 C 101 B 136 C 151 A 186 A
2 A 37 A 52 B 87 A 102 C 137 A 152 B 187 D
3 C 38 A 53 A 88 A 103 B 138 B 153 C 188 A
4 D 39 D 54 B 89 D 104 C 139 D 154 B 189 A
5 C 40 C 55 C 90 A 105 D 140 C 155 A 190 C
6 C 41 D 56 A 91 B 106 C 141 B 156 B 191 C
7 B 42 D 57 D 92 A 107 C 142 D 157 A 192 D
8 A 43 D 58 B 93 D 108 C 143 D 158 B 193 B
9 B 44 C 59 B 94 C 109 B 144 C 159 A 194 D
10 D 45 C 60 C 95 B 110 A 145 C 160 C 195 D
11 C 46 B 61 C 96 A 111 D 146 D 161 D 196 C
12 B 47 B 62 A 97 D 112 C 147 C 162 B 197 B
13 C 48 A 63 A 98 A 113 D 148 A 163 D 198 C
14 A 49 A 64 C 99 A 114 A 149 C 164 A 199 B
15 B 50 B 65 A 100 D 115 C 150 C 165 A 200 D
16 C 66 B 116 D 166 C
17 D 67 C 117 B 167 B
18 B 68 B 118 A 168 D
19 B 69 B 119 C 169 D
20 D 70 D 120 A 170 D
21 A 71 A 121 A 171 C
22 B 72 B 122 A 172 C
23 C 73 A 123 C 173 A
24 B 74 A 124 A 174 D
25 D 75 C 125 B 175 B
26 C 76 A 126 A 176 B
27 C 77 C 127 D 177 A
28 D 78 B 128 A 178 A
29 D 79 C 129 A 179 A
30 B 80 C 130 B 180 D
31 A 81 C 131 C 181 A
32 B 82 C 132 B 182 A
33 C 83 B 133 A 183 A
34 A 84 D 134 A 184 A
35 B 85 B 135 B 185 A
 2-25% TEST (13.03.2023)
PHYSICS SOLUTION
FL  T2 = 5328 k
1. (b) Y = Case , F = W1L = L1− L
AL 8. (a) As the temperature difference, T = 30 C and the
W1L thermal resistance is same for both the cases, so the
Y=
A (L1 − L ) rate of heat flow will also be the same for both the
cases.
Case  F = W2L = L2− L 9. (b) The mass will get detached at the upper extreme
w 2L
Y= position when pan the returns to its mean position.
A (L 2 − L ) At the point, R = mg – m2a = 0
ie
W1L
=
W2L i.e. g = 2a
A (L1 − L ) A (L 2 − L ) g mg  2 k 1 10
a= =  =  = = 5.5 cm
W1 (L2− L) = W2 (L1− L) 2 k  m 180
(W2− W1)L = W2L1− W1L2 10. (d) Vbdb = Vi d
W L − W1L 2 Vb is the volume of body,
L= 2 1
W2 − W1 Vi is the volume of body immersed in water,
mgh db is the density of the body
2. (a) = mL d is the density of the liquid.
2
3
2L 2  3.4  105 Vdb = V  1000 db = 750 kg m–3
h= = = 68 km 4
g 10
11. (c) According to principle of calorimetry
3. (c) Let f’ be the frequency of sound heard at the cliff, Heat lost = Heat gained
vf mLv + mCT = m CT
 f’ = ––––– (I)
v − vs  m  540+ m  1  (100 – 80) = 10  1  (80 – 5)
Now, for the reflected wave, cliff acts as a source,  m = 1.34 g
f ' (v + v s ) Therefore total mass of water at 80 C
 = 2f –––––– (II)
v = (10 + 1.34)g = 11.34g
From (I) and (II) 12. (b) As the source is not moving towards or away from
 v + vs  v
the observer in a straight line, so doppler
2f =  f  2v – 2vs = v + vs or = vs effect will not be observed by the observer.

 v − vs  3
p V p
13. (c) B =  =
4. (d) According to question, P  T4  V  V B
  
 V 
Now for an adiabatic process, P  T  −1
R p R p
 4 Cp 4 3 =  =
So, = 4  = or = R B R 3B
 −1 3 Cv 3
14. (a)
1
5. (c) Energy per unit volume = stress  strain
2
1 oil
=  Y  strain strain 30 cm
2 82 cm
2 80 cm
1  0.06 
= 21010   = 3600 J/m3
2  100 

6. (c) PE =
1
2
1
m2 y 2 and KE = m2 A 2 − y 2
2
( ) Mercury
K.E A −y2 2
 =
P. E y2
oil g hoil + Hg g  h2 = Hg g  h3
7. (b) vrms =
3RT
; oil 0.30 + 13600  0.8 = 13600  0.82
M oil 0.30 = 13600  0.02
T1 = 60 = 333k oil 907 kg m−3 = 0.907  103 kg m−3
MH = 2 Sp. gr. of oil = 0.907
M0 = 32 m1 T2 2000 m1
15. (b) =  = 2  m 2 =
3R  333 m 2 T1 1000 2
(vrms)H = –––––– (I)
2 16. (c) According to Bernoulli’s theorem
3R  T2 p+
1 2
v = constant and Av = constant
(vrms)0 = –––––––– (II)
32 2
If A is minimum  v is maximum and p is minimum.
(I) 3R  333
=
3R  T2
(II) , we get 2 32
 f  
17. (d) Internal energy U = nRT 25. (d) y1 = 8 sin 2t +   A1 = 8
2  4 
n(H2) = 4 f(H2) = 5
y2 = 4 2 sin 2t + 4 2 cos 2t
n(Ar) = 2 f(Ar) = 3
U(total) =
5
2
(4)RT + 3 (2)RT = 13 RT
2
( ) ( )
A2 = 4 2 + 4 2 = 8
2 2

Ratio A1 : A2 = 1 : 1
18. (b) v = a 26. (c)
  A 2 − x 2 = x2 (a) Before they pass
 2   v + v   v + 30   330 + 30 
42 − 32 = 3  f’ =  f = 
 500 =  500  581 Hz
 T   v − vs   v − 20   330 − 20 
 2 
7 = 3 
 T  (b) After they pass

v − v 
 330 − 30 
T=
6 f’’ =  f = 
 500
7  v + vs   330 + 20 
19. (b) PE  (amplitude)2 (Displacement)2 =
300
 500  429 Hz
PE is maximum at maximum distance 350
PE is zero at equilibrium point  T 
PE curve is parabolic 27. (c) Tav− T0 = K  
 t 
20. (d) It is a closed organ pipe
Frequency  =
(2n − 1)v where n = 1, 2, 3, ....
 70 + 60 

 70 − 60 
 − T0 = K  
4  2   5 
According to question < 1250 Hz 65 − T0 = 2K
 2n − 1 60 + 54  60 − 54 
− T0 = K  
 4  v  1250 2  5 
 
(2n − 1)  340  1250 57 − T0 =
6K
4  0.85 5
 (2n − 1) < 12.5 Solving T0 = 45 C
Possible values of n = 1, 2, 3, 4, 5, 6
 number of possible natural frequencies lying below 28. (d) The difference between two harmonics
1250 Hz is 6. 2v
= = 240 − 210 = 30 Hz
21. (a) Change in surface area = 8(r22− r12) 4
= 8(32 10−4− 12 10−4) v 30
Fundamental frequency = = = 15 Hz
= 8 8  10−4 4 2
= 64 10−4 m2 5v
Frequency of fifth harmonic = = 5  15 = 75 Hz
Work done = Change in surface area  surface 4
2 r 2 ( − )g
tension
= 64 10−4 0.025 = 5.024  10−4 0.5 mJ 29. (d) vT =  vT  r2
9 
22. (b) It first accelerates till terminal velocity is attained
whereafter it comes down uniformly as the weight of v r2
= 2  v1 = 4 v
drop is balanced by viscous force of air. v1 4r
23. (c) 80 C 30. (b) W = pV = 1  105 1670 10−6
1 = 167.0 J
Q = 540  4.2 = 2268
10 C 3 U = Q − W
= 2268 − 167.0
2
= 2101 J
70 C F
F  Fv
31. (a) Y = A = = 2
 A  A 
Let  be the junction temperature. Heat flows towards

junction in rods 1 and 2 whereas it flows out of rod 3. 𝑌 𝐴2 
 KA
(80 − ) + KA (70 − ) = KA ( − 10) F=
𝑉
t t t i.e. F A2
80 − + 70 − = − 10 F1A2
160 F24A2
3 = 160  = = 53.3 C
3 F2 = 4F1
24. (b) Case I 
32. (b) = 74 − 22 = 52
1 T T 5 2
= 1− 2  2 =
6 T1 T1 6  = 52  2 = 104 cm = 1.04 m
Case II v =  = 326  1.04
1 (T − 62)  T2 − 62 = 2
= 1− 2
v = 339 m s−1
3 T1 T1 3 33. (c) Y = A sint
Solving T1 = 372 K, T2 = 310 K 2 = A sint
|a| = A2 sint
 18 = 2 2 x = A sin(t −ky)
=3 1
 = 50 rad s−1, k = m−1
2 2 50
T= =
 3 
v= = 50  50 = 2500 m s−1
v k
34. (a) n0 =
2 0 43. (d) V = 400 m s-1
5v
nC = f = 400 Hz
4 C
v
v 5v = = 1m
n0 = nC = f
2 0 4 C
2
2C = 50 = x

0 2 
= = 0 x = path difference
C 5 20
 1  1
20  2 x=  =  = m
0 = = 8 cm 2 2 3 6
5 2T P  r 150  0.01
W T − T2 T 44. (c) P = T = = = 0.75 N / m
35. (b)  = = 1 = 1− 2 r 2 2
Q T1 T1 45. (c) Particle is at x = A at t = 0
373 − 300 x = A cost
=  100 = 19.6%
373 v = −A sint
1 3 1 1
36. (b) Mv e 2 = k BT KE = mv 2 = mA 22 sin2 t
2 2 2 2
3k b T v 2M KE varies parabolically with v.
v e2 = T= e 
M 3k B At t = 0, x = A, KE = 0 at t =
2
T=
(11.2)2  106  2.415  10 −26 = 73.17  103 K x = 0, KE = KEmax
3  1.38  10 − 23 Hence (c) is the answer.
1
37. (a) Efficiency of heat engine is  =
10
46. (b)
(2 m + 1)f0 =
150 3
=
Work done on the system, W = 10 J (2n + 1)f0 550 11
Coefficient of performance of refrigerator  3f0 = 150  f0 = 50 Hz
2 1 −  9 1 The frequencies will be odd multiples of 50 Hz only.
 = Q2/ W = =  =9
W  10 10 Hence, 200 Hz is not possible.
Energy absorbed from reservoir, 47. (b) Incident wave is y = A sin (t − Kx). Reflected wave is
Q2 = W = 9  10 = 90 J traveling in the opposite direction and its equation would
38. (a) For f degree of freedom have been y = A sin (t + Kx) but for the extra phase
f difference  produced by denser medium. Hence
Cv = R
2 reflected wave is
f  y = A sin (t + Kx + )  y = −A sin (t + Kx)
Cp = Cv + R =  + 1 R 48. (a) UPQR = UPR (initial and final states being same)
 2 
PQ being isochoric WPQ = 0
f
+1 QPQ = UPQ = 300 J
Cp f +2 2
= = 2 = = 1+ QR is isobaric
Cv f f f
2 QQR = UQR + WQR
39. (d) TV− 1 = constant 100 = UQR + 4  104 (3  10−3− 2  10−3)
7 100 = UQR + 40
Cp R
7 UQR = 100 − 40 = 60 J
= = 2 = Also UPQR = UPR
CV 5 5
R
2 UPQ + UQR = QPR−WPR
 −1 2/5 2/5 300 + 60
T2  V1 
= 
T1  V2 
 V 
=  
 32V 
 1 
=  
 32 
=
1
4
( )
10 4  3  10 −3 − 2  10 −3 + 
 
= QPR −  1 −3 4 
 = 1−
T2
=
3  2  1 10  3  10  
T1 4   
360 = QPR− (10 + 15)

40. (c) T = 2 QPR = 360 + 25 = 385 J
g
As sand begins to drain the CM of bob slowly goes down
 
49. (a) E = (T4 – T04 ) =  (3T )4 − T 4 = [80T4]
Q1 Q2
and  increases, hence T increases. When fully empty 50. (b) =
CM restores the initial position for which  has to T1 T2
decrease, i.e. T has to decrease. Correct option (c). Q1 Q Q Q
= 2  Q2 = 1 =
41. (d) The combination is 600 300 2 2
3 Q Q
(k || 2k) series 3k 3k series 3k  k Work done = Q1 − Q2 = Q − =
2 2 2
42. (d) Comparing with the standard equation
 CHEMISTRY – 2ND 25%
51. (c)
13.6
𝐸𝑛 = − eV
𝑛2
For second excited state 𝑛 = 3,
13.6
𝐸3 = − = −1.51eV
9
52. (b)
A part of energy of photon is used up to do work against coulombic forces of attractions.
53. (a)
The rate of effusion of He and CH4
𝑟He 𝑀CH4 16
=√ =√ =2∶1
𝑟CH4 𝑀He 4
If 4 : 1 mixture of He and CH4 contained in a vessel, then the composition of mixture of He and CH4
effusing out initially is 8 : 1.
54. (b)
The value of van der Waals’ constant ‘𝑎’ increases in the same order as the critical temperature. Here,
the value of 𝑎 is highest of 𝑄 hence, gas 𝑄 has the highest critical temperature.
55. (c)
According to Graham’s law the rate of diffusion is inversely proportional to square root of molecular
weight and density.
1 1
𝑟∝ and 𝑟 ∝
√𝑑 √𝑀
56. (a)
The state of hybridization of carbon in fullerene is 𝑠𝑝2 hybridised
57. (d)
H3 BO3 has layer structure with H-bonding.

58. (b)
Cl2 + H2 O → 2HCl + [O] nascent oxygen
59. (b)
60. (c)
Although each possesses nearly same strength.
61. (c)
The end product of the hydrolysis of XeF6 is XeO3
H2O H2O H2O
XeF6−2HF XeOF4−2HF XeO2F2−2HFXeO3
62. (a)
−𝑊irr. = 𝑃ext. (𝑉2 − 𝑉1 )
= 1 × (15 − 3) = 12 litre atm
12 × 1.987 × 4.184
=
0.0821
 = 1.215 × 103 J
63. (a)
∆𝐻𝑣
∆𝑆 =
𝑇
∆𝐻 = 186.5 kJ
𝑇 = 373 K
186.5
∴ ∆𝑆 = = 0.5 kJ K −1 mol−1
373
64. (c)
1 1
Required equation is 2 H2 + 2 Cl2 → HCl
∆𝐻 = ∑ BE(products) − ∑ BE(reactants)
1 1
= BE(HCl) − [ BE(H2 ) + BE(Cl2 )]
2 2
1 1
= −103 − [ (−104) + (−58)]
2 2
= −103 − (−52 − 29) = −22 kcal
65. (a)
∆𝐻 = 18500 = ∆𝑈 + ∆𝑛𝑅𝑇
or 18500 = ∆𝑈 + (−1) × 2 × 298
or ∆𝑈 = 19096 cal
66. (b)
The correct option is C – 29.4 kJ
(i)BaCl2(s)→BaCl2(aq);ΔH1=−20.6kJ
(ii)BaCl22H2O(s)→BaCl2(aq);ΔH2=8.8kJ
Subtracting (ii) from (i) we getBaCl2(s)→BaCl2.2H2O(s);ΔH1−ΔH2=−29.4kJ
67. (c)
68. (b)
Teflon is a polymer of CF2 =CF2 .
69. (b)
When a diacid is condensed with dialcohol, the polymer obtained contains ester linkage.

70. (d)
Calgon, permutit and Na2 CO3 are used for the removal of hardness of water.
71. (a)
10 vol. H2 O2 means that 1 mL H2 O2 gives 10 mL O2 ; thus, 50 mL H2 O2 will give 500 mL O2 .
72. (b)
73. (a)
74. (a)
75. (c)
76. (a)
77. (c)
78. (b)
79. (c)
80. (c)

81. (c)

82. (c)

83. (b)

84. (d)

85. (b)

86. (c)
ℎ
Δ𝑢 ∙ ∆𝑥 =
4𝜋𝑚
6.626 × 10−34
∆𝑢 =
4 × 3.14 × 9.11 × 10−31 × 0.1 × 10−10
= 5.8 × 106 m/sec
87. (a)

Four quantum numbers are

1
𝑛 = 4, 𝑙 = 0, 𝑚 = 0, 𝑠 = +
2
𝑛 = 4 indicates that the valence electron is present in 4th shell (4th period), 𝑙 = 0 indicates that the
valence electron is present in 𝑠-subshell. 𝑚 = 0 indicates that the valence electron is present in
1
orbital of 𝑠-subshell. 𝑠 = + indicates that the spining of electron in orbital is clockwise. So, from the
2
above discussion it is clear that valence electron is present in 4𝑠 subshell as 4𝑠1 . 𝑠1 indicates that the
element is present in IA group. So, the element present in 4th period and IA group is potassium (K).
88. (a)
For shortest 𝜆 of Lyman series,
1 1 1
𝑛1 = 1 and 𝑛2 = ∞; = 𝑅H [ 2 − 2 ]
𝜆 𝑛1 𝑛2
ℎ𝑐
Because Δ𝐸 = 𝜆 is maximum when 𝜆 is small
Thus, Δ𝐸 = 𝐸∞ − 𝐸1
89. (d)
At very low pressure, Boyle’s plot is represented as

90. (a)
Maximum deviations are noticed at low 𝑇 and high 𝑃.
91. (b)
92. (a)
1
C (graphite)+ O2 (g) → CO(g)
2
1 1
∆𝑛𝑔 = 1 − 2 = 2
∆𝐻 = ∆𝐸 + ∆𝑛𝑔 𝑅𝑇
∆𝐸 = ∆𝐸 − ∆𝑛𝑔 𝑅𝑇
1
= −26.4 − × 0.002 × 298
2
= −26.7 kcal
93. (d)
Fe2 O3 + 3CO → 2Fe + 3CO2 ;
∆𝐻 = −26.8 kJ
2FeO + 2CO → 2Fe + 2C; ∆𝐻 = −33.0 kJ
一 一 一 一 +

Fe2 O3 + CO → 2FeO + CO2 ; ∆𝐻 = +6.2 kJ

94. (c)

Bakelite is a thermosetting plastic formed by reaction of phenol with HCHOin the presence of
conc.H2 SO4.
 It is thus cross-linked polymer,condensation taking place at o- and p- positions.
Thus, HCHO.
95. (b)
Catalyst
CO + H2 + H2 O → CO2 + 2H2
Water gas Steam
96. (a)
Ca ∶ C2
D2 O
OD ∶ D → C2 D2 + Ca (OD)2
OD ∶ D
97. (d)
Both the side chains will be oxidised by strong oxidant KMnO4/H+.
98. (a)

99. (a)

100. (d)