Photophysical properties

Dye Heterocyclic
Eg EHOMO ELUMO λ|¿
max |¿ (nm)
max
λ pl μh σ
Tdec (ºC) Tg (ºC) Tm (ºC) Ref.
(eV) (eV) (eV) [ε (10 M cm )]
4 -1 -1
(nm) (cm2 V-1 S-1) (S cm-1)
Z907 - 523 [1.22]
C102 Fu 547 [1.68] Gao2008
C101 Th 547 [1.75]
C105 Se 550 [1.84] Gao2009
1.7 506 [2.71] 689
C209 Fu -5.09 -3.35
4
1.6 514 [2.75] 715
C213 Th -5.09 -3.42
7
1.6 525 [3.15] 720
C216 Se -5.09 -3.43 (.40)
6
Li2009
1.6 522 [2.84] 716
C210 Fu -5.03 -3.41
2
1.5 523 [3.05] 723
C214 Th -5.05 -3.48
7
1.5 549 [3.51] 772
C216 Se -5.06 -3.53
3
2.1 Potentia 458 [2.14]
BTA-I Fu
6 l
2.1 454 [3.31]
BTA-III Th
3
Mao2012
2.1 454 [3.31]
BTA-II Fu
1
2.1 449 [3.69]
BTA-IV Th
5
2.4 460 [4.10] 565
1 Fu
2
2.3 462 [4.64] 583
2 Th Yen2013
9
2.3 478 [4.85] 593
3 Se
2
Photovoltaic properties

Γ Shelf-stability tests
Voc Jsc FF PCE HI IPCEmax (%)
Dye Heterocyclic Electrolyte (mol LHE Ref.
(V) (mA cm-2) (%) (%) x10-2 [λ (nm)] RH (%) Retained PCE (%)
cm−2)
C102 Fu - 17.80 - 9.5 82 [550]
Gao2008
C101 Th Iˉ/I3ˉ 0.744 18.62 75.5 10.5 89 [580]
C105 Se 0.754 18.74 75.1 10.8 95 [520] Gao2009
C209 Fu 0.794 12.08 74.8 7.17 Sin datos numéricos
C213 Th EL01 0.775 11.88 74.7 6.88
C216 Se 0.755 12.84 71.5 7.15
C209 Fu 0.747 12.02 74.2 6.66
C213 Th EL02 0.720 11.82 75.1 6.39
C216 Se 0.719 12.21 73.2 6.42
Li2009
C210 Fu 0.769 13.84 68.3 7.27
C214 Th EL01 0.744 14.32 72.0 7.67
C216 Se 0.720 14.57 74.0 7.77
C210 Fu 0.703 13.86 70.5 6.89
C214 Th EL02 0.688 14.16 71.6 7.00
C216 Se 0.664 14.01 71.0 6.60
BTA-I Fu 0.824 12.58 66 6.85 Sin datos numéricos
BTA-III Th 0.804 13.26 66 7.02
Mao2012
BTA-II Fu 0.834 12.64 64 6.72
BTA-IV Th 0.806 13.36 66 7.05
1 Fu 0.68 10.30 62 4.37 3.69 x 10-7
2 Th Iˉ/I3ˉ 0.65 14.60 66 6.20 3.29 x 10-7 Yen2013
3 Se 0.60 14.10 67 5.66 4.19 x 10-7

Dye loading

Shelf-stability Light-stability Thermal-stability

References