MARKING SCHEME

Q. Solutions/ Answers Value

Points

1. c 1

2. b 1

3. d 1

4. c 1

5. c 1

6. c 1

7. b 1

8. b 1

9. a 1

10 a 1
.

11 c 1
.

12 b 1
.

13 c 1
.

14 d 1
.

15 c 1
.

16 a 1
.

17 The external pressure that must be applied to the solution side 1

. to stop the passage of solvent into the solution through a semi-
 permeable membrane is known as osmotic pressure.

The osmotic pressure method has the advantage over other

method as:

(a) pressure measurement is around the room temperature.

½+½
(b) molarity of the solution is used instead of molality. (for
any 2
(c) As compared to other colligative properties, its magnitude is points
large even for every dilute solutions , and denaturation of )
protein does not occur.

18 (i) Rate= k[A]2[B] 1

.
(ii) Rate becomes 9 times. 1

19 (i) In haloalkanes, the halogen atom is attached to sp 3 - 1

. 2
hybridized carbon while in haloarenes, it is attached to sp -
3
hybridized carbon whose size is smaller than sp orbital carbon.
Therefore C – Cl bond in chlorobenzene is shorter than alkyl
chloride.

(ii) Grignard reagents are very reactive. In the presence of 1

moisture, they react to give alkanes. Therefore, Grignard
reagents should be prepared under anhydrous conditions.

RMgX +H2O → RH +Mg(OH)X

20 (a) C6H5COCH3<CH3COCH3<CH3CHO (due to steric & electronic 1

. factors).

(b) CH3—COOH<Cl—CH2—COOH <F—CH2—COOH

1
(increase in –I effect).

OR

(a)
1

(b)
21 (i) Amylose is water soluble component which constitutes about 1
. 15-20% of starch. Amylose is a long unbranched chain with 200-
1000 α-D-(+)-glucose units. Amylopectin is insoluble in water
and constitutes about 80- 85% of starch. Amylopectin is a
branched chain polymer of α-D-glucose units.

(ii) A peptide linkage (-CO-NH linkage) is a chemical bond formed

between the carboxyl group of one molecule and amino group 1
of the other molecule.The –O- linkage between two
monosaccharides in oligosaccharides/ polysaccharides is called
glycosidic linkage.

22 + electrode 1
(i) From the cell representation, Ag/Ag is cathode
.
+
and Cu/Cu electrode is anode.

2+
(ii) At anode: Cu(s) →Cu (aq) + 2e-
1
+
At Cathode: Ag + 1e-→Ag

+ 2+
Overall reaction is Cu(s)+ Ag (aq) → Cu (aq)+2 Ag(s)

0 0 0
(iii) E cell=E cathode–E anode
1
0 0
=E Ag+/Ag–E Cu2+/Cu

=+0.80 V – (+0.34V)

=+0.80V-0.34V

=0.46V
23 1.5
.

1.5

24 ½+½
. + 1/2

½+½
+1/2

½+
½+1/2
(Any two)

25 ½
.

½
 ½

26 1.5
.

(b) During the SN1 mechanism, intermediate carbocation

1.5
formed is sp2 hybridized and planar in nature. This allows the
attack of nucleophile from either side of the plane resulting in a
racemic mixture.

27 (A) gives characteristic odour which on treatment with NaOH 1

. and forms two compounds B and C.

½
 ½

28 (a) A= glycosidic, B= α –Glucose, C= β -Fructose ½ + ½

. +½

(b) Sucrose on hydrolysis gives glucose with dextrorotation

(+52.5) and fructose with laevorotation (-92.40), which is higher 1.5
than the dextrorotation.

29 (a) 0 (zero) 1
.
OR

(b) Linkage isomerism 1

(c) cis – [Pt(en)2Cl2]2+ shows optical isomerism,

because cis isomer cannot be superimposed on its mirror image. 1

1

30 (a) Specific conductance decreases on dilution of electrolyte 1

. solution.

m 0
(b)In KCl electrolyte solution λ and λ are equal.

+ -
(c) ⋀° m (NH4OH) = ⋀° NH4 + ⋀°OH

+ - 2+ -
= (⋀° NH4 + ⋀°Cl ) + 1⁄2 (⋀°Ba + 2⋀°OH )
2
 2+ -
= -1/2 (⋀°Ba + 2⋀°Cl )

2 -1
= 129.8 + 1⁄2 x 457.6- 1⁄2 240.6 = 238.3 Scm mol

OR

(I)The correct order of equivalent conductance at infinite

1
dilution is KCl>NaCl>LiCl.

(II) CORRECT STATEMENT.

31 (a) No effect. 1
.
(b) B is sea water, due to the presence of salts it freezes at lower 1
temperature (depression in freezing point).

(c) K3 [Fe(CN)6] gives 4 ions in aqueous solution

1/2
i=1+(n−1)α
1/2
i=1+(4−1) × 0.852

i = 3.556
1/2
ΔTb = iKb m = 3.556 x 0.52 x 1 = 1.85
1
Tb = 101.85oC
½
OR

(a) Negative Deviation is expected when phenol and aniline are

1
mixed with each other. The net volume of the mixture will
decrease, ΔV<0 due to stronger intermolecular interactions.

1
 Relative lowering of vapour pressure = (P° – P) / P° = x2 ½

x2 = n2/ n1

n2= 0.1

n1 = 100/18 = 0.1/ 5.55 +0.1 = 0.1/ 5.65 = 0.018 ½

P° = 23.8 mm Hg

Relative lowering of vapour pressure:

(23.80 – P) / 23.80 = 0.018 ½

23.80 - P = 0.428 ½

P = 23.80 -0.428 = 23.37 mm Hg 1

32 (a) (i) Aniline is less basic as lone pair is in conjugation with 1

. benzene ring. So its Kb is less and pKb is more.

(ii) Aniline is protonated to form anilinium ion, which is meta

directing. 1

(b) (i) NH3<C2H5NH2< (C2H5)2NH < (C2H5)3N 1

1
(ii) C2H5Cl < C2H5NH2 < C2H5OH
1
(iii) CH3COOH > C2H5OH > CH3NH2> CH3OCH3

OR
1
(a) Benzenesulphonyl chloride (C6H5SO2Cl), also known as
o o o
Hinsberg’s reagent, is used for the distinction of 1 , 2 and 3
amines and their separation from each other.

o
With 1 amines, Benzenesulphonyl chloride yields N- 1
ethylbenzenesulphonyl amide

o
With 2 amines, Benzenesulphonyl chloride gives 1
N,Ndiethylbenzenesulphonamide
 o
• With 3 amine, benzenesulphonyl chloride do not react.

(b)

1
(i)

(ii)

33 Any five:
.
(a) Due to presence of unpaired electrons. 1

(b) Transition elements exhibit higher enthalpies of atomization 1

because of large number of unpaired electrons in their atoms,
they have stronger interatomic interaction and hence stronger
metallic bond.

(c)Transition metals have similar atomic radii, therefore, in 1

molten form they can fit to each other’s crystalline structure and
form homogenous mixture and form the alloys.

(d) Mn+ has 3d54s1 configuration and configuration of Cr+ is 3d5 1

,therefore, ionisation enthalpy of Mn+ is lower than Cr+

(e) Sc and Zn both form colourless compounds and are

1
diamagnetic.

(f) The decrease in the atomic and ionic radii with increase in
atomic number of actinoids due to poor shielding effect of 5f 1
electrons.

(g) Oxidation state of manganese in manganate ion is +6 and

permanganate ion is +7. 1