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Abstract
Recent developments in compound semiconductor detectors are reviewed, highlighting the latest spectroscopic
performance from devices fabricated from a range of wide bandgap materials. Cadmium zinc telluride and cadmium
telluride continue to dominate the field, with a range of prototype imaging detectors under development, principally for
nuclear medicine and X-ray astronomy applications. Improvements in material quality and supply plus metal–
semiconductor contact technologies are discussed, as is the continued development of single polarity charge sensing
electrode structures. Other material systems are also reviewed, covering the latest results from intermediate-Z materials
such as gallium arsenide and indium phosphide, and high-Z materials including mercuric iodide and thallium bromide.
The technological challenges of these materials are summarised and the prospects for future imaging array detectors
highlighted.
r 2003 Elsevier B.V. All rights reserved.
PACS: 29.40.Wk
0168-9002/$ - see front matter r 2003 Elsevier B.V. All rights reserved.
doi:10.1016/j.nima.2003.08.058
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334 P.J. Sellin / Nuclear Instruments and Methods in Physics Research A 513 (2003) 332–339
P.J. Sellin / Nuclear Instruments and Methods in Physics Research A 513 (2003) 332–339 335
varying from B1 mm at 59 keV to B0:1 mm at cadmium telluride infra-red arrays and are now
662 keV: When used in combination with a 2D being transferred to CZT. An alternative low
pixel array, the depth sensing technique can temperature process bonding that has recently
produce a 3D position sensitive detector [14]. been applied to a CZT pixel detector is polymer
flip-chip bonding [19].
2.4. Imaging detectors Good results have been obtained from an 8 8
CZT pixel array detector developed by Caltec for
2.4.1. Strip detectors hard X-ray imaging from a balloon experiment
A variety of single-sided strip detectors have [20]. The 8 7 2 mm3 single crystal CZT pixel
been developed in CZT and CdTe, based closely array has a pixel pitch of 650 680 mm: Indium
on designs developed for silicon devices. The flip chip bonding was used to connect the array to
performance of these devices tends to be limited, a low-noise ASIC, with indium bumps of 30 mm
particularly in CZT, by hole trapping effects. Two- diameter. The photon counting ASIC outputs the
dimensional double-sided CZT strip detectors analogue pulse height and pixel address of each
using orthogonally crossed cathode and anode interaction, and has achieved a typical single pixel
strips have been developed by NASA for astron- energy resolution of B2:2 keV FWHM at 60 keV
omy applications [15]. at room temperature. A resolution of 670 eV
A more complex strip detector design is the CZT FWHM was achieved with the detector cooled to
drift-strip detector which has been developed as a 10 C [21].
potential large area detector for astronomical A number of CZT and CdTe pixel array
imaging [16]. In this device multiple drift strip detectors have been developed within NASA,
electrodes are positioned adjacent to a collecting summarised in Ref. [22]. These include the
anode strip. The other side of the detector contains INFOCmS CZT pixel detector which is indium
a planar cathode. The potential on the drift strip bonded to an ASIC developed at the University of
electrodes is adjusted to minimise the sensitivity of Arizona. Smaller scale pixel arrays are also under
the device to hole transport, acting as another development as prototype astronomical X-ray
variant of the single carrier charge sensing imaging detectors. A 4 4 pixel CZT pixel
detector. This device is also capable of depth detector developed by the Arizona group [23] has
information, derived from the ratio of the cathode achieved 1:2 keV FWHM at 60 keV; with wire-
to anode signal [17]. bonded connections from the pixel electrodes to
discrete readout electronics.
2.4.2. Pixel detectors Within medical applications, the Arizona group
Various results from two-dimensional pixel have an advanced programme to develop a high-
array detectors have been published recently, with resolution CZT pixel array detector for small
applications concentrated mainly in nuclear med- animal imaging, reported most recently in Refs.
icine imaging and hard X-ray astronomy. Barrett [24,25]. This device has a pixel size of 330 mm and
et al. [18] first showed that the effects of hole an inter-pixel separation of 50 mm: A pixellated
trapping can be significantly reduced in CZT pixel composite tungsten collimator is used to achieve
array detectors due to the ‘small pixel effect’. This high-resolution tomographic imaging of small
phenomenon allows the pixel array to function as animals with a 1–2 mm spatial resolution.
a predominantly electron sensing device, with the A number of relatively coarse pitch (1–5 mm)
weighting field geometrically produced due to the CZT and CdTe pixel array detectors are currently
ratio of the pixel pitch to material thickness. under commercial development, mainly aimed at
In comparison with silicon pixel detectors, flip- the nuclear medicine market. These devices gen-
chip bonding technologies are less mature for CZT erally consist of a pixel detector module with
with indium-based processes being generally used. integrated readout chip which is tiled onto a
Some commercial indium bonding processes have motherboard to produce a larger area sensor.
already been proven for use with mercuric The ability to fabricate CZT pixel arrays up to
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336 P.J. Sellin / Nuclear Instruments and Methods in Physics Research A 513 (2003) 332–339
the edge of the material without the use of a guard Additionally, the two-dimensional coplanar grid
ring is an advantage for this type of tiled device can be operated as a 3D imaging array with
arrangement. Suppliers include IMARAD (CZT, the depth of each interaction determined from the
2:5 mm pixel pitch) [26,27], LETI/BICRON transient signal induced on the non-collecting
(CZT 4:5 mm pixel pitch) [28], eV Products/Soreq strips [33,34]. However, the performance of these
(CZT 2:1 mm pixel pitch) [29], and Eurorad relatively complex strip detector designs has still to
(CdTe, pixel pitch 2:8 mm) [30]. be proven.
The continuing development of CZT/CdTe pixel An interesting application of the 3D position
array detectors needs to address a number of sensitive CZT array detector as a Compton scatter
material-related issues, including charge loss in the camera has been investigated [35]. In this study a
relatively large inter-pixel gap, and the nature of pair of 1 cm3 CZT pixel detectors were used, each
charge sharing between close-pitch pixels. containing 11 11 conventional anode pixels and
achieving a 3D spatial resolution of approximately
1 mm: The measured energy resolution at 662 keV
2.4.3. Two-dimensional coplanar grid detectors was 1.7% FWHM. This design has considerable
More complex strip detector designs have been potential as a medical Compton scatter camera for
suggested, the so-called two-dimensional coplanar PET studies, with a performance comparable to
grid detectors (Fig. 4), which combine the weight- that of HPGe detectors yet more compact and
ing field approach of non-collecting anodes with a easily portable.
strip detector geometry. In this device [31,32] an
array of small anode pixels are surrounded by non-
collecting anode electrodes in a strip formation. 3. Other compound semiconductor materials
The rear surface of the device is a planar contact.
The pixel anodes are interconnected in a direction Other wide bandgap compound semiconductor
orthogonal to the non-collecting strips. This materials continue to be of interest for ionising
design provides N 2 ‘pixels’ whilst only requiring radiation detection. Intermediate-Z materials such
2N contact strips on the anode side of the device. as GaAs and InP are being developed principally
A first prototype of this type of coplanar grid pixel for X-ray imaging applications, whilst high-Z
detector has recently been demonstrated [19]. materials such as TlBr and HgI2 are of particular
interest for hard X-ray and nuclear medicine
imaging.
Some of the most impressive recent results from
GaAs, InP, TlBr and HgI2 have come from the
ESA-funded detector programme at ESTEC,
reviewed in [36]. Here we summarise the ESTEC
data, plus other significant advances in these
materials. Outside the scope of this brief review
are a number of other materials which are still
some way from detector applications, for example
GaN, PbI2 ; and GaSe.
P.J. Sellin / Nuclear Instruments and Methods in Physics Research A 513 (2003) 332–339 337
studied extensively for detector applications, both developed by Bourgoin et al. [43] in which
in its bulk semi-insulating (SI) form and as high-pressure, high-temperature growth of
epitaxial material. Studies of SI GaAs for use as GaAs is achieved using a water-based transport
radiation imaging devices have not progressed reaction with growth rates up to 10 mm=min:
beyond prototype demonstrators due principally This technique offers a low-cost fabrication
to the inhomogeneous nature of the materials and technique for large wafer growth of thick epitaxial
the high concentration of the charge trapping EL2 GaAs.
defect. SI material grown by a range of methods The performance of InP detectors also continues
and treatments (LEC, VGF, zone refined) have to improve, concentrating on SI Fe-doped materi-
been studied and all show high concentrations of al grown by liquid encapsulated Czochralski
EL2 and poor mu-tau products (typically not (LEC). The lack of a rectifying contact on SI InP
greater than 104 cm2 =V). Non-uniformity of EL2 produces high leakage currents in these devices,
distributions tends to produce areas of low which must be reduced by cooling. The ESTEC
resistivity and high dark current. A variety of group have characterised a 180 mm thick InP at
groups have recently reported results of SI GaAs 60 C achieving 8:5 keV FWHM at 59:5 keV [44].
pixel detectors bonded to both current integrating Results from Pelfer et al. [45] using 250 mm thick
ASICs [37,38] and to the MEDIPIX photon SI InP achieved a resolution of 11 keV FWHM at
counting ASIC [39]. 122 keV when cooled to 60 C: Future improve-
The highest resolution X-ray spectra obtained ments in InP detector performance is dependent on
with single GaAs pad detectors has been reported less heavily compensated material to improve
by ESTEC [40,41] (Fig. 5). In this work epitaxial charge transport. The development of a rectifying
GaAs has been grown by Chemical Vapour contact will reduce the need to operate these
Phase Epitaxy (CPVE) with detectors up to devices at such reduced temperature.
400 mm thick achieving an energy resolution of
650 eV FWHM at 59:5 keV: A p–i–n structure was 3.2. TlBr and HgI2
used to produce a rectifying contact, with the
depletion thickness of the intrinsic layer limited to TlBr and HgI2 potentially offer excellent detec-
approximately 100 mm by the residual impurities tion efficiency at higher photon energies, with Z
in the material [42]. combinations of 81:35 and 80:53, respectively.
An alternative CVPE growth method for TlBr in particular has a high density ð7:56 g=cm3 Þ
producing thick epitaxial GaAs layers has been and hence a short mean free path for high-energy
photons (B1:0 cm at 511 keV). Currently the
supply of large volume TlBr crystals is very
limited; these are grown by either the travelling
molten zone (TMZ) or Bridegman–Stockbarger
(BS) methods. Devices typically use evaporated
gold contacts, relying on the material’s high
resistivity to limit leakage current. TlBr is highly
toxic and must be handled with care.
Good spectroscopic performance has been
reported from 3:8 mm thick TlBr devices produced
from TMZ material [46]. Extremely slow pulse
risetimes are observed from these devices due to
multiple trapping and detrapping of carriers, and
to achieve good performance operation with short
Fig. 5. X-ray spectrum obtained from an epitaxial GaAs shaping times is required. Results from TlBr
detector fabricated from material grown by chemical vapour arrays have also been reported by the ESTEC
phase epitaxy [40]. group, produced from 1 mm thick BS material
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