2018 for the

② reaction

<NcOs -> GNOz +Oz, the rate

(g) (g)(
of
formation of NO2 is 2.8x 10m.Calculate the
rate
of disappearance of N205 (g)
->

Al CNOs ->
SNO_tOz
Rate of
Ryt-IdO5] dENO2=+dO -
+

Given, rate of formation of NOz=dTNO2]=2.8x10.Ms+

at
rate of disappearance -

dINO5]-+I
&

dNO
t
& N285-dENc05]=?
&t
-

dENOs EdeNO2T =1x2.8NI

=
14 x 10-3
- Mst
 2013
Express following
-

# the rate of reaction in

ammouas
ter 8outog
Are
&
Rate of reaction
-

dEN27-itdIU) =tA deNIT

ROR in terms of formation of Ammonia

I dINHs]
-
at I
2011

a what is a complex Reachon? Define elementary

step in a reaction

An complex Reaction
-

Those reaction which takes

place in more than one step

As B ExCoD
each step of a complex reaction by called
elementary
-
step,
& What is order of a reaction? Give order
of w = KTA3Y2 [r5]2
A Consider a general reaction
aA+bB -> Product
Ralelaw ↳ is
Rate of Reaction & TAT TBTO
=
KTA] "[r]B
it is the sum of powers of cone
of reactant
terms according to rate law expression

v =
KTASYTBT
order= 6t2=91 or 52
2007
Ul
=>
for the reaction [NO
+

(g)
->
2N00cg)
(g)
The rate law is expressed as Rate =
KTU7 [NOTL
What is the overall order of reaction

Ale Rate = K [U7 [NO3L

=>

Order= 1+9 =
3
 2010 What is the difference blu order and
molecularity of a reaction?
Aus ORDER MOLECULARITY
E
⑧

It is the sum of powers It is the no. of

of concentration ferms acc alons, ions ormolecules
to rate that must collide with
law expression
each other to form a

Product.
- Experimental concept -> theoretical concept
->
order can be zero -
cholecularity can't be
Itr
Order can be fraction molecularity can't
be fractional
-
order can be defined -molecularity has no

for an elementary and a complexion meaning for a complex Re

2016 for a reaction
Ot Rate =
K
ENHy -> Nz 3H2
+

i) Write the order and molecularily

ii) Write the unit of K.

*
Order - O
i)
Molecularity = 2 [Bimolecular Reaction]

ii) Unit of K for different order

"

Is=(MOL 21) sect

(Moz1"O secs mozusect

D
 2015

⑧ For a
reaction, AtB-P, the rate's given by
Rate =
1 [A] [B]2
i) now is the rate of reaction affected
if cone
ofis doubled
B
ii) What is overall order of reaction, if A is in
excen

3
Are. Rate =
1 [A] [B]2 Rate =
1 TAT 71]2
&

is if B is doubled TA] in excess

come
of
R =
1 [A] [r] Rate =
K 1B]2

Rn =
19[A] [2132 #
2
-

AKCAT [B]2
=

new rate is 4 times

· old rate
25 Write unit of rate constant, for zero order
and for second order reaction. If cone is expressed
in
must and time in second ->

!-H
An
-
1 =
(MOLL1) sec -
I

⑭ =
(MOLL1)12 sec

MoLt (+1
=

sect

roU
T 13 =
GDOL (1) seC-

=
(MOLIDO sect

moject
o Write the factors which affect rate of
reaction.
·
CONCENTERATION OF REACTANT
increases
As come
of reactant
rate of reaction aboinneas

Rate = KTR]
"

TERATURE As temperature increases, rate of

reaction also increases, generally with every 200
->

rise in temperature rate of reaction doubles.

-

· CATALYST -

Those chemical substance which one

used to increase the speed of a chemical reaction

Mzt 3H. H ENHs

↑OF
REACTANT
much than
reactions
reaction
involving
which
ionic reactant.
contain
are
faster those
covalent reactant

SURFACE AREA OF REACTANT

As surface area
of
reactant increases, rate of reaction also increases
powdered sugar dissolve more speedly thou
crystalline sugar, due to the large surface
area of powdered sugar
SGUT In case of photochemical reaction,
increases
as pleasing o
rate of reaction

sunlight increase
12+U2 -> ance
 2
9 reaction is first order in it and second order
A
a) Write differential rate eg. is

⑬ How is rate affected when some of BI tripled

How rate affected when come of
& both A and s

⑨ What is the molecularity of reaction. is doubled

An @ Rate =
KTATTTBT2

⑬ -
v= KCATTR]2 ② r= KCA3Tr]"
Un Un
=
KT2A] T21]
=
KIAT 1]2
·
Un = 9KCASTB]
"
Un =
8K[A) [r5]2

s time 8 times
=>
BPLIVE