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CHEMICAL ENGINEERING DEPARTMENT

Semester: 5th (2018 session) Type of exam: mid-term

Subject name: Chemical Reaction Engineering Teacher’s name: Dr. Faheem sb


Q 1:

The Pyrolysis of Acetaldehyde (CH3CHO) has been proposed to involve the following reactions:

CH3CHO K1 CH3 + CHO

CH3 + CH3CHO K2 CH4 + CH3CO

CH3CO K3 CH3 +CO

2CH3 K4 C 2H 6

Pseudo steady state Assumption can be applied to the reaction intermediates (that is CH3, CHO
and CH3CO). Other species in the reaction mechanism (CH3CHO, CH4, CO and C2H6) are stable
molecules. Determine the rate of methane (CH4) formation in terms of stable molecules.

Q 2:

Derive analytical expression for testing the suitability of first order, uni-molecular, reversible
kinetics (A K1 R, R K2 A ) using integral method of Analysis

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