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Exotic
125
128
Materials
What makes the technology
around us so incredibly special?
Hint: the answer lies above
The Small Book of Big Thoughts
Exotic
Materials
All through history, exotic materials
have ruled. They still do.
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2 Chapter 01
AUGUST 2015
Materials
128
August 2015
What makes the technology
around us so incredibly special?
Hint: the answer lies in the headline.
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4 Introduction
Introduction
The usage of exotic materials has proven
to be one of the biggest catalysts of human
progress.
Introduction 5
T
he last two editions of dmystify have covered what
can essentially be categorised into hard theoretical
science. However, as geeks whose primary interest lies
in computing, gadgets and consumer electronics, no
other branch of science and technology shapes this realm more
than engineering. Hard science has saved us from the brink
of extinction with vaccines, whereas the marvels of genetic
research have ushered the Green Revolution that delivered
us from imminent starvation. It is amply evident that sci-
ence saved our collective souls on numerous occasions, but
humanity couldn’t unlock its true potential until it made strides
in engineering.
This may sound like hyperbole, but this veritable fact is clear
once you look at the timeline of human achievement. Great
strides in the hard sciences have been taking place since the
time of the ancient Greeks, with a vast majority of theoretical
physics, chemistry and other crucial disciplines of modern sci-
ence being perfected in the 18th and 19th centuries. However,
awe-inspiring real-world applications of this knowledge only
came to fruition during the 20th century through the Industrial
Revolution. That and the breakthroughs in computing, telecom-
munications and electronics made during the World War II and
Cold War formed the basis of all modern consumer electronics.
6 Introduction
I
n their penchant for romanticising the underdog, fiction writers
love to make pithy statements glorifying skill and how tools tend
to be secondary in the pursuit of excellence. Well, you might want
to tell that to our fist-swinging early primate ancestors who were
subsequently bludgeoned and stabbed out of the gene pool by Nean-
derthals with the help of improvised tools. Even the early humans
realised the worth of good materials and how they improve the
tools at hand.
That’s how humanity progressed from relying on stones to forging
tools made of bronze and then discovering iron. It’s no surprise why
human prehistory is divided according to the engineering mate-
8 The Divine Elements
rials available at the time into – stone, bronze, and iron ages. It’s
not just scientists and engineers in lab coats who appreciate the
significance of exotic engineering materials. Even our ancestors
discovered that evolution goes hand in hand with science and engi-
neering, and how the best way to accelerate that is through superior
engineering materials.
It took thousands of years for this concept to gradually be
ingrained within us, until a few thousand years later materials sci-
The Divine Elements 9
height of the Cold War is much superior to its successor – the F-16
Fighting Falcon. The results of recent one-on-one combat exercises
between USAF’s latest F-35 Lightning II and the F-16 indicate that
USAF’s trillion dollar frontline fighter cannot hope to win a dogfight
against the F-16.
In modern times, superpowers aren’t the only ones adopting
exotic engineering materials in the pursuit of excellence. High tech-
nology has a way of trickling down to the masses eventually. Not
surprisingly, after the governments gave up on war, corporates
have taken up the mantle of employing exotic materials on the next
The Divine Elements 15
Carbon: Embodying
Versatility
No other engineering material is as exotic
yet functional as carbon. From structural to
electronic, the applications are diverse as they
are fascinating.
Graphene
There isn’t a better alternative to begin a piece on exotic engineering
materials than graphene. The simplest way to describe the material
is that it’s an uncannily thin layer of pure carbon. By uncanny, I mean
single atom thin layer of carbon. This thin layer is bonded tightly and
quite strongly into a hexagonal honeycomb lattice. The lack of thick-
ness means that graphene can be classified as a two-dimensional
carbon allotrope.
Carbon: Embodying Versatility 17
Strength
How strong, you ask? Graphene is a whopping 200 times stronger
than steel by weight, which makes it the strongest material ever
tested. The single atom thick, two-dimensional material is not only
strong, but it is flexible and stretchy as well, which further improves
its structural integrity and desirability as an engineering material.
Most graphene research and testing are undertaken theoretically,
but US researchers actually tested out the bulletproof properties of
the material. The scaled down test involved firing micrometre-sized
bullets into 10-100 nanometre-thick graphene sheets at 3000 metres
per second, or twice the muzzle velocity of high-powered military
rifles. The sheet was found to possess ten times the stopping power
of a steel plate and twice that of Kevlar.
That sounds even more impressive when you consider the fact
that, unlike Kevlar, graphene layers are single atom thick, so they
can be stacked virtually indefinitely without the penalty of added
weight or bulk. To put this into perspective, a million layers of gra-
phene would only be a millimetre thick. This test merely shows the
prowess of a few nanometre-thick layers of graphene. What about
a layer of the material that’s palpably thick? According to research
conducted by James Hone of Columbia University, “it would take an
elephant, balanced on a pencil, to break through a sheet of graphene
the thickness of Saran Wrap”. The upshot is essentially thinner, but
20 Carbon: Embodying Versatility
Conductivity
The material’s strength is only rivalled by its capacity to conduct
electricity. Graphene exhibits what’s called ballistic conduction. This
Carbon: Embodying Versatility 21
Optoelectronic Applications
Graphene’s electrical conductivity becomes an even bigger boon
when combined with its unique optical property of transparency.
This opens a wide gamut of possibilities in the rarefied realm of
optical electronics. It is of great significance in the area of opto-
electronics, which is quite important in the world of mobile gadgets
Carbon: Embodying Versatility 23
Photovoltaic Cells
Silicon and ITO are the materials of choice in photovoltaic or solar
cells due to the former’s excellent conductivity and the latter’s
optoelectronic property. Graphene, however, ticks both the boxes
with consummate ease. The material absorbs just 2.7-percent of
white light, which makes it highly efficient at harnessing sunlight.
The electron mobility within the material is also demonstrably better
Carbon: Embodying Versatility 25
that that of silicon. The best part is that graphene based photovoltaic
solutions will be significantly cheaper than existing silicon and ITO
implementations. This is a rare case of cheaper being better because
silicon-based photovoltaic cells aren’t exactly efficient, with most of
the light being lost as heat.
Unlike silicon which generates a single electron for every photon
absorbed, graphene-based photovoltaic cells generate multiple
electrons for every photon absorbed. Furthermore, the material can
also generate electricity from all wavelengths of light, as opposed to
silicon which is limited to certain wavelengths. The real icing on the
cake is the inherent flexibility, thinness, and durability of graphene.
This means solar cells can be integrated onto clothing or even the
body of smartphones, which would ensure that electronic devices
of the future won’t run flat as long as the sun’s out.
batteries, but it’s paving the way for highly efficient and cheap super-
capacitors. These supercapacitors promise high current discharge
values at low costs, while also promising backup duration rivalling or
even exceeding that of contemporary battery technology.
Current supercapacitors are limited by their dismal backup
duration due to the lack of surface area. The extremely large surface
area offered by the two-dimensional carbon allotrope is an important
factor in its viability as a supercapacitor. The nature of the material
also ensures that the supercapacitors will not only be highly efficient
but also significantly lighter than conventional alternatives. Moreover,
since graphene is a form of carbon, it is also ecologically friendly when
compared to the highly toxic materials found in existing capacitors
and batteries. The efficacy of graphene-based supercapacitors is only
rivalled by its low cost and ease of production. Researchers at UCLA
were able to produce graphene supercapacitors using commercially
available thermo-lithography. In layman’s terms, they created gra-
phene supercapacitors using a simple LightScribe compatible DVD
writer. It doesn’t get any cheaper and easier than this.
Graphene isn’t just about supercapacitors. It is also being used
to significantly improve existing battery technology as well. Conven-
tional batteries have been let down by their poor backup, ridiculously
long recharge duration, and overall durability. Adding graphene to
the mix promises to solve all these glaring issues. For example,
Carbon: Embodying Versatility 27
that can travel farther, charge quicker, last longer, and cost lower
than existing batteries.
Biological Engineering
The Bioenginneering potential of graphene is largely untapped at the
moment. That’s primarily because so far, there’s no conclusive data
available on the possibility of biopermeability and hence toxicity on
account of the incredibly small size of the material. However, it is esti-
mated that the safety and regulatory trials clearing the material for
biological applications won’t be cleared until 2030. However, the high
strength, small size, thinness, large surface area, and conductivity
of graphene make it the best candidate for bioelectric sensors that
could make blood work a thing of the past. Monitoring platelet count,
haemoglobin levels, glucose levels, cholesterol, and other diagnostic
procedures can also be made potentially non-invasive and extremely
convenient. If future clinical tests confirm its biocompatibility, gra-
phene can also be used in complex medically procedures such as
tissue regeneration. If that sounds radical, University of Wisconsin
researchers have already created graphene-based optogenetic brain
implants and interfaced them with mice.
Ultrafiltration
The single atom thick, two dimensional nature of graphene is
Carbon: Embodying Versatility 29
Carbon Fibre
As the name suggests, the engineering material is comprised of
carbon atoms arranged to form fibres of approximately 5-10 micro-
metre in diameter. The man-made fibre is formed when carbon
atoms bond forming crystals that lie parallel along the length of
the fibre. A multitude of such fibres form something called the tow,
which is basically the term of untwisted form of fibre. These tows
are then woven at right angles to maximise structural integrity. This
woven material is in the form of a fabric, which is then layered and
formed into desired three-dimensional shape, thereby giving rise to
extremely strong carbon fibre structures.
Carbon: Embodying Versatility 31
Enhancing The
Television
CRT and Plasma technology might have
been replaced by the inferior LCD panel, but
nanotechnology has set out to set it right.
CRT technology of yore beats modern day LCD panels hollow when
it comes to the crucial aspects of colour reproduction, response
time, viewing angles, and contrast ratio. The existence of widescreen
flat CRT TVs such as the legendary Sony KV-HR36 showed that they
could achieve 1080 lines of resolution with finer pitch.
Enhancing The Television 35
One of the prime reasons for the industry moving from CRT to
LCD was rooted more in shipping weight and logistics issues, which
hurt bottom-lines. There’s absolutely nothing wrong with replacing
old, bulky technology with a lighter, sleeker, and power efficient
alternative. However, the problem with the display industry switching
to LCD panels was that this new technology was significantly infe-
rior to its predecessor. Plasma technology was an example of CRT
replacements that was leagues better than LCD panels. Unfortunately
even that has withered quietly and conceded the market to grossly
inferior competition. OLED technology is a worthy example of new
displays that can stand up to the quality expectations set by CRTs.
However, the fabrication cost, complexity, and the difficulty in mass
producing OLED panels means that the technology is in no position
to take on the incumbent LCDs at the moment.
If you pay attention, you’ll notice the one thing common with all
aforementioned display technologies that are superior to LCD. They all
are emissive displays. In layman’s terms, each pixel in plasma, OLED,
and CRT displays generates light and isn’t dependent upon backlighting
for illumination. This property is ideal because it categorically solves all
issues with colour reproduction, contrast levels, viewing angles, and
response time faced by LCD technology. That’s because transmissive
displays such as LCD use liquid crystals to block and bend light gener-
ated by a backlight to reproduce colour and contrast.
36 Enhancing The Television
Given the death of plasma and the slow development and uncer-
tain adoption of OLED technology, it seems the only viable solution
would be to find a way to fix existing LCD technology. Fortunately, the
field of materials science and engineering has come to the rescue.
TV manufacturers have resorted to nanotechnology to address
substantial shortcomings of the LCD panel. Researchers have not
only found a way to enhance the colour reproduction of LCD displays,
but the technology has already begun trickling out into the market.
The solution is quantum dot displays.
blue, and green light. It also contains impure pink, orange, and yellow
hues, which affect the overall quality of the primary RGB spectrum.
This problem can be addressed by using a backlight with indi-
vidual Red, Green, and Blue LED diodes, but this makes displays
prohibitively expensive. The solution lies in employing quantum dots
to enhance the backlight. QD displays ditch the phosphor coating for
pure blue LED diodes in the backlight. Blue because it is high-energy
visible light that can then easily be converted to red and green light.
The blue LEDs naturally generate the blue bit of the RGB spectrum,
but creating the other two colours requires nanoscience. This is
where quantum dots come into the picture.
They are essentially light-emitting semiconductor (cadmium
selenide) nanocrystals. Their main USP is the ability to absorb and
convert a light of one wavelength into that of specific required wave-
length. This is achieved with a layer of cadmium-selenium quantum
dots sandwiched between layers of electron-transporting and hole-
transporting organic materials. When an electric field is applied, the
electrons and holes in the organic layers are captured by the quantum
dot, which causes them to emit photons. The hue of the colour can
be accurately achieved by controlling the size of the quantum dots.
QD setups employ two sizes of nanocrystals. The relatively large
dots, which possess a diameter of approximately 50 atoms, generate
red light, whereas the 30 atom wide quantum dots glow green.
40 Enhancing The Television
IGZO based LCD TVs are faster and more power efficient
ice following prolonged copyright lawsuits and the main backers finding
the research costs unviable in the wake of emerging OLED technology.
IGZO displays
IGZO is an acronym for Indium Gallium Zinc Oxide, which is a semi-
conducting material that was discovered less than a decade ago.
It’s being used in Thin Film Transistors (TFT), which are crucial for
controlling liquid crystals to create picture in LCD panels. Like carbon
nanotubes, IGZO is another example of exotic engineering material
that has improved existing LCD technology. However, unlike CNT-
enhanced LCD panels, IGZO panels are already out in the market
– most notably helping Apple make its iPad Air lighter, thinner, and
more visually detailed than its predecessors. IGZO TFTs are meant
as a high-tech replacement for existing amorphous Silicon (a-Si)
based TFT LCD displays.
There are a plenty of reasons why IGZO is better than a-Si for
LCD panels. To understand how and why the former is better, it must
be noted that transparency is an important virtue in LCD panels. A
typical example of a panel has around six different layers consisting
of light diffuser/guide, polarisers, glass, TFT, and the liquid crystals.
All of these except the liquid crystal layer are transparent to varying
degrees. Transparency is crucial to ensure that the backlight passes
through the liquid crystals in order to create pictures. Existing a-Si
48 Enhancing The Television
based TFT layer isn’t entirely transparent. It’s just that the millions
of transistors are tiny and thin enough to allow light to pass through.
IGZO trumps a-Si as a better TFT material because unlike the
latter IGZO transistors are actually transparent. Moreover, IGZO
sports 50 times the electron mobility of a-Si transistors. This allows
IGZO transistors to be fabricated in much smaller dimensions. This
not only allows manufacturers to allow higher resolution and pixel
density, but it also makes the display more power efficient. The better
electron mobility also allows the liquid crystals to be manipulated
much faster, which in turn improves the overall response time. That
means, IGZO displays exhibit relatively lower ghosting and blurring
when compared to conventional LCD panels.
Nanopixels
If you think 4K displays are high tech, you might want to check out
the possibilities unlocked by nanopixels. This is yet another feather
in the cap of nanoscience discipline within the branch of materials
science and engineering. Created by British researchers, nanopixels
form the crux of a new display technology that not only promises an
incredible level of efficiency, but also unprecedented levels of resolu-
tion and pixel density. Some of the tiniest pixels in modern displays
such as iPhone 5’s Retina display measure in at 78 micrometres.
Nanopixels raise the game with an incredibly miniscule pixel size
Enhancing The Television 49
Batteries: The
Weakest Link
Existing battery technology might not be living
up to your expectations considering your
usage of mobile devices, but exotic materials
are going to make batteries much better.
B
ring up the subject of batteries and every single technology
user, whether he’s a geek or a layman, invariably has nothing
but complaints, as opposed to a single word of apprecia-
tion. Agreed that batteries are the very reason why mobile
devices are, well, mobile, but the risk, unwieldiness, and the overall
problems brought upon by the technology far outweigh the positives.
As yourselves, when was the last time any device that relied on bat-
teries didn’t outright such and left you in the lurch by transforming
into an expensive paperweight when you needed it the most?
52 Batteries: The Weakest Link
devices could now last longer without being bulky, heavy or taking
too long to charge.
However, the modern slim smartphones, hobby grade R/C, and
ultra-slick, lightweight and powerful laptops as well as other mobile
electronics came into their own with the lithium based batteries. This
includes lithium-ion (Li-Ion) originally seen as button cells or in their
larger cylindrical rechargeable form. This new technology improved
upon every aspect of NiMH battery technology. Li-Ion cells were more
energy efficient, high capacity, recharged faster and lasted longer. The
subsequent improvement in lithium-derived battery tech primarily
improved discharge rates and form factor. This technology works
by replacing the liquid electrolyte within Li-Ion batteries with a solid
polymer composite. This makes the existing lithium battery lighter,
slimmer and more efficient. Cutting edge lithium-polymer (Li-Po)
batteries made slim smartphones such as the recent variants of the
iPhone possible. The high discharge rate meant that manufacturers
could now include even more power-hungry (read: powerful) mobile
processors and memory banks without fearing for device stability
and backup duration.
absorbing or discharging
ions, but also leads to the
crystallisation within the
battery electrolyte which
renders it useless.
The problems aren’t
restricted to internal deg-
radation either. Any form
of collapse in the electrical
circuitry or the physical
integrity of batteries can
lead of catastrophic con- Li-Po batteries could be improved
by incorporating anodes made
sequences. Both Li-Ion and
from exotic materials
Li-Po batteries are liable to
explode or catch fire if they are subjected to short circuits and
punctures or any form of overheating and short circuits. Modern
chargers for these batteries incorporate several electronic safe-
guards to prevent overcharging, overheating and short circuits, but
even a slight failure in this regards can potentially burn down your
residence. The susceptibility of batteries to punctures or design
failures that don’t factor in ventilation for expansion and drainage
of flammable electrolytes are another causes of potential fire and
explosion hazards.
Batteries: The Weakest Link 59
Perfluoropolyether (PFPE)
From raging forest fires to apartment blazes – the hazards of Lith-
ium-based batteries explained earlier are enough to send shivers
down any smartphone users’ spine. Thankfully, the good lads at
the materials science and engineering department have been busy
making batteries safer. And it looks like they are on the verge of a
breakthrough as well. One of the major causes of battery explo-
sions and flame outs is the battery electrolyte itself. The lithium
Batteries: The Weakest Link 61