6th SEMESTER

DISCIPLINE SPECIFIC ELECTIVE (DSE)

PHY616D: PHYSICS: MODERN PHYSICS – II
CREDITS: THEORY: 4, PRACTICAL: 2
PHY616D: PHYSICS: MODERN PHYSICS – II (PRACTICAL) CREDITS: 2
 6TH SEMESTER
DISCIPLINE SPECIFIC ELECTIVES (DSEs)
OPTION -I
MM616DA: MATHEMATICS: LINEAR ALGEBRA
CREDITS: 6
Unit-I
Types and properties of matrices, Inverse of a square matrix, matrix polynomials, characteristic
equation, Cayley-Hamilton Theorem, Eigen values and eigenvectors of matrices and their
determination, rank of a matrix, invariance of rank matrix under elementary transformations.
Reduction of matrix t o normal f o r m , elementary matrices.

Unit-II
Linear dependence and linear independence of row(column) vectors, conditions for columns of a
matrix to be linearly dependent, matrix A has rank r iff it has r linearly independent columns,
analogous results for rows. Linear homogeneous and non• homogeneous equations, Linear product of
two vectors, orthogonal a n d unitary matrices, determination of orthogonal matrices.

Unit-Ill
Vector spaces, examples, subspaces, algebra of subspaces, quotient s p a c e s , linear dependence,
independence and linear span of vectors, basis and dimensions of vector spaces.

Unit-IV
Linear transformations, null space, range, rank and nullity of a linear transformation, matrix
representation of a linear transformation, algebra of linear transformations, dual space and dual
basis, homomorphism and isomorphism, isomorphism theorems.

Text Books Recommended:

1. A. Aziz, N. A. Rather and B. A. Zargar, A Text Book of Matrices, KBD.
2. Stephen H. Friedberg, Arnold J. lnsel, Lawrence E. Spence, Linear Algebra, PHI.
3. S. Lang, I n t r o d u c t i o n to Linear Algebra, Springer.
4. Shanti Narayan, A Text Book of Matrices.
5. Gilbert Strang, Linear Algebra and its Applications, Thomson (2007)
 6TH SEMESTER
DISCIPLINE SPECIFIC ELECTIVES (DSEs)
OPTION -II
MM616DB: MATHEMATICS: THEORY OF PROBABILITY
CREDITS: 6
UNIT-I

The probability set functions, its properties, probability density function, the distribution
function and its properties, mathematical expectations, some special mathematical expectations,
inequalities o f Markov, Chebyshev and Jensen.

Unit -II

Conditional probability, independent events, Baye's theorem, distribution of two and more random
variables, marginal and conditional distributions, conditional means and variances, correlation
coefficient, stochastic independence and its various criteria.

Unit-Ill

Some Special Distributions, Bernoulli, Binomial, trinomial, multinomial, negative binomial, Poisson,
gamma, chi-square, beta, Cauchy, exponential, geometric, normal and bivariate normal distributions.

Unit-IV

Distribution of functions of random variables, distribution function method, change of variables method,
moment generating function method, t and F distributions, distribution of order statistics, distribution of
• Limiting distributions, different modes of convergence, central limit theorem.

Recommended Books:

1. Hogg and Craig, An Introduction to Mathematical Statistics.

2. Mood and Grayball; An Introduction to Mathematical Statistics. References

3. C. R. Rao, Linear Statistical Inference and its Applications.

4. V. K. Rohatgi, An Introduction to Probability and Statistics.

 6TH SEMESTER
DISCIPLINE SPECIFIC ELECTIVES (DSES)
OPTION-I
CH616DA: CHEMISTRY: INSTRUMENTAL METHODS OF CHEMICAL ANALYSIS
CREDITS: THEORY-4, PRACTICAL-2
Unit I Introduction to spectroscopic methods of analysis (12 Contact hours)

(i) Properties of Electromagnetic radiations:

The Electromagnetic spectrum. General nature of electromagnetic waves; wave parameters, radiant
power (Intensity), superposition of waves, diffraction, transmission, dispersion, refraction, reflection,
scattering and polarization of radiation. Absorption, emission, fluorescence and phosphorescence.
(ii) Instruments for optical spectroscopy:
Components of optical instruments: radiation sources; continuous sources, line sources, lasers.
Wavelength selectors, sample holders. Radiation detectors; photon detectors; vacuum phototubes,
photomultiplier tubes, photoconductivity detectors, silicon diode detectors. Signal processors and read
outs.
Unit II Molecular Spectroscopy 15L
(i) UV-Visible -Near IR spectroscopy:
UV-Visible-Near IR regions of EMS. Transmittance, absorbance, Beer-Lambert. law, limitations
to the applicability of the Beer's law, molecular electronic excitations ( π-π:*, n-π*, d-d
transitions, charge transfer transitions, intra-ligand transitions). Fluorescence, phosphorescence.
Instrumentation: Light sources, wavelength dispersion (gratings, prisms, interference filters,
lasers).Sample holders, detection of signals (photocells, photo multipliers, diode arrays),Sensitivity
and S/N ratio. Single and double beam instruments.
(ii) Infrared spectroscopy:
Theoret i cal principles, vibrational modes and IR absorption process, selection rules.
Vibrational IR region (4000-400cm-1); group frequency region, the fingerprint region, metal•
ligand absorption region, IR peak positions of some common functional groups of organic
molecules- IR correlation tables.
Instrumentation: Light sour ces , infrared detectors, sample preparation techniques; liquids,
solids. Dispersive I R spectrometer. Fourier transfer spectrometer (FTIR), construction and
advantages.
Unit III Atomic spectroscopy I5L
Sample atomization; continuous atomizers, discrete atomizers. Sources of atomic spectra; atomic
absorption spectra, atomic emission spectra, atomic fluorescence spectra.. Flame atomization (fuel
and oxidants), Electrothermal atomization.
Atomic absorption spectroscopy; radiation s o u r c e s -hollow cathode l a m p s , i nst r ument s -
single beam spectrophotometer, double beam spectrophotometer. Flame emission spectroscopy;
instrumentation, spectrophotometer, photometer.
Unit IV Chromatographic techniques l5L
(i) Introduction to chromatography:
Basic Concept of chromatography; mobile phase and stationary phase. Classification of
chromatographic methods, chromatogram, partition coefficients, retention times, retention volumes,
the capacity factor, the selectivity factor theoretical plates and efficiency, Van Deemter
equation, column resolution.
(ii) Gas chromatography:
Principle of Gas C h r o m a t o g r a p h y . Instrumentation· carrier gas, sample injection
systems, column configuration and column ovens. Detectors; flame ionization detectors,
thermal conduction detectors, electron capture detectors etc.Columns; packed columns, solid
support materir.ls, particle size; open tubular columns. The stationary phase materials.
(iii) Liquid chromatography:
HPLC, column efficiency in liquid chromatography. Instruments for liquid chromatography; mobile
gas reservoirs, solvent treatment system, pumping s y s t e m s , liquid chromatographic columns,
detectors.
Books Recommended
1. Principles of Instrumental Analysis - 6th Edition by Douglas A . S ko o g , F. James Holler,
and S t a n l e y Crouch (ISBN 0-495-01201-7)
2. 2 Instrumental Methods of Analysis, 7th ed, Wil lard, Merritt, Dean, Settle.
3. P.W. Atkins: Physical Chemistry.
4. G.W. Castellan: Physical Chemistry.
5. C.N.Banwell: Fundamentals of Molecular Spectroscopy.
6. Brian Smith: Infrared Spectral Interpretations: Systematic A p p r o a c h .
7. W.J. Moore: Physical Chemistry.
PRACTICALS

Note: The suggested experiments cannot be C onducted in our colleges because

of lack of instrumental facilities. However, I may suggest the following few
experiments.

1. Determination of concentration of an acidic solution by pH metric titrations.

2. Determination of the isoelectric pH of a protein. .
3. Potentiometric titration of a Chloride-Iodide Mixture.
4. The standardization of an Fe (II) solution with a standard dichromate solution over
Pt and Calomel assembly.
5. Determination of concentration of Ce (IV) Sulfate solution with a standard Fe (II)
Solution over Pt and calomel assembly.
6. Determination of λmax of Potassium permanganate (KMn04)solution.
7. Determination of Fe (II) in a sample of well water with thiocyanate as complexation
agent, spectrophotometrically.
8. Determination of Aluminum in a given sample solution, spectrophotometrically.
9. Determination of concentration of sodium in an aquous solution by using a flame
photometer.
10. Separation of permanganate and dichromate ions from a binary mixture on an alumina
column.

Books Recommended:

1. Principles of instrumental Analysis - 6th Edition b Douglas A. Skoog, F. James Holler, and
Stanley Crouch (ISBN 0-495-01201-7).
2. Instrumental Methods of Analysis, 7th Ed, Willard, Merritt, Dean,
Settle.
 6TH SEMESTER
DISCIPLINE SPECIFIC ELECTIVES (DSES)
OPTION-II
CH616DB: CHEMISTRY: MATERIAL CHEMISTRY
CREDITS: THEORY-4, PRACTICAL-2

Unit-I Elementary Lattice Dynamics

Lattice Vibrations and Phonons: Linear Monatomic and Diatomic Chains. Acoustical and
Optical Phonons. Qualitative Description of the Phonon Spectrum in Solids. Dulong and Petit's Law,
Einstein and Debye theories of specific heat of solids. T3 law (15 Contact hours)

Unit-II Magnetic Properties of Matter

Dia-, Para-,Ferri- and Ferromagnetic Materials. Classical Langevin Theory of d i a - - a n d
Paramagnetic Domains. Quantum Mechanical Treatment of Paramagnetism.Curie’s law, Weiss’s.
Theory of Temperature dependence of magnetism.
(15 Contact hours)

Unit-III Nonmaterial
Nanormaterials-General introduction, special properties of Nanormaterials with special
reference to Nanotubes, Fullurenes, Nanometal Nanoparticles, carbon Nanotubes.Preparation of
gold and silver metallic Nanoparticles. Surfactant and Polymers based self-assemb1ies like
Micelles and gels etc. and brief account of their applications.
(15 Contact hours)
Unit-IV superconducting materials
History and introduction to Superconductivity, Characteristics of Superconductors Heat capacity
and Thermal Conductivity, Effect of Temperature on Superconductivity, BCS theory
of Superconductivity, Applications.

Books Recommended:

(15 Contact hours)

1. Fahlman B.D materials chemistry, springer, 2004.
2. Shriver & Atkins. Inorganic Chemistry.
3. Poole C.P & Owens, F.J Introduction to Nanotechnology John Wiley & Sons, 2003.
4. Rodger G.E Inorganic and solid state chemistry, learning India Edition, 2002.
5. Introduction of solid state physics, Charles kittel, 8th Ed, .2004, wiley India Pvt.Ltd.
6. Elements of solid state physics, J.P Srivastava, 2nd Ed., 2006, prentice-hall of India.
7. Introduction to solids, leonid V.Azaroof, 2004, Tata Mc-Graw Hill.
8. Solid state chemistry by west.

PRACTICALS

Note: Attempt any five exercises

1. Synthesis of silver and gold metal nanoparticles.

2. Preparation of nay two polymers,
3. Determination of molecular weight of polymer by Viscometry.
4. Measurement of susceptibility of paramagnetic solution (Quinck’s Tube method).
5. To measure the Magnetic Susceptibility of solids.
6. Determination of cmc of a detergent.

Books Recommended:

1. Shriver & Atkins inorganic chemistry.

2. Rodger G.E Inorganic and solid state chemistry, learning India Edition, 2002.
3. Introduction of solid state physics, Charles kittel, 8th Ed, .2004, wiley India Pvt.Ltd
4. Elements of solid state physics, J.P Srivastava, 2nd Ed., 2006, prentice-hall of India.
 6th SEMESTER
SKILL ENHANCEMENT COURSE (SEC)

PH617S: ELECTRICAL CIRCUITS AND NETWORK SKILLS

(Credits: Theory: 02, Practical: 02)

THEORY (2 CREDITS)

UNIT-I

Basic Electricity Principles: Voltage. Current, Resistance and Power. Ohm‘s law. Series. Parallel
and series-parallel combinations. AC Electricity and DC Electricity. Familiarization with
multimeter, voltmeter and ammeter. Understanding Electrical Circuits: Main electric circuit
elements and their combination. Rules to analyze DC sourced electrical circuits. Current and
voltage drop across the DC circuit elements.

UNIT-II

Generators and Transformers: DC Power sources. AC/DC generators. Inductance. /capacitance,

and impedance. Operation of transformers. Electric Motors: Single phase, three—phase & DC
motors. Basic design. Interfacing DC or AC sources to control heaters & motors. Speed & power
of ac motors. Solid-State Devices: Resistors, inductors capacitors. Diode and rectifiers.
Components in Series or in shunt. Response of inductors and capacitors with DC or AC sources.
Electrical Protection: Relays. Fuses and disconnect switches. Circuit breakers.

PRACTICAL (2 CREDITS):

1) Fabrication of Half Wave rectifier.

2) Fabrication of Full wave rectifier.
3) Working of Capacitors and Inductors for Voltage regulation.
4) Study Zener Diode as Voltage regulator.
5) Demonstration of Electrical Dynamo.
6) Demonstration and working of Step-up and Step-down transformers.
7) Demonstration and working of Invertors and UPS setup.
8) Demonstration, Working and Management of Chargeable 6 Volt/12 Volt electrical
batteries.
9) Demonstration, working & management of Household Appliances like Electric Iron, Oven,
Refrigerators etc.
10) Study of Electrical Grounding and Electrical Earthing circuits.
11) Study of Power Distribution Networks.
12) Demonstration of Electrical cabling for house hold requirements.

REFERENCE BOOKS:
(1) A text book in Electrical Technology : B. L.Theraja - S Chand & Co ,
(2) A textbook of Electrical Technology: A K Theraja
(3) Performance and design of'AC machines — MG Say ELBS Edn
 BA/BSc/BHSc/B.COM (GENERAL) 6th SEMESTER
ENGLISH
(For all General streams)
(FOR BATCHES ADMITTED IN 2019 & ONWARDS)
ENG619: ENGLISH - IV

Credits: 2

Unit I: Prose

I Have a Dream: Martin Luther King

How to Judge Globalism: Amartaya Sen

The Dog that Bit People: James Thurber

Unit II: Letter Writing

Group Discussion, Interview, Presentation, Telephonic Conversation

Textbook recommended: English-3, Cambridge University Press.

--------------