KENDRIYA VIDYALAYA SANGATHAN, JAMMU REGION

SAMPLE PAPER SET : 1

CLASS - XII SUBJECT: CHEMISTRY
TIME :3H MM: 70

MARKING SCHEME

Q.N. ANSWER MARKS

1 C 1
2 B 1
3 B 1
4 C 1
5 D 1
6 B 1
7 A 1
8 C 1
9 A 1
10 B 1
11 C 1
12 A 1
13 D 1
14 A 1
15 C 1
16 B 1
17 B 1
18 A 1
19 1/2

1/2
1
20 a. Due to formation of carbocation. 1
b. Can’t form Hydrogen bonding. 1
OR
A = CH3CH2Cl 1
B = CH3CH2CN 1
21 Geometrical isomers 1+1
22 In which heat produced by combustion is converted into electrical 1
energy.

1
23 (i) Rate of reaction = 1.8 x 10 MolL s
-4 -1 -1
1
(ii) Rate of disappearance of Hydrogen = 5.4 x 10-4 MolL-1s-1 1
24 1
(a)
 1
(b)
25 a. Butene-2 1
b. 1
2-Ethoxybutane
OR 1
(a)
(b) 1
Sandmeyer’s reaction
26 1

1
27 If amino acid contains more amino group than carboxylic group - 1
basic
If amino acid contains more carboxylic group than amino group –
acidic
If amino acid contains equal number of amino and carboxylic groups 1
– neutral.
Essential Amino acids – which can’t be synthesized inside our body. 1
Ex - Histidine
Non-essential amino acids – which can be synthesized inside our
1
body. Ex – Glycine
1
OR
a)DNA -- i) It has double helix structure.
ii) It has deoxyribose sugar 1
RNA --- I) It has single helix structure.
ii) It has ribose sugar.
b) In nucleotide there is present phosphate group along with
nucleoside.

28. (a) Pent-2-enal 1

(b) (i) Propanone gives Haloform test. 1
(ii) Acetophenone gives haloform test. 1
29 a. sp3d2 1
b. Octahedral 1
c. 4.8BM 1
30 a. Lone pair of electrons are involved in resonance. 1
b. Due to formation of anilinium ion. 1
c. Methylamine can form hydrogen bonding in water. 1
d. Due to formation of adduct with AlCl3. 1
OR
a) NH3 , C3H7NH2 , (CH3)2NC2H5 , (CH3)3N
b) Aniline , p-Amino phenol, Ammonia, Ethanamine
31. a. Blood cells swells due to endomosis. 1
b. Diffusion - Movement of solute from higher to lower 1
concentration.
Osmosis – Movement of solvent particles from its higher to 1
lower concentration through semi-permeable membrane.
c. Two solutions having same osmotic pressure. 1
OR
Blood pressure becomes high. 1
32. a. 15% 1
b. Fermentation 1
c. Cost goes to down. 2
OR
Any suitable points 2
33. (i) Zinc to copper 1

(ii) Because no ionic species is present during the reaction. 1

1
iii)
= 1

1
OR log Kc = 0.5
34.

1+1

(A) = (B) =
b. 1
c. 1
d. 1
OR
(a) (i) Suitable reason 1
(ii) Suitable reason 1
1
(b) (i)
1
(ii)
1
(c)
35. a. No absorption of visible light as these species has f0 and f7
configuration. 1
b. As it has 5 unpaired electrons. 1
c. It shows disproprotionation reaction. 1
1
d.
1
e.
OR
a. It attains d5 configuration. 1
b. Due to variation in their configuration and size. 1
c. Oxygen can form multiple bonds. 1
d. Actinoid contraction is more than lanthanoid. 1
Actinoids are radio-active. 1