NAMA : JUAYMA

NPM : 3335220036

KELAS : B

KIMIA FISIK DAN LARUTAN

Self Test 5.4

The vapour pressure of chloromethane at various mole fractions in a mixture at 25˚C was
found to be a follow.

x 0,005 0,009 0,019 0,024

p/kPa 27,3 48,4 101 126

Extimate Henry’s Law constant!

Jawab :

Henry’s Law  𝑃𝐵 = 𝑋𝐵𝐾𝐵

Maka, 𝐾𝐵 𝑃𝐵
= 𝑋𝐵
1. 𝐾𝐵
27,3 = 5460 𝑘𝑃𝑎 = 5,46 𝑀𝑃𝑎
= 0,005
2. 𝐾𝐵
48,4 = 5377,7 𝑘𝑃𝑎 = 5,378 𝑀𝑃𝑎
= 0,009
3. 𝐾𝐵
101 = 5315,79 𝑘𝑃𝑎 = 5,316 𝑀𝑃𝑎
= 0,019
4. 𝐾𝐵
126 = 5250 𝑘𝑃𝑎 = 5,25 𝑀𝑃𝑎
= 0,024
5.1 The following table gives the mole fraction of methylbenzene (A) in liquid and gaseous
mixtures with butanone at equilibrium at 303,15 K and the total pressure p. Take the vapour
to be perfect and calculate the partial pressures of the two components. Plot them against
their respective mole fractions in the liquid mixture and fine the Henry’s Law constant for the
two components.

xA 0 0,0898 0,2476 0,3577 0,5194 0,6036 0,7188

yA 0 0,041 0,1154 0,1762 0,2772 0,3393 0,445
p/kPa 36,066 34,121 30,9 28,626 25,239 23,402 20,6984

xA 0,8019 0,9105 1
yA 0,5435 0,7284 1
p/kPa 18,592 15,496 12,295

Jawab :

tekanan 1-xa (fraksi tekanan parsial

p xA yA
methylbenzene butanone) (butanone)
36,066 0 0 0 1 36,066
34,121 0,0898 0,041 1,398961 0,9102 31,0569342
30,9 0,2476 0,1154 3,56586 0,7524 23,24916
28,626 0,3577 0,1762 5,0439012 0,6423 18,3864798
25,239 0,5194 0,2772 6,9962508 0,4806 12,1298634
23,402 0,6036 0,3393 7,9402986 0,3964 9,2765528
20,6984 0,7188 0,445 9,210788 0,2812 5,82039008
18,592 0,8019 0,5435 10,104752 0,1981 3,6830752
15,496 0,9105 0,7284 11,2872864 0,0895 1,386892
12,295 1 1 12,295 0 0

Grafik nya