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Article history: Personal exposure to benzene of selected population groups, and impacts of traffic on commuters in
Received 27 March 2012 Ho Chi Minh City were investigated. The study was carried out in June, July and November 2010.
Received in revised form The preliminary data showed that on average, personal exposure to benzene for non-occupational
13 December 2012
people in Ho Chi Minh is w18 mg/m3 and most of the exposure is due to commuting. Benzene expo-
Accepted 16 December 2012
sure during travelling by bus, taxi and motorcycle is, respectively, 22e30, 22e39 and 185e240 mg/m3.
Motorcycleetaxi drivers, petrol filling employees and street vendors suffer high daily exposures at 116,
Keywords:
52, 32 mg/m3, respectively. Further measurements are needed for a better risk assessment and finding
Benzene
Personal exposure
effective measures to reduce exposure.
Ho Chi Minh Ó 2012 Elsevier Ltd. All rights reserved.
Motorcycle exhaust
Commuter
0269-7491/$ e see front matter Ó 2012 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.envpol.2012.12.017
T.T.N. Lan et al. / Environmental Pollution 175 (2013) 56e63 57
Motorcycles are preferred for their flexibility. The number of In Ho Chi Minh City, departure of the first and last bus from a terminal is 5 AM
motorcycles and automobiles in March 2008 were 3,444,868 and and 8 PM. The bus in the study was a diesel 47-seater, and was air-conditioned like
most of buses in Ho Chi Minh. The bus route was about 30 km. Working time of the
346,355, respectively, increasing to 3.9 million and 386,000 by June bus driver is from 5 AM to 10 PM with a break after each round. Taxis in Ho Chi Minh
2009. On average, vehicle population increases about 10% per year. run on petrol and operate throughout the day. A working shift of a taxi driver is
Following this trend, the number of motorcycles at the end of 2011 normally 12 h. A 7-seat air-conditioned taxi was employed for a whole day for the
was probably around 5 million. Traffic volume in the city is study. All taxis and <9-seat cars in Ho Chi Minh are air-conditioned. Working time of
the petrol-filling employee was 6 AM to 10 PM. The petrol-filling employee wore
extremely high. Our traffic survey at 29 major and 22 minor roads
a facemask made of cotton-cloth layers. This type of mask is very common in
on 24 November 2010 showed daily traffic volume in a range of Vietnam for protection from sunlight, particles and pollutants, and Vietnamese
1.7 104e4.7 105 vehicles/day with an average at citizens wear them when commuting by motorcycles. The protection ability of
1.4 105 vehicles/day. Traffic volume in rush hours (7 AMe8 AM facemasks from gas pollutants is not clear. Normally, petrol-filling employees, taxi
and 5 PMe6 PM) was 1.4 103e4.8 104, with average of drivers and bus drivers work one week on and one week off.
Table 1
Climatic conditions of the exposure campaigns.
Rain Temperature ( C) Relative humidity Pressure Wind speed Wind direction Mixed layer
(%) (atm) (km/h) depth (m)
p,m-xylenes and o-xylene. One working standard was routinely injected after each Approximately, the indoor benzene concentration in the evening and at night in the
ten injections to correct a change in calibration curves. The change was not more off-road house was assigned to the in-house exposure of the above individuals. This
than 2.6% for all analytes. way of evaluation was reasonable since most of the houses in Ho Chi Minh are
Pollutant concentrations in the air were evaluated using Eq. (1) for both active located on narrow residential lanes away from main roads, and the percentage of
and passive sampling roadside houses and buildings is very small.
The risk of leukaemia was roughly estimated using Eq. (4): here, the entire
ðW Wblank Þ 106 population groups were considered to be exposed to benzene levels found in this
C ¼ (1)
DE A t study for all their life.
Where W and Wblank (mg) are the amounts of pollutant in sample and blank sample
104 Daily exposure
by analyses, DE is desorption efficiency given by the producers for each lot of Risk ¼ (4)
17
charcoal and was 98% in this study, A is the sampling rate (ml/min), t is sampling
duration (hour). An average daily exposure to benzene for the non-occupational population in
Sampling rate of passive samplers was adjusted by using Eq. (2). the city was approximately using Eq. (5), where a transportation usage rate was
evaluated using Eq. (6).
1:5
T1
A1 ¼ A2 (2) Average exposure ¼ Daily exposurecommuting modei usage ratecommuting modei
303
(5)
Where A1 is a sampling rate at site temperature T1 (K), A2 is sampling rate at 30 C.
Two petrol types marketed in Vietnam, RON92 and RON95, were analysed. Usage ratecommuting modei
Petrol was diluted in benzene-free carbon disulphide containing IS and injected into Number of persons in vehiclei traffic volume of vehiclei (6)
the gas chromatograph for quantification. ¼ P3 100
1 Number of persons in vehiclei traffic volume of vehiclei
on many factors like traded amount of petrol, climatic conditions, Average for Population Population
and working behaviour. Benzene exposure of the bus driver was population commuting commuting
15 mg/m3e35 mg/m3 with an average of 22 mg/m3 (Fig. 3b), and was by bus by bus car
high in the morning and evening, and low at midday. It is difficult to Athens, Greece 13.1e24.6 Chatzis et al.,
2005
explain variation of the exposure of the bus driver, since a bus is
Helsinki, Finland 2.6ne4.7TSE Edwards et al.,
a moving object. Benzene levels inside a bus depends on many 2001
factors like moving speed, number of stops, ventilation conditions, Rouen, France 4.7 Gonzalez-Flesca
outside benzene concentration, etc. Low mixing layer depth or the Grenoble, France 6.4 et al., 2007
possible formation of a stable surface layer in the early morning and Ile de France, France 5.3
Strasbourg, France 5.9
at nighttime could be one of the many reasons for the observed Florence, Italy 2.4s, 7w 2.3s, 6.6w Fondelli et al.,
high exposure in morning and nighttime for the petrol-filling 2008
employee and bus driver. Perth (Australia) 1.76s, 1.98w Horton et al.,
Fig. 3c reports the daily profile of exposure to benzene of the 2006
Copenhagen, 5.22 Skov et al.,
students and the lecturer. Exposure during commuting by bus, taxi
Denmark 2001
and motorcycle was 22e30 mg/m3, 22e39 mg/m3 and 185e240 mg/ Windsor, Ontario 1.69s, 1.96w Stocco et al.,
m3, respectively. The high exposure of the motorcyclist is due to (Canada) 2008
direct exposure to highly polluted streams of exhaust gas from his Oxford (England) 4.6 Lai et al., 2004
own motorcycle and other on-road vehicles in a dense traffic fleet. Brussels (Belgium) 5.1 4.5 5 Ballesta et al.,
Lisbon (Portugal) 6.1 5 5.3 2006
According to Lan et al. (2010), benzene concentration in exhaust gas Bucharest (Hungary) 12.9 13.2 18.8
from 23 in-use motorcycles in Ho Chi Minh is in a range of 11e Ljubljana 5.5 4 5
1078 mg/m3 and largely depends on vehicle technology, moving Madrid 5.1 8.8 10.9
speed and accumulated mileage. Benzene exposure should be Dublin, Ireland 2.9 2.4 2.4
Daegu, Korea 2.6e8.1 Park and Jo,
higher for lower technology and higher fleet density, depend largely
2004
on climatic conditions. Eye irritation and headaches are symptoms Madrid, Spain 6.5 10 Ballesta et al.,
that motorcyclist in big cities in Vietnam often suffer; therefore, 2008
they normally wear protective facemasks. On average, exposure to California, USA 5.1 Marshall et al.,
benzene on the motorcycle was 7e8 times of those in the bus and 2006
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