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Problem Set on Enthalpy

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1. Given:
(a) 2NF3(g) + 2NO N2F4(g) + 2ONF(g) ΔH= -82.9 kJ
(b) NO(g) + ½ F2(g) ONF(g) ΔH= -156.9 kJ
(c) Cu(s) + F2(g) CuF2(s) ΔH= -531.0 kJ
Calculate the value of ΔH for the reaction.
2NF3(g) + Cu(s) N2F4(g) + CuF2(s)
2. Given:

(a) OSCl2(l) + H2O(l) SO2(g) + 2HCl (g) ΔH= +10.3 kJ


(b) PCl3(l) + ½ O2 (g) OPCl3(l) ΔH= -325.1 kJ
(c) P(s) + 3/2 Cl2(g) PCl3(l) ΔH= -306.7 kJ
(d) 4HCl(g) + O2(g) 2Cl2(g) + 2H2O(l) ΔH= -202.6 kJ
Calculate the value of ΔH for the reaction:
2P(s) + 2SO2(g) + 5Cl2(g) 2OSCl2(l) + 2OPCl3(l)

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