Liquid GMS Compositions

Ratio 5/3/3 UOM KCl MgCl2.6H2O CaCl2.2H2O Total

100 fold g/L 37.300 61.000 44.100 142.400
1 fold g/L 0.373 0.610 0.441 1.424
200 fold g/L 74.600 122.000 88.200 284.800
Water (L) 15 g 1,119.000 1,830.000 1,323.000 4,272.000

Solubility base on literature

UOM KCl MgCl2 CaCl2
Solubility g/L 355.000 543.000 745.000
Water (ml.) 200 g 71.000 108.600 149.000

Usage
GMS Conc Batch size GMS usage
(fold) (m3) (L)
1.000 5.000
2.000 10.000
5.000 25.000
200
10.000 50.000
15.000 75.000
20.000 100.000

GMS solution 200 fold

Composition Grand
Vol (m3) UOM KCl MgCl2.6H2O CaCl2.2H2O Total Total
1 kg 74.600 122.000 88.200 284.800 1,284.80
2,605.386 kg 194,362 317,857 229,795 742,014 3,347,400.00
Remark: Chemical consumption for 1,000,000 kg GMS base on solid form.

KCl 74.600 g/L 1.001 mol/L K 1.001

MgCl2.6H2O 122.000 g/L 0.600 mol/L Mg 0.600
CaCl2.2H2O 88.200 g/L 0.600 mol/L Ca 0.600
Total 284.800 g/L
Water 1,000.000 gram
Grand total 1,284.800 gram

5/3/3/ Dried GMS ratio: Calculate % Element

K Mg Ca
Ingredient Mixture (g)
(g) (%) (g) (%) (g)
KCl 74.600 39.124 13.737 0.000 0.000 0.000
MgCl2.6H2O 122.000 0.000 0.000 14.585 5.121 0.000
CaCl2.2H2O 88.200 0.000 0.000 0.000 0.000 24.045
Total 284.800 39.124 13.737 14.585 5.121 24.045

Ingredient Mixture (g) Ratio

KCl 26.194 1.0000

MgCl2.6H2O 42.837 1.6354
CaCl2.2H2O 30.969 1.1823
Total 100.000 3.8177

GMS 70 % portion
MD 30 % portion Dried MD 28.5 % portion MC in MD
MC in MD 5%
MC in FG 4%

Compositon of GMS+Malto

K Mg Ca Cl Water Malto (DS)

GMS 9.62 3.58 5.91 29.63 21.26 0.00
Malto 0.00 0.00 0.00 0.00 1.50 28.50
Add MC 0.00 0.00 0.00 0.00 2.60 0.00
Total 9.62 3.58 5.91 29.63 25.36 28.50
As 100% 9.37 3.49 5.76 28.88 24.71 27.78
% Ion 19.73 7.35 12.12 60.79
 Soluble screen Experiment
Dired solid Wt. in 200ml.
Chemical UOM Starting Wt.
Soluble part insoluble part Total
KCl g 71.0 64.23 5.88 70.11
MgCl2.6H2O g 108.6 113.99 0.85 114.84
CaCl2.2H2O g 149.0 165.13 1.39 166.52
Remark: All solution keep at room temp (21.5'C) before filter

Product Chemicals
Sp.Gr.
(g) (g) (ppm)
1.1158 22.17 %w/w 1,284.80 284.800 221,669
1.1158 22.17 %w/w 8.254 1.830 1,424

mol/L 39.1238406 g/L 30,451 ppm Chloride 1.001

mol/L 14.585391 g/L 11,352 ppm Chloride 1.200
mol/L 24.0451643 g/L 18,715 ppm Chloride 1.200
77.754 g/L
Total Chloride

Ca Chloride H2O
Ingredient
(%) (g) (%) (g) (%)
0.000 35.476 12.457 0.000 0.000 KCl
0.000 42.551 14.941 64.864 22.775 MgCl2.6H2O
 8.443 42.537 14.936 21.618 7.590 CaCl2.2H2O
8.443 120.564 42.333 86.482 30.366 Total

1.5 % portion

Proposed Specification for system G 2000 + Maltodextrin

Total (%) Fomulation: GMS 70 %

70.00 Maltodextrin 30 %
30.00
2.60 Element composition (%, +/- 15%)):
102.60
100.00 K Mg Ca
100.00 Target (Cal) 19.73 7.35 12.12
Min 16.77 6.25 10.31
Max 22.69 8.46 13.94

Total water (w/w)

Target (Cal) 24.71 %

Max 30.13 %

Maltodextrin (w/w, +/- 5%)

Target (Cal) 27.78 %

Min 26.39 %
Max 29.17 %
 Soluble part Weight in
Variance in 1000 ml. 200-fold
-0.89 321.2 74.600
6.24 570.0 122.000
17.52 825.7 88.200

% K Mg Ca
Target 3.05 1.14 1.87
Min (85%) 2.74 1.02 1.68
Max (115%) 3.35 1.25 2.06

mol/L 35.476 g/L H2O 0.000 mol/L 0

mol/L 42.551 g/L H2O 3.601 mol/L 64.8656417
mol/L 42.537 g/L H2O 1.200 mol/L 21.6168655
120.564 g/L 86.483
Total Chloride 9.38 %
93,839 ppm

Chloride Dried Ingredient

Mixture (g)
(g) % in Mixture % in Ingredient % Chloride Useage (g)
261.938 124.565 12.457 47.555 47.555 261.938
428.371 149.405 14.941 34.878 34.878 428.371
 309.691 149.358 14.936 48.228 48.228 309.691
1,000.000 423.328 42.333 - - 1,000.000

Maltodextrin

Cl Total
60.79 100.00
51.67 -
69.91 -
 Cl
9.38
8.45
10.32

g/L
g/L
g/L
g/L
5/3/3 Gen 1 V2 GMS

Chemicals MW
Calcium (Ca) 40.078
Magnesium ( 24.305
Potassium (K) 39.0983
Chorine (Cl) 35.453
Sulphate 96.063
H2O 18.015

Mass of K
Chemicals MW Mole Weight
K (g) % ppm
KCl 74.5513 5 372.757 195.49 52.4 524,448
MgSO4.7H2O 246.47456 3 739.424 0.00 0.0 0
Ca(Lactate)2 308.288 3 924.864 0.00 0.0 0
Total 2,037.044 195.49 9.60 95,968
Mass of Mg Mass of Ca Mass of Cl
Mg (g) % ppm Ca (g) % ppm (g)
0.00 0.00 0 0.00 0.00 0 177.27
72.92 9.86 98,611 0.00 0.00 0 0.00
0.00 0.00 0 120.23 13.00 130,002 0.00
72.92 3.58 35,795 120.23 5.90 59,024 177.27
 Cl Mass of SO4 Mass of H2O
% ppm SO4 (g) % ppm H2O (g) %
47.56 475,552 0.00 0.00 0 0.00 0.00
0.00 0 288.19 38.97 389,747 378.3 51.16
0.00 0 0.00 0.00 0 270.2 29.22
8.70 87,021 288.19 14.15 141,474 648.55 31.84
H2O Mass of Lactate Total
ppm Lactate (g) % ppm % ppm
0 0.00 0.00 0 100.00 1,000,000
511,643 0.00 0.00 0 100.00 1,000,000
292,183 534.41 57.78 577,825 100.00 1,000,010
318,378 534.41 26.23 262,346 100.00 1,000,004
GMS Mass Balance

Vacuum Feeder

KCl 196.33 kg/batch

MgCl2.6H2O 321.07 kg/batch
CaCl2.2H2O 232.12 kg/batch

3.29 m3/batch Mixing Tank 1 miron Filter

80% Working Vol. 2,631.70 kg/batch

3,381.21 kg/batch

Pump

1,521.55 kg/hr

Buffer Tank 1.23 m3/batch

3 hr/batch

507.18 kg/hr

Pump

507.18 kg/hr

1 miron Filter

507.18 kg/hr

0.22 micron Fllter

507.18 kg/hr
Filling Machine

507.18 kg/hr

GMS product
507.18 kg/hr
20 hr/day
10,143.64 kg/day
330 day/year
3,347,400.00 kg/year
RO water
2,631.70 kg/batch
8 hr/batch
Dired GMS Gen 2

w/o Buking agent

Packing size (kg)
Ingredient UOM 5 10 20 50 100
KCl (kg) 1.310 2.619 5.239 13.097 26.194
CaCl2.2H2O (kg) 1.548 3.097 6.194 15.485 30.969
MgCl2.6H2O (kg) 2.142 4.284 8.567 21.419 42.837
Total weight (kg) 5.000 10.000 20.000 50.000 100.000

w/ Buking agent @ ratio 95 %w/w

Packing size (kg)
Ingredient UOM 5 10 20 50 100
KCl (kg) 0.065 0.131 0.262 0.655 1.310
CaCl2.2H2O (kg) 0.077 0.155 0.310 0.774 1.548
MgCl2.6H2O (kg) 0.107 0.214 0.428 1.071 2.142
Bulking Agent (kg) 4.750 9.500 19.000 47.500 95.000
Total weight (kg) 5.000 10.000 20.000 50.000 100.000

Filling Range (kg) Turn dowm

Ingredient Min Max Ratio
KCl 0.131 26.194 200
MgCl2.6H2O 0.214 42.837 200
CaCl2.2H2O 0.155 30.969 200
Bulking Agent 9.500 95.000 10
 Recipe # 1 (5 kg bag with 3 ingredients)

Ingredient kg Density (g/L)

Density (g/L) A 1.310 610
LBD PBD B 1.548 570
450 760 605 C 2.142 760
420 740 580 Total weight 5.000 -
590 970 780
420 590 505

Recipe # 3 (5 kg bag with 4 ingredients)

Density (g/L) Ingredient kg Density (g/L)

LBD PBD A 0.065 610
450 760 B 0.077 570
420 740 C 0.107 760
590 970 D 4.750 500
420 590 Total weight 5.000 -
Recipe # 2 (10 kg bag with 3 ingredients)

Ingredient kg Density (g/L) Volumn (L)

A 2.619 610 4.29
B 3.097 570 5.43
C 4.284 760 5.64
Total weight 10.000 -

Recipe # 4 (10 kg bag with 4 ingredients)

Ingredient kg Density (g/L) Volumn (L)

A 0.131 610 0.21
B 0.155 570 0.27
C 0.214 760 0.28
D 9.500 500 19.00
Total weight 10.000 -
Gen.2 5/3/3 GMS (normal)
MW Mole
Ingredient Mixture (g)
(g/mol) Molecule K Mg Ca
KCl 261.938 74.551 3.514 3.514 0.000 0.000
MgCl2.6H2O 428.371 203.300 2.107 0.000 2.107 0.000
CaCl2.2H2O 309.691 147.015 2.107 0.000 0.000 2.107
Total 1,000.000 - 3.514 2.107 2.107
Ratio - - 5.0 3.0 3.0

Gen.2 5/3/3 GMS (Anh starting material)

MW Mole
Ingredient Mixture (g)
(g/mol) Molecule K Mg Ca
KCl 261.938 74.551 3.514 3.514 0.000 0.000
MgCl2 200.618 95.211 2.107 0.000 2.107 0.000
CaCl2 233.783 110.980 2.107 0.000 0.000 2.107
Total 696.339 - 3.514 2.107 2.107
Ratio - - 5.0 3.0 3.0

Gen.2 5/3/3 GMS (Anh starting material, Grant e-mail 18/03/21 03:20)
MW Mole
Ingredient Mixture (g)
(g/mol) Molecule K Mg Ca
KCl 373.000 74.551 5.003 5.003 0.000 0.000
MgCl2 286.000 95.211 3.004 0.000 3.004 0.000
CaCl2 333.000 110.980 3.001 0.000 0.000 3.001
Total 992.000 - 5.003 3.004 3.001
Ratio - - 5.0 3.0 3.0

Gen.2 5/3/3 GMS (with MgCl2.6H2O. Grant e-mail 18/03/21 23:15)

MW Mole
Ingredient Mixture (g)
(g/mol) Molecule K Mg Ca
KCl 373.000 74.551 5.003 5.003 0.000 0.000
MgCl2.6H2O 610.000 203.300 3.000 0.000 3.000 0.000
CaCl2 333.000 110.980 3.001 0.000 0.000 3.001
Total 1,316.000 - 5.003 3.000 3.001
Ratio - - 5.0 3.0 3.0
 Cl H2O
3.514 0.000
4.214 12.643
4.213 4.213
11.941 16.856
17.0 24.0

Cl
3.514
4.214
4.213
11.941
17.0

Cl
5.003
6.008
6.001
17.012
17.0

Cl
5.003
6.001
6.001
17.005
17.0