Professional Documents
Culture Documents
2852
M. R. J. WYLLIE AND WALTER D. ROSE, JUNIOR MEMBER AIME, GULF RESEARCH AND DEVELOPMENT CO.,
INTRODUCTION tionship which is presumed to exist be- different rock textures, the relationship
The use of electrical well logs for tween resistivity index and brine satu- between formation factor and perme-
the quantitative determination of such ration in reservoir rock. In particular, ability was markedly dependent on
reservoir parameters as connate water we will endeavor to draw attention to rock texture. The relationship found
saturation, formation permeability and the fact t.hat it is possible to express by Archie between formation factor
connate water salinity has recently been these logging concepts in terms of cap- and porosity was expanded by H.
attracting the attention of a number illary pressure-saturation relationships, Guyod 8 • Archie had suggested that the
of workers'·'·'····. permeability and tortuosity, parame- formation factor, F, could be expressed
ters ·which we will consider in this in terms of the porosity, ,p, as follows:
While the theory of the determina- paper to be fundamentally indicative F =,p-m (1)
tion of connate water salinity from the
~elf potential S.P. log has received
of rock texture. The probability of where, ,p= effective porosity fraction
being able to obtain from log record- of the sand,
rather detailed treatment, relatively ings alone the data theoretically essen- and, m = an exponent greater than
little attention has been paid to the tial to permit quantitative log inter- about 1.3.
theoretical aspects involved in the pretation will be examined, and con- Guyod introduced the term cementa-
quantitative interpretation of resistivity sideration will also be given to the tion factor for the exponent, m, since
data. It is clear that if electrical well problem of formulating simple semi- it may be qualitatively shown that for-
logs can be used for the quantitative empirical relationships for use in the mation factor for any given porosity
evaluation of physical characteristics field. tends to increase as the sand becomes
of reservoir ·rock, they will provide a
more cemented. It would appear that
valuable tool to supplement cheaply in-
THEORETICAL the concept of m as an exponent rep-
formation obtained by more laborious
CONSIDERATIONS resenting the cementation in a sand is
core analysis. In certain cases it is
The concept of formation resistivity strictly only of qualitative value, since
con~eivable that the coring program
factor, or as it is now commonly called, the quantitative estimation of m by
could be considerably curtailed if the
formation factor, appears to have been means other than the determination of
electric log could be relied upon to
introduced by G. E. Archie"'''. Forma- F and ,p has not been possible. Guyod
give reasonably accurate quantitative
tion resistivity factor as defined by suggests that m can be estimated from
information.
Archie is the resistivity of a rock 100 a visual examination of a sample of
It is our object in this paper to ex- per cent brine-saturated divided by the rock, but this method appears to be
amine the theoretical basis of quantita- resistivity of the brine. This relation- both arbitrary and unreliable. It can
tive log interpretation as expressed in ship had previously been used by physi- be. said, however, that in intergranular
such well-established logging concepts cal chemists and the concept is, for ex- reservoirs of practical interest, the
as formation factor and cementation ample, implicit in an early treatment range of m is from about 1.4 to 3.0. A
factor. It is also our object to investi- by Fricke' of the conductivity of aque- possible explanation for the fact that
gate the physical aspects of the rela- ous slurries. Archie was able to estab- m is found to lie between these limits
lish the fact that although the rela- will be offered below.
1 References given at end of paper. tionship between formation factor and The determination of formation fac-
Manuscript received at the office of the Pe- porosity did not change too greatly for tor is an essential preliminary to the
troleum Branch October 6, 1949.
COPYRIGHT, 1950, BY THE
employment of the electric log for to warrant the universal applicability water saturations, depending upon the
either the qualitative or quantitative which is generally attributed to it. The type of porous medium and the nature
interpretation of reservoir rocks for relationship, in fact, appears to rest on of the non· wetting phase. The results,
oil saturation. By Archie's original def· the experimental findings of Wyckoff however, tend in most cases to an ex-
inltion, F is a ratio and is independent and Botset," as supported by the work ponent of about 2.5 at water satura-
of the resistivity of the brine used to of lakosky and Hopper," Martin, Mur· tions less than 20 per cent. No details
s~turate the formation. As shown else- ray and Gillingham," Leverett" and are available regarding the experi-
others. Some confirmation was also
where' this definition of F has implicit mental technique employed by the Rus-
provided by Morse, Terwilliger and
in it the assumption that the solid sian workers. Variable values of the
Yuster." The data obtained by all
matrix of the formation is an insulator. exponent apparently less than 2 are
these workers apply in most cases to
If the solid matrix is a conductor, F explicable if formations contain cQn-
unconsolidated sands, although a few
will not be independent of the resis- data are applicable to moderately ce- ducting solids' but values of the ex·
tivity of the saturating fluid. However, mented sandstones. It is, however, im- ponent as high as 4.3 imply either a
in ideal cases a correction may be portant to note that the saturation proc- gross experimental error or a marked
made for the presence of conductive esses used by these workers may not influence of formation texture or type
Fig. 1 is a plot of fractional porosity where 6 and P. are the interfacial ten· some of Archie's data" where a log log
versus tortuosity where a graphical sion and the displacement pressure, plot of F and K gave a slope of -1f2.
solution can be made of Equation 3 for respectively, and t, is the pore shape The implication is that the term,
the formation factor. The dashed hori- factor referred to by Carman.'" This 6/q,'/2 t. 'l2p., was constant for the reser-
zontal line refers to the porosity of the would give as another definition for m: voirs giving such data plots. Such con-
cubic packing of spheres, which is the m = (Inq,'I2K'I2t•'l2P./6) / (Inq,) stancy, however, is not to be anticipated
maximum theoretical regular packing implying that a log log plot of q, versus as unique since the above referred to
porosity which can obtain and ,which (6/P.)/(Kt.)'12 would be linear with intercept term can also be expressed
is somewhat above the maximum poros· slope equal to (1- 2m) /2 and with as (TK)~" /q" showing its implicit de-
ity which will obtain in practical in- zero intercept if m 'were constant. How- pendence on K; and indeed Archie's
stances. Minimum porosities for gran- ever, for texturally similar porous me- data more generally show a slope of
ular materials will generally exceed dia, i.e., with identical tortuosities, it about -14 on the log log plot of F
0.05, and tortuosities will range from versus K.
is seen from Equation 6 that this plot
about 2.5 to perhaps 250; meaning the
will have a slope of (-2) and intercept To conclude this discussion of for-
formation factors will generally fall
equal to T, and that for texturally dis- mation factor as described by Equation
In the case of unconsolidated porous sure data are not usually also obtained. tive that Equation 10 will be found use·
media of relatively high porosity, the The first example to be considered ful as an expression for wetting liquid
apparent constancy of m at a value of is that of the single capillary tube sat- relative permeability. Thus, it is seen
about 1.3 is probably a coincidental urated with various proportions of wet- that an experiment which includes the
consequence of the compensating small ting (electrically conducting) and non-
changes in tortuosity which occur when wetting fluids, where either the non-
the porosity' of such systems is sub- wetting fluid will be considered as dis-
jected to small changes_ persed in the wetting phase as droplets
The expression for formation factor of radius less than the capillary tube
in terms of an hydraulic tortuosity is radius, or the wetting liquid will be
regarded as flowing as an annular
also of considerable utility in the ex-
cylinder around the centrally located
amination of the resistivity index con- 1- O,Ir--~'---+--~-hf'------t-----l
flowing non-wetting fluid. In a recent T.
cept, and we now consider this prob-
paper" it was shown the right-hand
lem_
term of Equation 10 reduces to I/Sw
for such a system, which is exactly
The Estimation of Connate the resistivity index, I. Each curve of tions are to be anticipated at satura-
Water Saturation from Log Data the family plotted may be shown to tions in the region of 14 per cent, the
have a slope given by the relationship errors at any other saturations in the
The use of electric logs for the quali- (o Sw/on),= -Sw1nSw/n" and all saturation range applicable to produc-
tative location of oil or gas saturation curves may be calculated from the ing formations are also extremely se-
in reservoir rock depends fundamental- appropriate value of (a'Sw/on'), = 0 rious. For example, if the probable
lyon the derivation of three param- to have a point of inflection at a satu- ,range of n vallies in commercial oil-
eters. These parameters are the true ration of 0.136 (13.6 per cera). bearing reservoirs is assumed to be
formation resistivity, the resistivity of It is cleat from Fig. 5 that if the from 1 to 4, a resistivity index of 10
the connate water at the formation exact value of n for a particular for- may be seen from Fig. 5 to indicate
temperature and the true formation mation is unkp.own to the log inter- saturations anywhere from 10 per cent
factor. It is believed that the first two preter, the maximum error in a water to 56.5 per cent, i.e., that reservoir may
parameters can now be obtained with saturation computed by arbitrarily as- be computed to be either a potential
a high degree of accuracy in many suming a value for n will result for producer of pipe line oil or a potential
instances. The estimation of formation true water saturations of about 14 per water sand, unless a more specific
Where,
F true formation factor,
Po connate water resistivity,
Pt true formation resistivity
(corrected for conducting
solids) .
From the standpoint of quantitative
log interpretation, the above difficulties
are reinforced by the additional diffi-
culty of finding the appropriate value
for the exponent, n, in the resistivity
index-saturation relationship,
I = Sw-n (2)
2
Fig. 5 shows a plot of water satura-
3 4 5 6 7
tions, Sw, against values of the expo- n
nent, n, for various constant values of FIG. 5 - GRAPHICAL SOLUTION OF I = sw- n
ity curve above the oil-water contact. its constancy does not seem to be prob- Rose and Bruce'· have shown that
Tixier's method is phy~ically limited able except in very ideal circumstances. when Sw is unity,
in scope by the relative paucity of logs
showing valid oil-water contacts and
It would appear from f'ixier's results
that the formations to which he applied Pd _ (1K )'/2
- - Il (</>
-
t'
)'/2
his method were singularly texturally
the necessity for estimating the hydro- (Contact angle assumed to be 0)
homogeneous and, thus, perhaps
carbon density as it exists in the res- But it has been shown in the theoreti-
uniquely amenable to his treatment.
ervoir. More fundamentally however,
Since Leverett's equation indicates cal section that, F =
t'/2 It:/2</>.
the equation connecting capillary pres- the factors which will affect Tixier's Hence,
sure and permea.bility at any satura- empirical "constant", it is reasonable Pd = III (Kts </> ) 1/2 F (7)
tion appears to us to represent a sim- to examine the possibilities of being The displacement pressure, Pd, does
plification which is in most cases quite able to express these factors in terms not seem to be obtainable from the
unreal. The assumption regarding the of measurable log data and thus to de- ele~tric log, but Pc may be derived in
value of n, with the reservations we rive an expression of somewhat wider prInciple by using the same technique
have outlined above, we consider to applicability. as that employed by Tixier. The gen-
9.0
/0
studied. The universal constancy of
Il Cos II in water-wet oil field reservoirs
is only acceptable as a first approxima-
'I 8.0 !
tion, since it would seem that surface:
active components of some crudes might
1.1-
'"
:::,.
!-... 7.0
V
-e-
markedly affect the interfacial surface
tension. Wide variations in porosity
are clearly to be expected, although in
~
6·0 I
an area such as the Rocky Mountains
a relatively constant porosity may have 5.0
V
obtained. Independent values for the
capillary pressure function at various
saturations are unobtainable at present,
although the value of lim j (Sw ) has
4.0
Vo
/
0
Sw~I /
3.0
/0
been shown by Rose and Bruce'· to be
equal to (lit) '/2, where t is the Ko-
zeny rock textural constant. At any 2.0
saturation, however, j (Sw) is a func- /
tion of the rock textural character of
1.0 /
the formation and, hence, it may have
wide variations not only from reservoir
to reservoir but within any particular
/
formation. Thus, the constant employed 10 20' 30 40 50 60 70 80 90 100
by Tixier, as Tixier noted, is certainly Swi
liable to vary very widely in different FIG, 6 - RelATIONSHIP BETWEEN IRREDUCIBLE SATURATION AND THE ROCK TEXTURAL
reservoirs and even in a particular area FUNCTION (K </»-'/2F-'
9.0
Ill. o RANGELY, COLORADO
• MID - CONTINENT
Tixier's method or the generalization
of it outlined above, lies in the prac-
tical consideration that insufficient logs
IV X GULF COAST showing suitable oil-water contacts are
obtained. Another inherent objection
8.0
7.0
If/
rl
. .
is the knowledge of the hydrocarbon
density in situ which is required and
which makes the method not immedi-
I:f . · • .
tained. With these severe limitations
3.0
2.0
/,
.
... . .. .· ..........
_ _./'
..... -
x the problem becomes that of finding a
relationship between permeability, for-
mation factor and connate water satu-
ration, since only the two latter quan-
/ ...
/
• • x. x•• tities appear in principle to be calcu-
~
. .. -<'---<
~
x -,...-- ~ lable from log data. We make, in addi-
1.0 tion, the further assumption that the
~ I~
V~10
~
l..----*-
~~ minimum water saturation computed in
a reservoir is equal to the irreducible
20 30 40 50 60 70 80 100 connate water saturation, Sw,' In this
Swi we follow the basic assumption of all
FIG. 7 - EMPIRICAL RELATIONSHIP BETWEEN IRREDUCIBLE SATURATION AND THE capillary pressure core analysis.
ROCK TEXTURAL FUNCTION ¢/K '12 The sole justification for attempting
to connect permeability to irreducible
water saturation and to formation fac-
tor lies in the probability that all three
++ From the logs published in Tixier's paper' the following approximate data may be derived.
Formation factors are computed from the true resistivities of the water sands and the stated eon-
parameters are functions of rock tex-
nate water salinities using temperaturEs appropriate to the depths shown. ture. It is well-known that in rocks of
Computed similar texture, i.e., from the same res-
Log F Sw Pc psi K(lab)md dynes/em o servoir, there is frequently a definite
Layton. Oklahoma 10 0.33 6.7 27 30.2
Cisco. North Texas 16 0.315 4.7 200-700 76.5-143 relationship between irreducible satu-
Tensleep. Wyoming 7 0.35 1 450 14.9 ration and permeability. However, the
Rangely. Colorado 50 0.37 18.5 2.72 79.5
permeability for the same irreducible
The values for interfacial ten:;ion are computed by solving for 0 in Equation 16. m assumed
1.5 and n as 2 in every case. It will be seen that the values for 0 so obtained are extremely vari- saturation may differ by several orders
able and rather high. Errors in the assumed m are insufficient to reduce significantly the high of magnitude if the rock texture
computed values of O. particularly as the high values of 0 are associated with high formation changes. In order to obtain a general
factors. The fact that Sw appears to be independent of K points also to errors in n since the
computed values of 0 are directly proportion to Sw '12. expression which will give permeability
(or at least its order of magnitude) in on a moderately good straight line and given porosity. Conversely, Thornton
terms of SWI and F, it follows that F that the value for the constant C' is and Marshall'~ data" which refer to a
must appear in the desired expression about 12 per cent water. Louisiana Gulf Coast reservoir of Mio-
in such a manner as to compensate The present dearth of data suitable cene Age, tend to fall about another
these rock textural variations. for testing Equation 17 results from line passing through the origin and
the scarcity of formation factor values, correspond to maximum permeabilities
With these considerations in mind
not from lack of determinations of per- at any given porosity. The Mid-conti-
we have approached the problem in the
meability, poro'sity and irreducible sat- nent and California data fall between
following manner. Rose and Bruce" these two extremes.
have discussed the application of the urations. However, as an approxima-
tion Equation 17 can be written in the Fig. 7 in itself does not lend support
Kozeny equation for the estimation of
form, to the hope that a reasonably accurate
interstitial surface areas and have
general constant can be found to ex-
found a reasonably linear relationship SWI = C . -cp-
K'I2
+ C' (I8) press the relationship between SWi and
when surface area is plotted against
cp/K'/o. Fig. 7 shows, in fact, that for
irreducible connate water determined if, F = cp-1.5 is assumed to hold in all
any given saturation and porosity the
by the capillary pressure method:++ cases. This form of the equation is maximum possible permeability may
SUMMARY AND Applying the same assumption re- Sw~, permeability and formation factor
CONCLUSIONS garding the equality of the hydraulic of the form:
and electrical tortuosities of the wet-
In this paper we have had as our
principal object the investigation of
ting phase in partially saturated porous
media, e.g., brine-oil systems, we have
]+ C"
the inherent probabilities of deriving
derived an expression for the resistiv- where C and C' are constants.
reliable information regarding the phy-
ity index, I, in terms of saturation and Evidence from a number of oil res-
sical characteristics of reservoir rock ervoirs in the United States is given
the ratio of the wetting liquid tortu-
ftom electrical log data. We have indi- to substantiate this type of correlation.
osities at 100 per cent saturation and
cated that since electric logs are now
an almost universal aid to well comple- the saturation, Sw, considered. Thus,
tion any information of a quantitative 1= (T,/T),I2S w • ACKNOWLEDGMENTS
character which can be derived from We show that the use of this expres- We 'Y"ish to acknowledge the help of
electric logs is in the nature of a gift. sion leads to the conclusion that the Paul Fulton in obtaining certain of
It may also be pointed out that the resistivity index exponent n in the rela- the experimental data incorporated in
value of this gift would be considerably tionship I = Sw-n is dependent on the this paper, and our thanks are due t<
enhanced if it led also to a curtailing texture of the porous medium and the Paul D. Foote, executive vice-president.
(:-~) 1
as the tortuosity affecting electrical ting phase.
conductivity through the fluid in the
K = Constant [. , L Actual length of core.
same medium, an expression for for-
mation factor, F, of the form, P, F Sw L. Mean effective length of pores
F = T'I2 / </>, where </> is the porosity of in core.
21.2 a2
the medium. From this expression, we where the constant is equal to m Cementation factor exponent.
t,
have shown that the common relation- n Saturation or resistivity index
ship F = </>-in is of no fundamental sig- for K in millidarcies, capillary pres-
sure, P" in psi and interfacial tension, exponent.
nificance and have indicated why the
practical limits of m are likely to be a, in dynes/cm. The value for ts lies N Number of pores in any cross
between 2.0 and 2.5 and may be taken section A,.
from 1.3 to 3.0. We have also shown
that the existence of reservoirs where as 2.25.
Pc Capillary pressure.
a constant _value of m will obtain, ir- In order to obtain ari estimate of per- Displacement pressure.
respective of porosity, is not to be an- meability when P, is unobtainable (i.e.,
ticipated. Experimental - evidence for in the absence of an oil-water contact Radius of hypothetical cylindri-
the formation factor relationship de- in the reservoir) we suggest a correla- cal core of area A,.
rived is also presented. tion between irreducible saturation, r Pore radius.
Fractional wetting phase satu- 8. "Fundamental Data for the Inter- ton. Trans. AIME, 186, 328,
ration. pretation of Electric Logs." H. (1949) .
Guyod. Oil Weekly, 115, 38, Octo· 22. "Theoretical Generalizations Lead-
Swl Fractional "irreducible" wet-
ber 30 (1944). ing to the· Evaluation of Relative
ting phase saturation.
9. "The Presence of Conductive Solids Permeability." Walter Rose. Trans.
t Kozeny rock textural constant. in Reservoir Rocks. as a Factor in AIME, 186, 111, (1949).
ts Pore shape fllctor. Electric Log Interpretation." H. W.
23. "Factors Which Allect True For-
Patnode and M. R. J. Wyllie.
T Tortuosity = (L./L) '. AIME T.P. 2797, Jour. Pet. Tech.,
mation Resistivity." S. J. Pirson.
T. Effective tortuosity at any satu- Oil and Gas Jour., 46, 76, Novem-
2, (2), 47, (1950).
ration of the wetting phase. ber 1 (1947).
10. "True Resistivity Determinations
il Interfacial tension. from the Electric Log - Its' Appli. 24. "The Size of Pores in Collodion
cation to Log Analysis." H. G. Membranes." P. I. Hitchcock. J.
</> Fractional porosity. Gen. Physiol., 9, 755, (1926).
Doll, L. C. Legrande and E. F.
p, Fluid viscosity. Stratton. Presented to Pacific Coast 25. Micromeritics. Pitman Publishing
Pc Interstitial water resistivity. District, Division of Production, Company, New York, 2nd Edition