Atomic Structure

Q1 Which of the following represents isotones?

6 6 6
Ops: A   ,
  13 C14
38 39 40
B    
18 19 20

16 18
C 8 , 8O

77 77
D 32  33
 

Q2 An element has atomic number 30 and it contains two unit positive charge, how many
proton and electrons are present in cation respectively ?

Ops: A 30, 28

B 28, 30

C 28, 28

D 30, 30
 

Q3 For a given value of n (principal quantum number) the energy of different subshells can be
arranged in order of :-

Ops: A f>d>p>s

B s>p>d>f

C f>p>d>s

D s>f>p>d
 

Q4 How many number of orbitals are possible in L-energy level ?

Ops: A 2

B 4

C 6

D 1
 

Q5 The radius of second stationary orbit in Bohr's atom in R. The radius of 3rd orbit will be :-

Ops: A 9R

B R/4

C 9R/4

D 2R
 

Q6 Which of the following sets of quantum numbers are correct?

Ops: A n = 1; l = 1; m = +2

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 B n = 2; l = 1; m = +1

C n = 3; l = 2; m = -2

D n = 3; l = 4; m = -2
 

Q7 1 KW radiotransmitter operates at frequency of 800 Hz, how many photons per sec. does
it emit:-

Ops: A 1.6 × 1031

33
B  
32
C  
16
 
 

Q8 If m is the magnetic quantum number and ℓ is the azimuthal quantum number then :-

Ops: A m=ℓ+2

B m=2ℓ2+1

C ℓ=(m-1)/2

D ℓ=2m+1
 

Q9 An element with mass no. 81 contains 31.7% more neutron as compared to protons so
atomic no. is :-

Ops: A 35

B 42

C 55

D 13
 

Q 10 In millikans oil drop experiment the charge on oil droplet was found to be –1.282 × 10–18
C. How many e– will be present in oil droplet ?

Ops: A 4

B  
A

C 8

D  A
 

Q 11 How many no. of orbitals associated with the principal quantum no. n = 3 ?

Ops: A 8

B 3

C 9

D 16
 

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 Q 12 Which of the following transition in H atom will emit maximum frequency of photon ?

Ops: A n = 4 to n = 1

B n = 2 to n = 1

C n = 4 to n = 2

D n = 1 to n = 5
 

Q 13 The speed of an electron in Bohr orbit of is proportional to :-

Ops: A Z/n

B n / Z

C n/Z
2
D  
 

Q 14 The difference in angular momentum associated with the e– in two successive orbits of
atom is :-

Ops: A

D
 

Q 15 A hydrogen atom is in its ground state absorbs a photon. The optimum energy of such a
photon is:-

Ops: A 1.5 eV

B 3.4 eV

C 10.2 eV

D 13.6 eV
 

Q 16 Which of the following configuration does not follow Hund's rule of maximum multiplicity?

Ops: A 1s2 2s2 2p6 3s2 3p2

B 1s2 2s2 2p6 3s2 3p6 4s2 3d6

2 2 6 2 6 1 5
C  
2 2 6 2 4 2
D  
 

Q 17 Electron is in one of the 3d orbitals. What are the possible values of n, ℓ and m for this
electron ?

Ops: A n = 3; ℓ = 0; mℓ = 0

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 B n = 3; ℓ = 1; mℓ = -1, 0, +1

C n = 3; ℓ = 1; mℓ = -2,-1, 0, +1, +2

D n = 3; ℓ = 1; mℓ = -3,-2,-1, 0, +1, +2, +3

 

Q 18 Which of the following is not correctly matched?

Ops:  
A

Energy gap between two orbits

B

Kinetic energy of the ejected electron

C

Energy of one mole of photons

D
 

Q 19 Electromagnetic radiation of wavelength 242 nm is just sufficient to ionize the sodium

atom. What is the ionization energy of sodium per atom ?

Ops: A 494.5 × 10-6 J/atom

B 3169.5 × 10–10 J/atom

C 5.85 × 10–15 J/atom

D 8.214 × 10–19 J/atom

 

Q 20 The potential energy of an electron in the hydrogen atom is –6.8 eV. Indicate in which
excited state, the electron is present :-

Ops: A First

B Second

C Third

D Fourth

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 Answers

Q1 B Q2 A Q3 A Q4 B Q5 C Q6 B

Q7 C Q8 C Q9 A Q 10 C Q 11 C Q 12 A

Q 13 A Q 14 B Q 15 D Q 16 D Q 17 C Q 18 D

Q 19 D Q 20 A

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