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Kalpavriksha Classes Carbocation Er. A. K.

Srivastwa (IIT Delhi)


CH3

HBr
(1)

CH3

HBr
(2)

CH3

(3) HBr

CH2 HBr
(4)

CH2 HBr
(5)
CH2

CH3
(6) HBr

CH3

HBr
(7)
CH2

HBr
(8)

CH3
HBr
(9)

CH3
CH3
(10) HBr

O
(11) HBr

Kalpavriksha Classes, Indira Nagar Colony, Hydel Road, Chitaipur, Vns-05. Ph:7054311100/8960843241
Kalpavriksha Classes Carbocation Er. A. K. Srivastwa (IIT Delhi)
CH3
CH3
HBr
(12)

HBr
(13)
CH3
HBr
CH3
(14)

O
HBr
(15)
H3C CH3

CH3
HBr
(16)
O

(17) HBr

HBr
(18)

HBr
(19)
CH3
H3C
(20) HBr
H3C

CH2

All questions just demand your presence of mind. Always think in step by step manner. First step is
protonation, thus forming a carbocation. Think about the stability and reactions of carbocation. Nature
favours stable end product. So, if possible, rearrangement will always take. Once, you have got the most
stable carbocation, then finally the nucleophile present, will attack the carbocation to get final product.

TRY IT. WRITE ALL MECHANISM STEPS.

Kalpavriksha Classes, Indira Nagar Colony, Hydel Road, Chitaipur, Vns-05. Ph:7054311100/8960843241

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