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    The document summarizes key findings about the Al-Mg-Sc ternary phase diagram from previous studies: 1) The phase diagram features a four-phase monotectic reaction characterized by two liquids in equilibrium with solid phases ScAl2, ScAl, and Sc2Al at two monotectic points M1 and M2. 2) Previous thermodynamic calculations by Grober et al. (1999, 2005) determined the liquidus surface and identified a miscibility gap within the ternary region resulting in two separate liquids. 3) The binary constituent systems - Al-Mg, Al-Sc, and Mg-Sc - involve several intermediate phases but have no stable or metast

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    Diagrama ternario

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    The document summarizes key findings about the Al-Mg-Sc ternary phase diagram from previous studies: 1) The phase diagram features a four-phase monotectic reaction characterized by two liquids in equilibrium with solid phases ScAl2, ScAl, and Sc2Al at two monotectic points M1 and M2. 2) Previous thermodynamic calculations by Grober et al. (1999, 2005) determined the liquidus surface and identified a miscibility gap within the ternary region resulting in two separate liquids. 3) The binary constituent systems - Al-Mg, Al-Sc, and Mg-Sc - involve several intermediate phases but have no stable or metast

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    © All Rights Reserved
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    11 views1 page

    Diagrama Ternario

    Uploaded by

    Álvaro Nieto Castro
    The document summarizes key findings about the Al-Mg-Sc ternary phase diagram from previous studies: 1) The phase diagram features a four-phase monotectic reaction characterized by two liquids in equilibrium with solid phases ScAl2, ScAl, and Sc2Al at two monotectic points M1 and M2. 2) Previous thermodynamic calculations by Grober et al. (1999, 2005) determined the liquidus surface and identified a miscibility gap within the ternary region resulting in two separate liquids. 3) The binary constituent systems - Al-Mg, Al-Sc, and Mg-Sc - involve several intermediate phases but have no stable or metast

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    of 1

    JPEDAV (2008) 29:185 Phase Diagram Evaluations: Section II

    DOI: 10.1007/s11669-008-9257-4
    1547-7037 ÓASM International

    Al-Mg-Sc (Aluminum-Magnesium-Scandium)
    V. Raghavan

    Ternary alloys having a four-phase monotectic reaction lished literature. In addition, the ternary solubility of Mg
    can possess interesting properties, with two different in ScAl3, ScAl2 and ScAl was taken into account. There
    solidified liquids in the microstructure. [1999Gro] and are no stable or metastable liquid miscibility gaps in the
    [2005Gro] computed a liquidus surface of this ternary three binary systems. Yet, a miscibility gap occurs within
    system. The other results of [1999Gro] on isothermal and the ternary region, Fig. 1. It is characterized by the
    vertical sections were reviewed by [2007Rag]. presence of two four-phase ternary monotectic reactions
    M1 and M2. At M1, the solid phases in equilibrium with
    Binary Systems the two liquids are ScAl2 and ScAl. At M2, they are ScAl
    and Sc2Al.
    The Al-Mg phase diagram has the following intermediate
    phases: Mg2Al3 (cubic, labeled b), R or e (rhombohedral), and
    Mg17Al12 (A12, aMn-type cubic, denoted c). The Al-Sc phase
    diagram depicts the following intermediate compounds: ScAl3 References
    (L12, AuCu3-type cubic), ScAl2 (C15, MgCu2-type cubic), ScAl 1999Gro: J. Grobner, R. Schmid-Fetzer, A. Pisch, G. Caccia-
    (B2, CsCl-type cubic), and Sc2Al (B82, Ni2In-type hexagonal). mani, P. Riani, N. Parodi, G. Borzone, A. Saccone, and R.
    The Mg-Sc phase diagram has one intermediate phase MgSc (B2, Ferro, Experimental Investigations and Thermodynamic Cal-
    CsCl-type cubic). See [Massalski2] for the above phase diagrams. culation in the Al-Mg-Sc System, Z. Metallkd., 1999, 90(11),
    p 872-880
    2005Gro: J. Grobner and R. Schmid-Fetzer, Phase Transforma-
    Liquidus Projection tions in Ternary Monotectic Aluminum Alloys, JOM, 2005,
    57(9), p 19-23
    In their thermodynamic calculation, [1999Gro] em- 2007Rag: V. Raghavan, Al-Mg-Sc (Aluminum-Magnesium-Scan-
    ployed the binary interaction parameters from the pub- dium), J. Phase Equilb. Diffus., 2007, 28(5), p 471-472

    Fig. 1 Al-Mg-Sc computed liquidus projection. A schematic enlarged view of the Mg corner is shown [1999Gro]

    Journal of Phase Equilibria and Diffusion Vol. 29 No. 2 2008 185

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