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PATHSHALA JEE Dropper

DPP-03
Solutions
1. Which of the following is not correct for 5. All form ideal solution except
ideal solution (A) C2H5Br and C2H5I
(A) Raoult's law is obeyed for entire (B) C6H5Cl and C6H5Br
concentration range and temperatures (C) C6H6 and C6H5CH3
(B) Smix = 0 (D) C2H5I and C2H5OH
(C) Vmix = 0
(D) Hmix = 0 6. Total vapour pressure of mixture of 1 mol A
( PA = 150 torr) and 2 mol B ( PB = 240 torr)
2. Azeotropic mixture of water and HCl boils is 200 mm. In this case
at 381.5 K. By distilling the mixture it is (A) There is positive deviation from
possible to obtain Raoult's law
(A) Pure HCl only (B) There is negative deviation from
(B) Pure water only Raoult's law
(C) Neither HCl nor water (C) There is no deviation from Raoult's law
(D) Both water and HCl in pure state (D) Molecular masses of A and B are also
required for predicting deviation
3. An azeotropic solution of two liquids has
boiling point lower than either when it 7. Which of the following will form an ideal
solution?
(A) shows a negative deviation from
Raoult's law (A) C2H5OH and water
(B) shows a positive deviation from (B) HNO3 and water
Raoult's law (C) CHCl3 and CH3COCH3
(C) shows no deviation from Raoult's law (D) C6H6 and C6H5CH3
(D) is saturated
8. Which of the following shows positive
4. 100 ml of liquid A and 25 ml of liquid B is deviation from Raoult's law?
mixed to give a solution which does not (A) C6H6 and C6H5CH3
obey Raoult's law. The volume of the (B) C6H6 and CCl4
solution (C) CHCl3 and C2H5OH
(A) will be 125 ml (D) CHCl3 and CH3COCH3
(B) can be > or < than 125 ml
(C) can be greater than, equal to or less 9. Which of the following shows negative
than 125 ml deviation from Raoult's law?
(D) will be less than 125 ml (A) CHCl3 and acetone
(B) CHCl3 and C2H5OH
(C) C6H5CH3 and C6H6
(D) C6H6 and CCl4
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10. Which of the following solution pairs can be 12. The diagram given below represents boiling
separated by fractional distillation ? point composition diagram of solution of
(A) Water HNO3 component A and B, what is true among the
(B) Water-HCl following?
(C) Benzene-toluene
(D) C2H5OH-water

11. The diagram given below is a vapour

pressure composition diagram for a binary
solution of A and B in the solution, A – B
interactions are-
(A) The solution shows negative deviation
(B) A-B-interactions are stronger than A-A
and B-B
(C) The solution is ideal solution
(D) The solution shows positive deviation.
(A) Similar to A – A and B – B interactions
(B) Greater than A – A and B – B
interactions
(C) Smaller than A – A and B – B
interactions
(D) Unpredictable
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ANSWER KEY
1. (B)
2. (C)
3. (B)
4. (B)
5. (D)
6. (B)
7. (D)
8. (C)
9. (A)
10. (C)
11. (C)
12. (D)