Total No.

of Printed Pages-11
22E-CHEM

2022

CHEMISTRY

( Theory)

Full Marks: 70
Pass Marks:21
Time: 3 hours

The figures in the margin indicate fiull marks for the questions

ALLOTMENT OF MARKS

1x8 8
Q. No. 1 carries 1 mark each

2x10 20
Q. No. 2 carries 2 marks each

3x9 2 7
Q. No. 3 carries 3 marks each

5x3 155
Q. No. 4 carries 5 marks each
Total 70

[ Contd.
/159
 2)
1. Answer the
following questions (any eight) 1x8-8

(a HoW many oxygen atoms are present in 2 moles of

oxygen gas?

(b) What is the value of angular momentum for nth

Bohr orbit?

(c) What is the oxidation state of K in

KO2?
KOT K 7{R0 fTA?

(d) Which of the following molecules shows geometrical

isomerism?

But-1-ene Or/Y7 But-2-ene

(e)Why are alkali metals not found freely in nature?

T9R AyT f TTPTE (TT TT ?

Write the IUPAC name of the following compound

TH SID IUPAC ATH fT:
OHC-CH2-CH2COOH
/159
 3)
electron-deficient covalent
(gGive one example of
hydride.

heat of a gas if the

specific
(h) What is the impact on
from its original
volume of the gas is reduced to half
volume?

each B atom in
What is the hybridization state of
BH molecule?

B2H6 afGTDI B °AI FRP YTTDI ?

the following in increasing order of their

G) Arrange
acidity

BO3, InO3 AlOs

Write two examples of greenhouse gases.

(k)

( State Hückel's rule of aromaticity.

/159 Contd.
 4)
2. Answer the
following questions (any ten): 2x10=20

I recAT44 FRI (R ICAI FRO):

(a) Why does He2 molecule not exist? 2
He2 aOY TNTCT?

(b) Define ionization

enthalpy. Why is the ionization
enthalpy of nitrogen greater than oxygen although the
ionization enthalpy increases from left to
a period? right in
1+1-2

(c) What is the cause of deviation of real gases from

ideal behaviour?
2

(d) Arrange the following in increasing order 1+1-2

(i) Br, CI, I, F

(Electron gain enthalpy/ IR1 4T)
(ii) Al2O3, SiO2, Na20, MgO
(Acidity/nron)
(e) What property of water makes it useful
as a
solvent? Why does H202 behave as universal
bleaching agent?P
1+12

/159
 5)

Why is acetylene acidic in nature? 2

What are the conditions in terms of entropy and

g)
of endothermic reaction to be
temperature an

spontaneous? 1+1-2

(n) Define electron affinity. Why is electron affinity of

CI more than F although electron affinity decreases
down the group? 1+1-2

, C17 RA YPs F U aR ?

A container contains 2 L of milk. Calculate the volume

of the milk in m3. 2
sD T 2L MTRI STTARA m 1

0) What are the significances of van der Waals'

constants a and b? 1+1-2

(k)The pH of a solution at 25 C is 2. If the pH is to

be doubled, then what will be the hydronium ion
concentration? 2
25 c o T 40 z pH A 2. gfoNT pH T 0 T

/159 Contd.
 6)
Why is CO more dangerous than CO2? 2

m) Describe one method of removal of permanent

hardness of water. 2

(n) What is the effect of temperature on equilibrium for

the following reaction?
2

N2g)+3H2(g)> 2NH3(g), AH =
-92.5 kcal mol

3. Answer the
following questions (any nine): 3x9-27

e fI SescaT74 fT ( CIAI T)

(a) What do you mean by limiting reagent? Calculate

the maximum amount of water that can be formed
when 3-0 g of H2 reacts with 29.0 g of
O2.1+2-3
ifA fRT 3 Z? 3-0 g Ha 29-0 g Oa O AI

(b) What is inorganic benzene? How can it be prepared?

1+2-3

/159
 7)
emitted when
c) Calculate the wavelength of the radiation
transition
in a hydrogen atom undergoes
a
an electron
ground state. 3
from fourth energy level to the

of ZSM-5. 1+2-3
What zeolites? Give two uses
(d) are

(e) Define hybridization. Suggest the structure of TeCl4

in the light of hybridization concept. 1+2-3

for detection of
Write the chemical reactions involved
test. 3
nitrogen in an organic compound by Lassaigne's

From kinetic gas equation, show that the total kinetic

(g)
energy of 1 mole of
an ideal gas is RT. 3

3TRT.

(h) What is a polar covalent bond? Why is NH3 more polar

than NFa? 1+2-3

/159 Contd.
 8)
A person inhales 640 g of O2 per day.
O2 is used If
1or
converting sucrose
how much sucrose is (C12Ha2011)
into CO2 and H20,
consumed by the body per day
and what will be the heat
evolved? Given, AcH° for
sucrose -5645 kJ mol
=

3
7TR CaAT 640 g
7I zA cTCbRfAfA O2
O
(C12H220i) CO2 7FHO fAaEa afNt a

HIC,
AcH =-5645 kJ mol.

Balance the following redox reaction: 3

MnO aq) + Br" (aq) > Mn* (ag)+ Br2 (lig)

(k) What happens when

(i) Mg is burnt in air;

Mg
(ii) quicklime is heated with silica,

ii) chlorine reacts with slaked lime?

1+1+1-3

( Discuss the mechanism involved in

Markovnikov's
rule.
3

/159
 9)
acid rain.
3
(m) Write a short note on

order of their
(rn) (i) Arrange the following in increasing 1
stability

CH3, (CHgla C, CH3 CH2, (CH3h CH

stabilized
() Why is carboxylate ion more resonance

acid? 2
than the corresponding carboxylic

5x3-15
4. Answer the following questions (any three):

is the aqueous solution of salt of strong acid

a
(a) Why of a 0-1 N
and strong base neutral? Calculate the pH
solution of acetic acid. Given, Ka for acetic
acid at
25 °C is 1-8x10-5 2+3-5

pH Aa I A , 25 °c O g6ib q g
9 7
I C Ka =1.8x10-.

Draw the molecular orbital energy level diagram

for
(b)
the magnetic property of O2
O2 molecule. What is
molecule? Arrange the following in increasing order
of bond length 3+1+1-=5

O2. O2, O

/159 Contd.
 10)
(C)State Pauli's exclusion principle and Hund's rule
of maximum
multiplicity. Write the electronic
configuration of Cr and Cu.
Arrange the followin8
orbitals in
increasing order of their energy
1+1+2+1=5

6s, 5d, 4f, 6p

(d) Complete the following reactions 1x5-5

(i) CHgl+ Na Dry ether

OH
(il) CH3-CH2-CH-CH3 Conc. HSO,
373 K

(tüi) CH-CH=CH2 O3/CH2Cl

2) Zn-H20 ?

iv) +Cl2 FeCl3 >?

(v) +Conc. HNO Conc. HSO.

/159
 11
(eDefine standard enthalpy of formation. Calculate the
standard enthalpy of formation of ethane from the
given data: 1+4-5

C(graphite) +O2 g) > CO2g); A,H° = -394 kJ mol

H2g+02g)>H,O0; 4,H = -286 kJ mol

CaH)+O2g)>20cOag) +3H,00; 4,H° = -1560 kJ mol

22C
/159