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Kimmo Luoma
Laboratory of Quantum Optics, Department of Physics and Astronomy,
University of Turku, FI-20014, Turun yliopisto, Finland∗
(Dated: May 1, 2023)
We introduce an exact open system method to describe the dynamics of quantum systems that
are strongly coupled to specific types of environments comprising of spins, such as central spin
systems. Our theory is similar to the established non-Markovian quantum state diffusion (NMQSD)
theory, but for a spin bath instead of a Gaussian bath. The method allows us to represent the
arXiv:2203.02417v2 [quant-ph] 28 Apr 2023
time-evolved reduced state of the system as an ensemble average of stochastically evolving pure
states. We present a comprehensive theory for arbitrary linear spin environments at both zero and
finite temperatures. Furthermore, we introduce a hierarchical expansion method that enables the
numerical computation of the time evolution of the stochastic pure states, facilitating a numerical
solution of the open system problem in relevant strong coupling regimes.
the solution of this equation with a hierarchy method, In the following we always consider an interaction pic-
thus allowing us to simulate the reduced system dynam- ture with respect to the free Hamiltonian of the bath
ics in spin bath problems via Monte-Carlo sampling of spins, which results in the following Hamiltonian
stochastic pure state trajectories.
N
The remainder of this work is structured as follows. We X
~ · Oλ (t)J~λ .
first introduce the open system model in Sec. II and dis- H(t) = HS + gλ L (4)
λ=1
cuss differences to the well known Gaussian bath model.
In the technical part of this work, we first give a brief In this expression, the orthogonal matrices Oλ (t) ∈
review on spin coherent states in Sec. III, as these will SO(3) describe the bare rotation of the spins around the
play an essential role in the following. Readers familiar z-axis
with spin coherent states may directly switch to Sec. IV,
where we develop the extension of NMQSD theory, the cos ωλ t sin ωλ t 0
main result of this work. As a demonstration we present Oλ (t) = − sin ωλ t cos ωλ t 0 . (5)
an application to the solvable pure dephasing model in 0 0 1
Sec. V. In Sec. VI we introduce a method which allows us
to numerically solve the dynamics of individual NMQSD Assuming a pure initial state of the system and a zero
trajectories and thus, in principle, to compute the re- temperature spin bath, the full system and bath state
duced dynamics of open systems with spin baths. Fi- |Ψ(t)i obeys unitary evolution from the Schrödinger
nally, we present our conclusions in Sec. VII. Various equation
longer derivations are provided in the appendix.
∂t |Ψ(t)i = −iH(t)|Ψ(t)i. (6)
where αij (t) is the bath correlation function and |vaci is Since R is a rotation there exists a unit vector ~n ∈ S 2
the bare vacuum state of the bath. The spin bath model ~ Thus, up to a phase, any spin
such that RJ z R† = ~n · J.
cannot be mapped to a Gaussian bath model because coherent state can be characterized by a point on the
higher order cumulants of the bath coupling operators sphere |ψSC i ≡ |~ni, with
N ~ ni = j|~ni.
~
X ~n · J|~ (15)
B(t) = gλ Oλ (t)J~λ (11)
λ=1 For a unique definition we have to assume some con-
do not vanish (this is a direct consequence of the nontrival vention, or gauge, in order to specify the phase of
algebra (2)). For a strong system and bath coupling it these states. This can be achieved for example in the
may not be sufficient to treat the spin bath within a Bargmann parameterization of spin coherent states, re-
Gaussian approximation in order to accurately describe lated to the stereographic projection of the sphere onto
the system dynamics, see for instance the analysis in the complex plane by z = tan θ2 eiφ , where θ and φ are
Ref. [9]. the polar angels pointing towards ~n. In this parame-
Non-Markovian quantum state diffusion (NMQSD) is terization a (unnormalized) spin coherent state can be
an established theoretical framework to describe dynam- explicitly written as [35, 37]
ics due to Gaussian environments, i.e. Hamiltonian (8). ~
It is a generalization of trajectory methods, such as quan-
− hz|J|zi
|zi = ezJ |j, ji, j~n = . (16)
tum state diffusion or quantum jumps, to non-Markovian hz|zi
systems [34]. NMQSD provides an unraveling of the sys-
This represents an analogy to bosonic Bargmann coher-
tem dynamics in terms of a stochastic process in the sys-
ent states [38]. The above definition already specifies a
tem Hilbert space |ψ(t)i, such that the average repro-
phase of the states. However, the spin coherent state
duces the mixed system state
|j, −ji, corresponding to ~n = −~ez which is orthogonal to
ρ(t) = M [|ψ(t)ihψ(t)|] . (12) |j, ji, is not included, as this would correspond to |z| = ∞
and the phase at this point is ill-defined. In fact, due to
The expectation value M [...] above is to be understood the nontrivial topology of the space of pure spin coher-
with respect to all stochastic realizations of the process ent states, it is impossible to find a smooth global phase
|ψ(t)i, and can in practice be evaluated using Monte gauge [39]. While the overlap of two spin coherent states
Carlo sampling of trajectories. This paper presents a gen- depends on the phases, the absolute value of this overlap
eralization of the NMQSD method to address spin bath is gauge independent and given as
problems described by the equation (4). Unlike most es- 2j
1 + ~n · ~n0
tablished open systems methods, this new approach can 0 2
handle spin baths in an exact manner. A detailed deriva- |h~n|~n i| = , (17)
2
tion of the theory is provided below. The main results
include an exact unraveling of the reduced system state where |~ni and |~n0 i are assumed to be normalized. While
in terms of normalized pure states (Eq. (26)) obeying a any set of 2j +1 distinct coherent states already spans the
closed evolution equation (Eq. (32)). full spin Hilbert space [40], the standard overcomplete-
ness relation from the general group theoretical construc-
tion of coherent states is most commonly used [41]
III. PROPERTIES OF SPIN COHERENT Z
STATES
1= dΩ|~nih~n|, (18)
S2
The microscopic derivation of NMQSD relies on coher-
ent states, which are also a crucial element in the general- with the proper uniform measure on S 2
ization to spin baths that we aim to establish. Therefore, 2j + 1 3 2j + 1
it is important to briefly introduce the essential proper- dΩ = d n δ(|~n| − 1) = dφ dθ sin θ. (19)
4π 4π
ties of spin coherent states. Spin coherent states can be
introduced in various ways, depending on the chosen pa- Similar to NMQSD for bosonic baths, this identity rela-
rameterization [35–37]. In general, a spin coherent state tion proves to be an elegant tool for developing a stochas-
refers to a rotation of the eigenstate of J z with a maxi- tic unraveling of open system dynamics from the micro-
mum eigenvalue of m = j scopic model of system and bath.
|ψSC i = R|j, ji. (13)
IV. SPIN NMQSD THEORY
R is a unitary rotation operator. This implicit definition
can be made more explicit by realizing that |ψSC i is an
eigenstate of the rotation of J z We consider model (1) and wish to establish a stochas-
tic theory similar to NMQSD based on spin coherent
RJ z R† |ψSC i = RJ z |j, ji = j|ψSC i. (14) states and in particular on the completeness relation (18).
4
We will first consider a zero temperature bath and elab- When inserted in (21), this yields an average of normal-
orate on the finite temperature case later. Our starting ized trajectories with time independent weights
point is the partial trace with respect to the environment
expressed in terms of coherent states: trE |Ψ(t)ihΨ(t)| =
n0 (t)|Ψ(t)ihΨ(t)|~
h~ n0 (t)i (26)
! Z
N
dµ(~n) .
Z
n0 (t)ih~
n0 (t)|Ψ(t)i
Y
trE |Ψ(t)ihΨ(t)| = dΩλ h~ n|Ψ(t)ihΨ(t)|~ni (20) hΨ(t)|~
λ=1
In equation (21) each pure state trajectory belongs to a
The bold vector ~ n = (~nλ ) is a shorthand notation for fixed set of coherent state labels and has a time depen-
the coherent state labels of all bath spins, and dΩλ is as dent weight. Through the transformation (25) resulting
in (19). The system Hilbert space vectors h~ n|Ψ(t)i can in equation (26) the coherent state labels now follow the
be used as a definition for pure state trajectories. How- evolution of the characteristic curves of the environment
ever, they are not normalized which is a severe issue for Q-function, but the weight of each trajectory becomes
Monte Carlo sampling of trajectories. After a short time, time independent. For a zero temperature bath initial
a large majority of trajectories may have a vanishing con- the initial conditions of the coherent state labels ~nλ are
tribution to the average whereas single, rare trajectories distributed according to the non-Gaussian measure
contribute with a significant weight. To find an average
over normalized states we divide by the norm to find YN
!
dµ(~
n) = dΩλ Q(0, ~ n)
trE |Ψ(t)ihΨ(t)| =
λ=1
N
! (27)
h~
n|Ψ(t)ihΨ(t)|~
ni (21)
Z N 2j
1 + nzλ
Y
dΩλ Q(t, ~
n) ,
Y
hΨ(t)|~
nih~
n|Ψ(t)i = dΩλ .
λ=1 2
λ=1
where we defined the function Q(t, ~ n) =
hΨ(t)|~nih~n|Ψ(t)i. In fact, this squared norm of Defining an average M [...] as the integration with respect
the system Hilbert space vectors h~ n|Ψ(t)i is the spin to dµ(~
n) we can obtain the reduced state of the system
Q-function (phase space distribution) of the reduced via
state of the environment. To proceed, we can derive 0
h~
n (t)|Ψ(t)ihΨ(t)|~ n0 (t)i
an evolution equation for this function. The derivation ρ(t) = M , (28)
is provided explicitly in appendix A. Due to the linear hΨ(t)|~ n0 (t)ih~
n0 (t)|Ψ(t)i
coupling and linear bath Hamiltonian, the Q-function
as in Eq. (12). Remarkably, this allows us to determine
satisfies a Liouville equation
the reduced state with Monte Carlo sampling of normal-
N
X ized pure states (‘stochastic states’) in the system Hilbert
n) = −
∂t Q(t, ~ ~λ·A
∇ ~ λ (t, ~nλ )Q(t, ~
n), (22) space, because every sample contributes to the mixed
λ=1 state evolution with the same weight.
∂
It remains to find an evolution equation for the
with ∇aλ = ∂na and the ‘drift’ term NMQSD trajectories |ψ(t, ~ n)i = h~ n0 (t)|Ψ(t)i. For this
λ
a projection formalism in terms of a Feshbach partition-
~ λ (t, ~nλ ) = gλ Oλ (t)T hLi(t)
A ~ × ~nλ . (23) ing can be used. This idea was introduced in Ref. [28].
It is based on finding a projection operator P (t) in the
~
hLi(t) = hΨ(t)|~ ~ n|Ψ(t)i/hΨ(t)|~
niLh~ nih~n|Ψ(t)i is the ex- full Hilbert space such that it extracts a single stochastic
pectation value of the coupling operators with respect to state and maps the initial state to itself. In our case the
the system state h~ n|Ψ(t)i. As should be, the character- requirements are explicitly
istic curves of this first order partial differential equation
remain on the sphere. The solution is given by transport P (t)|Ψ(t)i ∝ |ψ(t, ~
n)i, P (0)|0i = |0i. (29)
of the initial condition along the characteristic curves
As shown in Ref. [28], applying a standard Feshbach
~n˙ 0λ (t) = A
~ λ (t, ~n0λ (t)), ~n0λ (0) = ~nλ . (24)
method with such a projector gives a closed evolution
One can identify the classical equation of motion for the equation for the stochastic state. When defining this pro-
bath spins due to coupling to the system state h~ n|Ψ(t)i. jector in the spin case, we encounter the problem that
It is surprising that these classical equations appear in the spin coherent state |~ n0 (t)i is not smoothly defined
0
this exact theory even though the bath evolution is not for all values of ~nλ (t), because no smooth global phase
Gaussian. Using the method of characteristics we can gauge exists. To circumvent this issue, we define a time-
explicitly write the Q-function as dependent rotation operator as
Z N
! N
Y X
Q(t, ~
n) = dΩ00λ δ(~n00λ − ~n0λ (t)) Q(0, ~
n00 ). (25) ~
∂t R(t) = −ihLi(t) · gλ Oλ (t)J~λ R(t), (30)
λ=1 λ=1
5
with initial condition R(0) = 1. Since R(t) is a rotation Note that this termal state can also be expressed in terms
it acts on the spin operators as R† (t)J~λ R(t) = Sλ (t)J~λ , of a distribution of coherent states by using the so-called
where Sλ (t) ∈ SO(3) are orthogonal matrices. Note that P representation
this rotation propagates the coherent state |~ ni to the Z N
!
n0 (t)i = R(t)|~
shifted state |~ ni or equivalently Sλ (t)~nλ =
Y
ρβ = dΩλ Pβ (m)|~ mih
~ m|,
~ (35)
~n0λ (t). Because the dynamics of the phase of the shifted λ=1
state is smoothly specified by the rotation operator R(t),
the phase singularity issue is circumvented. We note in where m~ = (m~ λ ) denotes a set of coherent state labels
passing that by writing |~ n0 (t)i we abuse the notation for the bath spins. The P -function can be explicitly
because the phase of this state is not determined by the computed and reads
orientations ~nλ alone. With this construction we can
make the following choice for a time dependent projector N βωλ −2j−2
1 Y βωλ 1 + eβωλ
z1−e
Pβ (m)
~ = e + mλ .
n|R† (t)
R(t)|0ih~ Z 2 2
λ=1
P (t) = . (31) (36)
h~
n|0i
Since this function is positive the thermal initial state
This operator satisfies all desired properties required in
can be realized by averaging over pure state dynamics
the stochastic Feshbach theory. P (t) is well defined by
corresponding to coherent initial states [23, 28]. Note
construction because spin coherent states orthogonal to
that coherent initial states are just rotations of the zero
the initial state |0i have zero probability in the average
temperature bath state. A fixed rotation of the bath
(26). It is a projector for all times P (t)2 = P (t) and the
spins does not modify the linear form of the Hamiltonian,
relations (29) hold. Using this operator, the Feshbach
so that this can be captured by our theory. To be more
theory can be readily applied to find evolution equations
explicit, let Mβ [...] denote the average of coherent state
for the stochastic state. The derivation is provided in
labels m
~ with respect to the thermal P -function, so that
appendix B and the resulting equation reads
Mβ [|mih
~ m|]~ = ρβ . Then, the full system and bath state
∂t |ψ(t)i = can be obtained in the following way as an average over
dynamics with coherent initial states
− iHS |ψ(t)i
~ † (t) . (37)
N ρ(t) = Mβ U (t)|ψ(0)ihψ(0)| ⊗ |mih ~ m|U
~
X h~nλ |J~λ |j, ji
− i∆L(t) · gλ Oλ (t)Sλ (t) |ψ(t)i (32) U (t) denotes the time evolution operator for the full
h~nλ |j, ji
λ=1 system-and-bath state. By moving to a rotated frame,
Z t
the coherent initial conditions can be set to the zero
− ds K(t, s)|ψ(s)i,
0 temperature bath state. In particular, let R(m)~ be a
rotation operator which satisfies R(m)|0i
~ = |mi.
~ Then
where we introduced the abbreviation ∆L(t) ~ = L ~ − the Hamiltonian in the rotated frame is transformed as
~
hLi(t). The explicit form of the kernel operator K(t, s) ~ = R† (m)H(t)R(
H(t, m) ~ m)
~ and reads
is given in the appendix. In this equation the non- N
X
Markovian nature of the bath is apparent via the convo- H(t, m)
~ = HS + ~ · Oλ (t)M (m
gλ L ~ λ )J~λ , (38)
lution term which is not local in time. In general, the ker- λ=1
nel operator is difficult to determine except within per-
turbation theory. In fact, while the projector approach where M (m ~ λ ) ∈ SO(3) satisfies M (m ~ λ )~ez = m
~ λ . In
is very transparent and elegant, the hierarchy expansion summary, to realize a thermal initial condition of the
discussed in a later section may be more relevant in prac- bath one can propagate the state with zero temperature
tice, as it can be directly employed to numerically solve initial condition for a set of rotated Hamiltonians (38),
for the stochastic state. where the rotation is drawn randomly according to the P -
Finally, we want to show how to describe thermal ini- function (36). In practice this can be achieved by Monte
tial states within the same framework. At finite temper- Carlo sampling of the labels m ~ λ . Crucially, the form
ature kB T = 1/β the initial state of the bath in Hamil- of Hamiltonian (38) is identical to (4). Thus, all results
tonian (1) is given by from the zero temperature case can still be utilized. Since
NMQSD is a stochastic method itself, such a stochastic
N realization of the thermal initial state poses no further
1 O −βωλ (j−Jλz )
ρβ = e (33) complication [23].
Z
λ=1
Y 1 − e−βωλ (2j+1)
Z= . (34) To demonstrate the validity of the spin NMQSD theory
1 − e−βωλ we first consider a solvable model, namely pure dephasing
λ
6
hσx i
exact
we do not need to solve the intricate equation of motion 0.25
(32) to find the stochastic states. Instead, we can simply
0.00
extract these states directly from the exact system and
bath state, which reads −0.25
X N
O 0 1 2 3 4
|Ψ(t)i = e−iεn t hεn |ψS (0)i|εn i |ψλ,n (t)i. (39) εt
n λ=1
1.50
The summation above is with respect to all system en- (b) 1 no. samples
With a hierarchical expansion the equation of motion These allow us to write the action of spin operators
for the stochastic state (32) can be systematically solved. in a differential form. We can redefine the norm of
7
the stochastic states in order to express them with the finds that higher order derivatives with respect to the
Bargmann states hz|R† (t)|Ψ(t)i ≡ |ψ(t, ~ n)i. Taking the Bargmann labels occur. We label these ‘auxiliary states’
time derivative and making use of the relations (43) yields with a multi-index k ∈ NN
0 as
a differential equation for the stochastic state including
derivatives with respect to the state label N
Y
!
k
|ψ (t, ~
n)i = ∂zk∗λ hz|R† (t)|Ψ(t)i. (45)
∂t |ψi = λ
λ=1
− iHS |ψi
zλ∗
N To find the evolution equation for all auxiliary states we
can simply take the corresponding zλ∗ derivatives of (44).
X
~·
− i ∆L gλ jOλ Sλ izλ∗ |ψi
λ=1 1 Then, the following commutations can be used to move
1 ∗ 2
the derivatives to the right hand side
2 (1 − (zλ ) )
XN
~·
− i ∆L 1
gλ Oλ Sλ − 2i (−1 − (zλ∗ )2 ) ∂zλ∗ hz|R† |Ψi
λ=1 −zλ∗ [∂zkλ∗ , zλ∗ ] = k∂zk−1
∗ ,
λ
(46)
(44) [∂zkλ∗ , (zλ∗ )2 ] = 2kzλ∗ ∂zk−2
∗ + k(k − 1)∂zk−1
∗ .
λ λ
zλ∗
N
X
~·
∂t |ψ k i = − iHS |ψ k i − i ∆L gλ (j − kλ )Oλ Sλ izλ∗ |ψ k i
λ=1 1
1 ∗ 2
(47)
2 (1 − (zλ ) ) 1
N
~·
X h 1 i
− i ∆L gλ Oλ Sλ − 2i 1
(−1 − (zλ∗ )2 ) |ψ k+eλ i + kλ (j − (kλ − 1)) i |ψ k−eλ i
−zλ∗ 2 0
λ=1
In this equation, eλ = (δλγ ) is a unit vector. The k = 0 parameters or extremely strong coupling.
state of this hierarchy is the stochastic state which we For a proof of concept we computed a nontrivial ex-
aim to determine. The full hierarchy is as large as the full ample problem which cannot be solved analytically. In
Hilbert space of system and bath, i.e. exponentially large. particular, we considered a two level system HS = εσx /2
Therefore, the hierarchy must be truncated at a low or- coupled to a bath of two-level systems (j = 1/2) with
der to be numerically feasible, as in the case of HOPS. ~ = σz ~ex , i.e. the Hamiltonian
L
Formally, the truncation of the hierarchy at finite order
|k| corresponds to a perturbative expansion in gλ2 to the X 1
ε X
same order. Note, however, that the auxiliary states with H = σx + σz gλ Jλx + ωλ − Jλz . (48)
2 2
kλ = 2j+1 do not couple to the lower states and thus they λ λ
0.0
co-moving semi-classical evolution of the bath spins via
Eq. (24). In general, for non-Markovian dynamics, deter-
−0.5 mining evolution equations is difficult. With a projection
approach we can formally construct such an evolution
−1.0 equation for the stochastic state, but an intricate mem-
0 5 10 15 20 ory kernel remains to be determined. Alternatively, we
εt propose a hierarchical scheme to numerically propagate
the stochastic states. Although the full hierarchy does
FIG. 2. Decay of a two level system in a spin bath (Hamil- not cure the exponential complexity of the problem at
tonian (48)) computed with the hierarchy (47) in the second hand, we demonstrate with a simple example that a low
order truncation (average of 2000 samples). The bath consists order truncation is numerically feasible and gives good
of 60 spins with uniform randomly chosen frequencies and agreement with the exact dynamics. If, for instance in
couplings ωλ /ε ∈ [0, 3], gλ2 /(N ε2 ) ∈ [0, 1.6]. For comparison, the case of strong coupling, a larger hierarchy is required
the exact dynamics was computed with the ACE method [19]
to obtain accurate results, one could employ MPS tech-
(dashed lines, convergence was reached with a discretization
using 180 time steps and SVD compression with maximum
niques in order to keep the state dimension under control.
bond dimension of 180). Recently, such strategies have been successfully applied
within the hierarchical expansion of Gaussian NMQSD
[21, 51]. As a future perspective, it would be interesting
accurate tensor network representation of the influence to benchmark whether the proposed hierarchical scheme
functional. This is an indication of strong coupling and competes with other methods such as ML-MCTDH [52]
a nontrivial structure of the environment. As can be or ACE [19] from a numerical perspective. In our view,
seen in Fig. 2, the approximate NMQSD solution from the conditions under which a spin bath can be adequately
the second order hierarchy truncation is in good agree- described within a Gaussian framework [33] have not
ment with the ACE result. To improve the accuracy of been investigated thoroughly in the literature. With the
the NMQSD calculation, a deeper hierarchy has to be new range of methods available for treating non-Gaussian
considered which would require more advanced trunca- baths, it should now be possible to have a rigorous and
tion schemes [45, 49]. Compared to ACE, the hierarchy quantitative discussion of this question.
method has a more favourable scaling with respect to the
size of the system Hilbert space, since it is based on wave
function propagation instead of density matrices. How- ACKNOWLEDGMENTS
ever, a detailed analysis of the numerical performance of
the method is beyond the scope of this paper and will be VL acknowledges support from the international Max
addressed in future works. Planck research school (IMPRS) of MPI-PKS Dresden.
VL and WTS are grateful for inspiring discussions with
Chang-Yu Hsieh, Jianshu Cao and Shouryya Ray. Ac-
VII. CONCLUSIONS cess to the computer resources of the Finnish IT Center
for Science (CSC) and the FGCI project (Finland) is ac-
In this work, we have presented a generalization of the knowledged by KL.
non-Markovian quantum state diffusion method for ar-
bitrary quantum systems coupled to linear spin baths.
This advancement now enables the treatment of certain Appendix A: Equation of Motion for the Q Function
intricate many-body problems such as central spin mod-
els within the NMQSD framework. Our main contribu- To derive the equation of motion we crucially use the
tion is the derivation of a representation for the time- rules [53]
evolved reduced state of the system as the average of an
ensemble of pure states. These pure states are depen- 1
J a |~nih~n| = jna |~nih~n| + (δ ab − iεabc nc − na nb )∂ b |~nih~n|
dent on specific spin orientations ~nλ that are distributed 2
according to a non-Gaussian measure and can be sam- 1
pled using Monte Carlo methods. This approach allows |~nih~n|J a = jna |~nih~n| + (δ ab + iεabc nc − na nb )∂ b |~nih~n|.
2
for an approximate determination of the reduced state (A1)
by averaging over a finite set of stochastic pure states.
The labels ~nλ thus take the role of the colored Gaussian The Q function can be written as Q(t, ~n) =
noise process in the Gaussian NMQSD theory [20, 50]. nih~
tr|~ n|ρSE (t), where ρSE (t) = |Ψ(t)ihΨ(t)| is the full
9
state of system and environment. The derivation of the from (30) gives (32), where the kernel operator K(t, s)
evolution equation goes as follows: reads
n) = −i tr (|~
∂t Q(t, ~ nih~
n|[H(t), ρSE (t)]) 1
K(t, s) = − n| Ṙ† (t) − iR† (t)H(t) ·
h~
N h~
n|0i (B5)
X
gλ εabc nc ∂ b tr |~ ~ a ρSE (t)
n|(Oλ (t)T L)
= λ λ nih~ · W (t, s) Q̇(s) − iQ(s)H(s) R(s)|0i.
λ=1
N
X (A2) A perturbation expansion of this operator is obtained
= ~
gλ εabc ncλ ∂λb (Oλ (t)T hLi(t)) a
Q(t, ~
n) upon inserting a perturbation expansion for W (t, s). The
λ=1 lowest nonvanishing order is obtained from W (t, s) ≈ 1.
N
X
=− ~ λ · Oλ (t)T hLi(t)
gλ ∇ ~ × ~nλ Q(t, ~
n)
λ=1 Appendix C: Pure Dephasing
∂
Above, we have set ∂λa = ∂na and defined
λ The pure dephasing Hamiltonian with a spin bath
reads
nih~
tr|~ ~ SE (t)
n|Lρ hΨ(t)|~ ~ n|Ψ(t)i
niLh~
~
hLi(t) = = . (A3) N
nih~
tr|~ n|ρSE (t) hΨ(t)|~
nih~
n|Ψ(t)i X
H(t) = HS + L gλ (cos ωλ tJλx + sin ωλ tJλy ), (C1)
λ=1
Appendix B: Projection Formalism
where HS and L commute so that the energy eigenstates
HS |εn i = εn |εn i are also eigenstates of the coupling
The derivation of a closed evolution equation for the operator L|εn i = ln |εn i. Projecting the Schrödinger
stochastic state |ψ(t, ~ n0 (t))i is based on the projector equation onto an energy eigenstate then gives a closed
(31). The corresponding orthogonal projector is Q(t) = equation in the bath Hilbert space
1 − P (t). In the following we omit writing the depen-
dence on the labels ~ n. Taking the time derivative of the
stochastic state and inserting an identity 1 = P (t) + Q(t) i∂t hεn |Ψ(t)i =εn hεn |Ψ(t)i
yields N
X
+ ln gλ cos ωλ tJλx hεn |Ψ(t)i
n| Ṙ† (t) − iR† (t)H(t) P (t)|Ψ(t)i
∂t |ψ(t)i = h~ λ=1 (C2)
(B1) N
n| Ṙ† (t) − iR† (t)H(t) Q(t)|Ψ(t)i.
X
+ h~ + ln gλ sin ωλ tJλy hεn |Ψ(t)i.
λ=1
The first term is easy to evaluate because P |Ψi is pro-
portional to the stochastic state itself. In order to find This corresponds to non-interacting spins so that the
an expression for Q|Ψi we can use the standard Feshbach equation can be easily solved with a product ansatz
technique and formally integrate the evolution equation N
O
hεn |Ψ(t)i = cn e−iεn t |ψλ,n (t)i. (C3)
∂t Q(t)|Ψ(t)i = Q̇(t) − iQ(t)H(t) |Ψ(t)i λ=1
(B2)
= Q̇(t) − iQ(t)H(t) (Q(t) + P (t))|Ψ(t)i, The evolution equation for the individual bath spin states
conditioned on the system energy n are linear
which yields
i∂t |ψλ,n (t)i = gλ (cos ωλ tJλx + sin ωλ tJλy )|ψλ,n (t)i (C4)
Q(t)|Ψ(t)i = W (t, 0)Q(0)|Ψ(0)i
Z t (B3) and, thus, spin coherent states are solutions. The re-
+ dsW (t, s) Q̇(s) − iQ(s)H(s) P (s)|Ψ(s)i, duced state is obtained easily as
0
ρS = trE |Ψ(t)ihΨ(t)|
where we introduced the time evolution operator W (t, s)
N
which is the solution to W (s, s) = 1 and X X (C5)
= |εn ihεm |cn c∗m e−i(εn −εm )t hψλ,m |ψλ,n i.
nm λ=1
∂t W (t, s) = Q̇(t) − iQ(t)H(t) W (t, s). (B4)
Since HS commutes with H the diagonals of the density
Note that the first term in (B3) drops out because, by matrix in the energy representation are constant, ρS,nn =
construction, the initial state lies in the subspace spanned |cn |2 . The ‘dephasing’ is due to the time dependence of
by P (0), so that Q(0)|0i = 0. Inserting this formal solu- the nondiagonal terms which typically decay to zero for
tion into (B1) and inserting the time derivatives of R(t) large environments.
10
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