Professional Documents
Culture Documents
SENIOR
SCHOOL
Module
CHEMICAL KINETICS 5
Quarter 3
ANAMIE T. GALVES
Subject Teacher
For the learner:
Welcome to the General Chemistry 2 (Senior High School) Module 5 on Chemical
Kinetics.
The hand is one of the most symbolized part of the human body. It is often used to
depict skill, action and purpose. Through our hands we may learn, create and
accomplish. Hence, the hand in this learning resources signifies that you as a learner
is capable and empowered to successfully achieve the relevant competencies and skills
at your own pace and time. Your academic success lies in your own hands!
This module was designed to provide you with fun and meaningful opportunities for
guided and independent learning at your own pace and time. You will be enabled to
process the contents of the learning material while being an active learner.
Learning Goals - These are what you will be able to know after
completing the lessons in the module
Recall - This section will measure what learnings and skills that
you understand from the previous lesson.
Lesson- This section will discuss the topic for this module.
Post-test - This will measure how much you have learned from
the entire module.
LEARNING GOALS
PRE–ASSESSMENT
Read each of the following statements and choose the letter that corresponds to the best
answer.
COLLISION THEORY: states that in order for a reaction to occur, the reactants must collide
with one another. There must be a proper orientation for the molecules to have an effective
collision and there must be sufficient energy from the reacting molecules.
Chemists have proposed a model known as Collision Theory to explain why a reaction occurs.
For a given hypothetical reaction shown below:
In order for the reaction above to take place, the molecules of A2 must collide with the
molecules of B2 . Once the A2 comes in contact with B2 , a short-lived molecule A2 B2 is formed.
The bonds of A2 and B2 are destroyed and new bonds are formed. The rearrangement of bonds
of the starting molecules will cause the formation of a new substance AB. In a container filled
with the substance A2 and B2 initially, no AB is present. Then, molecular collision proceeds
and AB is formed.
However, not all collision of A2 and B2 form a product. Only effective collisions will result to
the formation of a product. For an effective collision to occur, there must be a proper
orientation of the reactants during collision. If the collision is ineffective like what is shown
below, products are not formed.
We can deduced from the Collision Theory that the greater the number of collisions, the
greater the chances of effective collisions, and the greater the amount of products formed per
unit time. Therefore, the greater the number of molecular collisions, the faster the reaction
rate.
Aside from the proper orientation of the molecules, it is also important that the molecules have
sufficient energy to collide with one another. The energy comes from kinetic energy of the
molecules. As they move, the potential energy is converted to kinetic energy. If the energy is
not sufficient, the collision will not take place.
TRANSITION STATE THEORY explains that there must be sufficient energy to overcome the
activation energy barrier in order for products to be formed.
Activated complex
Transition state
The formation of A2 B2 is crucial because it determines whether the reaction proceeds. The
energy needed for the formation of A2 B2 called an activated complex is called activation energy.
This is the energy needed for the formation of the activated complex and for the reaction to
occur. This is also considered as the rate determining step because once this is formed, the
product is formed immediately.
• At the start, the molecules may not have sufficient energy to reach the top or to form
the activated complex. As the reaction progresses, energy increases until such time that
enough energy has been attained to overcome the activation energy.
• The A2 B2 is called transition state and it determines how fast the reaction will occur. It
is a short-lived molecule and, therefore, very unstable because from the top, it rolls
down immediately to form the product AB. The activated complex has the following
characteristics:
1. It is unstable because it is a short-lived molecule
2. It possesses high energy
3. It is the rate-determining step in a reaction
Fig. 3 This shows the effect of temperature on the reaction rate. At lower temperatures,
there is a smaller number of molecules with sufficient energy to react. At higher energy,
the area with the number of molecules needed to react is greater.
Surface Area of the Reactants. The surface area of reactants affects the rate of reaction. If
the size of a particle is small, the surface area will be more and this increases the speed of
chemical reactions.
Presence of Catalyst. A catalyst can be defined as a substance that increases the rate of the
reaction without actually participating in the reaction. The definition itself describes it effect
on chemical reactions. The presence of a catalyst increases the speed of reaction in both
forward and reverse reaction by providing an alternate pathway which has lower activation
energy.
Fig. 4 Comparison of the activation energy of a reaction with and without a catalyst.
Source: https://nesslabs.com/wp-content/uploads/2020/12/activation-energy-illustration-graph-
catalyst.png
Types of Catalyst
A. Positive Catalyst – this type of catalyst decreases the activation energy by accepting an
alternative path for the reaction to occur. As such, the rate of reaction is decreased. The
effect of this type of catalyst is shown in figure 3. Some reaction that uses a positive
catalyst are the following examples.
2 KClO3 2 KCl + 3 O2
B. Negative Catalyst – this type of catalyst decreases or slow down the rate of reaction. It
increases the activation energy needed for the reaction to occur. For example, we want
rusting to slow down or slow down the decomposition of certain substances. We want
to slow down the process of aging. An example of a negative catalyst, also known as
inhibitors:
2 H2 O2 (l) 2 H2 O (l) + O2 (g)
C. Auto-Catalyst – when one of the products formed in the reaction acts as a catalyst for
the reaction to proceed.
D. Induced Catalyst – a substance that influences the speed of a reaction which is not
possible under ordinary conditions.
Orders and Rate Laws of Chemical Reactions
The order of a chemical reaction is defined as the sum of the powers of the concentration of
the reactants in the rate equation of that particular chemical reaction. Simply, it is the
relationship between the concentrations of species and the rate of a reaction. The rate law is
a mathematical relationship obtained by comparing reaction rates with reactant
concentrations. A reaction's rate law is experimentally determined and may be determined by
the initial rates method. The rate law describes the effect of concentration of reactants on the
reaction rate. The rate of reaction is directly proportional to the concentration of reactants.
For a hypothetical equation:
• Take note that the order of reaction is experimentally determined and base on the
graphical representation and is not based on stoichiometric ratio. Each order of the
reaction (although they have the same relationship) the graph between concentration
and time are different (see Figure 5, concentration vs time).
• The differential rate law for a chemical reaction can be integrated with respect to time
to give an equation that relates the amount of reactant or product present in a reaction
mixture to the elapsed time of the reaction. In addition, notice that there is k, or also
known as rate constant, in the equations.
• The k is the proportionality constant in the equation that expresses the relationship
between the rate of a chemical reaction and the concentrations of the reacting
substances. The value of k is obtained from the integrative rate law, which is actually
the slope of the straight-line plot or graph. Notice, that the y-axis is different on each
rate order, zero order y = [Conc.], first order y = ln [Conc.] and second order y =
1/[Conc.]. Therefore, knowing the k, and the initial concentration, we can calculate
amount left of the reactant in a reaction or vice versa.
Zero-Order Reactions
The rate of a zero-order reaction is independent of the concentration of reactant.
Where [𝐀]𝐨 is the initial concentration of A (the concentration at time 0), [A] is the
concentration of A at time t, k is the rate constant.
Half-life
From the equation based on integrative rate law on each order, a half-life can be derived. Half-
life is the time required for a quantity to reduce to half of its initial value. The term is commonly
used to describe how quickly unstable atoms undergo radioactive decay or how long stable
atoms survive. The term is also used more generally to characterize any type of exponential or
non-exponential decay. For example, the medical sciences refer to the biological half-life of
drugs and other chemicals in the human body. The converse of half-life is doubling time.
Sample problem
1. For the reaction in which A and B form C, the following data were obtained from three
experiments.
[A] mol/L [B] mol/L rate of formation [C] mol/L.s
0.30 0.15 7.0 x 10−4
0.60 0.30 2.8 x 10−3
0.30 0.30 1.4 x 10−3
Solution:
A + B C
a. r = k [A][B]
r
b. k = [𝐀][𝐁]
0.012 − 0.010
Average rate of reaction = = 0.001
2 − 0
Initial
Initial PO3 Initial H2
Rate
Experiment 1 0.100 0.100 1.50
Experiment 2 0.200 0.100 3.00
Experiment 3 0.100 0.200 6.00
x = 1 y = 2
a). What will the concentration of C2 H5Cl (g) be after 125 hours?
b). How many hours will it take for the concentration of C2 H5Cl (g) to drop to 0.100
mol/L?
c). How many hours will it take for 75% of the C2 H5Cl (g) to decompose?
d). Determine the half-life in hours for the decomposition of C2 H5 Cl (g) at 650 K?
[A]o 𝑘𝑡
log ( ) =
[A] 2.303
1.60 𝑥 10−6
0.165 mol/L
( )(450,000 s)
𝑠
log =
[C2 H5 Cl] 2.303
0.165 mol/L
= antilog 0.3126
[C2 H5 Cl]
0.165 mol/L
= 2.054
[C2 H5 Cl]
b. How many hours will it take for the concentration of C2 H5Cl (g) to drop to 0.100 mol/L?
[A]o 𝑘𝑡
log ( ) =
[A] 2.303
1.60 𝑥 10−6
( )t
0.165 mol/L 𝑠
log =
0.100 mol/L 2.303
1.60 𝑥 10−6
( )t
𝑠
log 1.65 =
2.303
1 hr
t = 313,041 s x = 87 hrs
3600 s
c. This type of problem can be solved by the method used in part. Since 75% of the [C2 H5Cl]
has decompose, [C2 H5 Cl] is equal to 25% of the original concentration, [C2 H5 Cl]0
[A]o 𝑘𝑡
log ( ) =
[A] 2.303
1.60 𝑥 10−6
0.165 mol/L ( )t
𝑠
log ( ) =
0.04125 mol/L 2.303
1.60 𝑥 10−6
( )t
𝑠
log 4 =
2.303
1 hr
t = 866,590 s x = 241 hrs
3600 s
d. Determine the half-life in hours for the decomposition of C2 H5Cl (g) at 650 K?
0.693
t1/2 = k
1 hr
t1/2 = 433,125 s x
3600 s
1. The reaction S2 F10 SF6 + SF4 is first order in S2 F10 . The rate constant
is 4.94 x 10 /s for the reaction conducted at 448K. In an investigation of the
−6
4. Consider the table of the initial rate for the reaction between hemoglobin (Hb) and
carbon monoxide.
[Hb] [CO] Initial Rate,
mol/L mol/L mol/L.s
Experiment 1 2.21 1.00 0.619
Experiment 2 4.42 1.00 1.24
Experiment 3 3.36 2.40 2.26
o The order of a reaction is equal to the sum of the exponents of the concentration terms
in the rate equation. The form of a rate equation can be determined by measuring the
initial rates of a series of reaction in which the initial concentrations of the reactants are
varied.
o Rate equation (which relate reaction rates to concentrations) can be converted into
mathematical expressions that relate concentrations to elapsed time. These expressions
can be used to find a concentration at a given time or to identify the order of a reaction
o The half-life of a reaction is the time that takes for half of a reactant to be converted
into products. For first-order reactions, the half-life is independent of the initial
concentrations of reactants. For the other reaction orders, the half-life varies with initial
concentrations.
o The collision theory accounts for the rate of a chemical reaction on the basis of collision
between reacting molecules. For an effective collision (one that results in a reaction), a
minimum energy is required and the colliding molecules must be aligned properly.
o The transition state theory describes a step in a chemical reaction in terms of the
attainment of a transition state (or an activated complex.
POST TEST
Read each of the following statements and choose the letter that corresponds to the best answer.
2. What is the unit of y for the first order rate of reaction if plotted linearly on the graph?
A. Concentration C. 1/Concentration
B. ln Concentration D. rate of reaction
3. For a reaction 2A + B 2C, with the rate equation: Rate = k[A]2 [B]
A. the order with respect to A is 1 and the order overall is 1.
B. the order with respect to A is 2 and the order overall is 2.
C. the order with respect to A is 2 and the order overall is 3.
D. the order with respect to B is 2 and the order overall is 4
5. If the initial concentration of the reactant is doubled, the time for half reaction is also
doubled. Then the order of the reaction is
A. Zero C. Fraction
B. One D. None
6. Which of the following refers to the half-life of a first-order reaction?
A. is constant
B. is the time necessary for the reactant concentration to drop to half its
original value
C. does not depend on the initial reactant
D. all of the above are correct
7. The rate law of the overall reaction A + B C is rate = k [A]2 . Which of the following
will not increase the rate?
A. increasing the concentration of reactant A
B. adding a catalyst for the reaction
C. increasing the concentration of reactant B
D. decreasing the pressure of the container
8. The rate constant of a reaction is 5.8 × 10−2 s−1.Which of the following is the order of
the reaction?
A. First order C. Second order
B. Zero order D. Third order
9. Given the reaction inside the container, CO2 (g) + H2 O(l) → H2 CO3 (aq). What will happen
if the pressure of the container increases?
A. The rate increases C. The rate will remain the same
B. The rate decreases D. Has no effect whatsoever
Books:
4. Brown, T. L., LeMay Jr, H. E., Bursten, B. E., Murphy, C., Woodward, P.,
Langford, S., ... & George, A. (2013). Chemistry: The Central Science. Pearson
Higher Education AU.
POST TEST
ACTIVITIES
Solve and analyze the following problems. (Show your solution)