XIII (ABCD) INORGANIC CHEMISTRY REVIEW TEST-6

P A P ER - 1

PART-A
Select the correct alternative(s). (One or More than one is/are correct) [15 × 5 = 75]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 Select the correct statement

(A) [Fe(NO)(H2O)5]SO4 is coloured because of d–d transition
(B) [Fe(NO)(H2O)5]SO4 is coloured because of charge transfer
(C) [Fe(NO)(H2O)5]SO4 is brown ring
(D) [Fe(NO)(H2O)5]SO4 is high spin complex

Q.212/13 Saturated solution of SO2 is heated at 150°C in a closed container. The product obtained is treated
with BaCl2 solution. What is/are the most suitable observation(s)
(A) No ppt. (B) white turbidity
(C) evolution of SO2 (D*) The turbidity becomes white ppt

Q3. Which reaction is(are) possible

(A) MgCl2 + NaNO3  (B) BaSO4 + HCl 
(C) ZnSO4 + BaS  (D) BaCO3 + CH3COOH 
Q.4 Which of the following complex are coloured
(A) MnO4– (B) CrO42– (C) Cr2O72– (D) MnO42–

Q.513 Which of the following statements is/are true

(A*) In Ferrocyanide ion, the effective atomic number is 36
(B*) Chelating ligands are atleast bidentate ligands
(C*) [CrCl 2 (CN) 2 ( NH3 ) 2 ]– and [CrCl3(NH3)3] both have d2sp3 hybridisation
(D*) As the number of rings in complex increases, stability of complex (chelate) also increases

Q.6 Select the correct statement

(A) Resonance energy is temperature dependent
(B) 4d & 5d series metals forms low spin complex
(C) Cisplatin express geometrical isomerism
(D) Benzene reacts with CrCl3 and forms organometallic compound

Q.713 The correct order of energies of d-orbitals of metal ion in a square planar complex is
(A) dxy = dyz = dzx > d =d (B) d = d 2 > dxy = dyz = dzx
x 2  y2 z2 x 2  y2 z

(C) d >d > dxy > dyz = dzx (D*) d > dxy > d > dzx = dyz
x 2  y2 z2 x 2  y2 z2

P A P ER - 2
 PART-B
MATCH THE COLUMN [3 × 10 = 30]
There is NEGATIVE marking. 0.5 Marks will be deducted for each wrong match.

INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
Q.112/13 List I List II
(A) Colourless gas evolved on addition (P) S2O 32 –
of dil. H2SO4
(B) White ppt. on addition of AgNO3 (Q) S2–
(C) Black ppt. obtained when HgCl2 is added (R) NO 2–
little amount
(D) The ppt. obtained on addition of AgNO3 (S) CH 3CO 2–
followed by NH3 solution
[Ans. (A) P,Q,S; (B) P,R,S; (C) P, Q; (D) Q]

PART-C
SUBJECTIVE: [5 × 10 = 50]
There is NO NEGATIVE marking.

Q1.

What is the Formula weight of Y. [5]