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Estimatethespin-onlymagneticmomentfor(Re(CN)6]and[MnCb]?

b.[NiCk(PPh›CH¿Ph):]isareddiamagneticcomplex.Onheatingto387Kfor2
hours,thecomplexundergoesastructuralchange.Thecolourbecomesblue-green
andthemagneticmomentincreasesto3.18BMat295K.Suggestanexplanation
fortheseobservations.

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Expert Answer

Setp 1

a. To estimate the spin-only magnetic moment for [Re(CN)6] and [MnCl], we need to determine the
number of unpaired electrons in each complex.

[Re(CN)6] :

Re has an atomic number of 75, and its electronic configuration is .[Xe]4f 145d 56s2. SinceCN −

Since CN^- is a strong-field ligand, it causes pairing of the 5d electrons, resulting in all the electrons
being paired. Therefore, there are no unpaired electrons, and the spin-only magnetic moment for
[Re(CN)6] is 0.

[MnCl]:

Mn has an atomic number of 25, and its electronic configuration is. [Ar]3d 54s2.

Similar to [Re(CN)6], the chloride ligand (Cl^-) is a strong-field ligand that causes pairing of the 3d
electrons. Thus, all the electrons in [MnCl] are paired, and the spin-only magnetic moment is 0.
Explanation:

Setp 2

b. The observed color change and increase in magnetic moment for [NiCl2(PPh!CH!Ph) 2]

upon heating can be explained by a change in the coordination geometry and the presence of
unpaired electrons.

Before heating, [NiCl2(PPh!CH!Ph) 2]

diamagnetic complex, indicating that all the electrons are paired, resulting in a net magnetic
moment of 0.

Upon heating, the complex undergoes a structural change. The new coordination geometry
formed at higher temperature likely leads to a distortion or weakening of the ligand field. As a
result, some of the paired electrons in the d orbitals of nickel may become unpaired, leading to the
observed increase in the magnetic moment.

The presence of unpaired electrons in the heated complex contributes to its paramagnetic
behavior, leading to a nonzero magnetic moment. The measured magnetic moment of 3.18 BM at
295 K indicates the presence of unpaired electrons.
Explanation:

The color change from red to blue-green is also indicative of a change in the electronic structure of
the complex. The absorption of certain wavelengths of light, which corresponds to the visible
spectrum, results in the observed color change.

finalAnswer
Overall, the structural change and weakening of the ligand field upon heating cause the complex
to undergo a transition from a diamagnetic state to a paramagnetic state, resulting in the observed
color change and increase in the magnetic moment.