Professional Documents
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2.Imtiaz Taimoor
Student ID: 0421322047
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BUET-INPE Uranium Mining & Milling Processing
Table of Contents
1.0 Abstract: ................................................................................................................................................ 4
1.1 Nuclear Fuel: ..................................................................................................................................... 4
1.2 Nuclear Fuel Cycle:........................................................................................................................... 5
2.0 Uranium Mining: .................................................................................................................................. 6
2.1 History of Uranium mining:............................................................................................................. 6
2.2 Uranium mines: ................................................................................................................................. 7
2.3 Types of Uranium Deposits: ............................................................................................................ 8
2.4 Necessary parameters for assessing uranium ore resource: ....................................................... 10
2.5 Mining Technique: .......................................................................................................................... 10
2.5 (a) Open Pit:................................................................................................................................. 10
2.5 (b) Underground Mining: ........................................................................................................... 10
2.5 (c) In-Situ Leaching (ISL)/ Recovery (ISR): ............................................................................. 10
2.5 (d) Heap Leaching:...................................................................................................................... 11
2.5 (e) Sea Water Recovery: ............................................................................................................. 11
2.5 (f) By-Product Uranium: ............................................................................................................ 12
2.6 Environmental & Health Effects of Uranium Mining: ................................................................ 12
2.7 Recent Trends in Mining:............................................................................................................... 13
3.0 Uranium Milling: ................................................................................................................................ 13
3.1 Introduction to Uranium Milling: ................................................................................................. 13
3.2 Overview on stages of Uranium Milling: ...................................................................................... 14
3.3 Detailed procedure of milling to produce Uranium Ore Concentrate (UOC) from excavated
ore:.......................................................................................................................................................... 15
3.3 (a) Ore Preparation: ................................................................................................................... 15
3.3 (b) Extraction: ............................................................................................................................. 16
3.3 (c) Solid/Liquid Separation: ....................................................................................................... 16
3.3 (d) Purification: ........................................................................................................................... 17
3.3 (e) Precipitation:.......................................................................................................................... 17
3.3 (f) Calcination: ............................................................................................................................ 18
3.4 Uranium Mill Tailings: ................................................................................................................... 18
3.5 Decommissioning: ........................................................................................................................... 19
3.6 Current Trend Followed: ............................................................................................................... 19
4.0 Conclusions:......................................................................................................................................... 20
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BUET-INPE Uranium Mining & Milling Processing
List of Tables:
Table 1: Isotopes of Uranium..................................................................................................................... 5
Table 2: Average uranium concentrations in ores, rocks and waters (ppm - parts per million) ......... 6
Table 3: Uranium resources by country in 2019 ...................................................................................... 7
Table 4: The largest-producing uranium mines in 2019 ........................................................................ 8
Table 5: Percentage distribution of world uranium production by processing method in 2016 ...... 12
Table 6: Leaching process chemicals ..................................................................................................... 16
Table 7: SX process chemicals. ............................................................................................................... 17
Table 8: Precipitation process chemicals ............................................................................................... 18
Table 9: Four largest Uranium production facilities ............................................................................ 20
List of Figures:
Figure 1: Uranium Fuel Cycle. .................................................................................................................. 5
Figure 2: ISL Mining Process. ................................................................................................................. 11
Figure 3: Typical conventional Uranium Mill ....................................................................................... 15
List of Nomenclature:
ADU: Ammonium diuranate.................................................................................................................. 17
CCD: Counter-Current-Decantation .................................................................................................... 16
Cu: Copper .............................................................................................................................................. 11
ISL: In-situ Leaching .............................................................................................................................. 10
ISR: In-situ Recovery ............................................................................................................................. 10
IX: Ion exchange ..................................................................................................................................... 16
SX: Solvant Extraction ........................................................................................................................... 16
U: Uranium ................................................................................................................................................ 4
U3O8: Triuranium octoxide .................................................................................................................... 18
UO2: Uranium dioxide ............................................................................................................................ 18
UO3.5H2O: Uranium(VI) oxide dihydrate ............................................................................................ 18
UO3: Uranium trioxide ........................................................................................................................... 18
UO4: Uranyl peroxide ............................................................................................................................. 17
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BUET-INPE Uranium Mining & Milling Processing
The significance of Uranium as nuclear fuel for power generation is great. The Uranium mining
& milling process of the fuel cycle is discussed at large in two separate parts in this paper.
A brief history of Uranium mining & on depth data about Uranium mines all over the world, their
deposit type was discussed. Necessary parameters for assessing uranium ore resource was also a
part of discussion. There are different types of Uranium mining method available such as open pit,
underground, ISL, by-product etc. methods had also been discussed. Recent concern on
environmental impact of mining & method to counteract them has also been discussed in the paper.
Lastly, for the mining part recent trends in mining was also briefly mentioned.
For Uranium milling part, after a brief introduction, stages of uranium milling were discussed on
depth. Handling mill tailings and decommissioning of Uranium mines are also part of the
discussion. Lastly current trends on milling process was mentioned.
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BUET-INPE Uranium Mining & Milling Processing
Table 2: Average uranium concentrations in ores, rocks and waters (ppm - parts per
million)
Average granite 4
Seawater 0.003
Groundwater >0.001 - 8
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2.5 (a) Open Pit: Where ore bodies lie close to the surface, they are usually accessed by open cut
mining, involving a large pit and the removal of much overburden (overlying rock) as well as a lot
of other waste rock. Overburden is removed by drilling and blasting to expose the ore body, which
is then mined by blasting and excavation using loaders and dump trucks. At Ranger in north
Australia, Rossing in Namibia, and most of Canada’s Northern Saskatchewan mines through to
McClean Lake, the ore bodies have been accessed by open cut mining [4].
2.5 (b) Underground Mining: Where ore bodies are deeper, underground mining is usually
employed, involving construction of access shafts and tunnels but with less waste rock removed
and less environmental impact. Olympic Dam in Australia, McArthur River, Rabbit Lake and
Cigar Lake in Northern Saskatchewan, and Akouta in Niger are underground, up to 600 meters
deep [4].
2.5 (c) In-Situ Leaching (ISL)/ Recovery (ISR): In-situ leaching (ISL), also known as solution
mining, or in-situ recovery (ISR) in North America, involves leaving the ore where it is in the
ground, and recovering the minerals from it by dissolving them and pumping the pregnant solution
to the surface where the minerals can be recovered. There is little surface disturbance and no
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BUET-INPE Uranium Mining & Milling Processing
tailings or waste rock generated. Uranium ISL uses the native groundwater in the ore body which
is fortified with a complexing agent and in most cases an oxidant. It is then pumped through the
underground ore body to recover the minerals in it by leaching. Once the pregnant solution is
returned to the surface, the uranium is recovered in much the same way as in any other uranium
plant (mill) [6].
2.5 (e) Sea Water Recovery: The uranium concentration in sea water is low, approximately 3.3
parts per billion or 3.3 micrograms per liter of seawater. If even portion of the uranium in seawater
could be used the entire world's nuclear power generation fuel could be provided over long time
period [7].
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BUET-INPE Uranium Mining & Milling Processing
2.5 (f) By-Product Uranium: Uranium can be recovered as a by-product along with other co-
products such as molybdenum, vanadium, nickel, zinc and petroleum products. The main by-
product source of uranium today is at Olympic Dam in South Australia, where low concentrations
of uranium (0.025 to 0.050%U) occur with copper grading about 1.8% Cu. Following primary
crushing underground, the ore is ground and treated in a copper sulphide flotation plant. About
80% of the uranium minerals remain in the tailings from the flotation cells, from which they are
recovered by acid leaching as in a normal uranium mill [4].
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BUET-INPE Uranium Mining & Milling Processing
Limiting the radiation exposure of workers in mine, mill and tailings areas so that it is as
low as possible, and in any event does not exceed the allowable dose limits set by the
authorities.
The use of radiation detection equipment in all mines and plants, often including personal
dose badges.
Imposition of strict personal hygiene standards for workers handling uranium oxide
concentrate.
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BUET-INPE Uranium Mining & Milling Processing
is blended and grinded as part of ore preparation and this preparation involves some physical
processes. Then the uranium is dissolute in the solution. The resultant is a solid-liquid mixture
and the next process involves the separation of pregnant solution from the solid. After that some
purification is done to remove impurities. Uranium is precipitated afterwards from the solution.
Subsequently, it is dried and calcinated to remove moisture and volatile contents [13].
9. Drums of yellow
10. It is then shipped
cake are loaded on
for further processing
transport trailers.
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BUET-INPE Uranium Mining & Milling Processing
A schematic diagram on a typical conventional milling facility will clarify the conversion
pathway from uranium ore to dry yellow cake:
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BUET-INPE Uranium Mining & Milling Processing
crushing the ore is reduced to a size which is suitable for feeding it to the milling circuit. Then the
ore is mixed with water to produce a Ore Slurry (70% solid and 30% water) [11] and it is prepared
for leaching. Sometimes radiometric sorting, paramagnetic sorting, optical sorting are done to
achieve pre-leach benefication and to avoid processing of non-uranium bearing gangue material
[12].
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BUET-INPE Uranium Mining & Milling Processing
3.5 Decommissioning:
Decommissioning and site rehabilitation is the work required to return a uranium mine, mill or
waste management facility to a condition which delivers a safe and sustainable environment that
requires little or no human intervention over the long term [11]. Decommissioning of a uranium
project is site specific and will depend in large measure on the design of the mining operations,
the process chosen and the geological environment in which it is situated.
Open Pit: Decommissioning open pits can take a number of forms. Most jurisdictions
require that material such as waste rock removed to gain access to the uranium ore to be
backfilled into the pit and steep side walls be given more modest slopes. In some cases
where there is sufficient rainfall, the pits are allowed to flood [11].
Underground excavation: There are a number of issues which must be addressed when
underground mines are abandoned. Complete and accurate maps of all underground
openings are required for permanent government records. Underground workings,
provided they can be properly isolated, are excellent repositories for contaminated surface
debris resulting from demolition of uranium mills and contaminated soils [11].
ISL: The major issue in decommissioning in situ leaching (ISL) operations is the
restoration of the aquifer in which the uranium ore is situated. Permits of up to three or
four years are sometimes required to restore water to an acceptable condition. It is
important to note that in some jurisdictions it is necessary to not only restore to original
condition but also improve water quality to drinking water standards [11].
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BUET-INPE Uranium Mining & Milling Processing
4.0 Conclusions:
Most popular uranium mining methods are In-Situ Leaching/ Recovery, Open pit, Underground
Mining, Heap Leaching. Initial product of uranium milling is uranium ore slurry which is milled
to final product: yellow cake. The milling process involves: grinding/crushing, extraction,
solid/liquid separation, purification, precipitation, calcination. Starting in uranium mines, ore is
mined and milled to produce uranium in the form of uranium oxide concentrate, commonly known
as U3O8. It has the same isotopic ratio as the ore, where U-235 is present to the extent of about
0.7%. Apart from traces of U-234, the rest is a heavier isotope of U-238.
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BUET-INPE Uranium Mining & Milling Processing
List of References:
1. Our world in data official website: https://ourworldindata.org/energy-production-
consumption.
2. Methods of exploitation of different types of uranium deposits by IAEA.
3. US Energy Information administration. Official website:
https://www.eia.gov/energyexplained/nuclear/the-nuclear-fuel-cycle.php.
4. Ian Crossland - Nuclear fuel cycle science and engineering (2012, Woodhead Publishing).
5. World Nuclear Association. https://world-nuclear.org/information-library/nuclear-fuel-
cycle/mining-of-uranium/uranium-mining-overview.aspx.
6. World Nuclear Association. https://www.world-nuclear.org/information-library/nuclear-
fuel-cycle/mining-of-uranium/in-situ-leach-mining-of-uranium.aspx.
7. V.I. Ferronsky, V.A. Polyakov (2012-03-06). Isotopes of the Earth's Hydrosphere. p. 399.
ISBN 9789400728561. Retrieved 2016-03-31.
8. International Atomic Energy Agency/OCED Nuclear Energy Agency, 2018, p.62.
9. C. Arnold, "Once Upon a Mine: The Legacy of Uranium on the Navajo Nation," Environ.
Health Perspect. 122, A44 (2014).
10. Trends in the Nuclear Fuel Cycle: Economic, Environmental and Social Aspects-Nuclear
Energy Agency Organization for Economic Co-Operation and Development.
11. IAEA Methods of exploitation of different types of uranium deposits, IAEA-TECDOC-
1174.
12. Lance K. Kim, Uranium Mining & Milling, Lawrence Livermore National Laboratory,
LLNL-TR-747582, 2018.
13. Uranium Extraction Technology. Vienna: International Atomic Energy Agency, 1993.
14. M. Benedict, T. H. Pigford, and Levi, Hans Wolfgang, Nuclear Chemical Engineering,
Second. McGraw-Hill, 1957.
15. Expertminds.com/Modifiers/Diluents.
16. Official website of USNRC. https://www.nrc.gov/waste/mill-tailings.html.
17. U.S Energy Information Administration (EIA).
18. Cameco Corporation Official Website.www.cameco.com/uranium_101/mining-
milling/milling/
End
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